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EP0098771B1 - Process for the production of form coke in a shaft furnace, and shaft furnace for carrying out the process - Google Patents

Process for the production of form coke in a shaft furnace, and shaft furnace for carrying out the process Download PDF

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Publication number
EP0098771B1
EP0098771B1 EP83401306A EP83401306A EP0098771B1 EP 0098771 B1 EP0098771 B1 EP 0098771B1 EP 83401306 A EP83401306 A EP 83401306A EP 83401306 A EP83401306 A EP 83401306A EP 0098771 B1 EP0098771 B1 EP 0098771B1
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EP
European Patent Office
Prior art keywords
oven
zone
electrodes
coke
burden
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EP83401306A
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German (de)
French (fr)
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EP0098771A1 (en
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Gérald Namy
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Individual
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/08Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form in the form of briquettes, lumps and the like
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B19/00Heating of coke ovens by electrical means

Definitions

  • the invention relates to a method for manufacturing coke molded in a shaft furnace and the corresponding shaft furnace.
  • a process is known for manufacturing coke molded in a tank furnace where coal balls are introduced into the tank furnace, at its upper part, to constitute a bed circulating from top to bottom through the furnace over its entire height.
  • coal balls are in contact with hot gases passing through the oven from bottom to top.
  • the upper part of the oven constitutes a balanced exchanger in which the bed of solids is dried and heated to a certain temperature and the circulating gases cooled before their exit to the upper part of the oven.
  • the middle part of the oven constitutes the coking zone in which heat is supplied to the bed of circulating solid materials, for example by means of burners.
  • This addition of heat can be carried out by combustion of part of the gases circulating in the shaft furnace, by means of oxidizing air introduced at the level of the central zone.
  • Coal balls liberate in particular at the time of their coking combustible gases coming from volatile materials of coal.
  • This process has the drawback of requiring the coke to overheat up to a temperature in the region of 1,400 ° C.
  • the coke temperature in conventional coke ovens does not exceed 1,200 ° C.
  • the FR.A. patent has also been proposed. 628 168, to use electrically heated ovens, with gas circulation against the current of solid materials, for cooking coke in order to manufacture electrodes.
  • the invention proposes, on the other hand, a process for manufacturing mold coke in which the heating of the charge is carried out by observing a heating law determined according to the nature of the coal so as to avoid the formation of clusters and to preserve the shape of the balls until the end of the treatment, in particular by avoiding their bursting and their overheating.
  • a known kiln is used, at the top of which coking charcoal balls are introduced which constitute a moving bed descending into the furnace against the gas flow passing through the furnace from bottom to top. , part of which consists of gases recovered at the top of the oven and recycled at its bottom and another part of which consists of the gases released by the coal during its heating and coking, a supply of heat being effected by passing electric currents through the bed of solids.
  • electrical heating is carried out in a controlled manner, in the central zone of the furnace over a determined height, by passing electrical currents, the intensities of which can be individually adjusted, in several horizontal planes of the load, by adjusting the heat exchanges between the solid charge and by adjusting the gas circulation and the electric power distributed over the different electrode levels according to the heat requirements and the electrical resistance of the charge, progressive heating is controlled and homogeneous thereof during its descent into the oven according to a heating law chosen according to the nature of the coal to maintain the shape of the balls, so that the temperature of the bed of solid material is between 600 ° C.
  • an adjustable flow rate of the rising current of hot gases is derived, so as to control a gradual rise in temperature of the materials at a speed chosen according to the nature of the coal for avoid melting or sticking of the balls.
  • the electrical resistance of the charge is increased after leaving the central coking zone by decompressing the charge in the cooling zone, capable of increasing the contact resistances between the balls.
  • the charcoal balls introduced into the upper part of the oven are mixed with particles of small coke or any other electrically conductive product, unalterable at temperatures reached in the oven and being in the form of grains of dimensions smaller than those of the coal balls, said grains being distributed homogeneously in the interstices between the balls.
  • the cell furnace for implementing the method according to the invention comprises at least two pairs of superposed electrodes, placed in horizontal planes spaced apart from one another and whose electrical supply voltages are individually adjustable by pair.
  • the electrodes placed in at least one of the horizontal planes are mounted movable horizontally and each connected to alternate advancing and reversing means, each electrode exerting constant pressure on the charge by progressive advancement towards the interior of the oven to a determined position from which a rapid reverse is controlled accompanied by a descent of the load and followed by a new advancement.
  • This mouthpiece is of a type similar to that of blast furnace mouths and allows, by means of a device 4, the recovery of gases at the upper part of the shaft furnace.
  • the gueulard is completely waterproof and avoids the entry of atmospheric air.
  • hoppers and rotary evacuators 5 allow a regular outlet of the coke reaching the bottom of the furnace.
  • a moving bed 6 of solid materials moves continuously in the oven.
  • the upper surface 60 of this bed of solids is maintained at a substantially constant level by introduction of coal balls thanks to the jaw 3 at a flow rate identical to the coke outlet flow rate.
  • a first set of electrodes 7 is introduced into the furnace through its upper part. These electrodes can be adjusted in height, so that the level of the plane AA in which electric currents of horizontal direction circulate between the electrodes can be adjusted by vertical displacement of all of the upper electrodes.
  • these electrodes comprise a conductive part 10 constituted by a graphite plate crimped in a piece of refractory steel 11.
  • the pieces 11 of refractory steel are connected to support tubes 12 also in refractory steel constituting conductors serving to bring the current to the end of the electrodes 7. Cooling air possibly circulates inside these tubes and comes to cool, at their lower part, the part 11 for fixing the conductive part 10.
  • Blocks of refractory material 14 make it possible to isolate the suspension and supply tubes from the current 12 from the bed of solid materials and from the high temperature gases circulating in the furnace.
  • the electrodes 7 plunge into the bed of solid materials to a depth of approximately 1.5 meters below the surface of the level 60. This depth of introduction of the electrodes can be adjustable.
  • These electrodes consist of blocks of graphite housed in the refractory located between the two walls 1 and 2 of the furnace and slightly projecting in the interior space of the furnace.
  • these electrodes are movable horizontally so as to exert a constant thrust on the load.
  • each electrode 8 can be mounted on a carriage 81 movable horizontally for example by means of a jack 82 at constant pressure.
  • the forward movement towards the inside of the furnace is limited in its course so that the electrodes 8 extend a few centimeters beyond the internal face of the wall 2 of the furnace.
  • the jack 82 then commands a rapid retreat of the electrode which is accompanied by a descent of the mstaires located above and the advance movement can resume.
  • An easy-to-design system compensates for the wear of electrode 8.
  • a gas recovery and treatment circuit 15 is connected on the one hand to the gas recuperator 4 at the upper part of the oven and on the other hand to the lower part of the oven by an injection pipe. 18.
  • the circuit can advantageously include equipment 19 limiting the vapor content water from the recycled gas and constituted for example by an exchanger lowering the dew point of the gas by cooling.
  • a valve 20 makes it possible to regulate the injection of gas at the base of the furnace and to direct a part of this gas towards a storage tank or a circuit of use.
  • the oven comprises several nivesux of electrodes 8 placed in horizontal planes staggered along the middle zone C and the power supply of which, not shown in the figure, can be adjusted individually in each plane, depending on the electrical power desirable for the realization of the heating law.
  • the required area of electrodes is determined by the intensity of the electric current to be circulated in the mass so as to avoid overheating.
  • the total surface area of the electrodes is therefore significant. But it is necessary that a ball does not stay too long under a strong intensity. There will therefore be a number of electrodes constituting horizontal planes and of small thickness.
  • the current voltage can be adjusted by group of electrodes according to the heating law.
  • the furnace 1 has a rectangular section allowing the modular production of an installation made up of adjoining cells.
  • the furnace is provided with means making it possible to divert part of the ascending current of hot gases and which can for example consist of a double side wall 21 providing a space for the circulation of gases which is effected by the difference in pressure drop between the two internal and peripheral circuits respectively thus formed.
  • a shutter system makes it possible to adjust the pressure drop and therefore the gas flow in the main circuit.
  • the oven has a greater width and is further crossed by horizontal bars 22 lined with refractory and possibly internally cooled and which extend from one wall to the other.
  • the extraction of the products at the base 5 of the furnace therefore ensures a decompression of the charge at the outlet of the coking zone C. 11 this results in an increase in the resistances of contact which reduces the flow of electric current from the start of the cooling zone. This limits downward the electric heating zone C.
  • FIG. 5 gives an example of a heating law and of the respective temperatures of the materials (indicated on the abscissa) according to the height of the oven (indicated on the ordinate).
  • the solid line curve gives the temperature of the solids and the dotted line the gas temperature.
  • a charcoal charge consisting of briquettes or balls of usual dimensions (for example: 40 x 25 x 20 mm) mixed with small coke with a particle size ranging from 5 to 15 mm .
  • This small coke is previously distributed homogeneously in the balls, in a suitable proportion, for example: 10% by weight or 19% by volume.
  • the small coke could be replaced by any equivalent product, of the same size, that is to say conductive of electricity and unalterable at the temperatures practiced in the gaseous medium considered).
  • This small coke is partially lodged between the coal balls, occupying the interstices of the charge.
  • the charcoal balls consist of a mixture of lean or flaming dry coal associated with fatty or flaming coals mixed with a binder consisting of pitch (possibly mixed with tar).
  • the homogenized mixture descends into the oven against the flow of gases and reaches the lower part of the upper exchanger of the oven at a temperature close to 850 ° C.
  • the coal balls are therefore dried and then heated so that their temperature is close to 800 ° C. at the outlet of the upper exchanger from the shaft furnace.
  • the gas flow rate and the heating of the furnace are regulated according to the flow rate of solid materials to obtain the adequate heat exchanges.
  • the temperature of the balls at the outlet of the upper exchanger P must, in practice, be higher than 700 ° C. so that the flow of the current occurs in a suitable manner and not exceed 850 ° C. for that the thermal efficiency of the operation is good.
  • the particles of small coke inserted between the coal balls favor the passage of the current in the bed of solid matter circulating in the furnace by multiplying the points of contact.
  • Raw balls as introduced into the shaft furnace are not very conductive of electricity. However, from a certain degree of devolatilization, the internal resistivity of these balls quickly decreases. For example at 800 ° C the measurements have shown that these balls have an internal resistivity which does not exceed 1500 ⁇ / 0m. Thus, by controlling the temperature rise of the balls in the preheating zone P, one limits upwards the zone C of electric heating.
  • the method according to the invention makes it possible to reduce the risk of overheating since it is easier to regulate the temperature of the electric heating by distributing it in several successive horizontal sections of the oven.
  • the small coke mixed with the balls of raw coal before being introduced into the oven is recovered at the base of the oven by screening the coke balls produced.
  • This small coke has not undergone any transformation throughout its passage through the furnace. Its role is limited to reducing the contact resistances between the carbon balls and obtaining a more homogeneous heating of the load.
  • the bed of solids On entering the central electric heating zone of the furnace lying essentially between the two planes A and B of the electrodes, the bed of solids has a very uniform temperature, on the one hand because of the movement of the charge of solids crossing the electrode area and subjected to Joule heating of the currents which cross it, resulting from the multiple contacts established by the grains of small coke distributed in the balls and which constantly change position, and on the other hand because of the circulation gases in this area.
  • electrodes arranged as shown in FIG. 4 are used. ie about 3.5 m apart.
  • Electrodes are supplied with a voltage which is preferably continuous and regulated for a power kept constant and give off a total power of 1,500 kw for example. This power is distributed between the various levels of electrodes so as to obtain the desired heating law.
  • This thermal power of electrical origin makes it possible to increase the temperature of the solid materials from 800 to 1,050 ° C. approximately in zone C of electric heating.
  • the gases injected at the base of the furnace through line 18 make it possible to cool the coke produced from the outlet temperature from the middle zone, that is to say a temperature close to 1000 ° C. to a temperature close to 150 ° vs.
  • the gas produced in the oven is recovered at the top, dusted and tared before being introduced into the oven through line 18.
  • an excess quantity of combustible gas is produced depending on the nature of the charcoals used, for example 500 m 3 per tonne of coke produced.
  • the calorific value of this gas is around 18810J / m 3 (4500 calories per m 3 ),
  • Electric power consumption is around 150 kWh per tonne of coke produced.
  • Coking therefore occurs at a relatively moderate temperature and generally a little lower than the coking temperature in conventional coke ovens.
  • the setting of the electric heating according to the flows of solids and gases may vary somewhat but to obtain a good thermal efficiency and optimal coking conditions, the maximum temperature of the bed of solids in the electric heating zone should not exceed a value between 950 and 1150 ° C.
  • the balance concerning the energy consumption in the process according to the invention is entirely favorable if it is compared to what it is for conventional coke ovens.
  • the main advantages of the process according to the invention are to allow a reduction in the energy consumption for the production of coke and the recovery of a gas with high calorific value which can be produced continuously.
  • the thermal adjustment of the process can be carried out in a simple manner, so that the exchanges between the gases and the solid materials are balanced and that the calorific contribution by electrical energy is used practically only to compensate for the heat losses of the furnace and the heat of endothermic reactions that can occur in the oven.
  • the flexibility of this type of oven makes it possible to modulate the consumption of electric current with load shedding during peak hours.
  • the thermal adjustment conditions may vary within the intervals mentioned.
  • the shape of the straight section of the oven is not necessarily square or rectangular but can also be circular.
  • the shape of the electrodes, their arrangement and their spacing can be variable depending on the shape of the oven and the desired heating conditions.
  • the gases recovered at the top of the furnace undergo treatments which depend on their end use.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Coke Industry (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Manufacture Of Iron (AREA)

Abstract

1. Process for producing moulded coke in a shaft oven with a vertical axis (1), which is supplied in its upper part (3) with a burden of coal for coking in the form of ovoids, forming a movable bed descending in the shaft (1) in counter flow to gas circulating from the bottom upwards and passing successively from the top downwards through a preheating zone, a coking zone and a cooling zone, the rising stream of gas being formed by the gases released by the coal during its heating and coking and by some of the gases recovered in the upper part of the oven and recycled in the lower part after washing and dust extraction, heat being supplied by circulation of electrical current through the bed of solid materials between electrodes (8) located on two opposite sides of the wall (2) of the oven (1), characterized in that the electrical heating is carried out in a controlled way over a specific height in the middle part (C) of the oven (1), electric currents, the intensities of which can be regulated, being passed through the burden in several staggered horizontal planes, and in that, by adjustment of the circulation of the gases and of the electrical power distributed to the various levels of electrodes according to the heat requirements and the electrical resistance of the burden, a progressive and uniform heating of the latter is controlled during its descent in the oven according to a law of heating selected as a function of the type of coal, to preserve the shape of the ovoids, in such a way that the temperature of the bed of solid material is between 600 degrees C and 850 degrees C at the entrance of the middle zone (C) of electrical heating and that coking is carried out completely in this zone (C) at a temperature remaining between 950 degrees C and 1150 degrees C, the coke ovoids subsequently being cooled in the lower part of the oven (1).

Description

L'invention concerne un procédé de fabrication de coke moulé dans un four à cuve et le four à cuve correspondant.The invention relates to a method for manufacturing coke molded in a shaft furnace and the corresponding shaft furnace.

On connaît un procédé de fabrication de coke moulé dans un four à cuve où des boulets de charbon sont introduits dans le four à cuve, à sa partie supérieure, pour constituer un lit circulant de haut en bas à travers le four sur toute sa hauteur.A process is known for manufacturing coke molded in a tank furnace where coal balls are introduced into the tank furnace, at its upper part, to constitute a bed circulating from top to bottom through the furnace over its entire height.

Pendant leur circulation à l'intérieur du four, ces boulets de charbon sont en contact avec des gaz chauds traversant le four de bas en haut.During their circulation inside the oven, these coal balls are in contact with hot gases passing through the oven from bottom to top.

La partie supérieure du four constitue un échangeur équilibré dans lequel le lit de matières solides est séché et chauffé jusqu'à une certaine température et les gaz en circulation refroidis avant leur sortie à la partie supérieure du four.The upper part of the oven constitutes a balanced exchanger in which the bed of solids is dried and heated to a certain temperature and the circulating gases cooled before their exit to the upper part of the oven.

La partie médiane du four constitue la zone de cokéfaction dans laquelle on apporte de la chaleur au lit de matières solides en circulation, par exemple grâce à des brûleurs.The middle part of the oven constitutes the coking zone in which heat is supplied to the bed of circulating solid materials, for example by means of burners.

Cet apport de chaleur peut être effectué par combustion d'une partie des gaz en circulation dans le four à cuve, grâce à de l'air comburant introduit au niveau de la zone médiane.This addition of heat can be carried out by combustion of part of the gases circulating in the shaft furnace, by means of oxidizing air introduced at the level of the central zone.

Dans ce cas, on recycle après dégoudronnage et dépoussiérage une partie au moins des gaz s'échappant au gueulard du four à cuve,en réinjectant ces gaz à l'extrémité inférieure de sortie des produits solides, à la base du four à cuve.In this case, at least part of the gases escaping from the top of the shaft furnace are recycled after taring and dusting, by reinjecting these gases at the lower end of the outlet for solid products, at the base of the shaft furnace.

La partie inférieure du four à cuve, en dessous de la zone médiane, constitue un second échangeur thermique équilibré où les matières solides cokéfiées dans la zone médiane sont refroidies par les gaz injectés à la partie inférieure du four à cuve. Les gaz sont donc à haute températurelorsqu'ils parviennent dans la zone médiane de chauffage et de cokéfaction.The lower part of the shaft furnace, below the middle zone, constitutes a second balanced heat exchanger where the solid materials coked in the middle zone are cooled by the gases injected into the lower part of the shaft furnace. The gases are therefore at a high temperature when they reach the middle zone of heating and coking.

Les boulets de charbon libèrent en particulier au moment de leur cokéfaction des gaz combustibles provenant des matières volatiles du charbon.Coal balls liberate in particular at the time of their coking combustible gases coming from volatile materials of coal.

Ces gaz ont une grande valeur industrielle, puisqu'ils peuvent être récupérés, traités et réutilisés soit dans le four à cuve lui-même, soit pour d'autres usages.These gases have great industrial value, since they can be recovered, treated and reused either in the shaft furnace itself, or for other uses.

Cependant, l'injection d'air comburant pour provoquer la combustion d'une partie des gaz en circulation dans le four à cuve est la bause de la présence dans les gaz récupérés au gueulard du four d'une proportion importante d'azote qui diminue le pouvoir calorifique du gaz. Il faut également traiter de plus grandes quantités de gaz, ce qui entraine un coût plus important de ce gaz récupéré. C'est ainsi que, pour chaque tonne de coke produite, on se trouve en présence d'un excédent de gaz dû aux matières volatiles du charbon et à l'air injecté, d'environ 680 m3 à 800 m3 suivant la nature des charbons traités.However, the injection of combustion air to cause the combustion of part of the gases circulating in the shaft furnace is the reason for the presence in the gases recovered from the furnace top of a large proportion of nitrogen which decreases the calorific value of the gas. It is also necessary to treat larger quantities of gas, which entails a higher cost of this recovered gas. Thus, for each tonne of coke produced, we are in the presence of an excess of gas due to the volatile matter of the coal and the injected air, of approximately 680 m 3 to 800 m 3 depending on the nature treated coals.

D'autre part, la maîtrise du procédé, en ce qui concerne le réglage thermique, est relativement difficile à obtenir.On the other hand, control of the process, as far as thermal adjustment is concerned, is relatively difficult to obtain.

Il faut en effet régler la température dans la zone de cokéfaction de façon relativement précise et éviter que l'air introduit pour la combustion du gaz et l'apport thermique dans la zone médiane du four n'oxyde une partie du carbone des boulets, ce qui se ferait au détriment du rendement et de l'efficacité de l'opération de cokéfaction.It is indeed necessary to adjust the temperature in the coking zone in a relatively precise manner and to prevent the air introduced for the combustion of the gas and the heat supply in the central zone of the furnace from oxidizing part of the carbon of the balls, this which would be at the expense of the efficiency and effectiveness of the coking operation.

On a donc proposé pour la production simultanée de coke et de gaz combustible d'effectuer l'apport de chaleur dans le four à cuve grâce à des électrodes traversant les parois du four et venant en contact avec le lit de matières solides en circulation. Un courant électrique de forte intensité peut ainsi traverser le lit de matières solides et produire un dégagement de chaleur par effet Joule.It has therefore been proposed for the simultaneous production of coke and combustible gas to carry out the supply of heat in the shaft furnace by means of electrodes passing through the walls of the furnace and coming into contact with the bed of circulating solid materials. A strong electric current can thus cross the bed of solid materials and produce a heat release by Joule effect.

Un tel procédé est décrit par exemple dans le brevet français 997.058 où une zone de chauffage électrique est ménagée dans le four, en dessous de la zone de cokéfaction. Le coke produit est ainsi porté à très haute température par chauffage électrique et les gaz venant de la base du four qui traversent cette zone s'échauffent fortement au contact du coke à très haute température et sont capables de provoquer la cokéfaction du charbon dans la zone du four située au-dessus de la zone de chauffage électrique.Such a process is described for example in French patent 997,058 where an electric heating zone is provided in the oven, below the coking zone. The coke produced is thus brought to very high temperature by electrical heating and the gases coming from the base of the furnace which pass through this zone heat up strongly in contact with the coke at very high temperature and are capable of causing the coking of coal in the zone. oven located above the electric heating zone.

Ce procédé a l'inconvénient de nécessiter une surchauffe du coke jusqu'à une température voisine de 1.400°C.This process has the drawback of requiring the coke to overheat up to a temperature in the region of 1,400 ° C.

A titre de comparaison, la température du coke dans les fours à coke classiques ne dépasse pas 1.200° C.By way of comparison, the coke temperature in conventional coke ovens does not exceed 1,200 ° C.

On a également proposé dans le brevet FR.A. 628 168, d'utiliser des fours à chauffage électrique, avec circulation de gaz à contre-courant des matières solides, pour la cuisson du coke en vue de fabriquer des électrodes.The FR.A. patent has also been proposed. 628 168, to use electrically heated ovens, with gas circulation against the current of solid materials, for cooking coke in order to manufacture electrodes.

De tels procédés demandent cependant des températures très supérieures aux températures nécessaires pour la cokéfaction.However, such processes require temperatures much higher than the temperatures necessary for coking.

On connait également des procédés de traitement du coke, par exemple pour sa désulfuration, qui utilisent à la fois un chauffage électrique et le passage de gaz dans la masse de coke portée à haute température.There are also known processes for treating coke, for example for its desulphurization, which use both electric heating and the passage of gas through the mass of coke brought to high temperature.

Cependant, de tels procédés sont conduits de façon très différente d'un procédé de cokéfaction et ne visent qu'au traitement du coke lui-même, or, il n'y a pas intéret à porter le coke à des températures pouvant dépasser 1.400 °C car la qualite métallurgique du coke s'en ressent et sa réactivite entre autre diminue.However, such processes are carried out very differently from a coking process and are only intended for the treatment of the coke itself, however, there is no point in bringing the coke to temperatures which may exceed 1.400 ° C because the metallurgical quality of coke is affected and its reactivity, among other things, decreases.

Dans le brevet US-A-2.127.542, les électrodes sont placées à la hauteur de la zone de cokéfaction mais, dans ce cas également, le passage du courant s'effectue dans du coke qui est chargé en même temps que le charbon à la partie supérieure du four à cuve en formant une couche annulaire qui entoure la charge de charbon et descend avec elle. c'est donc dans cette couche de coke que se produit par effet Joule un apport de chaleur se transmettant par conduction au charbon adjacent qui se transforme en coke et laisse à son tour passer le courant. Le processus de carbonisation s'étend donc radialement vers l'intérieur au cours de la descente de la charge et le degre de carbonisation des morceaux de charbon depend, à chaque niveau, de leur distance par rapport à la paroi du four.In patent US-A-2,127,542, the electrodes are placed at the level of the coking zone but, in this case also, the passage of the current takes place in coke which is charged at the same time as coal to the upper part of the shaft furnace forming an annular layer which surrounds the coal charge and descends with it. it is therefore in this layer of coke that the Joule effect produces a supply of heat which is transmitted by conduction to the adjacent coal which transforms into coke and in turn lets the current flow. The carbonization process therefore extends radially inwards during the descent of the charge and the degree of carbonization of the pieces of coal depends, at each level, on their distance from the wall of the furnace.

L'invention propose, en revanche, un procédé de fabrication de coke moule dans lequel l'échauffement de la charge est réalisé en observant une loi de chauffe déterminée en fonction de la nature du charbon de façon à éviter la formation de grappes et à conserver la forme des boulets jusqu'à la fin du traitement, notamment en évitant leur éclatement et leur surchauffe.The invention proposes, on the other hand, a process for manufacturing mold coke in which the heating of the charge is carried out by observing a heating law determined according to the nature of the coal so as to avoid the formation of clusters and to preserve the shape of the balls until the end of the treatment, in particular by avoiding their bursting and their overheating.

A cet effet, on utilise, de façon connue, un four a cuve à la partie supérieure duquel on introduit des boulets de charbon à cokéfier qui constituent un lit mobile descendant dans le four à contre- courant de gaz traversant le four de bas en haut, dont une partie est constituée par des gaz récupérés à la partie supérieure du four et recyclés à sa partie inférieure et dont une autre partie est constituée par les gaz libérés par le charbon au cours de son chauffage et de sa cokéfaction, un apport de chaleur étant effectué par passage de courants électriques dans le lit de matières solides.For this purpose, a known kiln is used, at the top of which coking charcoal balls are introduced which constitute a moving bed descending into the furnace against the gas flow passing through the furnace from bottom to top. , part of which consists of gases recovered at the top of the oven and recycled at its bottom and another part of which consists of the gases released by the coal during its heating and coking, a supply of heat being effected by passing electric currents through the bed of solids.

Conformément à l'invention, on réalise le chauffage électrique de façon contrôlée, dans la zone médiane du four sur une hauteur déterminée, en faisant passer dans plusieurs plans horizontaux échelonnés de la charge, des courants électriques dont on peut régler individuellement les intensités et, par réglage des échanges thermiques entre la charge solide et par réglage de la circulation des gaz et de la puissance électrique répartie sur les différents niveaux d'électrodes en fonction des besoins calorifiques et de la résistance électrique de la charge, on contrôle le chauffage progressif et homogène de celle-ci au cours de sa descente dans le four suivant une loi de chauffe choisie en fonction de la nature du charbon pour conserver la forme des boulets, de telle sorte que la température du lit de matière solide soit comprise entre 600°C et 850°C à l'entrée de la zone médiane (C) de chauffage électrique et que la réaction de cokéfaction soit réalisée complètement dans cette zone (C) à une température restant comprise . entre 950° C et 1150°C, les boulets de coke ainsi réalisés étant ensuite refroidis dans la partie inférieure du four.In accordance with the invention, electrical heating is carried out in a controlled manner, in the central zone of the furnace over a determined height, by passing electrical currents, the intensities of which can be individually adjusted, in several horizontal planes of the load, by adjusting the heat exchanges between the solid charge and by adjusting the gas circulation and the electric power distributed over the different electrode levels according to the heat requirements and the electrical resistance of the charge, progressive heating is controlled and homogeneous thereof during its descent into the oven according to a heating law chosen according to the nature of the coal to maintain the shape of the balls, so that the temperature of the bed of solid material is between 600 ° C. and 850 ° C at the entry of the central zone (C) of electric heating and that the coking reaction is carried out completely in this zone (C) at a e remaining temperature included. between 950 ° C and 1150 ° C, the coke balls thus produced are then cooled in the lower part of the oven.

Selon une autre caractéristique importante, dans la zone supérieure de préchauffage du four, on dérive un débit réglable du courant ascendant de gaz chauds, de manière à contrôler une élévation de température progressive des matières à une vitesse choisie en fonction de la nature du charbon pour éviter la fusion ou le collage des boulets.According to another important characteristic, in the upper preheating zone of the furnace, an adjustable flow rate of the rising current of hot gases is derived, so as to control a gradual rise in temperature of the materials at a speed chosen according to the nature of the coal for avoid melting or sticking of the balls.

De préférence, on augmente la résistance électrique de la charge après la sortie de la zone médiane de cokéfaction en réalisant une décompression de la charge dans la zone de refroidissement, susceptible d'augmenter les résistances de contact entre les boulets.Preferably, the electrical resistance of the charge is increased after leaving the central coking zone by decompressing the charge in the cooling zone, capable of increasing the contact resistances between the balls.

Pour favoriser le passage du courant électrique dans la zone médiane de cokéfaction, rendre homogène le chauffage électrique et faciliter le réglage électrique de la puissance consommée, les boulets de charbon introduits à la partie supérieure du four sont mélangés avec des particules de petit coke ou de tout autre produit conducteur de l'électricité, inaltérable aux températures atteintes dans le four et se trouvant sous forme de grains de dimensions inférieures à celles des boulets de charbon, lesdits grains étant répartis de façon homogène dans les interstices entre les boulets.To encourage the passage of electric current in the middle coking zone, to make electric heating homogeneous and to facilitate the electric adjustment of the power consumed, the charcoal balls introduced into the upper part of the oven are mixed with particles of small coke or any other electrically conductive product, unalterable at temperatures reached in the oven and being in the form of grains of dimensions smaller than those of the coal balls, said grains being distributed homogeneously in the interstices between the balls.

Le four à cuve pour la mise en oeuvre du procédé selon l'invention comprend au moins deux paires d'électrodes superposées, placées dsns des plans horizontaux écartés l'un de l'sutre et dont les tensions d'alimentation électrique sont réglables individuellement par paire.The cell furnace for implementing the method according to the invention comprises at least two pairs of superposed electrodes, placed in horizontal planes spaced apart from one another and whose electrical supply voltages are individually adjustable by pair.

Dans un mode de réalisation préférentiel, les électrodes placées dans au moins l'un des plans horizontaux sont montées mobiles horizontalement et reliées chacune à des moyens d'avancement et de recul alternés, chaque électrode exerçant une pression constante sur la charge par avancement progressif vers l'intérieur du four jusqu'à une position déterminée à partir de laquelle est commandé un recul rapide accompagné d'une descente de la charge et suivi d'un nouvel avancement.In a preferred embodiment, the electrodes placed in at least one of the horizontal planes are mounted movable horizontally and each connected to alternate advancing and reversing means, each electrode exerting constant pressure on the charge by progressive advancement towards the interior of the oven to a determined position from which a rapid reverse is controlled accompanied by a descent of the load and followed by a new advancement.

Afin de bien faire comprendre l'invention, on va maintenant décrire, à titre d'exemple non limitatif, en se référant aux figures jointes en annexe, un exemple de mise en oeuvre du procédé suivant l'invention dans le cas d'un four à cuve muni d'un double jeu d'électrodes.

  • La figure 1 représente schématiquement un four à cuve suivant l'invention dans une vue en coupe par un plan vertical.
  • La figure 2 représente une section du four suivant Il Il de la figure 1.
  • La figure 3 représente la partie inférieure des électrodes du premier ensemble représenté à la figure 1, dans une vue à plus grande échelle.
  • La figure 4 représente un mode de réalisation plus perfectionné d'un four à cuve selon l'invention.
  • La figure 5 est un diagramme représentant la loi de chauffe de la charge.
In order to clearly understand the invention, we will now describe, by way of nonlimiting example, with reference to the attached figures, an example of implementation of the method according to the invention in the case of an oven with tank fitted with a double set of electrodes.
  • Figure 1 shows schematically a tank furnace according to the invention in a sectional view through a vertical plane.
  • FIG. 2 represents a section of the furnace along II Il of FIG. 1.
  • FIG. 3 represents the lower part of the electrodes of the first assembly represented in FIG. 1, in a view on a larger scale.
  • FIG. 4 represents a more improved embodiment of a cell oven according to the invention.
  • FIG. 5 is a diagram representing the heating law of the load.

Sur la figure 1, on voit le four à cuve 1 comportant une double paroi isolante 2 et dont la partie supérieure constitue un gueulard 3 d'enfournement des boulets de charbon à cokéfier.In Figure 1, we see the tank furnace 1 having a double insulating wall 2 and the upper part of which constitutes a chute 3 for charging charcoal balls.

Ce gueulard est d'un type voisin de celui des gueulards de haut fourneau et permet grâce à un dispositif 4 la récupération des gaz à Is partie supérieure du four à cuve. Le gueulard est totalement étanche et permet d'éviter les rentrées d'air atmosphérique.This mouthpiece is of a type similar to that of blast furnace mouths and allows, by means of a device 4, the recovery of gases at the upper part of the shaft furnace. The gueulard is completely waterproof and avoids the entry of atmospheric air.

A la partie inférieure du four à cuve des dispositifs à trémies et évacuateurs rotatifs 5 permettent une sortie régulière du coke parvenant en bas du four.At the bottom of the shaft furnace, hoppers and rotary evacuators 5 allow a regular outlet of the coke reaching the bottom of the furnace.

Un lit mobile 6 de matières solides se déplace en continu dans le four. La surface supérieure 60 de ce lit de matières solides se maintient à un niveau sensiblement constant par introduction de boulets de charbon grâce au gueulard 3 à un débit identique au débit de sortie du coke.A moving bed 6 of solid materials moves continuously in the oven. The upper surface 60 of this bed of solids is maintained at a substantially constant level by introduction of coal balls thanks to the jaw 3 at a flow rate identical to the coke outlet flow rate.

Dans l'exemple représenté sur la figure 1, un premier jeu d'électrodes 7 est introduit dans le four par sa partie supérieure. Ces électrodes peuvent être réglées en hauteur, si bien que le niveau du plan AA dans lequel circulent des courants électriques de direction horizontale entre les électrodes peut être réglé par déplacement vertical de l'ensemble des électrodes supérieures.In the example shown in Figure 1, a first set of electrodes 7 is introduced into the furnace through its upper part. These electrodes can be adjusted in height, so that the level of the plane AA in which electric currents of horizontal direction circulate between the electrodes can be adjusted by vertical displacement of all of the upper electrodes.

Ainsi qu'il est visible sur les figures 2 et 3, ces électrodes comportent une partie conductrice 10 constituée par une plaque de graphite sertie dans une pièce en acier réfractaire 11. Les pièces 11 en acier réfractaire sont reliées à des tubes supports 12 également en acier réfractaire constituant des conducteurs servant à l'amenée du courant à l'extrémité des électrodes 7. De l'air de refroidissement circule éventuellement à l'intérieur de ces tubes et vient refroidir, à leur partie inférieure, la pièce 11 de fixation de la partie conductrice 10.As can be seen in FIGS. 2 and 3, these electrodes comprise a conductive part 10 constituted by a graphite plate crimped in a piece of refractory steel 11. The pieces 11 of refractory steel are connected to support tubes 12 also in refractory steel constituting conductors serving to bring the current to the end of the electrodes 7. Cooling air possibly circulates inside these tubes and comes to cool, at their lower part, the part 11 for fixing the conductive part 10.

Des blocs de matière réfractaire 14 permettent d'isoler les tubes de suspension et d'amenée du courant 12 du lit de mstières solides et des gaz à haute température circulant dans le four.Blocks of refractory material 14 make it possible to isolate the suspension and supply tubes from the current 12 from the bed of solid materials and from the high temperature gases circulating in the furnace.

Les électrodes 7 plongent dans le lit de matières solides à une profondeur d'à peu près 1 mètre 50 sous la surface du niveau 60. Cette profondeur d'introduction des électrodes peut être réglable.The electrodes 7 plunge into the bed of solid materials to a depth of approximately 1.5 meters below the surface of the level 60. This depth of introduction of the electrodes can be adjustable.

Sur la figure 2, on voit la section rectangulaire du four dans laquelle sont disposées six électrodes 7 permettant une circulation du courant entre les électrodes dans des directions horizontales. Le courant électrique passe d'une électrode à une autre suivant un trajet horizontal en traversant le lit de matières solides présentant au niveau de la zone de chauffage électrique une certaine conductibilité.In Figure 2, we see the rectangular section of the oven in which are arranged six electrodes 7 allowing a flow of current between the electrodes in horizontal directions. The electric current passes from one electrode to another following a horizontal path by crossing the bed of solids having at the level of the electric heating zone a certain conductivity.

Un second jeu d'électrodes 8 disposés à un niveau B inférieur au niveau du plan A, traversent horizontalement la double paroi 1, 2 du four. Ces électrodes sont constituées par des blocs de graphite logés dans le réfractaire situé entre les deux parois 1 et 2 du four et légèrement saillants dans l'espace intérieur du four.A second set of electrodes 8 disposed at a level B lower than the level of the plane A, pass horizontally through the double wall 1, 2 of the furnace. These electrodes consist of blocks of graphite housed in the refractory located between the two walls 1 and 2 of the furnace and slightly projecting in the interior space of the furnace.

De préférence, ces électrodes sont mobiles horizontalement de façon à exercer une poussée constante sur la charge.Preferably, these electrodes are movable horizontally so as to exert a constant thrust on the load.

A cet effet, comme on l'a représenté schématiquement sur la figure 1, chaque électrode 8 peut être montée sur un chariot 81 déplaçable horizontalement par exemple au moyen d'un vérin 82 à pression constante. Le mouvement d'avancée vers l'intérieur du four est limité dans sa course de telle sorte que les électrodes 8 dépassent de quelques centimètres la face interne de la paroi 2 du four. Le vérin 82 commande alors un recul rapide de l'électrode qui s'accompagne d'une descente des mstières se trouvant au-dessus et le mouvement d'avancée peut reprendre. Un système facile à concevoir permet de compenser l'usure de l'électrode 8.To this end, as shown schematically in Figure 1, each electrode 8 can be mounted on a carriage 81 movable horizontally for example by means of a jack 82 at constant pressure. The forward movement towards the inside of the furnace is limited in its course so that the electrodes 8 extend a few centimeters beyond the internal face of the wall 2 of the furnace. The jack 82 then commands a rapid retreat of the electrode which is accompanied by a descent of the mstières located above and the advance movement can resume. An easy-to-design system compensates for the wear of electrode 8.

A l'extérieur du four un circuit 15 de récupération et de traitement du gaz est raccordé d'une part au récupérateur de gaz 4 à la partie supérieure du four et d'autre part à la partie inférieure du four par une conduite d'injection 18.Outside the oven, a gas recovery and treatment circuit 15 is connected on the one hand to the gas recuperator 4 at the upper part of the oven and on the other hand to the lower part of the oven by an injection pipe. 18.

Sur ce circuit de gaz sont disposées une unité de lavage du gaz 16 où le gaz est dépoussiéré et dégoudronné ainsi qu'une pompe de circulation et d'injection 17. En outre, le circuit peut comprendre avantageusement un équipement 19 limitant la teneur en vapeur d'eau du gaz recyclé et constitué par exemple par un échangeur abaissant le point de rosée du gaz par refroidissement.On this gas circuit are arranged a gas washing unit 16 where the gas is dusted and tared as well as a circulation and injection pump 17. In addition, the circuit can advantageously include equipment 19 limiting the vapor content water from the recycled gas and constituted for example by an exchanger lowering the dew point of the gas by cooling.

Une vanne 20 permet de régler l'injection de gaz à la base du four et de diriger une partie de ce gaz vers un réservoir de stockage ou un circuit d'utilisation.A valve 20 makes it possible to regulate the injection of gas at the base of the furnace and to direct a part of this gas towards a storage tank or a circuit of use.

Dans un mode de réalisation plus perfectionné représenté sur la figure 4 le four comprend plusieurs nivesux d'électrodes 8 placées dans des plans horizontaux échelonnés le long de la zone médiane C et dont l'alimentation électrique, non représentée sur la figure, peut être réglée individuellement dans chaque plan, en fonction de la puissance électrique souhaitable pour la réalisation de la loi de chauffe.In a more perfected embodiment shown in FIG. 4 the oven comprises several nivesux of electrodes 8 placed in horizontal planes staggered along the middle zone C and the power supply of which, not shown in the figure, can be adjusted individually in each plane, depending on the electrical power desirable for the realization of the heating law.

La surface nécessaire d'électrodes est déterminée par l'intensité du courant électrique à faire circuler dans la masse de manière à éviter une surchauffe.The required area of electrodes is determined by the intensity of the electric current to be circulated in the mass so as to avoid overheating.

La surface totale d'électrodes est donc importante. Mais il est nécessaire qu'un boulet ne reste pas trop longtemps sous une intensité forte. On aura donc un nombre d'électrodes constituant des plans horizontaux et de faible épaisseur. La tension du courant peut être réglée par groupe d'électrodes en fonction de la loi de chauffe.The total surface area of the electrodes is therefore significant. But it is necessary that a ball does not stay too long under a strong intensity. There will therefore be a number of electrodes constituting horizontal planes and of small thickness. The current voltage can be adjusted by group of electrodes according to the heating law.

Par ailleurs, le four 1 a une section rectangulaire permettant la réalisation modulaire d'une installation constituée de cellules accolées.Furthermore, the furnace 1 has a rectangular section allowing the modular production of an installation made up of adjoining cells.

Dans la zone supérieure de préchauffage P le four est muni de moyens permettant de dériver une partie du courant ascendant de gaz chauds et qui peuvent par exemple être constitués par une double paroi latérale 21 ménageant un espace pour la circulation des gaz qui s'effectue par la différence de perte de charge entre les deux circuits respectivement interne et périphérique ainsi constitués.In the upper preheating zone P the furnace is provided with means making it possible to divert part of the ascending current of hot gases and which can for example consist of a double side wall 21 providing a space for the circulation of gases which is effected by the difference in pressure drop between the two internal and peripheral circuits respectively thus formed.

Un système de volet permet de régler la perte de charge et par conséquent le débit du gaz dans le circuit principal.A shutter system makes it possible to adjust the pressure drop and therefore the gas flow in the main circuit.

Dans la partie inférieure R de refroidissement, le four a une largeur plus grande et est en outre traverse par des barres horizontales 22 garnies de réfractaire et éventuellement refroidis intérieurement et qui s'étendent d'une paroi à l'autre. L'extraction des produits à la base 5 du four assure donc une décompression de la charge à la sortie de la zone de cokéfaction C. 11 en résulte une augmentation des résistances de contact qui diminue le passage de courant électrique dès le début de la zone de refroidissement. On limite ainsi vers le bas la zone C de chauffage électrique.In the lower cooling part R, the oven has a greater width and is further crossed by horizontal bars 22 lined with refractory and possibly internally cooled and which extend from one wall to the other. The extraction of the products at the base 5 of the furnace therefore ensures a decompression of the charge at the outlet of the coking zone C. 11 this results in an increase in the resistances of contact which reduces the flow of electric current from the start of the cooling zone. This limits downward the electric heating zone C.

Nous allons maintenant décrire le fonctionnement du four pour la production de coke moulé et de gaz à pouvoir calorifique élevé.We will now describe the operation of the furnace for the production of molded coke and high calorific gases.

La figure 5 donne un exemple d'une loi de chauffe et des températures respectives des matières (indiquées en abscisse) suivant la hauteur du four (indiquée en ordonnées). La courbe en trait plein donne la température des matières solides et la courbe en pointillé, la température des gaz.FIG. 5 gives an example of a heating law and of the respective temperatures of the materials (indicated on the abscissa) according to the height of the oven (indicated on the ordinate). The solid line curve gives the temperature of the solids and the dotted line the gas temperature.

On introduit dans le four, par l'intermédiaire du gueulard 3 une charge de charbon constituée par des briquettes ou boulets de dimensions habituelles (par exemple: 40 x 25 x 20 mm) mélangés à du petit coke de granulométrie allant de 5 à 15 mm. Ce petit coke est préalablement réparti de façon homogène dans les boulets, dans une proportion convenable, par exemple: 10 % en poids ou 19 % en volume. (Le petit coke pourrait être remplacé par tout produit équivalent, de même dimension, c'est à dire conducteur de l'électricité et inaltérable aux températures pratiquées dans le milieu gazeux considéré).Is introduced into the oven, via the gueulard 3 a charcoal charge consisting of briquettes or balls of usual dimensions (for example: 40 x 25 x 20 mm) mixed with small coke with a particle size ranging from 5 to 15 mm . This small coke is previously distributed homogeneously in the balls, in a suitable proportion, for example: 10% by weight or 19% by volume. (The small coke could be replaced by any equivalent product, of the same size, that is to say conductive of electricity and unalterable at the temperatures practiced in the gaseous medium considered).

Ce petit coke se loge partiellement entre les boulets de charbon en occupant les interstices de la charge.This small coke is partially lodged between the coal balls, occupying the interstices of the charge.

Les boulets de charbon sont constitués par un mélange de charbon maigre ou flambant sec associé à des charbons gras ou flambant gras mélangé à un liant constitué par du brai (mélangé éventuellement à du goudron).The charcoal balls consist of a mixture of lean or flaming dry coal associated with fatty or flaming coals mixed with a binder consisting of pitch (possibly mixed with tar).

Le mélange homogénéisé descend dans le four à contre-courant de la circulation des gaz et parvient à la partie inférieure de l'échangeur supérieur du four à une température voisine de 850°C. Les boulets de charbon sont donc séchés puis chauffés de façon que leur température soit voisine de 800°C à la sortie de l'échangeur supérieur du four à cuve.The homogenized mixture descends into the oven against the flow of gases and reaches the lower part of the upper exchanger of the oven at a temperature close to 850 ° C. The coal balls are therefore dried and then heated so that their temperature is close to 800 ° C. at the outlet of the upper exchanger from the shaft furnace.

Le débit de gaz et le chauffage du four sont réglés en fonction du débit de matières solides pour obtenir les échanges de chaleur adéquats.The gas flow rate and the heating of the furnace are regulated according to the flow rate of solid materials to obtain the adequate heat exchanges.

Comme on le voit sur la figure 5, en dérivant une partie réglable des gaz chauds entre les niveaux E et F de la zone supérieure de préchauffage, on peut contrôler la loi de chauffe de la charge notamment entre 400 et 700°C de façon à éviter la fusion des boulets.As can be seen in FIG. 5, by deriving an adjustable part of the hot gases between the levels E and F of the upper preheating zone, it is possible to control the heating law of the load, in particular between 400 and 700 ° C. so as to avoid the fusion of the balls.

Dans les conditions d'exploiration, la température des boulets à la sortie de l'échangeur supérieur P doit, en pratique, être supérieure à 700°C pour que le passage du courant se produise de façon convenable et ne pas dépasser 850°C pour que le rendement thermique de l'opération soit bon.In the operating conditions, the temperature of the balls at the outlet of the upper exchanger P must, in practice, be higher than 700 ° C. so that the flow of the current occurs in a suitable manner and not exceed 850 ° C. for that the thermal efficiency of the operation is good.

Lorsque le lit de matières solides comportant les boulets de charbon agglomérés et le coke parvient dans le plan A du premier ensemble d'électrodes, un courant traverse ce lit de matières et produit une élévation de température à l'intérieur des boulets par effet Joule.When the bed of solids comprising the agglomerated coal balls and the coke reaches plane A of the first set of electrodes, a current flows through this bed of materials and produces a rise in temperature inside the balls by the Joule effect.

Les particules de petit coke insérées entre les boulets de charbon favorisent le passage du courant dans le lit de matières solides circulant dans le four en multipliant les points de contact.The particles of small coke inserted between the coal balls favor the passage of the current in the bed of solid matter circulating in the furnace by multiplying the points of contact.

Les boulets crus tels qu'introduits dans le four à cuve sont peu conducteurs de l'électricité. Cependant, à partir d'un certain degré de dévolatilisation, la résistivité interne de ces boulets diminue rapidement. Par exemple à 800°C les mesures ont montré que ces boulets ont une résistivité interne qui ne dépasse pas 1500 σ/0m. Ainsi, en contrôlant l'élévation de température des boulets dans la zone de préchauffage P, on limite vers le haut la zone C de chauffage électrique.Raw balls as introduced into the shaft furnace are not very conductive of electricity. However, from a certain degree of devolatilization, the internal resistivity of these balls quickly decreases. For example at 800 ° C the measurements have shown that these balls have an internal resistivity which does not exceed 1500 σ / 0m. Thus, by controlling the temperature rise of the balls in the preheating zone P, one limits upwards the zone C of electric heating.

Il faut éviter également des élévations de température locsle trop importantes qui provoqueraient un cracking exagéré des hydrocarbures gazeux circulant dans le four et un dépôt de carbone-black entre les électrodes, ce qui créerait des courts-circuits, ce carbone-blsck étant conducteur.It is also necessary to avoid too high locsle temperature increases which would cause an excessive cracking of gaseous hydrocarbons circulating in the furnace and a carbon-black deposit between the electrodes, which would create short circuits, this carbon-blsck being conductive.

Mais le procédé selon l'invention permet de diminuer le risque de surchauffe car il est plus facile de régler la température du chauffage électrique en répartissant celui-ci dans plusieurs sections horizontales successives du four.However, the method according to the invention makes it possible to reduce the risk of overheating since it is easier to regulate the temperature of the electric heating by distributing it in several successive horizontal sections of the oven.

Le petit coke mélangé aux boulets de charbon cru avant son introduction dans le four est récupéré à la base du four par criblage des boulets de coke produits. Ce petit coke n'a subi aucune transformation dans toute sa traversée du four. Son rôle se limite à diminuer les résistances de contact entre les boulets de charbon et à obtenir un chauffage plus homogène de la charge.The small coke mixed with the balls of raw coal before being introduced into the oven is recovered at the base of the oven by screening the coke balls produced. This small coke has not undergone any transformation throughout its passage through the furnace. Its role is limited to reducing the contact resistances between the carbon balls and obtaining a more homogeneous heating of the load.

A l'entrée dans la zone médiane de chauffage électrique du four comprise essentiellement entre les deux plans A et B des électrodes, le lit de matières solides a une température très homogène, d'une part à cause du mouvement de la charge de matières solides traversant la zone des électrodes et soumise au chauffage par effet Joule des courants qui la traversent, résultant des multiples contacts établis par les grains de petit coke répartis dans les boulets et qui changent constamment de position, et d'autre part à cause de la circulation des gaz dans cette zone.On entering the central electric heating zone of the furnace lying essentially between the two planes A and B of the electrodes, the bed of solids has a very uniform temperature, on the one hand because of the movement of the charge of solids crossing the electrode area and subjected to Joule heating of the currents which cross it, resulting from the multiple contacts established by the grains of small coke distributed in the balls and which constantly change position, and on the other hand because of the circulation gases in this area.

Dans le cas d'un four à cuve ayant une section carrée dont le côté mesure 3 mètres 50, et dont la production de coke est d'environ 350 tonnes par jour, on utilise des électrodes disposées comme représenté sur la figure 4 c'est à dire distantes d'à peu près 3,5 m.In the case of a shaft furnace having a square section whose side measures 3.50 meters, and whose coke production is approximately 350 tonnes per day, electrodes arranged as shown in FIG. 4 are used. ie about 3.5 m apart.

Ces électrodes sont alimentées sous une tension de préférence continue et régulée pour une puissance maintenue constante et dégagent une puissance totale de 1 500 kw par exemple. Cette puissance est répartie entre les divers niveaux d'électrodes de manière à obtenir la loi de chauffe désirée.These electrodes are supplied with a voltage which is preferably continuous and regulated for a power kept constant and give off a total power of 1,500 kw for example. This power is distributed between the various levels of electrodes so as to obtain the desired heating law.

Cette puissance thermique d'origine électrique permet de faire passer la température des matières solides de 800 à 1 050°C environ dans la zone C de chauffage électrique.This thermal power of electrical origin makes it possible to increase the temperature of the solid materials from 800 to 1,050 ° C. approximately in zone C of electric heating.

La cokéfaction complète du charbon se produit dans cette zone, le coke à 1000°C pénétrant dans l'échangeur inférieur par la partie supérieure de celui-ci. Les gaz en circulation dans le four s'échauffent au contact du coke et du charbon en cours de cokéfaction dans la zone de chauffage électrique et leur débit s'accroît par volatilisation d'une partie des produits contenus dans les boulets de charbon.Full coking of coal occurs in this zone, the coke at 1000 ° C entering the lower exchanger through the upper part thereof. The gases circulating in the furnace heat up in contact with the coke and the coal being coked in the electric heating zone and their flow rate increases by volatilization of a part of the products contained in the coal balls.

Les gaz injectés à la base du four par la conduite 18 permettent de refroidir le coke produit depuis la température de sortie de la zone médiane, c'est à dire une température voisine de 1 000°C jusqu'à une température voisine de 150°C.The gases injected at the base of the furnace through line 18 make it possible to cool the coke produced from the outlet temperature from the middle zone, that is to say a temperature close to 1000 ° C. to a temperature close to 150 ° vs.

Pour le four mentionné ci-desssus, on injecte à la base du four environ 1000 m3 de gaz par tonne de matières solides circulant dans le four, ce qui assure des échanges équilibrés à la partie inférieure et à la partie supérieure du four.For the oven mentioned above, about 1000 m 3 of gas per tonne of solid matter circulating in the oven is injected at the base of the oven, which ensures balanced exchanges at the bottom and at the top of the oven.

Le gaz produit dans le four est récupéré à la partie supérieure, dépoussiéré et dégoudronné avant d'être introduit dans le four par la conduite 18.The gas produced in the oven is recovered at the top, dusted and tared before being introduced into the oven through line 18.

On produit de plus une quantité excédentaire de gaz combustible dépendant de la nature des charbones utilisés par exemple 500 m3 par tonne de coke produite. Le pouvoir calorifique de ce gaz est d'environ 18810J/m3 (4500 calories par m3),In addition, an excess quantity of combustible gas is produced depending on the nature of the charcoals used, for example 500 m 3 per tonne of coke produced. The calorific value of this gas is around 18810J / m 3 (4500 calories per m 3 ),

La consommation d'énergie électrique est voisine de 150 kWh par tonne de coke produite.Electric power consumption is around 150 kWh per tonne of coke produced.

La cokéfaction se produit donc à une température relativement modérée et généralement un peu inférieure à la température de cokéfaction dans les fours à coke classiques.Coking therefore occurs at a relatively moderate temperature and generally a little lower than the coking temperature in conventional coke ovens.

Le réglage du chauffage électrique en fonction des débits de matières solides et des gaz pourra varier quelque peu mais pour obtenir un bon rendement thermique et des conditions de cokéfaction optimales, la température maximum du lit de matières solides dans la zone de chauffage électrique ne devra pas dépasser une valeur comprise entre 950 et 1150°C.The setting of the electric heating according to the flows of solids and gases may vary somewhat but to obtain a good thermal efficiency and optimal coking conditions, the maximum temperature of the bed of solids in the electric heating zone should not exceed a value between 950 and 1150 ° C.

En répartissant la puissance électrique sur plusieurs niveaux, on obtient un chauffage progressif et adapté à toutes les natures de charbon, ce qui ne serait pas le cas si l'on utilisait un seul ensemble d'électrodes permettant un passage du courant dans un seul plan horizontal.By distributing the electric power on several levels, we obtain a progressive heating and adapted to all types of coal, which would not be the case if we used a single set of electrodes allowing a passage of current in a single plane horizontal.

Le bilan concernant la consommation d'énergie dans le procédé suivant l'invention est tout à fait favorable si on le compare à ce qu'il en est pour les fours à coke classiques.The balance concerning the energy consumption in the process according to the invention is entirely favorable if it is compared to what it is for conventional coke ovens.

En effet, de tels fours à coke consomment approximativement 800 thermies par tonne de coke produite alors que la consommation d'énergie électrique dans le four à cuve suivant l'invention correspondrait approximativement à une consommation de 150 kWh par tonne de coke produite.Indeed, such coke ovens consume approximately 800 therms per tonne of coke produced while the consumption of electrical energy in the shaft furnace according to the invention would correspond approximately to a consumption of 150 kWh per tonne of coke produced.

On voit donc que les principaux avantages du procédé suivant l'invention sont de permettre une diminution de la consommation d'énergie pour la production de coke et une récupération d'un gaz à haut pouvoir calorifique qui peut être produit en continu.It can therefore be seen that the main advantages of the process according to the invention are to allow a reduction in the energy consumption for the production of coke and the recovery of a gas with high calorific value which can be produced continuously.

De plus, le réglage thermique du procédé peut être effectué de façon simple, de façon que les échanges entre les gaz et les matières solides soient équilibrées et que l'apport calorifique par énergie électrique soit utilisé pratiquement uniquement pour compenser les déperditions thermiques du four et la chaleur des réactions endothermiques pouvant se produire dans le four. La souplesse de ce type de four permet de moduler la consommation de courant électrique avec un délestage aux heures de pointe.In addition, the thermal adjustment of the process can be carried out in a simple manner, so that the exchanges between the gases and the solid materials are balanced and that the calorific contribution by electrical energy is used practically only to compensate for the heat losses of the furnace and the heat of endothermic reactions that can occur in the oven. The flexibility of this type of oven makes it possible to modulate the consumption of electric current with load shedding during peak hours.

Enfin, l'étanchéité complète du four permet d'éviter toutes fuites de gaz, ce qui évite toute pollution de l'environnement.Finally, the complete tightness of the oven makes it possible to avoid any gas leaks, which avoids any pollution of the environment.

Il est bien évident que l'invention ne se limite pas au procédé et au dispositif décrits de façon non limitative mais qu'ils en comportent toutes les variantes.It is obvious that the invention is not limited to the process and to the device described in a nonlimiting manner, but that they include all variants thereof.

C'est ainsi que suivant les conditions d'exploitation et la qualité des charbons utilisés, les conditions de réglage thermique pourront varier à l'intérieur des intervalles mentionnés.Thus, depending on the operating conditions and the quality of the coals used, the thermal adjustment conditions may vary within the intervals mentioned.

La forme de la section droite du four n'est pas obligatoirement carrée ou rectangulaire mais peut aussi être circulaire.The shape of the straight section of the oven is not necessarily square or rectangular but can also be circular.

La forme des électrodes, leur disposition et leur écartement peuvent être variable en fonction de la forme du four et des conditions de chauffage recherchées.The shape of the electrodes, their arrangement and their spacing can be variable depending on the shape of the oven and the desired heating conditions.

Les gaz récupérés à la partie supérieure du four subissent des traitements qui sont fonctions de leur utilisation finale.The gases recovered at the top of the furnace undergo treatments which depend on their end use.

Claims (12)

1. Process for producing moulded coke in a shaft oven with a vertical axis (1), which is supplied in its upper part (3) with a burden of coal for coking in the form of ovoids, forming a movable bed descending in the shaft (1) in counter flow to gas circulating from the bottom upwards and passing successively from the top downwards through a preheating zone, a coking zone and a cooling zone, the rising stream of gas being formed by the gases released by the coal during its heating and coking and by some of the gases recovered in the upper part of the oven and recycled in the lower part after washing and dust extraction, heat being supplied by circulation of electrical current through the bed of solid materials between electrodes (8) located on two opposite sides of the wall (2) of the oven (1), characterized in that the electrical heating is carried out in a controlled way over a specific height in the middle part (C) of the oven (1), electric currents, the intensities of which can be regulated, being passed through the burden in several staggered horizontal planes, and in that, by adjustment of the circulation of the gases and of the electrical power distributed to the various levels of electrodes according to the heat requirements and the electrical resistance of the burden, a progressive and uniform heating of the latter is controlled during its descent in the oven according to a law of heating selected as a function of the type of coal, to preserve the shape of the ovoids, in such a way that the temperature of the bed of solid material is between 600°C and 850°C at the entrance of the middle zone (C) of electrical heating and that coking is carried out completely in this zone (C) at a temperature remaining between 950°C and 1150°C, the coke ovoids subsequently being cooled in the lower part of the oven (1).
2. Process for producing moulded coke according to Claim 1, characterized in that, in the preheating zone (P), an adjustable flow rate of the rising stream of hot gases is derived so as to control a progressive increase in temperature of the materials at a speed selected as a function of the type of coal, to prevent the fusion or caking of the ovoids.
3. Process for producing moulded coke according to one of Claims 1 and 2, characterized in that the electrical resistance of the burden is increased after it leaves the coking zone (C), by producing a decompression of the burden in the cooling zone (R), which is capable of increasing the contact resistances between the ovoids.
4. Process for producing moulded coke according to Claim 1, characterized in that the coal ovoids introduced into the upper part (3) of the oven (1) are mixed with particles of small sized coke or any other product in the form of electrically conductive grains resistant to the temperatures reached in the oven and of dimensions less than those of the ovoids, the said grains being distributed uniformly in the gaps between the coal ovoids and assisting the passage of electrical current through the middle coking zone (2), making the heating uniform and facilitating the electrical adjustment of the power consumption.
5. Process for producing moulded coke according to Claim 4, characterized in that the size of the particles of small sized coke is between 5 and 15 mm.
6. Shaft oven for producing coke by means of the process according to one of Claims 1 to 5, consisting of a shaft (1) of vertical axis having, in its upper part, a throat (3) for introducing a burden of coal in the form of ovoids and gas recovery means and, in its lower part, a component for discharging the solid materials and gas injection means, and equipped in its middle part with electrodes (8) making it possible to pass an electric current through the burden, characterized in that it possesses at least two pairs of electrodes (8) located one below the other in two horizontal planes (A, B) spaced from one another, and means of individually adjusting the electrical supply to each pair of electrodes.
7. Shaft oven according to Claim 6, characterized in that it is associated with elements for assisting the passage of electric current and constituted by particles of a conductive and resistant product, such as small sized coke having dimensionsless than those of the ovoids and distributed uniformly between these.
8. Shaft oven according to Claim 6, characterized in that it has at least one pair of electrodes (8) mounted so as to be horizontally movable and each connected to means of alternate advance and retraction (81, 82), each electrode (8) exerting a constant thrust on the burden as result of a progressive advance towards the interior of the oven (1), up to a specific position, from which a rapid retraction is controlled, this being accompanied by a descent of the burden, and so on and so forth.
9. Shaft oven according to Claim 6, characterized in that it possesses a first set of electrodes (10) located at the upper level (A) and suspended on vertical conductors (12), the position of which is adjustable according to the height of the oven, and at least one second set of electrodes (8) extending horizontally at a lower level (B) through the lateral wall of the oven (1).
10. Shaft oven according to Claim 9, characterized in that the vertical conductors allowing the suspension and displacement of the movable electrodes (10) are constituted by tubes (12) surrounded with refractory material and connected in their upper part to a device for blowing in cooling air for the electrodes.
11. Shaft oven according to one of Claims 6 to 10, characterized in that it possesses a meansfor decompressing the burden at the outlet of the coking zone (C), consisting of a widening of the cross-section of the oven in the cooling zone (R) below the middle coking zone (C).
12. Shaft oven according to Claim 11, characterized in that it is equipped with horizontal bars passing through the burden in the cooling zone (R).
EP83401306A 1982-06-23 1983-06-23 Process for the production of form coke in a shaft furnace, and shaft furnace for carrying out the process Expired EP0098771B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT83401306T ATE19527T1 (en) 1982-06-23 1983-06-23 PROCESS FOR THE PRODUCTION OF SHAPED COKE IN A SHAFT FURNACE AND SHAFT FURNACE FOR CARRYING OUT THE PROCESS.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR8211540 1982-06-23
FR8211540A FR2529220A1 (en) 1982-06-23 1982-06-23 PROCESS FOR MANUFACTURING MOLDED COKE IN ELECTRICALLY HEATED TANK OVEN AND CORRESPONDING TANK OVEN

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EP0098771A1 EP0098771A1 (en) 1984-01-18
EP0098771B1 true EP0098771B1 (en) 1986-04-30

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EP (1) EP0098771B1 (en)
AT (1) ATE19527T1 (en)
DE (1) DE3363268D1 (en)
FR (1) FR2529220A1 (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2587713B1 (en) * 1985-09-26 1987-12-18 Usinor METHOD OF MANUFACTURING MOLDED COKE BY ELECTRIC HEATING IN A TANK OVEN AND TANK OVEN FOR MANUFACTURING SUCH A COKE
CN115371255A (en) * 2022-08-18 2022-11-22 中国石油化工股份有限公司 Electric heating furnace system for heating raw oil and operation method
CN117143620B (en) * 2023-10-19 2024-06-18 重庆富燃科技股份有限公司 Adjustable integrated furnace

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE409341C (en) * 1922-08-18 1925-02-03 Hermann Roechling Manufacture of coke
FR628168A (en) * 1926-04-22 1927-10-19 Aluminum Co Of America Coke Cooking Improvements
FR658014A (en) * 1927-07-26 1929-05-30 Improvements in calcination processes for combustible agglomerated ovoids
US2127542A (en) * 1935-08-14 1938-08-23 Ralph B Stitzer Electrical carbonization of coal
FR1022465A (en) * 1949-07-25 1953-03-05 Bulk material heating process and furnace
FR1163853A (en) * 1956-08-18 1958-10-02 Coal carbonization process

Also Published As

Publication number Publication date
DE3363268D1 (en) 1986-06-05
EP0098771A1 (en) 1984-01-18
FR2529220B1 (en) 1984-12-28
ATE19527T1 (en) 1986-05-15
FR2529220A1 (en) 1983-12-30

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