EP0082456A2 - Prémélanges concentrés d'agents adoucissant le linge - Google Patents
Prémélanges concentrés d'agents adoucissant le linge Download PDFInfo
- Publication number
- EP0082456A2 EP0082456A2 EP82111555A EP82111555A EP0082456A2 EP 0082456 A2 EP0082456 A2 EP 0082456A2 EP 82111555 A EP82111555 A EP 82111555A EP 82111555 A EP82111555 A EP 82111555A EP 0082456 A2 EP0082456 A2 EP 0082456A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- alkyl
- eines
- bis
- methyl
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/645—Mixtures of compounds all of which are cationic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
- C11D3/0015—Softening compositions liquid
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/165—Ethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/372—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen containing etherified or esterified hydroxy groups ; Polyethers of low molecular weight
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/47—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds
- D06M13/473—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds having five-membered heterocyclic rings
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
Definitions
- washed textiles especially those made from cellulose fibers, have an unpleasant hardening after drying. This occurs particularly when the laundry is done in the washing machine.
- Such undesirable hardening of the handle can be eliminated by treating the textiles after washing in a rinsing bath with cationic substances which contain at least two long-chain aliphatic residues in the molecule.
- the water-dispersible dialkyldimethylammonium salts or imidazoline derivatives of the formulas I - III are used in particular for this purpose:
- R 1 is alkyl or alkenyl with 8-22, preferably 10-18, carbon atoms
- R 3 is methyl or hydrogen
- x is 1-5
- A is an anion such as C1 (-) , Br (-) , CH 3 OSO 3 (-) or CH 3 OPO 3 (-) .
- the products of these formulas I - III have a liquid or solid consistency. If R 1 is a saturated residue, the product is solid at room temperature. The transport then takes place in heated tankers or rail tank cars. It is delivered in barrels for transport to overseas.
- the manufacturers of fabric softeners then have the products transferred to heated tank systems. If the raw material is processed, the warmed-up product is dispersed in hot water. If barrel goods are processed, the products must first be liquefied in a barrel heating system and can then be further processed.
- the alkyl radicals of the compounds I - III consist of unsaturated units
- these derivatives are liquid at room temperature. They can be processed into dispersions with cold water. Liquid fabric softener raw materials, however, have a reduced softening effect compared to the saturated derivatives. In order to achieve comparable grip properties, much more cationic substance has to be offered to the tissue in the case of unsaturated compounds.
- 1 kg of the types of compounds of the formula I to III with a saturated radical R 1 corresponds to approximately 1.33 kg of the types of compound of the formula I to III with an unsaturated radical R 1 .
- auxiliary plasticizers listed under b) can each be used individually or in mixtures with one another.
- the premixes according to the invention can also contain further substances and auxiliaries.
- auxiliaries such as cationic or nonionic surface-active substances, solubilizers such as e.g. p-cumene sulfonate, electrolytes, acidifying agents such as e.g. Phosphoric acid, acetic acid, organic complexing agents, optical brighteners as well as colors and fragrances. They serve to additionally influence the handle of the goods or other properties of the textiles to be treated or to adjust the viscosity, to regulate the pH or to increase the stability at low temperatures.
- laundry softener premixes according to the invention are described. Percentages are percentages by weight in all cases. In all cases, these premixes are prepared by simply stirring the liquid individual components in the cold.
- liquid cloudy viscosity 650 mPas
- liquid cloudy viscosity 700 mPas
- Example 2 25 g of the premix from Example 2 are mixed with 0.9 g of perfume. and 1 g of a non-ionic emulsifier of the isctridecyl alcohol type mixed with 10 EO. 5 ml of a 10% CaCl 2 solution in 61.4 ml of cold water are added. This solution is stirred into the premix. A stable emulsion is obtained. The viscosity is approx. 150 mPas.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Detergent Compositions (AREA)
- Treatment Of Water By Ion Exchange (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT82111555T ATE22919T1 (de) | 1981-12-18 | 1982-12-13 | Konzentrierte vormischungen von waescheweichspuelmitteln. |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19813150179 DE3150179A1 (de) | 1981-12-18 | 1981-12-18 | Konzentrierte vormischungen von waescheweichspuelmitteln |
| DE3150179 | 1981-12-18 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP0082456A2 true EP0082456A2 (fr) | 1983-06-29 |
| EP0082456A3 EP0082456A3 (en) | 1984-11-28 |
| EP0082456B1 EP0082456B1 (fr) | 1986-10-15 |
Family
ID=6149087
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP82111555A Expired EP0082456B1 (fr) | 1981-12-18 | 1982-12-13 | Prémélanges concentrés d'agents adoucissant le linge |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US4476030A (fr) |
| EP (1) | EP0082456B1 (fr) |
| JP (1) | JPS58109681A (fr) |
| AT (1) | ATE22919T1 (fr) |
| BR (1) | BR8207359A (fr) |
| CA (1) | CA1193403A (fr) |
| DE (2) | DE3150179A1 (fr) |
| ZA (1) | ZA829282B (fr) |
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2139658A (en) * | 1983-05-11 | 1984-11-14 | Colgate Palmolive Co | Concentrated fabric softening composition |
| GB2157729A (en) * | 1984-04-19 | 1985-10-30 | Unilever Plc | Aqueous concentrated fabric softening composition |
| GB2157730A (en) * | 1984-04-19 | 1985-10-30 | Unilever Plc | Aqueous concentrated fabric softening composition |
| GB2157728A (en) * | 1984-04-19 | 1985-10-30 | Unilever Plc | Aqueous fabric softening composition |
| EP0163910A1 (fr) * | 1984-05-04 | 1985-12-11 | Hoechst Aktiengesellschaft | Produits de lavage contenant un agent adoucissant |
| EP0186967A1 (fr) * | 1984-11-30 | 1986-07-09 | Thomas Swan And Co., Ltd. | Dérivés d'imidazolines quaternisés appropriés pour l'application d'amollissants de textile |
| EP0164966A3 (en) * | 1984-06-12 | 1988-04-20 | Imperial Chemical Industries Plc | Fabric conditioners |
| EP0122141B1 (fr) * | 1983-04-08 | 1989-11-15 | Unilever Plc | Compositions adoucissantes pour matières textiles |
| EP0374609A3 (fr) * | 1988-12-17 | 1992-03-04 | Pfersee Chemie GmbH | Adoussicant hydrophile pour matériaux fibreux et son application |
| GB2260771A (en) * | 1991-10-23 | 1993-04-28 | Cussons Int Ltd | Fabric softener concentrate |
| WO1995006097A1 (fr) * | 1993-08-24 | 1995-03-02 | Sasol Chemical Industries (Proprietary) Limited | Composition de traitement de tissus |
| WO1996016147A1 (fr) * | 1994-11-17 | 1996-05-30 | Henkel Kommanditgesellschaft Auf Aktien | Dispersions aqueuses de cire |
| EP0437988B1 (fr) * | 1989-12-08 | 1996-06-19 | Rhone-Poulenc Chimie | Composé lessiviel à base d'un polyphosphate et d'un agent optiquement actif, son procédé de préparation et son utilisation en détergence |
| WO1997034976A1 (fr) * | 1996-03-22 | 1997-09-25 | The Procter & Gamble Company | Melange concentre stable servant a preparer une composition adoucissante pour tissus |
| WO1997034975A1 (fr) * | 1996-03-22 | 1997-09-25 | The Procter & Gamble Company | Composition concentree adoucissante pour textiles stable aux temperatures extremes et compose adoucissant hautement insature |
| EP0730023A3 (fr) * | 1995-03-01 | 1999-08-11 | Colgate-Palmolive Company | Concentrés de détergents |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3204165A1 (de) * | 1982-02-06 | 1983-08-11 | Hoechst Ag, 6230 Frankfurt | Konzentrierte waescheweichspuelmittel |
| US4772403A (en) * | 1985-01-30 | 1988-09-20 | Colgate Palmolive Company | Fabric softener composition |
| US4654152A (en) * | 1985-10-07 | 1987-03-31 | Domtar Inc. | Base mix fabric softener |
| US4741842A (en) * | 1986-01-27 | 1988-05-03 | Colgate-Palmolive Company | Particulate detergent softener compositions comprising a mixture of cationic softener and ethoxylated amine |
| DE3706664A1 (de) * | 1987-02-28 | 1988-09-08 | Henkel Kgaa | Fluessige textilbehandlungsmittel |
| US4885102A (en) * | 1987-07-17 | 1989-12-05 | Kao Corporation | Cloth-softening liquid composition containing quaternary ammonium compound and a polyether derivative or cationic surfactant polymer |
| DE68919236T2 (de) * | 1988-01-28 | 1995-04-06 | Unilever Nv | Textilbehandlungszubereitung und deren Herstellung. |
| JPH0756112B2 (ja) * | 1988-02-17 | 1995-06-14 | 花王株式会社 | 濃縮型衣料用柔軟仕上剤 |
| JP2631389B2 (ja) * | 1988-05-19 | 1997-07-16 | ライオン株式会社 | 柔軟剤組成物 |
| BR9610336A (pt) * | 1995-08-31 | 2005-08-23 | Colgate Palmolive Co | Composição de amaciamento de tecidos e processo de conferir maciez a tecidos |
| GB0121802D0 (en) | 2001-09-10 | 2001-10-31 | Unilever Plc | Fabric conditioning compositions |
| GB0121806D0 (en) | 2001-09-10 | 2001-10-31 | Unilever Plc | A method of reducing the viscosity of fabric conditioning compositions |
| AU2022407270A1 (en) | 2021-12-06 | 2024-07-04 | Reckitt Benckiser Health Limited | Laundry sanitizing and softening composition |
| GB2613660B (en) * | 2021-12-06 | 2024-07-17 | Reckitt Benckiser Health Ltd | Laundry sanitizing and softening composition |
| GB2629206A (en) | 2023-04-21 | 2024-10-23 | Reckitt Benckiser Llc | Laundry sanitizing and softening compositions |
| WO2025040730A1 (fr) | 2023-08-21 | 2025-02-27 | Reckitt Benckiser Health Limited | Composition de désinfection et d'assouplissement du linge |
| WO2025040727A1 (fr) | 2023-08-21 | 2025-02-27 | Reckitt Benckiser Health Limited | Composition aseptisante et assouplissante pour le linge |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3154489A (en) * | 1960-07-18 | 1964-10-27 | Armour & Co | Surface active compositions |
| DE2966013D1 (en) * | 1979-01-11 | 1983-09-01 | Procter & Gamble | Concentrated fabric softening composition |
| EP0018039B2 (fr) * | 1979-04-21 | 1988-08-24 | THE PROCTER & GAMBLE COMPANY | Composition adoucissante pour tissus |
| GR67665B (fr) * | 1979-05-21 | 1981-09-02 | Unilever Nv | |
| DE2928141A1 (de) * | 1979-07-12 | 1981-02-05 | Hoechst Ag | Waescheweichspuelmittel |
| DE2930061A1 (de) * | 1979-07-25 | 1981-02-19 | Hoechst Ag | Waescheweichspuelmittel |
| DE3263800D1 (en) * | 1981-01-16 | 1985-07-04 | Procter & Gamble | Textile treatment compositions |
-
1981
- 1981-12-18 DE DE19813150179 patent/DE3150179A1/de not_active Withdrawn
-
1982
- 1982-12-09 US US06/448,305 patent/US4476030A/en not_active Expired - Fee Related
- 1982-12-13 AT AT82111555T patent/ATE22919T1/de not_active IP Right Cessation
- 1982-12-13 DE DE8282111555T patent/DE3273801D1/de not_active Expired
- 1982-12-13 EP EP82111555A patent/EP0082456B1/fr not_active Expired
- 1982-12-17 CA CA000417988A patent/CA1193403A/fr not_active Expired
- 1982-12-17 ZA ZA829282A patent/ZA829282B/xx unknown
- 1982-12-17 BR BR8207359A patent/BR8207359A/pt unknown
- 1982-12-17 JP JP57220387A patent/JPS58109681A/ja active Granted
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0122141B1 (fr) * | 1983-04-08 | 1989-11-15 | Unilever Plc | Compositions adoucissantes pour matières textiles |
| GB2139658A (en) * | 1983-05-11 | 1984-11-14 | Colgate Palmolive Co | Concentrated fabric softening composition |
| GB2157729A (en) * | 1984-04-19 | 1985-10-30 | Unilever Plc | Aqueous concentrated fabric softening composition |
| GB2157730A (en) * | 1984-04-19 | 1985-10-30 | Unilever Plc | Aqueous concentrated fabric softening composition |
| GB2157728A (en) * | 1984-04-19 | 1985-10-30 | Unilever Plc | Aqueous fabric softening composition |
| US4622154A (en) * | 1984-04-19 | 1986-11-11 | Lever Brothers Company | Aqueous fabric softening composition |
| US4627925A (en) * | 1984-04-19 | 1986-12-09 | Lever Brothers Company | Aqueous concentrated fabric softening composition |
| EP0159196A3 (fr) * | 1984-04-19 | 1987-03-18 | Unilever N.V. | Composition adoucissante aqueuse concentrée pour tissus |
| EP0163910A1 (fr) * | 1984-05-04 | 1985-12-11 | Hoechst Aktiengesellschaft | Produits de lavage contenant un agent adoucissant |
| EP0164966A3 (en) * | 1984-06-12 | 1988-04-20 | Imperial Chemical Industries Plc | Fabric conditioners |
| EP0186967A1 (fr) * | 1984-11-30 | 1986-07-09 | Thomas Swan And Co., Ltd. | Dérivés d'imidazolines quaternisés appropriés pour l'application d'amollissants de textile |
| EP0374609A3 (fr) * | 1988-12-17 | 1992-03-04 | Pfersee Chemie GmbH | Adoussicant hydrophile pour matériaux fibreux et son application |
| EP0437988B1 (fr) * | 1989-12-08 | 1996-06-19 | Rhone-Poulenc Chimie | Composé lessiviel à base d'un polyphosphate et d'un agent optiquement actif, son procédé de préparation et son utilisation en détergence |
| GB2260771A (en) * | 1991-10-23 | 1993-04-28 | Cussons Int Ltd | Fabric softener concentrate |
| WO1995006097A1 (fr) * | 1993-08-24 | 1995-03-02 | Sasol Chemical Industries (Proprietary) Limited | Composition de traitement de tissus |
| GB2295626A (en) * | 1993-08-24 | 1996-06-05 | Sasol Chemical Ind | Fabric treatment composition |
| GB2295626B (en) * | 1993-08-24 | 1998-02-11 | Sasol Chemical Ind | Fabric treatment composition |
| WO1996016147A1 (fr) * | 1994-11-17 | 1996-05-30 | Henkel Kommanditgesellschaft Auf Aktien | Dispersions aqueuses de cire |
| EP0730023A3 (fr) * | 1995-03-01 | 1999-08-11 | Colgate-Palmolive Company | Concentrés de détergents |
| WO1997034976A1 (fr) * | 1996-03-22 | 1997-09-25 | The Procter & Gamble Company | Melange concentre stable servant a preparer une composition adoucissante pour tissus |
| WO1997034975A1 (fr) * | 1996-03-22 | 1997-09-25 | The Procter & Gamble Company | Composition concentree adoucissante pour textiles stable aux temperatures extremes et compose adoucissant hautement insature |
Also Published As
| Publication number | Publication date |
|---|---|
| US4476030A (en) | 1984-10-09 |
| DE3273801D1 (en) | 1986-11-20 |
| CA1193403A (fr) | 1985-09-17 |
| BR8207359A (pt) | 1983-10-18 |
| JPH0325549B2 (fr) | 1991-04-08 |
| JPS58109681A (ja) | 1983-06-30 |
| EP0082456A3 (en) | 1984-11-28 |
| DE3150179A1 (de) | 1983-06-23 |
| ZA829282B (en) | 1983-09-28 |
| ATE22919T1 (de) | 1986-11-15 |
| EP0082456B1 (fr) | 1986-10-15 |
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