EP0048008A1 - Method and apparatus for the direct production of hot metal from lump iron ore - Google Patents
Method and apparatus for the direct production of hot metal from lump iron ore Download PDFInfo
- Publication number
- EP0048008A1 EP0048008A1 EP81107215A EP81107215A EP0048008A1 EP 0048008 A1 EP0048008 A1 EP 0048008A1 EP 81107215 A EP81107215 A EP 81107215A EP 81107215 A EP81107215 A EP 81107215A EP 0048008 A1 EP0048008 A1 EP 0048008A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- melter gasifier
- gas stream
- shaft furnace
- direct reduction
- gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims abstract description 54
- 229910052742 iron Inorganic materials 0.000 title claims abstract description 27
- 238000000034 method Methods 0.000 title claims description 24
- 238000004519 manufacturing process Methods 0.000 title claims description 3
- 239000002184 metal Substances 0.000 title 1
- 229910052751 metal Inorganic materials 0.000 title 1
- 239000002245 particle Substances 0.000 claims abstract description 15
- 238000001816 cooling Methods 0.000 claims abstract description 5
- 239000007789 gas Substances 0.000 claims description 73
- 239000000112 cooling gas Substances 0.000 claims description 8
- 239000003245 coal Substances 0.000 claims description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 229910000805 Pig iron Inorganic materials 0.000 claims description 2
- 239000000428 dust Substances 0.000 description 7
- 238000002156 mixing Methods 0.000 description 5
- 239000013590 bulk material Substances 0.000 description 4
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000011946 reduction process Methods 0.000 description 2
- 230000000630 rising effect Effects 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000001174 ascending effect Effects 0.000 description 1
- 230000001914 calming effect Effects 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 230000010006 flight Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000033001 locomotion Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B13/00—Making spongy iron or liquid steel, by direct processes
- C21B13/14—Multi-stage processes processes carried out in different vessels or furnaces
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B13/00—Making spongy iron or liquid steel, by direct processes
- C21B13/0006—Making spongy iron or liquid steel, by direct processes obtaining iron or steel in a molten state
- C21B13/0013—Making spongy iron or liquid steel, by direct processes obtaining iron or steel in a molten state introduction of iron oxide into a bath of molten iron containing a carbon reductant
- C21B13/002—Reduction of iron ores by passing through a heated column of carbon
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B2100/00—Handling of exhaust gases produced during the manufacture of iron or steel
- C21B2100/40—Gas purification of exhaust gases to be recirculated or used in other metallurgical processes
- C21B2100/44—Removing particles, e.g. by scrubbing, dedusting
Definitions
- the invention relates to a method according to the preamble of patent claim 1. It also relates to a device according to the preamble of patent claim 8.
- a method and a ' device of this type are known from DE-OS 28 43 303.
- the reducing gas generated in the melter gasifier still has a temperature of about 1200 to 1400 ° C. at the point of exit from the melter gasifier and is also high in dust. load part. Therefore, it can only be fed to the direct reduction shaft furnace after cleaning and cooling to the temperature of around 800 ° C required for the direct reduction process. Direct introduction into the reduction furnace would quickly result in the bulk material sticking together and clogging the gaps due to the amount of dust carried along, making the direct reduction process impossible. Therefore, a direct connection between the direct reduction shaft furnace and the melter gasifier is prevented and the hot sponge iron is conveyed from the direct reduction shaft furnace into the melter gasifier by means of a lock designed as a shut-off device.
- the object of the invention is to enable a continuous transport of the hot sponge iron particles from the direct reduction shaft furnace into the melter gasifier in a method and a device of the type mentioned in the introduction, without causing the difficulties mentioned.
- the process is intended to ensure reliable, long-term transport of iron sponge particles heated to just below the softening temperature from the direct reduction shaft furnace into the melter gasifier.
- the inventive solution is dispensed with the locks, the hot, the over 1200 0 C and prevent polluted reducing gas from the melter gasifier from passing through the discharge opening into the reduction shaft furnace. It has been shown that a small part of the reducing gas generated in the melter gasifier can be introduced into the reduction unit in countercurrent to the sponge iron particles if this gas is cooled in front of the discharge device to temperatures below the softening temperature of the sponge iron being conveyed. In the cooling process it appears essential that this does not reduce the quality of the reducing gas. It has proven to be particularly advantageous, sufficient in the Usually to below 100 ° C, add cooled and cleaned reducing gas.
- a substantial proportion of the dust carried is deposited in the area of the outlet side of the discharge device and is discharged together with the sponge iron particles by the discharge device. Because: with the proportion of the uncleaned reducing gas flowing in directly via the discharge device in relation to the gas blown into the reduction zone, cleaned and cooled to process temperature, the flow resistance in the flow path of the uncleaned reducing gas must be considerably higher than in the flow path of the cleaned and up Process temperature cooled cooling gas. The flow resistance for the first-mentioned flow path is primarily determined by the discharge device and the pouring column up to the injection nozzles for the cleaned and cooled reducing gas.
- a discharge device should therefore be used which has a relatively high flow resistance, while the flow resistance in the main flow path of the reducing gas should be kept as small as possible by suitable selection of dedusting and cooling devices.
- Screw conveyors the conveyor part of which is designed as a paddle screw and the outlet opening of which opens directly into a downpipe connected to the melter gasifier, have proven to be particularly suitable as the discharge device.
- the screw conveyors cause a relatively high pressure loss and at the same time form a good dust filter that "cleans itself” together with the sponge iron particles due to the constant discharge of the collected dust particles.
- the device schematically shown in Fig. 1 for the direct production of molten pig iron from lumpy iron ore contains a melter gasifier 1 of the type described in DE-OS 28 43 303. Above the melter gasifier is a direct reduction shaft furnace 2 suspended in a steel structure, not shown, arranged in the Principle is described for example in DE-OS 29 35 707.
- the direct reduction shaft furnace is supplied with 3-piece iron ore via a gas-tight double bell lock, which sinks in the form of a loose bed in the shaft furnace and is reduced to sponge iron at a temperature between 760 and 850 ° C by means of a hot reducing gas blown in via a central gas inlet 4.
- the used reducing gas leaves the shaft furnace 2 via an upper gas outlet 5 and can be returned to the reducing gas circuit in a known manner or used in some other way.
- the hot sponge iron obtained by reducing the lumpy iron ore is discharged from the direct reduction shaft furnace 2 at a temperature of about 750 ° to 800 ° C. and continuously charged into the melter gasifier from above.
- a coal fluidized bed 8 is formed in the melter gasifier from coal introduced through openings 6 and oxygen-containing gas, in particular oxygen and air, which is blown in through twelve radially arranged nozzles 7, in which even larger iron sponge particles are noticeably decelerated and up to the entry into a high-temperature zone in the lower section of the coal fluidized bed one substantial amount in their temperature and finally be melted.
- the coal fluidized bed 8 there is a calming space into which radial nozzles 9 open, through which water vapor, hydrocarbons or a reducing gas, for example cooled down to 50 ° C., are blown in to cool the hot reducing gas generated in the melter gasifier.
- the reducing gas generated in the melter gasifier leaves the melter gasifier above the settling chamber through two gas outlets 10 with a temperature between 1200 and 1400 ° C. and a pressure of about 2 bar. It then arrives at a mixing point 11, in which it is at a sufficiently low temperature for the cooling gas. Direct reduction necessary temperature, usually from 760 to 850 ° C, is brought.
- the mixing point is designed such that a part of the kinetic energy of the cooling gas is recovered as pressure after mixing with the hot reducing gas supplied by the melter gasifier, and the pressure loss in the hot gas path is thus kept as low as possible.
- the gas reaches a cyclone separator 12, in which the coke dust and ash entrained with the gas flow are largely separated.
- the hot gas stream cooled and cleaned to the prescribed process temperature is divided, namely about 60 vol .-% of which are blown as the first partial gas stream 13 through the gas inlet 4 into the reduction zone of the direct reduction shaft furnace 2, while the other part for cooling gas extraction is an injection cooler 14 and then a washing tower 15 is supplied.
- the cooling gas emerging here is compressed by a compressor 16 and at a temperature of approximately 50 ° C. for temperature control of the hot reducing gas of the mixing point 11 emerging from the melter gasifier, to control the temperature of the reducing gas in the melter, the nozzles 9 and, as described later, a ring line 22.
- each screw conveyor 17 is arranged radially symmetrically to the central axis of the furnace, which are designed as paddle screws and are supported on one side.
- the outlet opening 18 of each screw conveyor is connected to a connecting line in the form of a downpipe 19 which opens through the ceiling of the melter gasifier 1 into the settling chamber of this gasifier. Accordingly, six axially symmetrically arranged downpipes are also provided in the present case.
- a nozzle 21 from a ring line 22 opens into each downpipe, to which the compressor 16 feeds a stream of the reducing gas, which has been cooled to 50 ° C and is supplied by the melter gasifier, and which is called the third partial gas stream 23.
- second partial gas stream 24 The entire gas stream from unpurified reducing gas flowing directly from the melter gasifier into the downpipes is referred to as second partial gas stream 24.
- the temperature of the second partial gas stream 24 'flowing into the downpipes 19 is cooled to a temperature between 760 and 850 ° C. by means of the cooling gas introduced in a controlled amount via the nozzles 21 before the gas streams via the Screw conveyor 17 get into the reduction shaft furnace.
- the cooling gas is supplied in such a way that there is particularly good swirling with the rising raw gas.
- the dust contained in the ascending gas stream when entering the screw conveyor 17 settles essentially in the area of the screw conveyor and is successively conveyed back together with the sponge iron particles back into the downpipe in question and into the melter gasifier.
- the second partial gas stream 24 i.e. That is, the amount of raw gas flowing directly upwards from the melter gasifier via the six downpipes 19 to a maximum of 30% by volume of the total amount of reducing gas introduced into the direct reduction shaft furnace.
- the flow resistance for the second partial gas stream 24 in the flow path up to the reduction zone in the direct reduction shaft furnace i.e. So up to the level of the gas inlet 4 is greater than the flow resistance for the first partial gas flow 13 in the flow path from the gas outlet 10 to the gas inlet 4.
- This requirement meets the design of the discharge device 17 as a screw conveyor, the conveyor part is designed as a paddle screw.
- the flow resistance and thus the pressure losses in the flow path of the first partial gas stream 13 are deliberately kept low.
- the inventive design of the method and the device enables a direct continuous transport of the hot sponge iron particles from the direct reduction shaft furnace 2 into the melter gasifier 1 without locks or other complex devices for sealing against the hot reducing gas being required, which at the high temperature and A rt of the material to be conveyed can only be realized with difficulty with the required operational safety.
- the screw conveyor is. flanged to a socket 31 welded to the jacket of the direct reduction shaft furnace.
- a socket 31 welded to the jacket of the direct reduction shaft furnace.
- an outlet socket 32 on the outlet side 18 of the conveyor for flange-mounting a downpipe 19 (see also FIG. 1).
- the conveying part envelops a cladding tube 33, which is also flanged to the socket 31.
- the screw conveyor 17 contains a conveyor part 36 protruding into the furnace, a bearing part 34 flanged out of the furnace on the connecting piece 31 and a drive part 44.
- the conveying part 36 has the shape of an interrupted worm gear formed by paddles 37, the envelope 38 of the paddle screw shown in broken lines tapering conically towards the free end of the shaft 35. This free end extends almost to the middle of the shaft furnace and ensures the conical tapering of the envelope. an even removal of the bulk material from the bulk column.
- the shaft 35 is water-cooled and hollow for this purpose with an inner tube 39, which ends just before the free end of the shaft 35 and into which the cooling water is introduced, which is then diverted at the free end and in the annular gap between the central tube 39 and the inner wall of the shaft 35 flows back.
- the drive 44 is constructed as follows. To rotate the shaft 35, a ratchet mechanism 45 with a wheel 40, in the teeth of which a pawl 41 engages, which is rotatably attached to a lever 42, which in turn is rotatably seated on the shaft 35, and by means of a hydraulically or pneumatically actuated piston 43 by one predetermined angular movement can be pivoted back and forth.
- the pawl 41 rotates the wheel 40 by an amount corresponding to the tooth pitch or a multiple of the tooth pitch.
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture Of Iron (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Vertical, Hearth, Or Arc Furnaces (AREA)
- Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
- Revetment (AREA)
- Artificial Fish Reefs (AREA)
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
- Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
Abstract
Heiße Eisenschwammpartikel werden aus einem Direktreduktionsschactofen (2) durch Schneckenförderer (17) über Verbindungsleitungen (19) direkt in einen Einschmelzvergaser (1) gefördert und ein sich über diesen direkten Weg ausbildender Gasstrom (24) von Einschmelzvergaser (1) in den Direktreduktionsschachtofen (2) nach Kühlung auf unterhalb 950°C auf maximal 30 Vol.-% der dem Direktreduktionsschachtofen (2) insgesamt zugeführten Reduktionsgasmenge begrenzt.Hot sponge iron particles are conveyed from a direct reduction choke furnace (2) by screw conveyors (17) via connecting lines (19) directly into a melter gasifier (1) and a gas stream (24) from the melter gasifier (1) that forms via this direct path into the direct reduction shaft furnace (2) After cooling to below 950 ° C., it is limited to a maximum of 30 vol.% of the total amount of reducing gas supplied to the direct reduction shaft furnace (2).
Description
Die Erfindung betrifft ein Verfahren gemäß dem Oberbegriff des Patentanspruchs 1..Sie bezieht sich ferner auf eine Vorrichtung gemäß dem Oberbegriff des Patentanspruchs 8.The invention relates to a method according to the preamble of patent claim 1. It also relates to a device according to the preamble of patent claim 8.
Ein Verfahren und eine'Vorrichtung dieser Art sind durch die DE-OS 28 43 303 bekannt geworden. Das im Einschmelzvergaser erzeugte Reduktionsgas weist an der Austrittsstelle aus dem Einschmelzvergaser noch eine Temperatur von etwa 1200 bis 1400°C auf und ist außerdem mit einem hohen Staub- . anteil beladen. Deshalb kann es erst nach dem Reinigen und Abkühlen auf die für den Direktreduktionsprozess erforderliche Temperatur von etwa 800°C dem Direktreduktionsschachtofen zugeführt werden. Ein unmittelbares-Einleiten in den Reduktionsofen würde binnen kurzer Zeit zum Verkleben des Schüttgutes und zum Zusetzen der Zwischenräume durch den mitgeführten Staubanteil führen und damit den Direktreduktionsprozess unmöglich machen. Deshalb wird eine direkte Verbindung zwischen dem Direktreduktionsschachtofen und dem Einschmelzvergaser verhindert und der heiße Eisenschwamm wird mittels einer als Absperrorgan ausgebildeten Schleuse vom Direktreduktionsschachtofen in den Einschmelzvergaser gefördert.A method and a ' device of this type are known from DE-OS 28 43 303. The reducing gas generated in the melter gasifier still has a temperature of about 1200 to 1400 ° C. at the point of exit from the melter gasifier and is also high in dust. load part. Therefore, it can only be fed to the direct reduction shaft furnace after cleaning and cooling to the temperature of around 800 ° C required for the direct reduction process. Direct introduction into the reduction furnace would quickly result in the bulk material sticking together and clogging the gaps due to the amount of dust carried along, making the direct reduction process impossible. Therefore, a direct connection between the direct reduction shaft furnace and the melter gasifier is prevented and the hot sponge iron is conveyed from the direct reduction shaft furnace into the melter gasifier by means of a lock designed as a shut-off device.
Derartige Schleusen haben sich wegen der hohen Temperaturen und wegen der Baschaffenheit des Schüttgutes als störanfällig erwiesen. Es kommt vor, daß sich an den Schließstellen der Absperrorgane Material festsetzt und damit kein gasdichter Abschluß mehr gewährleistet ist. Die heißen aufsteigenden Gase, die das Schüttgut über ihren Erweichungspunkt erwärmen, führen dann bald zu weiteren Schwierigkeiten infolge eines Zusammenbackens der Eisenschwammpartikel.Such locks have proven to be prone to failure because of the high temperatures and because of the bulk of the bulk material. It happens that material closes at the closing points of the shut-off devices and therefore no more gas-tight closure is guaranteed. The hot rising gases that heat the bulk material above their softening point will soon lead to further difficulties due to caking of the iron sponge particles.
Aufgabe der Erfindung ist es, bei einem Verfahren und einer Vorrichtung der einleitend genannten Art einen kontinuierlichen Transport der heißen Eisenschwammpartikel aus dem Direktreduktionsschachtofen in den Einschmelzvergaser zu ermöglichen, ohne daß es zu den erwähnten Schwierigkeiten kommt. Das Verfahren soll im Hinblick auf einen hohen thermischen Wirkungsgrad des Gesamtprozesses einen auf Dauer betriebssicheren Transport von auf knapp unterhalb der Erweichungstemperatur erhitzten Eisenschwammpartikeln aus dem Direktreduktionsschachtofen in den Einschmelzvergaser ermöglichen.The object of the invention is to enable a continuous transport of the hot sponge iron particles from the direct reduction shaft furnace into the melter gasifier in a method and a device of the type mentioned in the introduction, without causing the difficulties mentioned. In view of the high thermal efficiency of the overall process, the process is intended to ensure reliable, long-term transport of iron sponge particles heated to just below the softening temperature from the direct reduction shaft furnace into the melter gasifier.
Diese Aufgabe ist bei einem Verfahren der genannten Art durch die kennzeichnenden Merkmale des Anspruches 1 gelöst. Vorteilhafte Ausgestaltungen des Verfahrens sind den Ansprüchen 2 bis 7 zu entnehmen. Die erfindungsgemäße Vorrichtung ist durch die Merkmale des Anspruchs 8 gekennzeichnet, vorteilhafte Ausgestaltungen der Vorrichtung sind den restlichen Ansprüchen zu entnehmen.This object is achieved in a method of the type mentioned by the characterizing features of claim 1. Advantageous embodiments of the method can be found in
Bei der erfindungsgemäßen Lösung wird auf die Schleusen verzichtet, die das über 12000C heiße und verschmutzte Reduktionsgas aus dem Einschmelzvergaser daran hindern, über die Austragöffnung in den Reduktionsschachtofen zu gelangen. Es hat sich gezeigt, daß ohne Schwierigkeiten ein kleiner Teil des im Einschmelzvergaser erzeugten Reduktionsgases im Gegenstrom zu den Eisenschwammpartikeln in das Reduktionsaggregat eingeleitet werden kann, wenn dieses Gas vor der Austragvorrichtung auf Temperaturen unterhalb der Erweichungstemperatur des geförderten Eisenschwammes abgekühlt wird. Beim Abkühlprozess erscheint es wesentlich, daß dieser die Güte des Reduktionsgases nicht verringert.:Als besonders vorteilhaft hat es sich erwiesen, ausreichend, in der Regel auf unterhalb 100°C,abgekühltes und gereinigtes Reduktionsgas beizumischen. Ein wesentlicher Anteil des mitgeführten Staübs setzt sich im Bereich der Austrittsseite der Austragvorrichtung ab und wird durch die Austragvorrichtung zusammen mit den Eisenschwammpartikeln ausgetragen. Da-: mit der Anteil des über die Austragvorrichtung direkt einströmenden ungereinigten Reduktionsgases im Verhältnis zu dem in die Reduktionszone eingeblasenen, gereinigten und auf Prozesstemperatur abgekühlten Gas klein gehalten wird, muß der Strömungswiderstand im Strömungsweg des ungereinigten Reduktionsgases wesentlich höher als im Strömungsweg des gereinigten und auf Prozesstemperatur abgekühlten Reduktionsgases sein. Der Strömungswiderstand wird für den erstgenannten Strömungsweg in erster Linie durch die Austragvorrichtung und die Schüttsäule bis zu den Einblasdüsen für das gereinigte und gekühlte Reduktionsgas bestimmt. Es sollte deshalb eine Austragvorrichtung zur Anwendung kommen, die einen verhältnismäßig hohen Strömungswiderstand aufweist, während der Strömungswiderstand im Hauptströmungsweg des Reduktionsgases durch geeignete Auswahl von Entstaubungs-und Kühlvorrichtungen möglichst klein gehalten werden soll. Als Austragvorrichtung haben sich Schneckenförderer, deren Förderteil als Paddelschnecke ausgebildet ist und deren Austrittsöffnung jeweils unmittelbar in ein mit dem Einschmelzvergaser verbundenes Fallrohr mündet, als besonders geeignet erwiesen. Die Schneckenförderer bedingen einen verhältnismäßig hohen Druckverlust und bilden zugleich ein gutes Staubfilter, das sich durch den ständigen Austrag der aufgefangenen Staubteilchen zusammen mit den Eisenschwammpartikeln "selbst reinigt".In the inventive solution is dispensed with the locks, the hot, the over 1200 0 C and prevent polluted reducing gas from the melter gasifier from passing through the discharge opening into the reduction shaft furnace. It has been shown that a small part of the reducing gas generated in the melter gasifier can be introduced into the reduction unit in countercurrent to the sponge iron particles if this gas is cooled in front of the discharge device to temperatures below the softening temperature of the sponge iron being conveyed. In the cooling process it appears essential that this does not reduce the quality of the reducing gas. It has proven to be particularly advantageous, sufficient in the Usually to below 100 ° C, add cooled and cleaned reducing gas. A substantial proportion of the dust carried is deposited in the area of the outlet side of the discharge device and is discharged together with the sponge iron particles by the discharge device. Because: with the proportion of the uncleaned reducing gas flowing in directly via the discharge device in relation to the gas blown into the reduction zone, cleaned and cooled to process temperature, the flow resistance in the flow path of the uncleaned reducing gas must be considerably higher than in the flow path of the cleaned and up Process temperature cooled cooling gas. The flow resistance for the first-mentioned flow path is primarily determined by the discharge device and the pouring column up to the injection nozzles for the cleaned and cooled reducing gas. A discharge device should therefore be used which has a relatively high flow resistance, while the flow resistance in the main flow path of the reducing gas should be kept as small as possible by suitable selection of dedusting and cooling devices. Screw conveyors, the conveyor part of which is designed as a paddle screw and the outlet opening of which opens directly into a downpipe connected to the melter gasifier, have proven to be particularly suitable as the discharge device. The screw conveyors cause a relatively high pressure loss and at the same time form a good dust filter that "cleans itself" together with the sponge iron particles due to the constant discharge of the collected dust particles.
Die Erfindung wird durch ein Ausführungsbeispiel anhand von zwei Figuren näher erläutert. Es zeigen
- Fig. 1 eine schematische Darstellung des Verfahrens und der Vorrichtung,
- Fig. 2 in einem Längsschnitt einen Schneckenförderer zum Heißaustrag der Eisenschwammpartikel.
- F ig. 1 shows a schematic representation of the method and the device,
- Fig. 2 in a longitudinal section a screw conveyor for hot discharge of the sponge iron particles.
Die in Fig. 1 schematisch dargestellte Vorrichtung zur direkten Erzeugung von flüssigem Roheisen aus stückigem Eisenerz enthält einen Einschmelzvergaser 1 der in der DE-OS 28 43 303 beschriebenen Art. Oberhalb des Einschmelzvergasers ist ein in einer nicht dargestellten Stahlkonstruktion aufgehängter Direktreduktionsschachtofen 2 angeordnet, der im Prinzip beispielsweise in der DE-OS 29 35 707 beschrie- ― ben ist. Dem Direktreduktionsschachtofen wird über einen gasdichten Doppelglockenverschluß 3 stückiges Eisenerz zugeführt, das in Form einer losen Schüttung im Schachtofen absinkt und mittels eines über einen mittleren Gaseinlaß 4 eingeblasenen heißen Reduktionsgases einer Temperatur zwischen 760 und 850°C zu Eisenschwamm reduziert wird. Das verbrauchte Reduktionsgas verläßt den Schachtofen 2 über einen oberen Gasauslaß 5 und kann in bekannter Weise in den Reduktionsgaskreislauf zurückgeführt oder anderweitig ausgenutzt werden.The device schematically shown in Fig. 1 for the direct production of molten pig iron from lumpy iron ore contains a melter gasifier 1 of the type described in DE-OS 28 43 303. Above the melter gasifier is a direct
Der durch Reduktion des stückigen Eisenerzes erhaltene heiße Eisenschwamm wird mit einer Temperatur von etwa 750° bis 800°C unten aus dem Direktreduktionsschachtofen 2 ausgetragen und kontinuierlich von oben in den Einschmelzvergaser chargiert. Im Einschmelzvergaser wird aus über öffnungen 6 eingebrachter Kohle und durch zwölf radial angeordnete Düsen 7 eingeblasenem sauerstoffhaltigem Gas, insbesondere Sauerstoff und Luft, ein Kohlefließbett 8 gebildet, in dem auch größere Eisenschwammpartikel merklich abgebremst und bis zum Eintritt in eine Hochtemperaturzone im unteren Abschnitt des Kohlefließbettes um einen wesentlichen Betrag in ihrer Temperatur erhöht und schließlich aufgeschmolzen werden.The hot sponge iron obtained by reducing the lumpy iron ore is discharged from the direct
Oberhalb des Kohlefließbettes 8 schließt sich ein Beruhigungsraum an, in den radiale Düsen 9 münden, durch die zur Kühlung des im Einschmelzvergaser erzeugten heißen Reduktionsgases Wasserdampf, Kohlenwasserstoffe oder ein beispielsweise auf 50°C herabgekühltes Reduktionsgas eingeblasen werden. Das im Einschmelzvergaser erzeugte Reduktionsgas verläßt den Einschmelzvergaser oberhalb des Beruhigungsraumes durch zwei Gasauslässe 10 mit einer Temperatur zwischen 1200 und 1400°C und einem Druck von etwa 2 bar. Es gelangt dann zu einer Mischstelle 11, in der es mit Kühlgas ausreichend niedriger Temperatur auf die für die . Direktreduktion notwendige Temperatur, in der Regel von 760 bis 850°C, gebracht wird. Die Mischstelle ist strömungstechnisch so ausgebildet, daß ein Teil der kinetischen Energie des Kühlgases nach Durchmischung mit dem heißen vom Einschmelzvergaser gelieferten Reduktionsgas als Druck wiedergewonnen wird und damit der Druckverlust im Heißgasweg möglichst gering gehalten wird. Von der Mischstelle gelangt das Gas zu einem Zyklonabscheider 12, in dem der mit dem Gasstrom mitgerissene Koksstaub und Asche weitgehend abgeschieden werden. Sodann wird der auf die vorgeschriebene Prozesstemperatur abgekühlte und gereinigte Heißgasstrom geteilt, und zwar werden etwa 60 Vol.-% hiervon als erster Teilgasstrom 13 durch den Gaseinlaß 4 in die Reduktionszone des Direktreduktionsschachtofens 2 eingeblasen, während der andere Teil zur Kühlgasgewinnung einem Einspritzkühler 14 und dann einem Waschturm 15 zugeführt wird. Das hier austretende Kühlgas wird durch einen Kompressor 16 komprimiert und mit einer Temperatur von etwa 50°C zur Temperaturregelung des aus dem Einschmelzvergaser austretenden heißen Reduktionsgases der Mischstelle 11, zur Temperaturregelung des Reduktionsgases im Einschmelzvergaser den.Düsen 9 und ferner, wie später beschrieben, einer Ringleitung 22 zugeführt.Above the coal fluidized bed 8 there is a calming space into which radial nozzles 9 open, through which water vapor, hydrocarbons or a reducing gas, for example cooled down to 50 ° C., are blown in to cool the hot reducing gas generated in the melter gasifier. The reducing gas generated in the melter gasifier leaves the melter gasifier above the settling chamber through two
Für den Heißaustrag der Eisenschwammpartikel aus dem.Direktreduktionsschachtofen 2 sind symmetrisch zur Mittelachse des.Ofens radial sechs Schneckenförderer 17 angeordnet, die als Paddelschnecken ausgebildet und einseitig gelagert sind. Die Austrittsöffnung 18 jedes Schneckenförderers steht mit einer Verbindungsleitung in Form eines Fallrohres 19 in Verbindung, die durch die Decke des Einschmelzvergasers 1 in den Beruhigungsraum dieses Vergasers mündet. Es sind demnach im vorliegenden Fall auch sechs axialsymmetrisch angeordnete Fallrohre vorgesehen. Möglichst nahe am Eintritt in den Einschmelzvergaser mündet in jedes Fallrohr eine Düse 21 aus einer Ringleitung 22, der vom Kompressor 16 ein als dritter Teilgasstrom 23 bezeichneter Strom des auf 50°C abgekühlten und gereihigten vom Einschmelzvergaser gelieferten Reduktionsgases zugeführt wird.For the hot discharge of the sponge iron particles from the direct
Während bei bekannten Verfahren und Anlagen durch aufwendige Maßnahmen verhindert wird, daß das ungereinigte und zu heiße Reduktionsgas ohne Aufbereitung in den Direktreduktionsschachtofen gelangen kann, wird bei dem vorliegenden Verfahren ein begrenzter Gasstrom unmittelbar vom Einschmelzvergaser über die Austragvorrichtung 17 für den heißen Eisenschwamm im Gegenstrom zu diesem zugelassen. Der gesamte, direkt aus dem Einschmelzvergaser in die Fallrohre strömende Gasstrom aus ungereinigtem Reduktionsgas ist als zweiter Teilgasstrom 24 bezeichnet. Die Temperatur des in die Fallrohre 19 einströmenden zweiten Teilgasstromes 24 'wird mittels des über die Düsen 21 in geregelter Menge eingeleiteten Kühlgases auf eine Temperatur zwischen 760 und 850°C abgekühlt, bevor die Gasströme über die Schneckenförderer 17 in den Reduktionsschachtofen gelangen. Das Kühlgas wird so zugeführt, daß eine besonders gute Verwirbelung mit dem aufsteigenden Rohgas eintritt. Der beim Eintritt in den Schneckenförderer 17 im aufsteigenden Gasstrom enthaltene Staub setzt sich im wesentlichen im Bereich des Schneckenförderers ab und wird sukzessive zusammen mit den Eisenschwammpartikeln wieder in das betreffende Fallrohr und in den Einschmelzvergaser zurück befördert.While in known methods and systems, complex measures prevent the unpurified and too hot reducing gas from entering the direct reduction shaft furnace without preparation, in the present method a limited gas flow is directly from the melter gasifier via the
Wesentlich ist eine Begrenzung des zweiten Teilgasstromes 24, d.h. also der über die sechs Fallrohre 19 unmittelbar vom Einschmelzvergaser nach oben strömenden Rohgasmenge auf einen Anteil von maximal 30 Vol.-% der gesamten in den Direktreduktionsschachtofen eingeleiteten Reduktionsgasmenge. Zu diesem Zweck ist es erforderlich, daß der Strömungswiderstand für den zweiten Teilgasstrom 24 im Strömungsweg bis zur Reduktionszone im Direktreduktionsschachtofen, d.h. also bis zur Ebene des Gaseinlasses 4, größer ist als der Strömungswiderstand für den ersten Teilgasstrom 13 im Strömungsweg vom Gasauslaß 10 bis zum Gaseinlaß 4. Dieser Forderung kommt die Ausbildung der Austragvorrichtung 17 als Schneckenförderer, deren Förderteil als Paddelschnecke ausgebildet ist, entgegen. Im übrigen werden der Strömungswiderstand und damit die Druckverluste im Strömungsweg des ersten Teilgasstromes 13 bewußt klein gehalten.It is essential to limit the second
Durch die erfindungsgemäße Ausbildung des Verfahrens und der Vorrichtung wird ein unmittelbarer kontinuierlicher Transport der heißen Eisenschwammpartikel aus dem Direktreduktionsschachtofen 2 in den Einschmelzvergaser 1 ermöglicht, ohne daß Schleusen oder andere aufwendige Einrichtungen zur Abdichtung gegenüber dem heißen Reduktionsgas erforderlich sind, die bei der hohen Temperatur und der Art des zu fördernden Materials nur unter Schwierigkeiten mit der erforderlichen Betriebssicherheit realisierbar sind.The inventive design of the method and the device enables a direct continuous transport of the hot sponge iron particles from the direct
In Fig. 2 ist teilweise im Längsschnitt einer der sechs Schneckenförderer 17 dargestellt. Der Schneckenförderer ist . an einem mit dem Mantel des Direktreduktionsschachtofens verschweißten Stutzen 31 angeflanscht. Im Stutzen 31 befindet sich an der Austrittsseite 18 des Förderers ein Austrittsstutzen 32 zum Anflanschen eines Fallrohres 19 (siehe auch Fig. 1). Als Verschleißschutz für das Mauerwerk umhüllt den Förderteil ein Hüllrohr 33, das ebenfalls am Stutzen 31 angeflanscht ist.2 one of the six
Der Schneckenförderer 17 enthält einen in den Ofen hineinragenden Förderteil 36 sowie einen am Stutzen 31 angeflanschten aus dem Ofen herausragenden Lagerteil 34 und einen Antriebsteil 44.The
Der Förderteil 36 hat die Form eines durch Paddeln 37 gebildeten unterbrochenen Schneckengangs, wobei sich die gestrichelt eingezeichnete Umhüllende 38 der Paddelschnecke zum freien Ende der Welle 35 hin konisch verjüngt. Dieses freie Ende reicht bis nahezu in die Mitte des Schachtofens und gewährleistet durch die konische Verjüngung der Umhüllenden . eine gleichmäßige Entnahme des Schüttgutes aus der Schüttsäule.The conveying
Die Welle 35 ist wassergekühlt und für diesen Zweck hohl ausgebildet mit einem Innenrohr 39, das kurz vor dem freien Ende der Welle 35 endet und in das das Kühlwasser eingeführt wird, welches sodann am freien Ende umgeleitet wird und im Ringspalt zwischen dem zentralen Rohr 39 und der Innenwand der Welle 35 zurückströmt.The
Der Antrieb 44 ist wie folgt aufgebaut. Zum Drehen der Welle 35 dient ein Klinkenschaltwerk 45 mit einem Rad 40, in dessen Zähne eine Klinke 41 eingreift, die drehbar an einem Hebel 42 befestigt ist, der wiederum drehbar auf der Welle 35 sitzt und mittels eines hydraulisch oder pneumatisch betätigbaren Kolben 43 um eine vorgegebene Winkelbewegung hin und her geschwenkt werden kann. Hierbei wird durch die Klinke 41 das Rad 40 jeweils um einen der Zahnteilung oder einem Vielfachen der Zahnteilung entsprechenden Betrag weitergedreht.The
Bei größeren Durchmessern des Direktreduktionsschachtofens kann es erforderlich sein, die Welle des Schneckenförderers durch den Ofen zu führen und beidseitig in der Wand des Ofengefäßes zu lagern. In diesem Fall ist es zweckmäßig, die Schneckengänge vom Zentrum aus gegenläufig, d. h. zum Umfang fördernd, anzuordnen.With larger diameters of the direct reduction shaft furnace, it may be necessary to pass the shaft of the screw conveyor through the furnace and to store it on both sides in the wall of the furnace vessel. In this case, it is advisable to reverse the screw flights from the center, i. H. promoting to scope.
Claims (12)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT81107215T ATE8799T1 (en) | 1980-09-12 | 1981-09-12 | PROCESS AND APPARATUS FOR DIRECT PRODUCTION OF LIQUID PIG IRON FROM CHILLED IRON ORE. |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3034539A DE3034539C2 (en) | 1980-09-12 | 1980-09-12 | Method and device for the direct production of liquid pig iron from lumpy iron ore |
| DE3034539 | 1980-09-12 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0048008A1 true EP0048008A1 (en) | 1982-03-24 |
| EP0048008B1 EP0048008B1 (en) | 1984-08-01 |
Family
ID=6111837
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP81107215A Expired EP0048008B1 (en) | 1980-09-12 | 1981-09-12 | Method and apparatus for the direct production of hot metal from lump iron ore |
Country Status (19)
| Country | Link |
|---|---|
| US (2) | US4409023A (en) |
| EP (1) | EP0048008B1 (en) |
| JP (1) | JPS5848607B2 (en) |
| KR (1) | KR890002797B1 (en) |
| AT (1) | ATE8799T1 (en) |
| AU (1) | AU542484B2 (en) |
| BR (1) | BR8105812A (en) |
| CA (1) | CA1189705A (en) |
| DD (1) | DD201697A5 (en) |
| DE (1) | DE3034539C2 (en) |
| ES (1) | ES505397A0 (en) |
| GB (1) | GB2084196B (en) |
| IN (1) | IN155081B (en) |
| MX (1) | MX158677A (en) |
| PH (1) | PH18291A (en) |
| PL (1) | PL133135B1 (en) |
| SU (1) | SU1151220A3 (en) |
| UA (1) | UA6580A1 (en) |
| ZA (1) | ZA815863B (en) |
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- 1981-08-29 IN IN974/CAL/81A patent/IN155081B/en unknown
- 1981-08-31 AU AU74766/81A patent/AU542484B2/en not_active Expired
- 1981-09-02 CA CA000385087A patent/CA1189705A/en not_active Expired
- 1981-09-04 PH PH26153A patent/PH18291A/en unknown
- 1981-09-05 KR KR1019810003308A patent/KR890002797B1/en not_active Expired
- 1981-09-10 UA UA3335454A patent/UA6580A1/en unknown
- 1981-09-10 MX MX189131A patent/MX158677A/en unknown
- 1981-09-10 SU SU813335454A patent/SU1151220A3/en active
- 1981-09-10 DD DD81233193A patent/DD201697A5/en not_active IP Right Cessation
- 1981-09-10 US US06/300,904 patent/US4409023A/en not_active Expired - Lifetime
- 1981-09-11 ES ES505397A patent/ES505397A0/en active Granted
- 1981-09-11 BR BR8105812A patent/BR8105812A/en not_active IP Right Cessation
- 1981-09-11 PL PL1981232996A patent/PL133135B1/en unknown
- 1981-09-11 GB GB8127503A patent/GB2084196B/en not_active Expired
- 1981-09-11 JP JP56142569A patent/JPS5848607B2/en not_active Expired
- 1981-09-12 EP EP81107215A patent/EP0048008B1/en not_active Expired
- 1981-09-12 AT AT81107215T patent/ATE8799T1/en not_active IP Right Cessation
-
1983
- 1983-05-12 US US06/494,096 patent/US4448402A/en not_active Expired - Lifetime
Patent Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH376134A (en) * | 1956-12-28 | 1964-03-31 | Inland Steel Co | Process for reducing iron oxide ore |
| DE1238941B (en) * | 1957-01-15 | 1967-04-20 | Inland Steel Co | Process for reducing crushed oxydic iron ore by burning carbonaceous fuel with oxygen-rich gas |
| DE2424028A1 (en) * | 1973-05-17 | 1974-12-05 | Rolf Linder | PRODUCTION OF FLOWING METAL MELT FROM POWDERED OR SMALL-PIECE METAL OXYDES |
| DE2612868A1 (en) * | 1975-04-28 | 1976-11-11 | Kinglor Metor Spa | DEVICE FOR DISCHARGING THE IRON SPONGE FROM EXTERNALLY HEATED RETORTEN |
| GB1502090A (en) * | 1975-04-28 | 1978-02-22 | Kinglor Metor Spa | Means for discharging sponge iron from retorts |
| DE2655813A1 (en) * | 1976-12-09 | 1978-06-22 | Kloeckner Humboldt Deutz Ag | METHOD AND DEVICE FOR DIRECT IRON PRODUCTION |
| DE2935707A1 (en) * | 1978-09-08 | 1980-03-20 | Midrex Corp | METHOD FOR DIRECTLY REDUCING METAL OXIDES AND DEVICE FOR IMPLEMENTING IT |
| DE2843303A1 (en) * | 1978-10-04 | 1980-04-10 | Korf Stahl | METHOD AND PLANT FOR PRODUCING LIQUID GUT IRON AND REDUCING GAS IN A MELT-UP GASIFIER |
| US4235425A (en) * | 1979-07-16 | 1980-11-25 | Midrex Corporation | Impact bed gasifier-melter |
| US4238226A (en) * | 1979-07-16 | 1980-12-09 | Midrex Corporation | Method for producing molten iron by submerged combustion |
| US4248626A (en) * | 1979-07-16 | 1981-02-03 | Midrex Corporation | Method for producing molten iron from iron oxide with coal and oxygen |
| DE3026949A1 (en) * | 1979-07-16 | 1981-02-12 | Midrex Corp | METHOD AND DEVICE FOR REDUCING IRON OXIDE PARTICLES AND FOR PRODUCING MOLTEN IRON |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102008026835A1 (en) | 2008-06-05 | 2009-12-17 | Kurt Himmelfreundpointner | Conveyable material e.g. foam particle feeding method for shaft furnace in cement production, involves conveying air or gas into starting region of lance through mechanical conveyor operating at zero pressure |
| CN113720142A (en) * | 2021-08-23 | 2021-11-30 | 西安交通大学 | Vertical cooling kiln with uniform heat exchange |
Also Published As
| Publication number | Publication date |
|---|---|
| IN155081B (en) | 1984-12-29 |
| PL133135B1 (en) | 1985-05-31 |
| US4409023A (en) | 1983-10-11 |
| CA1189705A (en) | 1985-07-02 |
| AU542484B2 (en) | 1985-02-21 |
| KR830007847A (en) | 1983-11-07 |
| JPS57120607A (en) | 1982-07-27 |
| ES8206634A1 (en) | 1982-08-16 |
| US4448402A (en) | 1984-05-15 |
| DE3034539A1 (en) | 1982-03-25 |
| ES505397A0 (en) | 1982-08-16 |
| PH18291A (en) | 1985-05-20 |
| PL232996A1 (en) | 1982-04-26 |
| BR8105812A (en) | 1982-06-08 |
| ZA815863B (en) | 1982-08-25 |
| GB2084196A (en) | 1982-04-07 |
| JPS5848607B2 (en) | 1983-10-29 |
| KR890002797B1 (en) | 1989-07-31 |
| DE3034539C2 (en) | 1982-07-22 |
| DD201697A5 (en) | 1983-08-03 |
| SU1151220A3 (en) | 1985-04-15 |
| GB2084196B (en) | 1984-08-08 |
| MX158677A (en) | 1989-02-27 |
| EP0048008B1 (en) | 1984-08-01 |
| UA6580A1 (en) | 1994-12-29 |
| AU7476681A (en) | 1982-03-18 |
| ATE8799T1 (en) | 1984-08-15 |
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