EP0039242A1 - Bronze à l'aluminium - Google Patents
Bronze à l'aluminium Download PDFInfo
- Publication number
- EP0039242A1 EP0039242A1 EP81301885A EP81301885A EP0039242A1 EP 0039242 A1 EP0039242 A1 EP 0039242A1 EP 81301885 A EP81301885 A EP 81301885A EP 81301885 A EP81301885 A EP 81301885A EP 0039242 A1 EP0039242 A1 EP 0039242A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- aluminium
- chromium
- bronze alloy
- aluminium bronze
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 86
- 229910000906 Bronze Inorganic materials 0.000 title claims description 57
- 239000011651 chromium Substances 0.000 claims abstract description 39
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 37
- 239000000956 alloy Substances 0.000 claims abstract description 37
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 35
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 35
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000002245 particle Substances 0.000 claims abstract description 15
- 229910021332 silicide Inorganic materials 0.000 claims abstract description 11
- 229910052751 metal Inorganic materials 0.000 claims abstract description 10
- 239000002184 metal Substances 0.000 claims abstract description 10
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000011159 matrix material Substances 0.000 claims abstract description 8
- FHTCLMVMBMJAEE-UHFFFAOYSA-N bis($l^{2}-silanylidene)manganese Chemical compound [Si]=[Mn]=[Si] FHTCLMVMBMJAEE-UHFFFAOYSA-N 0.000 claims abstract description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 42
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 30
- 229910052710 silicon Inorganic materials 0.000 claims description 30
- 239000010703 silicon Substances 0.000 claims description 30
- 239000004411 aluminium Substances 0.000 claims description 29
- 229910052782 aluminium Inorganic materials 0.000 claims description 29
- 229910052742 iron Inorganic materials 0.000 claims description 21
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 17
- 229910052802 copper Inorganic materials 0.000 claims description 17
- 239000010949 copper Substances 0.000 claims description 17
- 239000012535 impurity Substances 0.000 claims description 17
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 13
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 8
- 239000011572 manganese Substances 0.000 claims description 8
- 229910052748 manganese Inorganic materials 0.000 claims description 7
- 230000005540 biological transmission Effects 0.000 claims description 4
- 229910052759 nickel Inorganic materials 0.000 claims description 4
- 229910021357 chromium silicide Inorganic materials 0.000 claims description 3
- 150000002739 metals Chemical class 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 description 5
- 238000007792 addition Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 3
- 238000005461 lubrication Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000010008 shearing Methods 0.000 description 3
- 229910000881 Cu alloy Inorganic materials 0.000 description 2
- 229910017028 MnSi Inorganic materials 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- DYRBFMPPJATHRF-UHFFFAOYSA-N chromium silicon Chemical compound [Si].[Cr] DYRBFMPPJATHRF-UHFFFAOYSA-N 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 230000013011 mating Effects 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 229910021359 Chromium(II) silicide Inorganic materials 0.000 description 1
- 229910019909 CrAl3 Inorganic materials 0.000 description 1
- 229910019921 CrAl4 Inorganic materials 0.000 description 1
- 229910019974 CrSi Inorganic materials 0.000 description 1
- 229910016756 Mn3 Si Inorganic materials 0.000 description 1
- 229910016586 Mn5Si3 Inorganic materials 0.000 description 1
- 229910016577 MnAl3 Inorganic materials 0.000 description 1
- 229910016579 MnAl4 Inorganic materials 0.000 description 1
- 229910017025 MnSi2 Inorganic materials 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000003483 aging Methods 0.000 description 1
- JRBRVDCKNXZZGH-UHFFFAOYSA-N alumane;copper Chemical compound [AlH3].[Cu] JRBRVDCKNXZZGH-UHFFFAOYSA-N 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 229910000765 intermetallic Inorganic materials 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 238000004881 precipitation hardening Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C9/00—Alloys based on copper
- C22C9/01—Alloys based on copper with aluminium as the next major constituent
Definitions
- This invention relates to aluminium bronze alloys and more particularly, but not exclusively, to aluminium bronze alloys which are utilised to form products in which the wear resistance properties of the alloys are of importance.
- an aluminium bronze alloy comprises by weight 6% to 15% aluminium and includes within the matrix thereof intermetallic particles of metal silicide for increasing the. wear resistance of the alloy.
- the intermetallic particles of metal silicide have a greater hardness than the matrix of the alloy and form asperities at the free surface thereof.
- the asperities of metal silicide which protrude from the free surface of the alloy structurally reinforce the alloys aluminium oxide film at said free surface.
- the intermetallic particles are, preferably, formed substantially of chromium silicide or, alternatively, the particles may be formed substantially of manganese silicide. As a further alternative, the intermetallic particles may be formed substantially of iron silicide.
- the aluminium bronze alloy comprises by weight 6% to 15% aluminium, 0.1% to 0.3% silicon and 0.1% to0.4% chromium or 0.1% to 5% manganese or a combination thereof.
- the aluminium bronze alloy preferably, comprises by weight 10.3% aluminium, 0.25% silicon, 0.1% chromium, 1.5% iron or equivalent iron content, the balance being copper and the usual impurities.
- the aluminium bronze alloy may comprise by weight 10.5% aluminium, 0.2% to 0.3% silicon, 0.2% to 0.3% chromium, 1% manganese, up to 1.5% iron, up to 0.5% nickel, the balance being copper and the usual impurities.
- an aluminium bronze alloy comprises by weight 6% to 15% aluminium and includes chromium and silicon wherein the silicon content is equal to or greater than the chromium content.
- the chromium content of the alloy comprises by weight 0.1% to 0.4% chromium.
- an aluminium bronze alloy for forming gears and other power transmission products comprises by weight 9% to 11% aluminium, 0.4% chromium, 0.25% silicon and up to 2% manganese, the balance being copper and the usual impurities.
- an aluminium bronze alloy for forming slides; support plates; guides, rolls and equipment used in the processing of metals comprises by weight 11.5% to 12.5% aluminium, 0.4% chromium, 0.25% silicon, and up to 2.00% manganese, the balance being copper and the usual impurities.
- an aluminium bronze alloy for forming press tool inserts and dies comprises by weight 14% aluminium, 0.4% chromium, 0.25% silicon, and up to 2.00% manganese, the balance being copper and the usual impurities.
- the alloy contains up to 1.5% iron and the silicon content is equal to or.greater than the chromium content.
- the silicon content of the alloy is also found to be beneficial for the silicon content of the alloy to be equal to or greater than the chromium content of the alloy, particularly, where the alloy contains iron.
- aluminium bronze alloys referred to above which are the subject of this invention, have been shown to maintain a considerably more stable oxide film and the stability of the oxide film is considered to be due to the reinforcement of the oxide film by intermetallic particles formed substantially of chromium silicide and/or manganese silicide. It has also been found that in alloys containing iron, iron is present in these complex silicides and therefore in such a case, the silicides are formed of various percentages of chromium, manganese and iron.
- intermetallic particles are small, are uniformly distributed throughout the matrix of the alloy and are very much harder than the matrix. Furthermore, the intermetallic particles protrude from the free surface of the alloy in the form of minute asperities which are better able to sustain load supplied thereto than the normal aluminium oxide film. As these asperities are much harder than the matrix, they offer considerable resistance to shear and readily form oxide layers so as to resist welding to the mating surface under conditions of boundary lubrication.
- aluminium bronze alloys are most suitably prepared by melting the correct proportions of aluminium and copper in a coreless induction furnace and adding thereto manganese, silicon and chromium in that order to the high temperature liquid. The liquid having these additions is then mixed mechanically and is then poured without any undue delay.
- alloys are not sensitive . to small proportions of impurities with the exception of lead, arsenic and bismuth and conveniently may contain up to 0.5% iron, zinc, tin, vanadium, titanium, molybdenum, nickel, cobalt and tungsten. Where the alloys are to be manufactured in oil-fired furnaces, it has been found to be beneficial for the higher melting point constituents to be added as master alloys of copper.
- the distribution and size of the intermetallic particles can be modified by utilising various forms of heat treatment such as a solution treatment, and precipitation or age hardening.
- various forms of heat treatment such as a solution treatment, and precipitation or age hardening.
- chromium silicon and manganese do not impair the already good corrosion resistance properties of aluminium bronze alloys and the improved wear resistance of.the aluminium bronze alloys containing chromium silicon and manganese are still retained when the alloy is applied as a weld deposit.
- aluminium bronze alloys according to this invention can be produced in a cast or wrought condition thereby facilitating economic production of various forms of components.
- aluminium bronze alloys having an aluminium content in the range of 6% to 11% by weight aluminium, and a hardness in the range of 180 to 280 Viewers pyramid number would be suitable, due to their increased wear resistance for the formation of gears of various types, particularly, worm wheels and other power transmission products.
- One particularly suitable aluminium bronze alloy for the formation of such products comprises by weight 9% to 11% aluminium, 0.4% chromium, 0.25% silicon, and up to2.00% manganese, the balance being copper and the usual impurities.
- aluminium bronze alloys have an aluminium content in the range of 11% to 15% by weight and a hardness in the range of 250 to 350 Vickers pyramid number
- the alloy will be particularly useful for forming components such as slides, and support plates of machine tools, and guides and forming rolls and similar equipment used in the processing of other metals where an important criterion is the wear resistance of such products.
- an aluminium bronze alloy comprising by weight 11.5% to 12.5% aluminium, 0.4% chromium, 0.23% silicon, and up to 2.00% manganese, the balance being copper and the usual impurities, would be particularly suitable for the production of such products.
- aluminium bronze alloys having an aluminium content in the range of 11% to 15% by weight, and a hardness in the range of 300 to 450 Vickers pyramid number
- one particularly suitable aluminium bronze alloy for forming such products would comprise by weight 14% aluminium, 0.4% chromium, 0.25% silicon, and up to 2.00% manganese,' the balance being copper and the usual impurities.
- alloys previously described which are suitable for forming gears, worm wheels, other power transmission products, slides, support plates of machine tools, guides and forming rolls, press tool inserts and dies, it is found that such alloys can usefully contain up to 1.9% iron. Where such an iron content is included in the alloy it is then desirable to increase the silicon content so that the silicon content is equal to or greater than the chromium content.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture Of Alloys Or Alloy Compounds (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Electroplating Methods And Accessories (AREA)
- Mechanical Operated Clutches (AREA)
- Sliding-Contact Bearings (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB8014265 | 1980-04-30 | ||
| GB8014265 | 1980-04-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP0039242A1 true EP0039242A1 (fr) | 1981-11-04 |
Family
ID=10513110
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP81301885A Withdrawn EP0039242A1 (fr) | 1980-04-30 | 1981-04-29 | Bronze à l'aluminium |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP0039242A1 (fr) |
| JP (1) | JPS56169738A (fr) |
| DE (1) | DE3032767A1 (fr) |
| ES (1) | ES501767A0 (fr) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2155241C2 (ru) * | 1998-10-12 | 2000-08-27 | Институт физики прочности и материаловедения СО РАН | Спеченный антифрикционный материал на основе алюминиевой бронзы |
| WO2001032948A1 (fr) * | 1999-10-29 | 2001-05-10 | Man B & W Diesel A/S | Procede et dispositif pour produire des pieces de machine pourvues d'au moins une surface de glissement |
| WO2001087542A1 (fr) * | 2000-05-16 | 2001-11-22 | Sierra Machinery, Inc | Outil de galetage et de drayage |
| WO2003072837A1 (fr) * | 2002-02-28 | 2003-09-04 | Sandvik Ab | Alliage a base de cuivre et son utilisation dans des environnements de carburation |
| CN114990380A (zh) * | 2022-06-24 | 2022-09-02 | 上海交通大学 | 一种无铍超级高强高韧铜合金及其制备方法 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DD5241A (fr) * | ||||
| GB530447A (en) * | 1938-07-01 | 1940-12-12 | American Brass Co | Improvements in or relating to copper base alloys |
| DE733166C (de) * | 1939-06-28 | 1943-03-23 | Ver Deutsche Metallwerke Ag | Verwendung von bleihaltigen Aluminiumbronzen fuer gleitend beanspruchte Maschinenteile |
| US3993479A (en) * | 1975-08-04 | 1976-11-23 | Olin Corporation | Copper base alloy |
| DE2621602A1 (de) * | 1975-05-16 | 1976-12-02 | Hitachi Ltd | Aluminiumbronze mit hoher verschleissfestigkeit |
-
1980
- 1980-08-30 DE DE19803032767 patent/DE3032767A1/de not_active Withdrawn
-
1981
- 1981-04-28 JP JP6514181A patent/JPS56169738A/ja active Pending
- 1981-04-29 EP EP81301885A patent/EP0039242A1/fr not_active Withdrawn
- 1981-04-29 ES ES501767A patent/ES501767A0/es active Granted
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DD5241A (fr) * | ||||
| GB530447A (en) * | 1938-07-01 | 1940-12-12 | American Brass Co | Improvements in or relating to copper base alloys |
| DE733166C (de) * | 1939-06-28 | 1943-03-23 | Ver Deutsche Metallwerke Ag | Verwendung von bleihaltigen Aluminiumbronzen fuer gleitend beanspruchte Maschinenteile |
| DE2621602A1 (de) * | 1975-05-16 | 1976-12-02 | Hitachi Ltd | Aluminiumbronze mit hoher verschleissfestigkeit |
| US3993479A (en) * | 1975-08-04 | 1976-11-23 | Olin Corporation | Copper base alloy |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2155241C2 (ru) * | 1998-10-12 | 2000-08-27 | Институт физики прочности и материаловедения СО РАН | Спеченный антифрикционный материал на основе алюминиевой бронзы |
| WO2001032948A1 (fr) * | 1999-10-29 | 2001-05-10 | Man B & W Diesel A/S | Procede et dispositif pour produire des pieces de machine pourvues d'au moins une surface de glissement |
| WO2001087542A1 (fr) * | 2000-05-16 | 2001-11-22 | Sierra Machinery, Inc | Outil de galetage et de drayage |
| US6367137B1 (en) * | 2000-05-16 | 2002-04-09 | Sierra Machinery, Inc. | Skiving and roller burnishing tool |
| US6560835B2 (en) | 2000-05-16 | 2003-05-13 | Sierra Machinery, Inc. | Skiving and roller burnishing tool |
| WO2003072837A1 (fr) * | 2002-02-28 | 2003-09-04 | Sandvik Ab | Alliage a base de cuivre et son utilisation dans des environnements de carburation |
| US7041252B2 (en) | 2002-02-28 | 2006-05-09 | Sandvik Intellectual Property Ab | Copper base alloy |
| CN114990380A (zh) * | 2022-06-24 | 2022-09-02 | 上海交通大学 | 一种无铍超级高强高韧铜合金及其制备方法 |
| CN114990380B (zh) * | 2022-06-24 | 2023-02-21 | 上海交通大学 | 一种1500MPa级无铍超级高强高韧铜合金及其制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS56169738A (en) | 1981-12-26 |
| DE3032767A1 (de) | 1981-11-19 |
| ES8303539A1 (es) | 1983-02-01 |
| ES501767A0 (es) | 1983-02-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| AK | Designated contracting states |
Designated state(s): BE CH DE FR IT NL |
|
| 17P | Request for examination filed |
Effective date: 19820504 |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
|
| 18D | Application deemed to be withdrawn |
Effective date: 19840821 |
|
| RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: LITTLEWOOD, GEOFFREY Inventor name: ASHTON, NORMAN COUPE |