EP0078277A1 - Chambre d'immersion et de vaporisation - Google Patents
Chambre d'immersion et de vaporisationInfo
- Publication number
- EP0078277A1 EP0078277A1 EP82901349A EP82901349A EP0078277A1 EP 0078277 A1 EP0078277 A1 EP 0078277A1 EP 82901349 A EP82901349 A EP 82901349A EP 82901349 A EP82901349 A EP 82901349A EP 0078277 A1 EP0078277 A1 EP 0078277A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- chamber
- immersion
- evaporation chamber
- melt
- openings
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000007654 immersion Methods 0.000 title claims abstract description 24
- 238000009834 vaporization Methods 0.000 title abstract description 3
- 230000008016 vaporization Effects 0.000 title abstract description 3
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 25
- 239000011777 magnesium Substances 0.000 claims abstract description 25
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 22
- 229910001018 Cast iron Inorganic materials 0.000 claims abstract description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 7
- 239000010439 graphite Substances 0.000 claims abstract description 7
- 238000004519 manufacturing process Methods 0.000 claims abstract description 6
- 239000000654 additive Substances 0.000 claims abstract description 5
- 238000006477 desulfuration reaction Methods 0.000 claims abstract description 5
- 230000023556 desulfurization Effects 0.000 claims abstract description 5
- 229910001296 Malleable iron Inorganic materials 0.000 claims abstract description 3
- 238000001704 evaporation Methods 0.000 claims description 30
- 230000008020 evaporation Effects 0.000 claims description 30
- 239000000155 melt Substances 0.000 claims description 30
- 238000011049 filling Methods 0.000 claims description 12
- 239000000945 filler Substances 0.000 claims description 6
- 238000007789 sealing Methods 0.000 claims description 6
- 230000002787 reinforcement Effects 0.000 claims description 5
- KKEBXNMGHUCPEZ-UHFFFAOYSA-N 4-phenyl-1-(2-sulfanylethyl)imidazolidin-2-one Chemical compound N1C(=O)N(CCS)CC1C1=CC=CC=C1 KKEBXNMGHUCPEZ-UHFFFAOYSA-N 0.000 claims description 4
- 229910000805 Pig iron Inorganic materials 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 3
- 239000000161 steel melt Substances 0.000 claims description 3
- 241000272814 Anser sp. Species 0.000 claims 1
- 239000000919 ceramic Substances 0.000 claims 1
- 230000001788 irregular Effects 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 2
- 239000010959 steel Substances 0.000 abstract description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- 229910001208 Crucible steel Inorganic materials 0.000 abstract 1
- 238000010348 incorporation Methods 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 description 5
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 230000009189 diving Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 230000001681 protective effect Effects 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 229910010293 ceramic material Inorganic materials 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000010349 pulsation Effects 0.000 description 2
- 239000011819 refractory material Substances 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C1/00—Refining of pig-iron; Cast iron
- C21C1/02—Dephosphorising or desulfurising
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C1/00—Refining of pig-iron; Cast iron
- C21C1/10—Making spheroidal graphite cast-iron
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
Definitions
- the present invention relates to an immersion evaporation chamber for introducing vaporizable additives into a melt, in particular pure magnesium, into a pig iron, cast iron or steel melt in a treatment vessel for desulfurization and / or for the production of cast iron with spheroidal graphite or vermicular graphite or magnesium-treated Te perguss.
- the immersion bulb made famous by DAS 2208960 for introducing magnesium into a melt is structurally complicated and complex.
- the arrangement shown allows only a slight utilization of the stirring effect produced by the kinetic energy of the steam emerging from this immersion bulb, combined with an intensive rinsing effect in the melt.
- the pressure changes (control vibration test) generated by the controlled evaporation in the chamber and thus also the escaping steam are to be largely reduced.
- Fer ⁇ ner the diving evaporation chamber should be simple constructive tion in the Kon ⁇ , production and be in use and as necessary as reusable chamber or only when his workedbiluet ⁇ "disposable chamber".
- a ratio of the total cross sections of the upper and lower opening, or openings _o ⁇ .2, has proven to be optimal
- a conventional treatment vessel e.g. a transport pan for the melt, which is lined with refractory material, is filled with melt.
- melt This can be cast iron, pig iron or steel melt.
- An immersion evaporation chamber according to the invention is immersed in the melt at a predetermined speed.
- This chamber is connected to a filling and holding tube.
- the chamber is either immersed in the melt through an opening in the easily removable lid of the treatment vessel, the filling and holding tube being able to be provided with a stop which is seated in a holder on the lid, or with the lid easily attached to the holding tube .
- the frictional connection of the buoyancy, evaporation and reaction forces acting on the chamber can or only via the immersion device and the cover of the treatment vessel can be reached via the diving device or the cover.
- the interior of the chamber is filled with pure magnesium, for example.
- the pure magnesium can be introduced into the chamber in lump or liquid form.
- the inner and outer shape of the chamber is selected and dimensioned according to flow-technical criteria with regard to steam and bath flow.
- the chamber is preferably immersed into the melt in an eccentric position with respect to the vertical central axis of the treatment vessel because of the criteria just mentioned and in order to make optimum use of the stirring effect which occurs when the magnesium vapors are mixed with the melt.
- the eccentric position of the chamber in the treatment vessel and / or the openings arranged eccentrically on the chamber support and reinforce the bath rotation and thus the flushing action and thus the separation of the reaction products, such as e.g. Slag.
- the openings provided in the chamber wall are arranged on at least two levels with regard to the installation position and can differ in their number and in their total cross-sectional area.
- the number, size and arrangement of the openings in the chamber wall are selected such that an optimal course of the evaporation of the re-magnesium in the chamber and the reaction of the steam with the melt is ensured. In this way, controlled, metered evaporation of the pure magnesium and thus a reaction process controlled within narrow limits is achieved.
- the total cross section Q of the opening or openings is preferably smaller than the total cross section Q of the opening or openings in the upper two thirds of the chamber wall.
- the number and size of the openings and the distance between the opening levels depend on various factors, such as, for example, the amount, the sulfur content and the treatment temperature of the melt to be treated.
- the chamber is connected to a filling and holding tube which protrudes through the protective cover of the treatment vessel.
- This tube can be covered with a refractory layer, preferably made of ceramic material, on the outside or inside or on both sides of part or all of the length protruding from the reaction chamber.
- the vertical axes of the holding or filling tube can coincide or be arranged offset.
- the holding and / or filler pipe can execute a rotating and / or pulsating movement, whereby three rotating movements and / or one vertical pulsation can be combined.
- the rotational and / or pulsating movement (s) of the immersion evaporation chamber enables an optimal mixing of the steam emerging from the chamber with the melt and thus the highest possible efficiency with the best possible reproducibility of the melt treatment.
- the protective cover has a collar-shaped jacket projecting downwards along the outside of the treatment vessel wall.
- OMPI which serves as a splash guard.
- One or more outlet openings for vapors that are not absorbed by the melt or that are released by the melt can be provided in the protective cover itself.
- the length of the jacket must be chosen so that the bottom edge of the jacket covers the top edge of the treatment vessel before the chamber is immersed in the melt.
- the hood-shaped cover can also be used directly for suction of the above-mentioned vapors and their reaction products with the air, for example MgO, by the above-mentioned outlet opening (s) directly with one or more suction line (s), for example via one or more flexible metal pipes can be connected.
- the chamber can also be designed as a disposable chamber in such a way that, after the evaporation has ended, the chamber completely or partially detaches from the holder and exits the melt as a unit or disintegrated.
- the chamber can also have two or more parts be, with a two-part design, a lower part of the container after it has been filled with magnesium is attached to a cover part which is connected to a stem, for example by means of a simple screw cap.
- a filler pipe of the type described above is superfluous and can be replaced by a simple handle.
- the chamber is filled with liquid magnesia, e.g. through one or more openings in the wall of the chamber and after the magnesium has solidified, it can be immersed in the melt, because of the more favorable volume-surface ratio of the piece of magnesium solidified in the chamber than in the case of lumpy magnesium, a quieter reaction course can be observed.
- a finer dosage of the filling weight of the magnesium is possible and the filling tube in the holding handle of the chamber is no longer required.
- the walls of the chamber can be made of conventional or high-strength refractory materials or combinations of materials
- the treatment sequence can be increased considerably, since the treatment device is better adapted to the operational conditions with regard to the previously known immersion devices and its handling is simplified .
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
- Treatment Of Steel In Its Molten State (AREA)
- Removal Of Specific Substances (AREA)
- Cylinder Crankcases Of Internal Combustion Engines (AREA)
Abstract
Dans cette chambre d'immersion et de vaporisation pour fonderie en fonctionnement, on prevoit, dans le tiers inferieur du cote du recipient de manutention ainsi que dans les deux tiers superieurs de la paroi interieure, une ouverture. Le nombre, la dimension et la section des ouvertures sont choisis de maniere a ce que la section totale Qu de l'ouverture ou des ouvertures du tiers inferieur est egale ou plus petite que la section totale Qo de l'ouverture ou des ouvertures des deux tiers superieurs. Selon une forme d'execution le rapport Qo/Qu est au moins egal a 2. L'application de cette chambre se concretise en l'incorporation d'additifs vaporisables dans la fonte notamment de magnesium pur dans un recipient de manutention contenant du fer brut, de la fonte ou de l'acier. Le procede convient pour la desulfuration et/ou la fabrication de fonte a graphite spheroidal ou vermicule et la fonte malleable.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH2990/81A CH656399A5 (de) | 1981-05-08 | 1981-05-08 | Tauch-verdampfungskammer. |
| CH2990/81 | 1981-05-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP0078277A1 true EP0078277A1 (fr) | 1983-05-11 |
Family
ID=4246178
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP82901349A Withdrawn EP0078277A1 (fr) | 1981-05-08 | 1982-05-04 | Chambre d'immersion et de vaporisation |
Country Status (23)
| Country | Link |
|---|---|
| US (1) | US4496393A (fr) |
| EP (1) | EP0078277A1 (fr) |
| JP (1) | JPS58500667A (fr) |
| AR (1) | AR228491A1 (fr) |
| AU (1) | AU551528B2 (fr) |
| BR (1) | BR8207694A (fr) |
| CA (1) | CA1194698A (fr) |
| CH (1) | CH656399A5 (fr) |
| DD (1) | DD202454A5 (fr) |
| DK (1) | DK4883A (fr) |
| ES (1) | ES511987A0 (fr) |
| HU (1) | HU191461B (fr) |
| IL (1) | IL65587A (fr) |
| IT (1) | IT1151385B (fr) |
| NO (1) | NO830038L (fr) |
| PH (1) | PH19358A (fr) |
| PL (1) | PL236323A1 (fr) |
| PT (1) | PT74800B (fr) |
| RO (1) | RO88051A (fr) |
| SU (1) | SU1232149A3 (fr) |
| WO (1) | WO1982003875A1 (fr) |
| YU (1) | YU89182A (fr) |
| ZA (1) | ZA823161B (fr) |
Families Citing this family (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4626244A (en) * | 1985-02-01 | 1986-12-02 | Consolidated Controls Corporation | Implantable medication infusion device |
| DK173273B1 (da) * | 1989-11-28 | 2000-06-05 | Fischer Ag Georg | Magnesiumbehandlingsfremgangsmåde og apparat til udøvelse af denne |
| IT1248457B (it) * | 1991-04-05 | 1995-01-19 | Benet Di Bennati Ettore | Metodo e apparecchiatura per il trattamento di bagni metallici mediante un materiale con elevato potenziale di gas o vapore |
| LU90005B1 (fr) * | 1997-01-15 | 1998-07-16 | Wurth Paul Sa | Procédé et installation pour le traitement de l'acer en poche |
| RU2247157C2 (ru) * | 2002-06-12 | 2005-02-27 | Сергей Николаевич Чепель | Способ ввода реагентов в расплав, перемешивания расплава металла и устройство для его осуществления |
| US7402276B2 (en) * | 2003-07-14 | 2008-07-22 | Cooper Paul V | Pump with rotating inlet |
| US20050013715A1 (en) | 2003-07-14 | 2005-01-20 | Cooper Paul V. | System for releasing gas into molten metal |
| US7470392B2 (en) * | 2003-07-14 | 2008-12-30 | Cooper Paul V | Molten metal pump components |
| US20070253807A1 (en) | 2006-04-28 | 2007-11-01 | Cooper Paul V | Gas-transfer foot |
| US7906068B2 (en) | 2003-07-14 | 2011-03-15 | Cooper Paul V | Support post system for molten metal pump |
| US8613884B2 (en) | 2007-06-21 | 2013-12-24 | Paul V. Cooper | Launder transfer insert and system |
| US8337746B2 (en) | 2007-06-21 | 2012-12-25 | Cooper Paul V | Transferring molten metal from one structure to another |
| US9156087B2 (en) | 2007-06-21 | 2015-10-13 | Molten Metal Equipment Innovations, Llc | Molten metal transfer system and rotor |
| US8366993B2 (en) | 2007-06-21 | 2013-02-05 | Cooper Paul V | System and method for degassing molten metal |
| US9205490B2 (en) | 2007-06-21 | 2015-12-08 | Molten Metal Equipment Innovations, Llc | Transfer well system and method for making same |
| US9409232B2 (en) | 2007-06-21 | 2016-08-09 | Molten Metal Equipment Innovations, Llc | Molten metal transfer vessel and method of construction |
| US9410744B2 (en) | 2010-05-12 | 2016-08-09 | Molten Metal Equipment Innovations, Llc | Vessel transfer insert and system |
| US9643247B2 (en) | 2007-06-21 | 2017-05-09 | Molten Metal Equipment Innovations, Llc | Molten metal transfer and degassing system |
| US8524146B2 (en) | 2009-08-07 | 2013-09-03 | Paul V. Cooper | Rotary degassers and components therefor |
| US8444911B2 (en) | 2009-08-07 | 2013-05-21 | Paul V. Cooper | Shaft and post tensioning device |
| US10428821B2 (en) | 2009-08-07 | 2019-10-01 | Molten Metal Equipment Innovations, Llc | Quick submergence molten metal pump |
| US8535603B2 (en) | 2009-08-07 | 2013-09-17 | Paul V. Cooper | Rotary degasser and rotor therefor |
| US8449814B2 (en) * | 2009-08-07 | 2013-05-28 | Paul V. Cooper | Systems and methods for melting scrap metal |
| US8714914B2 (en) | 2009-09-08 | 2014-05-06 | Paul V. Cooper | Molten metal pump filter |
| US9108244B2 (en) * | 2009-09-09 | 2015-08-18 | Paul V. Cooper | Immersion heater for molten metal |
| US9903383B2 (en) | 2013-03-13 | 2018-02-27 | Molten Metal Equipment Innovations, Llc | Molten metal rotor with hardened top |
| US9011761B2 (en) | 2013-03-14 | 2015-04-21 | Paul V. Cooper | Ladle with transfer conduit |
| US10052688B2 (en) | 2013-03-15 | 2018-08-21 | Molten Metal Equipment Innovations, Llc | Transfer pump launder system |
| US10465688B2 (en) | 2014-07-02 | 2019-11-05 | Molten Metal Equipment Innovations, Llc | Coupling and rotor shaft for molten metal devices |
| US10947980B2 (en) | 2015-02-02 | 2021-03-16 | Molten Metal Equipment Innovations, Llc | Molten metal rotor with hardened blade tips |
| US10267314B2 (en) | 2016-01-13 | 2019-04-23 | Molten Metal Equipment Innovations, Llc | Tensioned support shaft and other molten metal devices |
| US11149747B2 (en) | 2017-11-17 | 2021-10-19 | Molten Metal Equipment Innovations, Llc | Tensioned support post and other molten metal devices |
| US11931802B2 (en) | 2019-05-17 | 2024-03-19 | Molten Metal Equipment Innovations, Llc | Molten metal controlled flow launder |
| MX2023006967A (es) * | 2020-12-17 | 2023-06-23 | Foseco Int | Dispositivo giratorio para el tratamiento de metal fundido. |
| US11873845B2 (en) | 2021-05-28 | 2024-01-16 | Molten Metal Equipment Innovations, Llc | Molten metal transfer device |
| US12146508B2 (en) | 2022-05-26 | 2024-11-19 | Molten Metal Equipment Innovations, Llc | Axial pump and riser |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1168458B (de) * | 1961-06-16 | 1964-04-23 | Grafitschmelztiegelfabrik Cosa | Tauchglocke zum Einbringen von Legierungen in Metallschmelzen, insbesondere Gusseisen |
| DE1939140A1 (de) * | 1968-08-14 | 1970-02-19 | Allegheny Ludlum Steel | Vorrichtung zum Zugeben von Stoffen zu einem Gefaess mit geschmolzenem Metall |
| DE2208960C3 (de) * | 1972-02-25 | 1982-06-24 | Klöckner-Humboldt-Deutz AG, 5000 Köln | Tauchgefäß aus feuerfestem Material zum Einbringen von Reinmagnesium in eine Gußeisenschmelze |
| US3788624A (en) * | 1972-06-21 | 1974-01-29 | Bethlehem Steel Corp | Immersion bell |
| US4022444A (en) * | 1975-08-25 | 1977-05-10 | Reactive Metals & Alloys Corporation | Apparatus for adding mischmetal to molten steel |
| CH638242A5 (de) * | 1978-01-06 | 1983-09-15 | Fischer Ag Georg | Verfahren zur entschwefelung von groesseren mengen roheisen-, stahl- oder gusseisen-schmelzen. |
-
1981
- 1981-05-08 CH CH2990/81A patent/CH656399A5/de not_active IP Right Cessation
-
1982
- 1982-04-15 CA CA000401061A patent/CA1194698A/fr not_active Expired
- 1982-04-23 IL IL65587A patent/IL65587A/xx unknown
- 1982-04-26 PT PT74800A patent/PT74800B/pt unknown
- 1982-04-26 YU YU00891/82A patent/YU89182A/xx unknown
- 1982-04-26 PH PH27193A patent/PH19358A/en unknown
- 1982-04-28 AR AR289243A patent/AR228491A1/es active
- 1982-04-29 IT IT20993/82A patent/IT1151385B/it active
- 1982-05-04 US US06/459,539 patent/US4496393A/en not_active Expired - Fee Related
- 1982-05-04 HU HU821838A patent/HU191461B/hu unknown
- 1982-05-04 EP EP82901349A patent/EP0078277A1/fr not_active Withdrawn
- 1982-05-04 AU AU83939/82A patent/AU551528B2/en not_active Expired - Fee Related
- 1982-05-04 JP JP57501439A patent/JPS58500667A/ja active Pending
- 1982-05-04 WO PCT/CH1982/000065 patent/WO1982003875A1/fr not_active Ceased
- 1982-05-04 BR BR8207694A patent/BR8207694A/pt unknown
- 1982-05-06 DD DD82239638A patent/DD202454A5/de unknown
- 1982-05-06 PL PL23632382A patent/PL236323A1/xx unknown
- 1982-05-07 ZA ZA823161A patent/ZA823161B/xx unknown
- 1982-05-07 ES ES511987A patent/ES511987A0/es active Granted
-
1983
- 1983-01-06 RO RO83109626A patent/RO88051A/fr unknown
- 1983-01-06 SU SU833532671A patent/SU1232149A3/ru active
- 1983-01-07 NO NO830038A patent/NO830038L/no unknown
- 1983-01-07 DK DK4883A patent/DK4883A/da not_active Application Discontinuation
Non-Patent Citations (1)
| Title |
|---|
| See references of WO8203875A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| AR228491A1 (es) | 1983-03-15 |
| HU191461B (en) | 1987-02-27 |
| CH656399A5 (de) | 1986-06-30 |
| SU1232149A3 (ru) | 1986-05-15 |
| IT1151385B (it) | 1986-12-17 |
| HUT38401A (en) | 1986-05-28 |
| PL236323A1 (en) | 1983-02-28 |
| JPS58500667A (ja) | 1983-04-28 |
| BR8207694A (pt) | 1983-04-12 |
| ES8307299A1 (es) | 1983-06-16 |
| US4496393A (en) | 1985-01-29 |
| YU89182A (en) | 1985-04-30 |
| WO1982003875A1 (fr) | 1982-11-11 |
| PT74800A (de) | 1982-05-01 |
| DK4883D0 (da) | 1983-01-07 |
| NO830038L (no) | 1983-01-07 |
| IL65587A (en) | 1985-12-31 |
| AU551528B2 (en) | 1986-05-01 |
| AU8393982A (en) | 1982-11-24 |
| CA1194698A (fr) | 1985-10-08 |
| DD202454A5 (de) | 1983-09-14 |
| IL65587A0 (en) | 1982-07-30 |
| PH19358A (en) | 1986-04-02 |
| IT8220993A0 (it) | 1982-04-29 |
| ES511987A0 (es) | 1983-06-16 |
| RO88051B (ro) | 1985-10-31 |
| RO88051A (fr) | 1985-11-30 |
| ZA823161B (en) | 1983-03-30 |
| DK4883A (da) | 1983-01-07 |
| PT74800B (de) | 1983-10-26 |
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