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EP0145424A2 - Produit à fumer sans tabac - Google Patents

Produit à fumer sans tabac Download PDF

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Publication number
EP0145424A2
EP0145424A2 EP19840308340 EP84308340A EP0145424A2 EP 0145424 A2 EP0145424 A2 EP 0145424A2 EP 19840308340 EP19840308340 EP 19840308340 EP 84308340 A EP84308340 A EP 84308340A EP 0145424 A2 EP0145424 A2 EP 0145424A2
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EP
European Patent Office
Prior art keywords
product
weight
tobacco
sheet
coffee
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP19840308340
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German (de)
English (en)
Inventor
William E. Rosen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WOOLERY-ROSEN ASSOCIATES
Original Assignee
WOOLERY-ROSEN ASSOCIATES
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by WOOLERY-ROSEN ASSOCIATES filed Critical WOOLERY-ROSEN ASSOCIATES
Publication of EP0145424A2 publication Critical patent/EP0145424A2/fr
Withdrawn legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24BMANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/10Chemical features of tobacco products or tobacco substitutes
    • A24B15/16Chemical features of tobacco products or tobacco substitutes of tobacco substitutes

Definitions

  • This invention relates to tobacco substitute smoking materials intended to be used as tobacco replacement or supplement. More specifically, it relates to such materials which are intended to have physical and smoking characteristics close, if not identical, to that of real tobacco.
  • Processed cellulosic material has been developed as a substitute smoking material, as a tobacco replacement or a tobacco supplement.
  • alpha-cellulose and other types of cellulosic material in untreated form have been found to be unsatisfactory either as to their burning characteristics or as to other physical properties.
  • Heat treated cellulosic materials are also'shown in USPN 3,705,589 and 3,545,448.
  • USPN 3,807,414 relates to untreated cellulose in combination with other materials.
  • a fluid obtained by boiling resin in a solvent of NaCl and by boiling the same in a solvent of NaHC0 3 and a solution of organic salt of iron is used for treating tobacco leaves or plant pulp or cellulose as shown in USPN 1,334,752.
  • Wood pulp can be made into paper sheets and soaked with tobacco extract as shown in USPN 2,576,021.
  • Sugar cane pulp fibers once the sugar ladened juice has been pressed therefrom, cotton, linen, sisal and other similar fibers which have compositions similar to tobacco with respect to cellulose fats, waxes or gums are also used when treated with sodium hydroxide or other alkali. Taste, aroma and color additives are then added.
  • USPN 2,907,686 relates to a charcoal tobacco substitute which includes as a carrying agent Fuller's Earth or natural or activated clay including aromatic flavoring agents such as vanilla, eucalyptus oil or isoamyl isovalerate. Glycerol or Glycerol monoacetate may be added.
  • An ash forming agent e.g. ZnCl 2 , Ca(OH) 2 , KOH or K 2 C0 3 , MgO, A1 2 0 3 .
  • Coating agents e.g. sugar solutions or hard gum or resin may also be used.
  • a tobacco substitute base extracted from plant leaves with water or an organic solvent with many additives listed is shown in USPN 3,369,551. Dry materials are toasted to a golden brown color and treated with appropriate additives.
  • USPN 3,461,879 relates to a tobacco substitute of oxidized cellulose in combination with a hydrated metal compound, such as magnesium citrate, hydrated alumina, calcium tartrate or magnesium sulfate.
  • a hydrated metal compound such as magnesium citrate, hydrated alumina, calcium tartrate or magnesium sulfate.
  • a smoking material comprising a carbohydrate material, such as cellulose which is thermally degraded at 100 to 250oC, is shown in USPN 3,545,448.
  • the material is processed in the presence of a strong mineral acid catalyst until a weight loss of at least 10% has occurred.
  • Carbohydrate materials reduced include alpha-cellulose, and cellulose derivatives such as methyl cellulose, and various polysaccharides and gums.
  • USPN 3,556,109 relates to smoking materials made from 100% wood pulp cellulose with 1 to 30% mild organic acid added in the presence of a calcium, magnesium, barium or strontium salt.
  • US P N 3,556,110 relates to a method of making oxidized cellulose as a smoking material when treated with a dilute solution of an organic acid to produce purified pulp by removing sugars, protein, chlorophylls, flavones, colors, oils, waxes and resins.
  • USPN 3,559, 655 relates to a process for manufacturing a smoking material from oxidized cellulose to contain a mineral- izing agent in the form of strontium or barium oxalate, lactate, glycolate, diglycolate or pivalate in the amount of 5 to 40%, by weight.
  • U S P N 3,612,063 relates to a smoking material made of oxidized cellulose combined with organic salts of potassium, lithium and copper such as oxalic, lactic, glycolic, diglycolic, pivalic or tannic acid salts with titanium dioxide.
  • USPN 3,638,660 relates to a tobacco substitute material prepared from fibrous wood pulp containing at least 90 % alpha-cellulose which is formed into a sheet having a density of 12 to 35 lbs. per cubic foot.
  • Certain combustion modifiers such as potassium sulfate, sodium sulfate, magnesium sulfate, magnesium chloride and potassium chloride or carbonates or bi-carbonates of sodium potassium, magnesium and aluminum as well as potassium nitrate, ferric oxide, ferric hydroxide, alumina and citrates and acetates of magnesium and glyconic acid are suggested.
  • USPN 3,640,285 relates to a cigarette paper containing calcium oxalate or certain other alkaline earth metal salts of organic acids.
  • USPN 3,720,660 relates to cellulose and polysaccharides which are oxidized by strong acids.
  • USP N 3,840,024 relates to a reconstituted tobacco material containing bilbulous fibers in the range of 5 to 25%, by weight, which fibers are water insoluble and wet cross-linked derivatives of carboxymethyl cellulose.
  • USPN 3,812,864 relates to a smoking material of vinyl methyl ether being maleic anhydride copolymers with inorganic materials such as calcium carbonate.
  • Combustible material is added such as tobacco dust, cellulose, pectins or natural gums.
  • US P N 3,840,026 discloses a method of treating cured tobacco to improve taste, aroma, feel and color involving a treatment with calcium or magnesium porous silicous material carried in a gel or used in a talc or absorbent clay such as diatomite.
  • USPN 3,851,653 relates to a method pf treating tobacco to increase volume and reduce nicotine. An amount of hydrogen peroxide and catalase is added to the tobacco.
  • USPN 4,328,816 relates to mechanical working under steam conditions of reconstituted tobacco to shatter and wrinkle a reconstituted tobacco sheet.
  • US PN 3,871,390 relates to heating cellulose to 100-300° C to obtain a degradation of 55 to 30%, by weight, to produce a carbonized cellulose with a morganic filler such as hydroxide to form a slurry which is then cast into a sheet.
  • a morganic filler such as hydroxide
  • USPN 4,333,484 shows an improved smoking material comprising cellulosic material, made from an-aqueous slurry of slightly beaten fibers. Calcium, magnesium, iron or aluminum salts are added to the slurry which is thereafter cast, dried, conditioned and slit. About 5-40% and preferably 10-30% by weight of the product is the added salts. Modified cellulose gum may also be added.
  • An object of this invention is to provide a non-tobacco product with burning and ashing characteristics very similar to natural tobacco.
  • Another object is to provide such a product with taste and aroma characteristics similar to natural tobacco.
  • Another object is to provide such a product which exhibits looks, feel, texture and mechanical strengths very similar to natural tobacco.
  • a further object is to provide a process for manufacturing such a non-tobacco product.
  • non-tobacco smoking product usuable as a tobacco substitute or tobacco supplement which is made using any of a variety of cellulosic containing materials exhibiting desirable burn, aroma and taste characteristics such as hardwood flour, i.e. oak or maple, obtained by sanding, coffee, such as the freeze dried variety, and chickory.
  • An initial slurry is formed from a cellulose base and gum materials to generate the binder or "base web” material for making a "sheet” of product.
  • other ingredients which may include any of combustion control and ash forming agents, such as calcium carbonate, titanium dioxide; and an inert filler, other combustion, aroma, taste and ash contributing materials, such as coffee, chickory, hardwood flour and other flavor and color agents to form a completed slurry.
  • the slurry is then cast into a sheet and dried into sheet material of desired thickness.
  • the sheet may be tempered to a desired moisture range and then dried again before being mechanically worked to provide proper texture.
  • the sheet is also dried into squares, which are in turn shredded into elongate pieces. These elongate rectangular pieces approximate natural tobacco filler material for cigarette, cigar and pipe smoking uses.
  • Flavor and aromatic qualities of the product approach that of natural tobacco, as well as, do its appearance, burn and ash formation, and also mechanical strength, texture and weight.
  • a non-tobacco smoking product usable as a tobacco substitute or as a tobacco supplement is provided.
  • the product is made into sheets which can be texturized and shredded into a bulk product which may then be handled with standard and commonly available tobacco handling equipment for making cigarette-like, cigar-like, or packaged pipe smoking products.
  • the product of the invention has color, flavor, aroma, texture, tensile strength smoking or burning and ash forming characteristics approaching those of class 1, grade A, "gold" natural tobacco.
  • This base web is made from loose and slightly beaten cellulosic material suspended in a binder and castable into sheet form. It usually includes soft wood pulp to which triethylene glycol, guar gum, methythydroxytropyl cellulose, ethyhdroxyethl cellulose, phosphoric acid, trimethylether of trimethylol melamine are added.
  • this base web source of cellulose is wood pulp, but sisal, sugar cane pulp, cotton, etc. can also be used. They are beaten to break up the fibers and then are subjected to an acid or caustic solution to further reduce the fibers and to eliminate tars, gums, waxes, sugars and fats and to leave a fibrous pulp residue.
  • a controlled quantity of binder material such as natural gums, i.e. guar gum, is then added. Often glycerine or glycerol is also added so that the mixture is cast and dried into sheet form.
  • H.R. base web a highly refined base web, (H.R. base web) consisting of the cellulosic material and gums, but without the soft wood pulp may be used.
  • a first form of the product contains hard wood flour as an ingredient.
  • This important ingredient of the product is generated as sanding dust, and obtained typically from commercia sanding operations, wherein white maple and/or white oak are sanded with the grain to provide a fine dust or flour.
  • White oak provides a flour with especially pleasing aroma
  • flour generated by sanding with the grain provides a product which contributes to a steady slow consistent burn of the product and adds to the product's body.
  • Hardwood "pulp" generated by milling, grinding or chopping is a less satisfactory a constituent.
  • the hardwood flour can comprise approximately 18-70% of the product by weight.
  • the hard wood flour contributes to a clean burn, having little resin content, aids in keeping the ash from curling and controls the burn rate.
  • ingredients can be added to enhance the mechanical handling properties and burning or smoking characteristics of the product.
  • These ingredients can include calcium carbonate, syrup, including any of the family of sucroses and fructoses, titanium dioxide, flavoring, western bentonite (i.e. sodium aluminum silicate) and natural fruit juices, such as prune juice.
  • Calcium carbonate contributes to a steady and consistent burn rate. Calcium carbonate is added at 2-10%, by weight of the ingredients.
  • Syrup contributes to an adhering of the ash to the unburnt product.
  • Bentonite contributes to ash adherence to the unburnt product, while titanium dioxide, which comprises about 0.5-1 5% by weight of the ingredients whitens the ash. Bentonite constitutes about 1-25% by weight of the product ingredients.
  • a preferred kind of bentonite is western bentonite mineral colloid 101, available from the Georgia Kaolin Co., Inc., Elizabeth, New Jersey.
  • Flavoring including fruit juices such as prune juice, contribute to the aroma, taste and coloring of the product.
  • a mix of 50% corn syrup and 50% sucrose is prefered. It acts as a binder and a plasticizer of the coals, as well as, a flavor and aroma contributor.
  • One hundred percent corn inverted sugar or alternatively, 100% fructose may be also used. However, as the choice of sweetener changes,the flavoring, aroma and plasticizing characteristics change.
  • Inverted sugar any of the fructoses or other syrups, including any of the sucroses, are added at about 16-30% by weight of the product ingredients.
  • Flavoring comprising about 10-25% by weight of the ingredients, such as Felton 814 supplied by the Felton Flavor Co., Brooklyn, New York, may be added, or used as a substitute for the syrups above.
  • Prune licquer may be added to comprise about 10-25% by weight of the ingredients. It adds flavor and aroma, as well as, acts as a humectant.
  • Coloring may be added as an ingredient to provide a golden brown color. This coloring can comprise up to 1%, by weight, of the ingredients of the product, but, typically, it is added in a range of about..25%-.74%. Coloring ingredients may include F, D, C, yellow No. 5; F, D, C,'blue No. 1; and F, D, C red No. 40.
  • the hard wood flour 11 obtained from sanding
  • the syrup or other plasticizer 13 are added together in a first blender 15.
  • a 'filler product When a 'filler" product is intended, natural tobacco 23, if desired, is to be added into the product composition, such addition being in the neighborhood of 1-99% by weight.
  • This tobacco 23 is added into the second blender 19 with base web 17 and other ingredients 21.
  • the mixture from the first blender 15 and the second blender 19 are placed into a third blender 25 where the entirety of the ingredients of the composition is mixed together.
  • the output from the blender 25 is sent to a casting box 27 and thereafter formed into a sheet 30 of the composition by being cast or extruded as a slurry layer onto a moving stainless steel conveyor belt 29.
  • This material, in sheet form 30, is carried through drying ovens 31 and then on to a moisture control step 33 where either water mist or a prune juice mist is sprayed onto the surface of the dried product sheet 30 to regulate its moisture.
  • a knife 35 removes the sheet 30, whereinafter it is placed into a rotary dryer 37.
  • the sheet 30 may be texturized by mechanical working, either in the rotary dryer 37 or as part of a texturizing and shredding operation 39 carried out by a shredder-texturizer 39.
  • the sheets 30 are cut into squares in the operation 39.
  • the squares or wafers can be from 1 inch by 1 inches square to 2 inches by 2 inches square. Typically, the sheet 30 is 5.5.mils thick.
  • the squares are shredded at 25-100 cuts per inch.
  • a bulk product 41 provided by the shredder and texturizing equipment 39 can then be made available to standard tobacco handling machinery 43 which is used to package cigarettes, cigars and package pipe tobacco.
  • Prune syrup and prune juice is a desirable organic moisturizer and plasticizer which can be added 33 to the surface of the sheet product following the drying oven 31 and prior to mechanical working by the rotary dryer 37 and the shredder 3 9 .
  • Th prune syrup or prune juice can alternatively, and/or ad -tionally be added to the product by being sprayed 44 on the sr face following the rotary dryer 37 operation.
  • Titanium dioxide may also be mixed with the prune juice or prune syrup when it is sprayed 33 on the surface of the product.
  • the present invention departs considerably from other forms of material used as natural tobacco substitutes or tobacco supplements. It differs in that hardwood flour must be provided by sanding when the grain, i.e. cellular structure of the wood is not completely destroyed. If hard wood pulp which is provided by grinding, chopping or beating is used, the product acquires less desirable characteristics, as the sheet tends to curl and the burn characteristics degenerate. Hardwood flour, especially that provided from white maple or white oak, being very low in natural resin, and not bleached or refined by an acedic or caustic solution, provides a product which does not curl up when burning. It promotes a steady, slow burn similar to natural tobacco and provides an ash which clings similar to natural tobacco.
  • the final slurry which is pumped from the third blender 25 to the casting box 27 and then extruded/cast onto the continuous stainless steel belt 29 to form the sheet 30 is at ambient temperatures throughout.
  • This sheet 30 is then passed through a series of drying ovens 31 at temperatures between 100 o C and 300°C.
  • the moisture content of the sheet 30 is then judged, and if it is too dry, it is sprayed with a fine water mist on its upper surface at the moisture control point 33.
  • the moisture is then controlled on the sheet via the rotary dryer 37 to 5-12%.
  • the bulk product 41 produced has a weight, thickness and texture similar to that of natural tobacco and has a tensile strength in the range of which approaches that of natural tobacco. These physical characteristics allow the product to be further handled and packaged with standard tobacco handling equipment 43.
  • the product 41 can also have a surface coating of potassium chloride or calcium carbonate which is added to the prune syrup or prune juice 33 sprayed as a surface coating.
  • Polypropylene glycol can be also added to the sheet. However, polypropylene glycol should not be present in a concentration of greater than 3% by weight.
  • a hardwood recipe which provides excellent smoking product is as follows:
  • the hardwood recipe above, following the shredding and texturizing step 39 ma be subjected to being sprayed by a finish coating 44.
  • This finish coating 44 is sprayed to a single side of the product whether it is still in its uncut form (sheet 30) or in its shredded form (bulk product 41), this finish coating 44 contains prune concentrate syrup loaded with titanium dioxide and flavoring such as Felton flavor 814.
  • the prune syrup may also be loaded with sodium bicarbonate or potassium chloride or calcium carbonate or any combination of these, and also with propylene glycol.
  • Variations of the recipe provide acceptable smoking characteristics for the product. These variations are shown in examples 1, 2, 3, 4 and 5, below where each of the constituents or ingredients is identified by per cent dry weight of the total composition.
  • Each of the recipes of these tables provide a non-tobacco smoking product 41 whose smoking characteristics, i.e. aroma, burn rate, and ash formation, and mechanical handling characteristics vary, but which all are in the range desirable for an acceptable non-tobacco smoking product.
  • a preferred formulation is manufactured according to the process of figure 2.
  • Water 45 as well as cellulose material 47 is fed into a first blender 49.
  • a gum or other plasticizer 51 and other ingredients 53 To this is added a gum or other plasticizer 51 and other ingredients 53.
  • the binder or "base web" material, which can eventually constitute about 20% of the product is mixed in this first blender 49.
  • the cellulose 47 is made from soft wood pulp.
  • the gum 51 is guar gum, while the other ingredients 53 include methylhydroxply cellulose, ethylhydroxyelthyl cellulose and phosphoric acid.
  • these ingredients are mixed in the following percentages by dry weight:
  • the base web slurry which is output from the first blender 49 is input to a second blender 55 along with coffee 56, chicory 58, inert filler 60, calcium carbonate 62, titanium dioxide 64 and selective portions of flavoring and coloring 66.
  • the percentages of each of these additional constituents as a function of the total product by dry weight is as follows: and minute amounts of flavoring and coloring.
  • the coffee constituent 56 can be replaced with chicory, or the chicory constituent 58 can be replaced with coffee.
  • a preferred recipe is:
  • a further preferred recipe is:
  • the inert filler 60 material can include any of the following materials either solely or in combination: clay, brick dust, crushed stone particles, diatomaceous earth, sand, and bentonite.
  • the flavoring and coloring 66 can include any of the following: F D &C Yellow No. 5, a chocolate brown blend (containing FD&C Yellow No. 5, FD&C Blue No. 1, FD&C Red No. 40), and Felton Corporation flavoring No. 814.
  • the blended product fed from the second blender 55, figure 2 is entered into a casting box 57 which provides a layer of slurry material 59 on a first conveyor 61.
  • This conveyor 61 travels a drying ovens 63 which dry the slurry 59 into a sheet material 65.
  • the conveyor 61 then carries the sheet material 65 past a moisture control station 67 which can temper the moisture content of the sheet 65 prior to a knife removal operation 69.
  • a rotary dryer 71 is employed to dry the sheet material 65 removed from conveyor 61 by the knife 69.
  • the output of the rotary dryer 71 is fed to a shredder and texturizing station in which any of a number of machines may chop up the sheet while texturizing it into small elongate particle bits similar in size and weight to shredded tobacco products.
  • the output of the shredding and texturizing stations 73 is bulk product 75 which is then shipped to standard tobacco handling and packaging machinery 43 which packages the product into cigarette type or cigar type or pipe tobacco type smoking product.
  • the sheet 61 thickness is similar to sheet 30, figure 1, the dicing and shredding sizes are similar to the process of figure 1 and the operating temperatures are similar to those described in connection with figure 1.
  • shredded tobacco 77 may be dry mixed with bulk product 75 in a dry mixing operation 79 to produce a blended mix 81 of from 1-99% tobacco, or conversely, from 1-99% bulk product 75. This blended mix is then fed to the standard tobacco handling and packaging machinery 43.
  • the bulk product 75 is intended to have the same or similar physical properties such as size, texture, tensile strength, and weight as shredded natural tobacco 77.
  • the bulk products 41, 75 above can have other constituents added to the blender before it is cast into sheet.
  • the addition of triethylene glycol in amounts from 1-5% by weight could supplant other ingredients, such as gum thereby reducing the amount of the guar gum to approximately 1-4%. It is to be noted that all percentages are by weight on a dry basis.
  • the addition of propylene glycol will permit, typically, the amount of inert filler material 61 to be reduced.
  • the percentage of coffee 56 can be increased from the 10% level above, and going as high as 70%.
  • the percentage of chicory 58 can be varied from 10% to as much as 70%.
  • the approximate percentages of calcium carbonate 62 and titanium dioxide 64 are held approximately constant. Calcium carbonate 62 acts as a combustion control constituent while titanium dioxide 64 acts as an ash whitening agent.
  • Other examples of the recipe for the bulk product 75 provided in figure 2 are as follows:
  • This formulation can provide a sheet with a weight of approximately 8 grams per square foot and a moisture content of about 9%.
  • Example 10 With moisture content high, the sheet material will become sticky. Regardless, the longitudinal dry strength of the product 75, Example 10, was in excess of 1000 grams per inch while the transverse dry strength of the product 75 provided by this Example 10 ranged from approximately 500 grams to 700 grams per inch.
  • Example 10 The constituents of Examples 9 and 10 can also be varied to include soluble "chicory” 58. instead of ground “chicory” 58 and spray dried coffee 56 instead of freeze dried coffee 56-When spray dried coffee 56 is used, Example 10 becomes as follows:
  • the bulk product 75, Example 11, produced with these constituents has a weight from 10-20% less than the bulk product 75 produced by Example 9, or Example 10 with approximately the same moisture content. Moreover, dry longitudinal strength of the product 75, Example 11, was in excess of 500 grams per inch, less than with the previous Examples 9 and 10; and transverse dry strength was from 300 to 500 grams per inch, less than with the previous Examples 9 and 10.
  • Example 12 weight is approximately that of Examples 9 and 10 for the same approximate moisture content.
  • the dry strength exhibited by this Example 12 product 75 was in excess of 1000 grams per inch for longitudinal dry strength and in a range of 500-700 grams per inch for transverse dry strength.
  • the Examples 9 through 12 above can also be mixed with no flavoring and no propylene glycol or, as an alternative to Felton Company flavoring 770, Felton Flavoring 214 can be used.
  • Different forms of coffee 56 can be mixed in the second blender 55, figure 2. Dehydrated coffee and dry roasted ground coffee can be substituted for freeze-dried or spray dried coffee. Likewise, the chicory 58 can take other forms. Ground, ground and roasted, and dehydrated chicory can be substituted.
  • the taste, aroma, coloring and weight and tensile strength of the bulk products 41 or 75 will vary. It is important that a certain tensile strength and "texturizing memory" be imparted to the product.
  • the dicing-shredder and surface crinkle (texturizing) apparatus 39, 73, figures 1, 2, respectively, and the process step performed thereby, can be replaced with ribbon shredding.
  • This variation for the apparatus 39, 73 first slices the sheet 30, 65 into longitudinal ribbons 1/32 inches wide and then cuts 1/2 inch long slices off of these ribbons.
  • This apparatus and process provides more uniform sizing of product which in turn facilitates the paper tube packing of the smokes. Without the texturizing, easier filling of the paper tubes is accomplished by the handling machinery 43.
  • the inventive product and process for manufacturing the product is to be read and considered as illustrative, and is not to be interpreted in the limiting sense. Variations in the recipes for the product and variations in the process may be made without departing from the intent or scope of the invention.
  • the tobacco or tobacco plant parts could be added either in the first blender 49, figure 2, or the second blender 55 to form a tobacco bearing sheet 61.
  • any type of sheet or paper making machine can be substituted for the structure described above, such other machine would understandably carry its own substituted manufacturing steps. This, too, is contemplated as part of the invention.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacture Of Tobacco Products (AREA)
EP19840308340 1983-12-02 1984-11-30 Produit à fumer sans tabac Withdrawn EP0145424A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US55742683A 1983-12-02 1983-12-02
US557426 1983-12-02

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EP0145424A2 true EP0145424A2 (fr) 1985-06-19

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AU (1) AU3745385A (fr)
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2202422A (en) * 1987-03-23 1988-09-28 Imp Tobacco Co Ltd Smoking materials
WO1997032490A1 (fr) * 1996-03-07 1997-09-12 British American Tobacco (Investments) Limited Materiau de remplissage fumable pour articles a fumer
WO1998051169A1 (fr) * 1997-05-12 1998-11-19 Hugo Bachmaier Substance a priser stimulante
AU726153B2 (en) * 1996-03-07 2000-11-02 British-American Tobacco (Investments) Limited Smokable filler material for smoking articles
EP1265503A4 (fr) * 2000-03-21 2004-07-07 Jung-O An Cigarettes contenant des particules d'or et d'argent et procedes de fabrications du filtre de cigarettes
WO2011026051A3 (fr) * 2009-08-31 2011-07-14 Rodney Masri Produit à fumer à base de thé

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4817640A (en) * 1985-09-19 1989-04-04 Better Life International Life, Inc. Herbal chew and snuff compositions
US9695033B1 (en) 2013-10-17 2017-07-04 Andrew Alshouse System for dispensing custom blended electronic cigarette liquid
CN117441930A (zh) * 2023-10-27 2024-01-26 湖南中烟工业有限责任公司 烟碱逐口释放均匀性的新型烟草制品及其烟碱调节剂、稠浆、薄片的制备方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1927984A (en) * 1931-11-13 1933-09-26 Krensky Process of manufacturing smoker's articles
US3931824A (en) * 1973-09-10 1976-01-13 Celanese Corporation Smoking materials
US4165752A (en) * 1975-10-07 1979-08-28 Bustamante Carlos R Tobacco substitute made from coffee cherries and a process for making such

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2202422A (en) * 1987-03-23 1988-09-28 Imp Tobacco Co Ltd Smoking materials
GB2202422B (en) * 1987-03-23 1991-09-25 Imp Tobacco Co Ltd Smoking material and process for making same
WO1997032490A1 (fr) * 1996-03-07 1997-09-12 British American Tobacco (Investments) Limited Materiau de remplissage fumable pour articles a fumer
AU720501B2 (en) * 1996-03-07 2000-06-01 British-American Tobacco (Investments) Limited Smokable filler material for smoking articles
AU726153B2 (en) * 1996-03-07 2000-11-02 British-American Tobacco (Investments) Limited Smokable filler material for smoking articles
WO1998051169A1 (fr) * 1997-05-12 1998-11-19 Hugo Bachmaier Substance a priser stimulante
EP1265503A4 (fr) * 2000-03-21 2004-07-07 Jung-O An Cigarettes contenant des particules d'or et d'argent et procedes de fabrications du filtre de cigarettes
WO2011026051A3 (fr) * 2009-08-31 2011-07-14 Rodney Masri Produit à fumer à base de thé
US9022041B2 (en) 2009-08-31 2015-05-05 Rodney Masri Tea based smoking product

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WO1985002325A1 (fr) 1985-06-06
AU3745385A (en) 1985-06-13

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