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EP0155021B1 - Capsule de bouchage en polypropylène pourvue d'un joint et d'une bande de garantie - Google Patents

Capsule de bouchage en polypropylène pourvue d'un joint et d'une bande de garantie Download PDF

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Publication number
EP0155021B1
EP0155021B1 EP85200149A EP85200149A EP0155021B1 EP 0155021 B1 EP0155021 B1 EP 0155021B1 EP 85200149 A EP85200149 A EP 85200149A EP 85200149 A EP85200149 A EP 85200149A EP 0155021 B1 EP0155021 B1 EP 0155021B1
Authority
EP
European Patent Office
Prior art keywords
closure cap
gasket
plastisol
container
sealing ring
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
EP85200149A
Other languages
German (de)
English (en)
Other versions
EP0155021A1 (fr
EP0155021B2 (fr
Inventor
Wiebren Durk Halbe Kornelis
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kornelis' Kunsthars Producten Industrie BV
Kornelis Kunsthars Producten Industrie BV
Original Assignee
Kornelis' Kunsthars Producten Industrie BV
Kornelis Kunsthars Producten Industrie BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=19843469&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP0155021(B1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Kornelis' Kunsthars Producten Industrie BV, Kornelis Kunsthars Producten Industrie BV filed Critical Kornelis' Kunsthars Producten Industrie BV
Priority to AT85200149T priority Critical patent/ATE34148T1/de
Publication of EP0155021A1 publication Critical patent/EP0155021A1/fr
Publication of EP0155021B1 publication Critical patent/EP0155021B1/fr
Application granted granted Critical
Publication of EP0155021B2 publication Critical patent/EP0155021B2/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D53/00Sealing or packing elements; Sealings formed by liquid or plastics material
    • B65D53/06Sealings formed by liquid or plastic material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D41/00Caps, e.g. crown caps or crown seals, i.e. members having parts arranged for engagement with the external periphery of a neck or wall defining a pouring opening or discharge aperture; Protective cap-like covers for closure members, e.g. decorative covers of metal foil or paper
    • B65D41/02Caps or cap-like covers without lines of weakness, tearing strips, tags, or like opening or removal devices
    • B65D41/04Threaded or like caps or cap-like covers secured by rotation
    • B65D41/0435Threaded or like caps or cap-like covers secured by rotation with separate sealing elements
    • B65D41/0442Collars or rings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D41/00Caps, e.g. crown caps or crown seals, i.e. members having parts arranged for engagement with the external periphery of a neck or wall defining a pouring opening or discharge aperture; Protective cap-like covers for closure members, e.g. decorative covers of metal foil or paper
    • B65D41/32Caps or cap-like covers with lines of weakness, tearing-strips, tags, or like opening or removal devices, e.g. to facilitate formation of pouring openings
    • B65D41/34Threaded or like caps or cap-like covers provided with tamper elements formed in, or attached to, the closure skirt
    • B65D41/3461Threaded or like caps or cap-like covers provided with tamper elements formed in, or attached to, the closure skirt the tamper element being retracted by heat or by heat and pressure
    • B65D41/3466Threaded or like caps or cap-like covers provided with tamper elements formed in, or attached to, the closure skirt the tamper element being retracted by heat or by heat and pressure and being integrally connected to the closure by means of bridges
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D53/00Sealing or packing elements; Sealings formed by liquid or plastics material
    • B65D53/02Collars or rings

Definitions

  • the invention relates to a closure cap for a container made from an olefin polymer comprising an endwall, a circumferential side wall and a sealing ring with which the container can be sealably closed in conjunction with a locking collar disposed around the neck of the container, which sealing ring is integrally connected with the side wall of the closure cap via frangible bridges capable of being broken on the first opening of the container.
  • Such a closure cap is known from EP-A-34997.
  • the sealing ring When applied for closing a container the sealing ring when in undamaged condition guarantees that the container has not been opened yet. As such the sealing ring is valuable as an anti-theft means.
  • This prior closure cap including the sealing ring is in its entirety made by injection molding. The cap is not provided with a gasket.
  • a screw closure comprising a cap made of, for example, an olefin polymer such as polypropylene.
  • the closure cap is provided internally with a flowed-in gasket which is also made of a plastics material which, however, is softer than the plastics material the cap is made of.
  • the gasket may be shaped, for example, by spinning a plastisol, i.e.
  • a dispersion of a resin for example a vinyl resin
  • a resin for example a vinyl resin
  • the gasket receiving recess being annularly shaped and bordered by an outer rib and a inner rib both shaped as an outer undercut and an inner undercut, respectively, on the inner side of the cap's.
  • the ribs are shaped as an undercut for the purpose of both to limit radially inward migration of the plastisol during formation of the gasket and to prevent detachment of the gasket.
  • this prior closure cap is not provided with a sealing ring of the type being integrally connected with the side wall of the closure cap through frangible bridges which are capable of being broken on the first opening of the container.
  • closure caps comprising a gasket, made of a plastisol material
  • an ideal manufacturing process is to add the plastisol material such as a vinyl resin plastisol to the closure cap and subsequently to let the plastisol flow in the closure cap until a solid gasket has been formed in situ as is normal with closure caps made of a metal.
  • a closure cap made of an olefin polymer said process is not applicable because of the difficulty that the maximum melt temperature of the olefin polymer is close to the minimum melt temperature of a plastisol material.
  • a closure cap often made by injection moulding from an olefin polymer, in particular a high-melting polypropylene having a melting point of approximately 165°C, after having been provided with a vinyl chloride resin plastisol, is preheated to a temperature which must be 5-35°C below the melting point of the employed olefin polymer, e.g., polypropylene, preferably 5-15°C, i.e. it must be preheated to a temperature of at least 130°C, preferably 145-160°C, followed by exposure at this temperature in an appropriate oven to microwave energy having a frequency which is not critical from a technical point of view indeed, but is effectively 300-300,000 MHz. Exposure to the microwave energy takes place at the moment when the plastisol shaped into a gasket configuration is completely liquid, i.e. completely molten, which means that the resin has been completely solvated by the plasticizer.
  • an olefin polymer in particular a high-melting poly
  • Preheating can be appropriately carried out in a hot air oven.
  • a temperature of the closure cap of more than 35°C below the melting temperature thereof is probably not suitable for the conventional plastisols. If there is used a plastisol having a lower melting point, then also a lower temperature of the closure cap can be maintained in the preheating step. However, if there is started from a closure cap made from an olefin polymer melting at a lower temperature, then, conversely, the temperature range to be maintained for the closure cap in the preheating step must preferably be only 5-15°C, in particular 5-10°C below the melting point of the olefin polymer. Therefore, if the closure cap is made from, e.g., polyethylene having a high density, then, accordingly, the temperature range of the closure cap in the preheating step is preferably 120-125°C.
  • this closure cap is brought into a hot air oven having an air temperature which is 30°C, preferably 20°C, below the melting point of the olefin polymer material from which the closure cap has been made.
  • the preheating step is carried out, in practice, at an air temperature of 135-160°C for 1-10 min., e.g., an air temperature of 155°C for approximately 3 minutes, followed by the procedure in a microwave oven in which the ambient temperature is likewise high enough to prevent the preheated closure cap from sustaining heavy losses of heat, and which is, e.g., at least 140°C.
  • the duration of the microwave procedure depends on the energy supplied and is not less than approximately 1 min.
  • the step of shaping the plastisol in the closure cap until a gasket configuration has been obtained can be performed in the conventional manner, preferably by injecting the plastisol in liquid or semi-liquid condition into the closure cap which is advantageously arranged upside down, i.e. the end wall is positioned at the bottom side, and distributing same therein by subjecting the closure cap to a rapid rotation.
  • a closure cap the end wall of which is internally provided with an inner edge, the plastisol being injected into the annular space between the inner edge and the side wall of the closure cap.
  • the known process is suitable for a variety of types of closure caps and containers, in particular, however, for closure caps of bottles of threaded construction or of the snap-on type, which caps can be provided with not specified anti-theft means, said caps, however, normally having a limited inner diameter of approximately 25-32 mm.
  • the type comprising a sealing ring produced in one piece with the closure cap and connected with the side wall of the closure cap via a number of narrow frangible bridges to be broken on the first opening of the container cannot be used within the framework of the known process. Because of the high temperature of the closure cap to be maintained in the preheating step and subsequently upon exposure to the microwave energy of only 5-35°C below the melting point of the olefin polymer material used for making the closure cap, the narrow frangible bridges and the sealing ring, respectively, will be softened and deformed, which results in that the whole construction becomes useless.
  • the object of the invention is to provide a closure cap made from an olefin polymer and of the type specified in the opening paragraph and further provided with a gasket of a plastisol material, which is suitable for use on a container having a wide mouth the diameter of which may be up to 90 mm and more.
  • the invention is characterized in that the end wall (2) is internally provided with an annular space bounded by two undercuts (3, 4), said annular space is provided with a gasket (5) made from a plastisol material and said gasket (5) is sealing on the edge of the container neck (1), said end wall (2) having a wall thickness decreased by 20-50% at the gasket (5) while the closure cap (10) is obtained starting from an integral combination of the closure cap (10) with the sealing ring (13), adding, as is known per se, an amount of the plastisol material to the annular space and, to form the gasket (5), carrying out the melting operation by heating the closure cap (10) after addition of the plastisol to a temperature of 50-110°C and by exposing the resulting plastisol shaped into the gasket configuration subsequently, as is known per se, to microwave energy until the plastisol has been completely molten.
  • the closure cap according to the invention may be made of a standard grade polypropylene; it is therefore not necessary to use a high-melting polypropylene material.
  • a normal type of plastisol e.g., that consisting of a microsuspension of a vinyl chloride copolymer resin with 5% vinyl acetate and further comprising conventional constituents, e.g., one or more stabilizers, plasticizers, viscosity-reducing and/or torsion-reducing agents.
  • the starting point of a closure cap according to the invention is a cap provided with a sealing ring which is integrally connected with the side wall of the cap via the frangible bridges capable of being broken on the first opening of the container to be closed with the cap, the end wall of which is internally provided with an annular space bounded by two undercuts the outer one of which is substantially bounded by the inner periphery of the side wall of the closure cap, and into which annular space a dosed amount of plastisol is injected in the conventional manner.
  • the closure cap according to the invention to start from is such that its end wall is thinner by 20-50% at the position where the gasket is to be formed, such as at the position of the annular space bounded by the undercuts mentioned before.
  • the plastisol disposed in situ in the closure cap is melted by preheating the combination of closure cap and plastisol to 50-110°C and then exposing the resulting gasket configuration to microwave energy which may have a frequency of 10-200 MHz.
  • the melting operation is carried out by heating the closure cap after addition of the plastisol to 100°C within 15-30 sec. and completely melting the plastisol shaped into the gasket configuration by 3-15 sec. exposure to microwave energy having a frequency of 27.10-27.15 MHz. This frequency is permitted for industrial uses in the whole world.
  • the closure cap according to the invention is of a type comprising a homogeneous gasket, and which is further provided with an undamaged, undeformed sealing ring, and which may have such an inner diameter that it can be applied to a container having a wide mouth.
  • a closure cap can be obtained having an inner diameter which may be up to 90 mm or more, advantageously up to 100 mm.
  • the invention is particularly suitable for, although not limited to, the preparation of a closure cap with an integrally connected sealing ring the-inner side wall of which is threaded so that this container can be opened or closed by rotation of the closure cap, in conjunction with corresponding provisions made at the neck of the container.
  • the closure cap of the invention is provided with an annular space bounded by two undercuts within which the gasket is contained, the inner undercut of which is tapered in cross-section and resilient and has such a width that upon closure of the container with the closure cap the undercut partly rests on the upper surface of the container edge.
  • the closure cap according to the invention is the first to incorporate a combination of three properties, namely that (a) the container closed with the closure cap after filling can be closed in compression-proof and vacuum-tight condition substantially without any restriction; (b) the container can be closed again after opening so that it is completely shut off from the atmosphere, and (c) the closure of the container after the first filling is irreversibly sealable.
  • the closure cap according to the invention can be made available with an inner diameter which may be up to 100 mm so that for the first time foodstuffs which, in practice, are packed mainly in containers having a wide mouth, e.g., a neck diameter of 90 mm, whether or not under a partial vacuum, can be offered to consumers in sealed condition with a guarantee of freshness.
  • This ensures that the date indicating until when the product will keep, as it occurs on containers for foodstuffs, is a practically reliable date indeed. In the case of a closure without a sealing capable of being broken irreversibly such a date is actually a fiction.
  • Fig. 1 the wall of the neck of a container made of glass is indicated by 1, and 2 shows the closure cap of polypropylene.
  • On the inside the closure cap is provided with an annular space formed by the two circumferential undercuts 3 and 4, which annular space comprises the gasket 5.
  • the inner undercut 3 is crescent-shaped and is resilient due to the outwardly decreasing thickness of the material.
  • the crescent-shaped construction permits the inner undercut to rest on a part of the edge of the neck opening of the container. As a result thereof a part of the higher unscrewing torsion of the gasket is absorbed and reduced by the undercut.
  • the crescent-shaped undercut 3 ensures that in case of pasteurization of the contents of the container the expanded air generated in that process flows out between the undercut 3, which is thereby resiliently deflicted somewhat, and the edge of the neck whereby the deflected undercut simultaneously causes an additional clamping force to be exerted on the gasket and the gasket is retained in position.
  • Figs. 2-5 show the closure cap of polypropylene at 10, comprising side wall 11 and sealing ring 13 which is connected with side wall 11 via a frangible bridge 12.
  • the neck portion of the container is shown at 14, which neck portion 14 is provided with locking collar 17.
  • a closure cap according to the invention may be sealed after closed a container with it. As shown in Fig. 2 in the state before sealing. The side wall 11 with frangible bridges 12 and sealing ring 13 is clear of the container.
  • Fig. 4 shows the situation in which the frangible bridge 12 with the sealing 13, which where previously exposed to the action of hot air having a temperature of 400°C for 2 sec., has been grasped by the clamp 15 moving towards the container.
  • the frangible bridge 12 is then overstretched over and under the locking collar 17 and flattened, the sealing ring 13 also being flattened simultaneously between the clamp 15 and the neck portion 14 of the container.
  • Fig. 5 shows, in comparison with Fig. 3, the deformation experienced by the frangible bridge 12 and the sealing ring 13, which has resulted in that the sealing ring has a diameter smaller than the largest diameter of the locking collar 17.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Closures For Containers (AREA)
  • Glass Compositions (AREA)
  • Sealing Battery Cases Or Jackets (AREA)

Claims (3)

1. Capsule de bouchage (10) pour un récipient, réalisée en un polymère d'oléfine, comprenant une paroi d'extrémité (2), une paroi latérale périphérique (11) et une bande de garantie (13), avec laquelle le récipient peut être bouché de façon hermétique conjointement avec un collet de verrouillage (17) disposé autour du col (1) du récipient, ladite bande de garantie (13) étant reliée à la paroi latérale (11) de la capsule de bouchage (10) en étant d'un seul tenant avec elle, par l'intermédiaire de ponts cassables 12), susceptibles de se rompre à la première ouverture du récipient, caractérisée par le fait que la paroi d'extrémité (2) est dotée intérieurement d'un espace annulaire délimité par deux parties en contre-dépouille (3, 4), ledit espace annulaire est garni d'un joint (5), réalisé en une matière de plastisol, et ledit joint (5) fait etancheite sur la bordure du col (1) du récipient, ladite paroi d'extrémité (2) présentant une épaisseur de paroi diminuée de 20-50% au niveau du joint (5), alors que l'on fabrique la capsule de bouchage (10) en partant d'une combinaison d'un seul tenant de la capsule de bouchage (10) avec la bande de garantie (13), en ajoutant, comme cela est connu en soi, une quantité de la matière de plastisol dans l'espace annulaire, et, pour former le joint (5), en effectuant l'opération de fusion par chauffage de la capsule de bouchage (10), après addition du plastisol, à une température de 50-100°C et par exposition du plastisol résultant façonné suivant la configuration de joint ultérieurement, comme cela est connu en soi, à une énergie hyperfréquence, jusqu'à ce que le plastisol ait été complètement fondu.
2. Capsule de bouchage selon la revendication 1, caractérisée par le fait que la partie en contre-dépouille interne (3) est effilée en coupe transversale et résiliente, et qu'elle présente un diamètre le plus large pour avoir l'étanchéité du joint (5) sur la bordure du col (1) du récipient, partiellement en combinaison avec ladite partie en contre-dépouille (3).
3. Capsule de bouchage selon les revendications 1-2, caractérisée par le fait que le diamètre interne de la capsule de bouchage (10) va jusqu'à 100 mm.
EP85200149A 1984-02-09 1985-02-07 Capsule de bouchage en polypropylène pourvue d'un joint et d'une bande de garantie Expired - Lifetime EP0155021B2 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT85200149T ATE34148T1 (de) 1984-02-09 1985-02-07 Verschlusskappe aus polypropylen mit abdichtung und garantieband.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NL8400428A NL8400428A (nl) 1984-02-09 1984-02-09 Werkwijze ter vervaardiging van een van een afdichtpakking voorziene sluitdop uit een polypropeenmateriaal voor een houder; van een afdichtpakking voorziene sluitdop uit een alkeenpolymeer, alsmede werkwijze voor het sluiten en verzegelen van een houder met een sluitdop vervaardigd uit polypropeenmateriaal.
NL8400428 1984-02-09

Publications (3)

Publication Number Publication Date
EP0155021A1 EP0155021A1 (fr) 1985-09-18
EP0155021B1 true EP0155021B1 (fr) 1988-05-11
EP0155021B2 EP0155021B2 (fr) 1994-03-02

Family

ID=19843469

Family Applications (1)

Application Number Title Priority Date Filing Date
EP85200149A Expired - Lifetime EP0155021B2 (fr) 1984-02-09 1985-02-07 Capsule de bouchage en polypropylène pourvue d'un joint et d'une bande de garantie

Country Status (11)

Country Link
EP (1) EP0155021B2 (fr)
JP (1) JP2545207B2 (fr)
AT (1) ATE34148T1 (fr)
CA (1) CA1292443C (fr)
DE (1) DE3562601D1 (fr)
DK (1) DK61285A (fr)
ES (1) ES8606173A1 (fr)
GR (1) GR850303B (fr)
IN (1) IN162719B (fr)
NL (1) NL8400428A (fr)
ZA (1) ZA85865B (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11713166B2 (en) 2018-12-17 2023-08-01 Crown Packaging Technology, Inc. Low migration container

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE939052C (de) * 1948-12-14 1956-02-16 Anton Springer Bohrloch-Impfgeraet fuer Holzschutztraenkung
US4675139A (en) * 1985-10-21 1987-06-23 Continental Can Company, Inc. Method of forming plastisol gaskets in container closures fabricated from synthetic plastic resins
GB2186558A (en) * 1986-02-17 1987-08-19 Grace W R & Co Container closure
IT1232058B (it) * 1989-03-29 1992-01-23 Alplast Spa Capsula a vite di materiale termoplastico
GB2252267A (en) * 1991-01-31 1992-08-05 Grace W R & Co Curing of plastisol liner material in thermoplastic closure
US6142325A (en) * 1998-10-19 2000-11-07 Playtex Products, Inc. Container assembly and bottom cap therefor
FR2822810B1 (fr) * 2001-03-28 2003-08-22 Rical Sa Dispositif de bouchage pour une bonbonne, munie de moyens de retenue et d'accorchage d'un joint coule ou moule, et procede de realisation
JP4994172B2 (ja) * 2007-09-26 2012-08-08 日本クラウンコルク株式会社 容器用のキャップ
CA2808350C (fr) * 2010-08-30 2019-05-14 Tetra Laval Holdings & Finance S.A. Bouchon d'etancheite destine a un contenant
CN108910251A (zh) * 2018-08-02 2018-11-30 宁国市双阳精密制造有限公司 一种耐磨材料生产销售用物流箱

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GR66059B (fr) * 1977-01-28 1981-01-14 Continental Group
GR72763B (fr) * 1980-02-14 1983-12-02 Obrist Ag Albert
GB2116529B (en) * 1982-03-10 1985-07-17 Grace W R & Co Screw closure
ZA831232B (en) * 1982-03-10 1983-11-30 Grace W R & Co Screw cap
JPS5915059A (ja) * 1982-07-06 1984-01-26 日本クラウンコルク株式会社 合成樹脂製容器蓋
WO1984000346A1 (fr) * 1982-07-09 1984-02-02 Metal Closures Group Plc Ameliorations a des fermetures pour recipients filetes

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11713166B2 (en) 2018-12-17 2023-08-01 Crown Packaging Technology, Inc. Low migration container

Also Published As

Publication number Publication date
DK61285A (da) 1985-08-10
DE3562601D1 (en) 1988-06-16
JPS60204473A (ja) 1985-10-16
ATE34148T1 (de) 1988-05-15
IN162719B (fr) 1988-07-02
JP2545207B2 (ja) 1996-10-16
DK61285D0 (da) 1985-02-08
GR850303B (fr) 1985-04-03
NL8400428A (nl) 1985-09-02
AU3856485A (en) 1985-08-15
EP0155021A1 (fr) 1985-09-18
CA1292443C (fr) 1991-11-26
ZA85865B (en) 1985-10-30
EP0155021B2 (fr) 1994-03-02
ES540171A0 (es) 1986-04-16
AU580751B2 (en) 1989-02-02
ES8606173A1 (es) 1986-04-16

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