EP0016763A1 - Methode de degazage controle du petrole brut - Google Patents
Methode de degazage controle du petrole brutInfo
- Publication number
- EP0016763A1 EP0016763A1 EP79900400A EP79900400A EP0016763A1 EP 0016763 A1 EP0016763 A1 EP 0016763A1 EP 79900400 A EP79900400 A EP 79900400A EP 79900400 A EP79900400 A EP 79900400A EP 0016763 A1 EP0016763 A1 EP 0016763A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- gas
- tanks
- crude oil
- tanker
- oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000010779 crude oil Substances 0.000 title claims abstract description 30
- 238000000034 method Methods 0.000 title claims description 21
- 238000010943 off-gassing Methods 0.000 title claims description 13
- 239000007789 gas Substances 0.000 claims abstract description 68
- 239000011261 inert gas Substances 0.000 claims abstract description 21
- 238000013019 agitation Methods 0.000 claims description 2
- 230000005501 phase interface Effects 0.000 claims description 2
- 239000003921 oil Substances 0.000 abstract description 23
- 238000007872 degassing Methods 0.000 abstract 3
- 238000003756 stirring Methods 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 description 11
- 239000012071 phase Substances 0.000 description 11
- 230000032258 transport Effects 0.000 description 10
- 229930195733 hydrocarbon Natural products 0.000 description 9
- 238000009835 boiling Methods 0.000 description 6
- 239000000446 fuel Substances 0.000 description 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 5
- 239000004215 Carbon black (E152) Substances 0.000 description 4
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 238000001704 evaporation Methods 0.000 description 4
- 230000008020 evaporation Effects 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000007791 liquid phase Substances 0.000 description 4
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000001273 butane Substances 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 238000005086 pumping Methods 0.000 description 2
- 239000004291 sulphur dioxide Substances 0.000 description 2
- 235000010269 sulphur dioxide Nutrition 0.000 description 2
- 238000009423 ventilation Methods 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 239000007792 gaseous phase Substances 0.000 description 1
- 238000012432 intermediate storage Methods 0.000 description 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
- B63J—AUXILIARIES ON VESSELS
- B63J99/00—Subject matter not provided for in other groups of this subclass
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D19/00—Degasification of liquids
- B01D19/0005—Degasification of liquids with one or more auxiliary substances
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C9/00—Methods or apparatus for discharging liquefied or solidified gases from vessels not under pressure
- F17C9/02—Methods or apparatus for discharging liquefied or solidified gases from vessels not under pressure with change of state, e.g. vaporisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
- B63J—AUXILIARIES ON VESSELS
- B63J99/00—Subject matter not provided for in other groups of this subclass
- B63J2099/001—Burning of transported goods, e.g. fuel, boil-off or refuse
- B63J2099/003—Burning of transported goods, e.g. fuel, boil-off or refuse of cargo oil or fuel, or of boil-off gases, e.g. for propulsive purposes
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2227/00—Transfer of fluids, i.e. method or means for transferring the fluid; Heat exchange with the fluid
- F17C2227/01—Propulsion of the fluid
- F17C2227/0128—Propulsion of the fluid with pumps or compressors
- F17C2227/0135—Pumps
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2227/00—Transfer of fluids, i.e. method or means for transferring the fluid; Heat exchange with the fluid
- F17C2227/03—Heat exchange with the fluid
- F17C2227/0367—Localisation of heat exchange
- F17C2227/0388—Localisation of heat exchange separate
- F17C2227/0393—Localisation of heat exchange separate using a vaporiser
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2227/00—Transfer of fluids, i.e. method or means for transferring the fluid; Heat exchange with the fluid
- F17C2227/04—Methods for emptying or filling
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2250/00—Accessories; Control means; Indicating, measuring or monitoring of parameters
- F17C2250/06—Controlling or regulating of parameters as output values
- F17C2250/0605—Parameters
- F17C2250/0636—Flow or movement of content
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2270/00—Applications
- F17C2270/01—Applications for fluid transport or storage
- F17C2270/0102—Applications for fluid transport or storage on or in the water
- F17C2270/0105—Ships
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T70/00—Maritime or waterways transport
- Y02T70/50—Measures to reduce greenhouse gas emissions related to the propulsion system
Definitions
- a purpose of the invention is to replace during the transport of crude oil in tankers a part of the bunker oil required for the propulsion of the tanker with gas from the cargo.
- the cost of the bunker oil required for the propulsion of a tanker of 300.000-400.000 tons during a voyage from the oil-producing countries at the Persian Gulf to the refinery plants in Europe amounts at present to 1,3-2,2 million SKr, at which a bunker consumption of 3-900-5.600 tons is estimated, which corresponds to 1-2% of the quantitv of transported crude oil.
- Gas is used for producing so called compressed gas and for producing energy required for the process.
- Crude oils normally contain 1-2 and in certain cases 2-4 percentage by weight of gaseous components (methane to butane). As was previously mentioned the bunker consumption during a transport voyage corresponds to 1-2% of the cargo. A considerable amount of the bunker oil required for the propulsion of the tanker could therefore be replaced by gas, which is taken aboard and is stored dissolved in the crude oil cargo.
- the method according to the invention can also be utilized for energy production in tanker tonnage being laid up and being intended as a stock reserve of crude oil and where the tankers perform the function as an intermediate storage in the crude oil harbours of the refineries.
- the four lightest hydrocarbon compounds of alkane type are methane CH 4 , ethane. C 2 H 6 , propane C 3 H 8 and butane C 4 H 10 . They all have boiling points below 0oC and therefore exist in gaseous state at normal room temperatures. They however are soluble in heavier liquid hydrocarbon compounds, and can therefore exist in a liquid state also at normal ambient temperatures.
- the net transport between the gas phase and the liquid phase can thus be effected e.g. by varying the composition of the gas phase.
- a gas-rich oil is meant an oil being in a state of equilibrium with a gas phase with high partial pressures of low-boiling components. If a decrease of the amount of low-boiling components in a crude oil is desired, this can thus be achieved by keeping the concentration of these compounds in the ambient gas phase low.
- verv big tanks (15.000- 50.000 m 3 ) and the transport of low-boiling components in the liquid phase is slow the outgassing will however take place relatively slowly. In order to increase the outgassing speed it is required besides a ventilation of the gas phase that the liquid phase is agitated and that the interface, through which a transport of low-boiling components can take place, is increased.
- the method according to the invention is based on that inert gas or tank gas is pressed . into the tanks close to the bottom through nozzles, which atomize the gas stream, so that small bubbles are formed. When these bubbles rise through the crude oil they cause an agitation of the oil and an increase of the phase interface gas-oil, whereby the outgassing process is accelerated. By the fact that the gas flow can be adjusted the outgassing process can be controlled.
- the inert gas is taken from so called inert gas plants, which often are provided in modern crude oil tankers. These plants comprise an arrangement of flue gas washer (scrubber), fan, conduits, valves and control means, by aid of which combustion gases from the boilers are scrubbed and is led into the -tanks mainly in connec- tion with the discharging of the cargo.
- the purpose of this procedure is to decrease the oxygen content of the tank-gas below the limit at which a comhustion can be maintained.
- the main components of the inert gas are nitrogen, oxygen (15%), carbon dioxide and water vapour. Other components are nitrogen oxides, carbon monoxide and sulphur dioxide.
- the inert gas flow should not be allowed to be too high.
- the concentration of hydrocarbons in the gas will then be so low that the introduction of the gas in the boilers would involve a poor combustion economy.
- energy is required for heating the inert gas a too extensive ventilation of the crude oil also involves that certain amounts of heavier, valuable fractions are removed from the crude oil.
- the mean molecular weight of the gas is 40
- the inert gas flow required for driving off this quantity of gaseous hydrocarbons from the crude oil depends on a number of factors. Some of them are: a) The amount of gaseous hydrocarbons dissolved in the oil b) The desired concentration of hydrocarbons in the gas phase c) The temperature of the oil d) The method used for introducing the inert gas into the tanks. The number and design of the blower nozzles. If the gas leaving the tanks has a volume ratio hydrocarbons/inert gas between 10/1 to 1/1 an inert gas flow of between 250-2.500 m 3 /hour (about 4-40 m 3 /min) is required for driving off 2.500 m 3 hydrocarbon gas per hour at NTP.
- the inert gas plants in tankers usually have a capacity of at least 10.000 m 3 /hour.
- Figure 1 shows schematically an arrangement for controlling the outgassing from the crude oil in the tanks of a tanker
- Figure 2 and 3 show schematically a system working according to the counter flow principle.
- B denotes a boiler, S a scrubber, FR a flow regulator, K a compressor and D drop separators.
- the outgassing is controlled by leading inert gas and/or tank gas into the tanks at the bottom level thereof.
- a system of ejectors E mounted at the bottom of some tanks and being driven by crude oil flows O. These flows are taken from other tanks in the tanker and are forced with pumps P placed in the pump room of the tanker.
- the ejectors suck inert gas I from the inert gas conduit on deck or tank gas T from the ullage space of the tanks to the bottom level thereof.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Ocean & Marine Engineering (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Flow Control (AREA)
- Separation By Low-Temperature Treatments (AREA)
- Filling Or Discharging Of Gas Storage Vessels (AREA)
Abstract
Methode de degazage controle du petrole brut contenu dans les reservoirs d'un petrolier. Le but est d'utiliser les gaz comme source d'energie, par exemple pour la propulsion du petrolier. Le degazage est accelere en introduisant un gaz inerte (1) et/ou un gaz de reservoir (T) dans les reservoirs avec un debit reglable, produisant ainsi une agitation du petrole et une augmentation de l'interface de la phase liquide-gaz. Compte tenu du fait que le debit est reglable, il est possible de controler le procede de degazage.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE7803962A SE409314B (sv) | 1978-04-10 | 1978-04-10 | Kontrollerad avgasning av raolja i lasttankarna hos ett fartyg |
| SE7803962 | 1978-04-10 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP0016763A1 true EP0016763A1 (fr) | 1980-10-15 |
Family
ID=20334531
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP79900400A Withdrawn EP0016763A1 (fr) | 1978-04-10 | 1979-11-19 | Methode de degazage controle du petrole brut |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP0016763A1 (fr) |
| JP (1) | JPS55500351A (fr) |
| GB (1) | GB2043009B (fr) |
| NO (1) | NO791198L (fr) |
| SE (1) | SE409314B (fr) |
| WO (1) | WO1979000909A1 (fr) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NO823336L (no) * | 1982-10-04 | 1984-04-05 | Moss Rosenberg Verft As | Anordning ved tostoffs-dieselmotor og fremgangsmaater ved drift av tostoffs-dieselmotorer |
| NO304483B1 (no) * | 1996-04-25 | 1998-12-28 | Norske Stats Oljeselskap | FremgangsmÕte for oppfanging av lavmolekylµre, flyktige forbindelser fra hydrokarbonholdige vµsker |
| NO961666L (no) * | 1996-04-25 | 1997-10-27 | Norske Stats Oljeselskap | Fremgangsmåte og system for oppfanging og lagring av lett hydrokarbondamp fra råolje |
| DE102010007328A1 (de) * | 2010-02-08 | 2011-08-11 | Meyer Werft GmbH, 26871 | Seeschiff, insbesondere gasbetriebenes Seeschiff |
| EP3481523A4 (fr) * | 2016-07-11 | 2020-02-26 | Terra Primoris Holdings, LLC | Procédé d'aération d'un liquide inflammable pour extraire de la vapeur inflammable |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3039862A (en) * | 1959-07-13 | 1962-06-19 | Rose B Yocham | Apparatus for producing burnable gas from liquid gasoline |
| DE2109501B2 (de) * | 1971-03-01 | 1973-06-07 | Aktieselskabet Burmeister & Wain's Motor og Maskinfabnk af 1971, Kopen hagen | Antriebsmaschinenanlage fuer tankschiffe zum transport fluessiger, brennbarer gase |
-
1978
- 1978-04-10 SE SE7803962A patent/SE409314B/sv unknown
-
1979
- 1979-04-09 NO NO791198A patent/NO791198L/no unknown
- 1979-04-09 WO PCT/SE1979/000084 patent/WO1979000909A1/fr not_active Ceased
- 1979-04-09 JP JP50064779A patent/JPS55500351A/ja active Pending
- 1979-04-09 GB GB8015769A patent/GB2043009B/en not_active Expired
- 1979-11-19 EP EP79900400A patent/EP0016763A1/fr not_active Withdrawn
Non-Patent Citations (1)
| Title |
|---|
| See references of WO7900909A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| NO791198L (no) | 1979-10-11 |
| SE409314B (sv) | 1979-08-13 |
| JPS55500351A (fr) | 1980-06-19 |
| GB2043009B (en) | 1982-10-06 |
| GB2043009A (en) | 1980-10-01 |
| WO1979000909A1 (fr) | 1979-11-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| AK | Designated contracting states |
Designated state(s): FR |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
|
| 18D | Application deemed to be withdrawn |
Effective date: 19801024 |
|
| RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: SVEDUNG, INGE |