EP0008805B1 - Détergents pour le nettoyage des fours et des grils et procédé pour leur préparation - Google Patents
Détergents pour le nettoyage des fours et des grils et procédé pour leur préparation Download PDFInfo
- Publication number
- EP0008805B1 EP0008805B1 EP19790103370 EP79103370A EP0008805B1 EP 0008805 B1 EP0008805 B1 EP 0008805B1 EP 19790103370 EP19790103370 EP 19790103370 EP 79103370 A EP79103370 A EP 79103370A EP 0008805 B1 EP0008805 B1 EP 0008805B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- carbon atoms
- alkali
- preparation
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 12
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 15
- 239000003513 alkali Substances 0.000 claims description 15
- 125000004432 carbon atom Chemical group C* 0.000 claims description 15
- 239000007787 solid Substances 0.000 claims description 15
- 239000002904 solvent Substances 0.000 claims description 14
- 238000003756 stirring Methods 0.000 claims description 12
- 238000004140 cleaning Methods 0.000 claims description 11
- 239000002736 nonionic surfactant Substances 0.000 claims description 11
- 238000002360 preparation method Methods 0.000 claims description 11
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 10
- 239000007864 aqueous solution Substances 0.000 claims description 10
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 10
- 239000011707 mineral Substances 0.000 claims description 10
- 239000003960 organic solvent Substances 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- XPFVYQJUAUNWIW-UHFFFAOYSA-N furfuryl alcohol Chemical compound OCC1=CC=CO1 XPFVYQJUAUNWIW-UHFFFAOYSA-N 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 8
- 239000004094 surface-active agent Substances 0.000 claims description 8
- 150000002191 fatty alcohols Chemical class 0.000 claims description 7
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 7
- 150000001412 amines Chemical class 0.000 claims description 6
- 238000005260 corrosion Methods 0.000 claims description 5
- 230000007797 corrosion Effects 0.000 claims description 5
- 239000003205 fragrance Substances 0.000 claims description 5
- 239000003112 inhibitor Substances 0.000 claims description 5
- -1 alkyl phenols Chemical class 0.000 claims description 4
- 239000000975 dye Substances 0.000 claims description 4
- 150000002334 glycols Chemical class 0.000 claims description 4
- 239000010453 quartz Substances 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- BSYVTEYKTMYBMK-UHFFFAOYSA-N tetrahydrofurfuryl alcohol Chemical compound OCC1CCCO1 BSYVTEYKTMYBMK-UHFFFAOYSA-N 0.000 claims description 4
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 3
- 239000001089 [(2R)-oxolan-2-yl]methanol Substances 0.000 claims description 3
- 125000002947 alkylene group Chemical group 0.000 claims description 3
- 239000004579 marble Substances 0.000 claims description 3
- 238000006386 neutralization reaction Methods 0.000 claims description 3
- 229920000151 polyglycol Polymers 0.000 claims description 3
- 239000010695 polyglycol Substances 0.000 claims description 3
- 125000005270 trialkylamine group Chemical group 0.000 claims description 3
- 229940092714 benzenesulfonic acid Drugs 0.000 claims 3
- 229910001854 alkali hydroxide Inorganic materials 0.000 claims 2
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims 2
- 150000004996 alkyl benzenes Chemical class 0.000 claims 2
- 150000002170 ethers Chemical class 0.000 claims 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 1
- 229940077388 benzenesulfonate Drugs 0.000 claims 1
- 239000011591 potassium Substances 0.000 claims 1
- 229910052700 potassium Inorganic materials 0.000 claims 1
- 239000012459 cleaning agent Substances 0.000 description 21
- 239000003518 caustics Substances 0.000 description 9
- 239000002253 acid Substances 0.000 description 7
- 238000003860 storage Methods 0.000 description 7
- 230000000694 effects Effects 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 238000007792 addition Methods 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 235000013312 flour Nutrition 0.000 description 3
- 238000011065 in-situ storage Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 2
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 description 2
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 description 1
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 241000467686 Eschscholzia lobbii Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- AMLAIYYMUZUOGT-UHFFFAOYSA-N N-methyl-N-pentadecylhydroxylamine Chemical compound CCCCCCCCCCCCCCCN(C)O AMLAIYYMUZUOGT-UHFFFAOYSA-N 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 description 1
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical group CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000010794 food waste Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000011086 high cleaning Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229920003145 methacrylic acid copolymer Polymers 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- ONHFWHCMZAJCFB-UHFFFAOYSA-N myristamine oxide Chemical compound CCCCCCCCCCCCCC[N+](C)(C)[O-] ONHFWHCMZAJCFB-UHFFFAOYSA-N 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0057—Oven-cleaning compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/0013—Liquid compositions with insoluble particles in suspension
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/06—Hydroxides
Definitions
- the invention relates to highly alkaline storage stable oven and grill cleaning agents in the form of sprayable viscous aqueous solutions.
- the invention also relates to a method for producing these agents.
- Strongly alkaline cleaning agents containing caustic alkali are usually used to clean heavily soiled ovens, grills, grates, deep fryers, tilting frying pans in the household and in catering, which are contaminated with firmly dried or burnt-on food residues. It is desirable to thicken such cleaning agents so that they adhere to vertical surfaces sufficiently long to effectively soften or dissolve the dirt so that it can be removed without effort by simply wiping the surface.
- DE-B 1 924 332 discloses oven and grill cleaning agents in the form of viscous aqueous solutions or pastes based on caustic alkalis, surfactants and water-miscible organic solvents and solubilizers which contain acrylic acid and / or methacrylic acid copolymers as alkali-soluble thickeners .
- These cleaning agents are stable in storage, so they retain their viscosity and are characterized by their high cleaning effectiveness. However, they can only be sprayed onto bottles to be cleaned discontinuously from bottles with a relatively large opening. They are preferably applied with the help of brushes, sponges, rags, brushes or similar aids. However, this type of application is too labor-intensive when cleaning larger areas.
- the object of the present invention was therefore to find a cleaning agent which is at least as effective, but which can be sprayed onto the surfaces to be cleaned more easily and practically continuously by means of manually operated pumps, and nevertheless, due to its viscosity, also for a sufficiently long time for the cleaning action vertical surfaces.
- alkaline cleaning agents containing surfactants, solvents and solubilizers can also be applied to the surfaces to be cleaned in the form of aerosol foam which adheres for a long time.
- fuels and spray cans the use of which, as is well known, does not receive undivided approval.
- aqueous, strongly alkaline solutions made from alkalis, nonionic surfactants, solvents containing hydroxyl groups and water can be thickened permanently without using organic polymers, and yet can be sprayed excellently by hand pumps if free alkylbenzenesulfonic acids are added to them and from them with excess added Alkali forms the known anionic surfactants in situ.
- the agents can also contain additions of a finely divided mineral solid and, if appropriate, colorants and fragrances and corrosion inhibitors. They also retain their viscosity after long storage.
- the invention further relates to a process for the preparation of storage-stable, viscous aqueous oven and grill cleaning agents based on alkalis, surfactants and water-miscible organic solvents, which is characterized in that the aqueous solution of a free C 8 -C 18 -alkylbenzenesulfonic acid is passed through at room temperature Addition of an aqueous solution of an alkali is initially neutralized with stirring and then further alkali, nonionic surfactants and water-miscible organic solvents and, if appropriate, customary auxiliaries are also added at room temperature with stirring.
- finely divided mineral solids are also added. These solids are first dispersed in part of the water content of the agents. The free alkylbenzenesulfonic acid is then added with stirring and the procedure is as described above.
- the grill cleaning agents according to the invention are not real solutions, but are slightly cloudy or opaque, but viscous liquids which remain homogeneous.
- the solid-containing variants are homogeneous suspensions, which either do not separate at all or only so weakly after long storage that they are homogenized again by shaking gently before use.
- the claimed agents are applied by spraying in commercially available hand pumps onto the dirty, warm or already cooled inner surfaces of the ovens and the like. After an exposure time of about 10 to 60 minutes, the soiling can be easily rinsed off with water, to which small amounts of acetic acid are expediently added to neutralize the cleaning agent.
- the claimed cleaning agents are produced by simple mixing at room temperature.
- the free alkylbenzenesulfonic acid is placed in aqueous solution and first neutralized by adding the required amounts of a 30-50% solution of the desired caustic alkali or caustic alkali and amine, the addition and stirring mechanism being designed so that no lumps are formed through neutralization. Then you give the excess proportion of caustic alkali or caustic alkali and amine solution like the rest of the recipe ingredients, stir in succession. If, in the particular embodiment, a mineral solid is added, it is first dispersed in water, then the alkylbenzenesulfonic acid is added with stirring and the procedure is as described above.
- a grill and oven cleaner is prepared as described above by mixing the following components at room temperature
- the product has a viscosity of 670 mPa.s. After 3 months of storage at room temperature, the product was still completely homogeneous and the viscosity unchanged.
- the product could be sprayed using a commercially available hand pump and cleaned greasy and mixed soiling on vertical surfaces better than a commercially available, low-viscosity grill cleaning agent with the same potassium hydroxide content.
- a grill cleaner was made from the following components:
- the product had a permanent viscosity of 430 mPa.s, could be sprayed and showed a very good cleaning effect on vertical surfaces.
- the product has a permanent viscosity of 800 mPa.s, shows an excellent cleaning effect, can be sprayed and has a shelf life of more than one year.
- a grill cleaner was made from the following components:
- the product has a viscosity of 750 mPa.s, a very good cleaning effect even on vertical surfaces and can be sprayed with hand pumps just as well after 3 months of storage as immediately after production.
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Claims (15)
1. Agents de nettoyage de fours de cuisson et de grills qui sont aqueux, visqueux et stables à l'entreposage et à base d'alcalis, de tensioactifs et de solvants organiques miscibles avec l'eau, caractérisés par une teneur
a) de 0 à 10, de préférence de 1 à 5% en poids d'une matière solide minérale finement divisée,
b) de 3 à 20, de préférence de 4 à 10% en poids d'un alcali,
c) de 5 à 15, de préférence de 5 à 10% en poids d'un alcoyl(Ca-C1a)benzène-sulfonate,
d) de 3 à 12, de préférence de 3 à 8% en poids d'un tensioactif non ionique,
e) de 5 à 15, de préférence 5 à 10% en poids d'un solvant organique contenant des groupes hydroxyle,
f) le restant pour faire 100% en poids étant de l'eau et autres substances auxiliaires en usage.
2. Agents selon la revendication 1, caractérisés en ce qu'ils contiennent comme matières solides minérales finement divisées de la farine de silicate, de quartz ou de marbre ayant des granulométries entre > 0 et 100 lim.
3. Agents selon les revendications 1 et 2, caractérisés en ce qu'ils contiennent comme alcalis des hydroxydes alcalins, de préférence de l'hydroxyde de potassium.
4. Agents selon les revendications 1 à 3, caractérisés en ce qu'ils contiennent comme tensioactifs non ioniques des produits d'addition de 4 à 20 moles d'oxyde d'alcoylène, de préférence d'oxyde d'éthylène, sur des alcools gras ayant 8 à 20 et/ou sur des alcoylphénols ayant 8 à 15 atomes de carbone dans le radical alcoyle, de même qu'éventuellement en plus des oxydes de trialcoylamines tertiaires de formule générale R1R2R3N→O, où R1 signifie un radical alcoyle ayant 8 à 20, de préférence 12 à 18 atomes de carbone et R2 de même que R3 signifient des radicaux alcoyle identiques ou différents ayant 1 à 4, de préférence 1 à 2 atomes de carbone.
5. Agents selon les revendications 1 à 4, caractérisés en ce qu'ils contiennent comme solvants contenant des groupes hydroxyle des glycols, leurs éthers avec des alcanols en C,-C4, des polyglycols ayant des poids moléculaires d'environ 200 à 600, de l'alcool furfurylique, de l'alcool tétrahydrofurfurylique ou des mélanges de ces solvants.
6. Agents selon les revendications 1 à 5, caractérisés en ce qu'ils contiennent en outre d'autres substances auxiliaires usuelles, en particulier des colorants et des parfums et des inhibiteurs de corrosion.
7. Procédé de fabrication d'agents de nettoyage pour fours de cuisson et grills qui sont aqueux, visqueux et stables à l'entreposage et à base d'alcalis, de tensioactifs et de solvants organiques miscibles à l'eau selon les revendications 1 à 6, caractérisé en ce qu'on neutralise tout d'abord la solution aqueuse d'un acide alcoylbenzène-sulfonique libre à la température ordinaire par l'addition d'une solution aqueuse d'un alcali tout en agitant puis, également à la température ordinaire, on ajoute sous agitation un supplément d'alcali, des tensioactifs non ioniques et des solvants organiques miscibles avec l'eau.
8. Procédé selon les revendications 1 à 7, caractérisé en ce que tout d'abord on disperse une matière solide minérale finement divisée dans de l'eau, puis on ajoute sous agitation l'acide alcoylbenzène-sulfonique libre et à la température ordinaire on le neutralise tout d'abord par addition d'une solution aqueuse à 30-50% d'un alcali sous agitation et l'on ajoute ensuite, de même à la température ordinaire et sous agitation, de nouveau de l'alcali, des tensioactifs non ioniques et des solvants organiques miscibles avec l'eau.
9. Procédé selon les revendications 1 à 8, caractérisé en ce qu'après la neutralisation on ajoute encore d'autres substances auxiliaires usuelles, en particulier des colorants, des parfums et/ou des inhibiteurs de corrosion.
10. Procédé selon les revendications 1 à 9, caractérisé en ce que pour 100% en poids de l'agent total on utilise 0 à 10, de préférence 1 à 5% en poids d'une matière solide minérale finement divisée, 5 à 15, de préférence 5 à 10% en poids d'un acide alcoyle(C8-C18)benzène-sulfonique, 3 à 20, de préférence 4 à 10% en poids d'un alcali, 3 à 12, de préférence 3 à 8% en poids d'un tensioactif non ionique, 5 à 15% en poids, de préférence 5 à 10% en poids d'un solvant contenant des groupes hydroxyle, le restant étant de l'eau ainsi qu'éventuellement de faibles quantités d'autres auxiliaires usuels, en particulier des colorants, des parfums et/ou des inhibiteurs de corrosion.
11. Procédé selon les revendications 1 à 6 et 8 à 10, caractérisé en ce qu'on utilise comme matières solides minérales finement divisées de la farine de silicate, de quartz ou de marbre.
12. Procédé selon les revendications 7 à 11, caractérisé en ce qu'on utilise comme alcalis des hydroxydes alcalins, de préférence de l'hydroxyde de potassium, qui peuvent être remplacés jusqu'à concurrence de 50% de leur poids par des amines organiques à poids moléculaire inférieur ayant 2 à 6 atomes de carbone.
13. Procédé selon les revendications 7 à 12, caractérisé en ce qu'on utilise comme tensioactifs non ioniques des produits d'addition de 4 à 20 moles d'oxyde d'alcoylène, de préférence d'oxyde d'éthylène, sur des alcools gras ayant 8 à 20 et/ou des alcoyl phénols ayant 8 à 15 atomes de carbone dans le radical alcoyle de même qu'éventuellement en plus des oxydes de trialcoylamines tertiaires de formule générale R1R2R3N→O où R, représente un radical alcoyle ayant 8 à 20, de préférence 12 à 18 atomes de carbone et R, de même que R3 représentent des radicaux alcoyle identiques ou différents ayant 1 à 4, de préférence 1 à 2 atomes de carbone.
14. Procédé selon les revendications 7 à 13, caractérisé en ce qu'en tant que solvant contenant des groupes hydroxyle on utilise des glycols, leurs éthers avec des alcanols en C1-C4, des polyglycols ayant des poids moléculaires d'environ 200 à 600, de l'alcool furfurylique, de l'alcool tétrahydrofurfurylique ou des mélanges de ces solvants.
15. Agent de nettoyage pour fours de cuisson et grills, qui est aqueux, visqueux et stable à l'entreposage, consistant en
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19782839857 DE2839857C3 (de) | 1978-09-13 | 1978-09-13 | Backofen- und Grillreinigungsmittel und Verfahren zu ihrer Herstellung |
| DE2839857 | 1978-09-13 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0008805A1 EP0008805A1 (fr) | 1980-03-19 |
| EP0008805B1 true EP0008805B1 (fr) | 1982-05-05 |
Family
ID=6049357
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP19790103370 Expired EP0008805B1 (fr) | 1978-09-13 | 1979-09-10 | Détergents pour le nettoyage des fours et des grils et procédé pour leur préparation |
Country Status (2)
| Country | Link |
|---|---|
| EP (1) | EP0008805B1 (fr) |
| DE (1) | DE2839857C3 (fr) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3065274D1 (en) * | 1979-06-29 | 1983-11-17 | Procter & Gamble | Abrasive-containing liquid detergent compositions and non-clogging dispensing package therefor |
| US4600522A (en) * | 1982-01-22 | 1986-07-15 | At&T Technologies, Inc. | Detergent cleaning composition |
| US4686065A (en) * | 1986-05-23 | 1987-08-11 | Miles Laboratories, Inc. | Caustic based cleaning composition containing THFA and a propoxylated alcohol or phenol |
| AU4702289A (en) * | 1989-01-19 | 1990-07-26 | Sterling Drug Inc. | Hard surface cleaning composition |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1462127A (fr) * | 1965-03-09 | 1966-02-25 | Reckitt & Colman Overseas | Nouvelles compositions de nettoyage de fours de cuisine, sous forme d'aérosols |
| US3644210A (en) * | 1968-03-15 | 1972-02-22 | Chemed Corp | Oven cleaner |
| DE1924332A1 (de) * | 1969-05-13 | 1970-11-19 | Henkel & Cie Gmbh | Backofen- und Grillreiniger |
| GB1346184A (en) * | 1971-03-17 | 1974-02-06 | Unilever Ltd | Detergent composition |
| GB1534680A (en) * | 1977-10-14 | 1978-12-06 | Colgate Palmolive Co | Cleaning compositions |
-
1978
- 1978-09-13 DE DE19782839857 patent/DE2839857C3/de not_active Expired
-
1979
- 1979-09-10 EP EP19790103370 patent/EP0008805B1/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| EP0008805A1 (fr) | 1980-03-19 |
| DE2839857A1 (de) | 1980-03-27 |
| DE2839857C3 (de) | 1982-03-25 |
| DE2839857B2 (de) | 1981-06-19 |
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