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EA201900237A1 - HYDRAULIC CATALYST OF HYDROCARBON RAW MATERIAL - Google Patents

HYDRAULIC CATALYST OF HYDROCARBON RAW MATERIAL

Info

Publication number
EA201900237A1
EA201900237A1 EA201900237A EA201900237A EA201900237A1 EA 201900237 A1 EA201900237 A1 EA 201900237A1 EA 201900237 A EA201900237 A EA 201900237A EA 201900237 A EA201900237 A EA 201900237A EA 201900237 A1 EA201900237 A1 EA 201900237A1
Authority
EA
Eurasian Patent Office
Prior art keywords
catalyst
rest
carrier
norbergite
albo
Prior art date
Application number
EA201900237A
Other languages
Russian (ru)
Other versions
EA037191B1 (en
Inventor
Олег Владимирович Климов
Владимир Владимирович ДАНИЛЕВИЧ
Евгений Юрьевич ГЕРАСИМОВ
Галина Ивановна КОРЯКИНА
Юлия Витальевна ВАТУТИНА
Елена Александровна СТОЛЯРОВА
Александр Степанович НОСКОВ
Original Assignee
Акционерное Общество "Газпромнефть-Омский Нпз" (Ао "Газпромнефть-Онпз")
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Акционерное Общество "Газпромнефть-Омский Нпз" (Ао "Газпромнефть-Онпз") filed Critical Акционерное Общество "Газпромнефть-Омский Нпз" (Ао "Газпромнефть-Онпз")
Publication of EA201900237A1 publication Critical patent/EA201900237A1/en
Publication of EA037191B1 publication Critical patent/EA037191B1/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0207—Pretreatment of the support
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/882—Molybdenum and cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/04—Sulfides
    • B01J27/047—Sulfides with chromium, molybdenum, tungsten or polonium
    • B01J27/051—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/20—Carbon compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)

Abstract

Изобретение относится к катализаторам получения нефтяных дистиллятов с низким содержанием серы. Описан катализатор, содержащий, мас.%: [Co(HO)(CHO)][MoO(CHO)] - 33,0-43,0; носитель - остальное; при этом носитель содержит, мас.%: борат алюминия AlBOсо структурой норбергита - 5,0-25,0; натрий - не более 0,03; γ-AlO- остальное. Входящий в состав катализатор борат алюминия AlBOсо структурой норбергита представляет собой частицы с размерами от 10 до 200 нм, характеризующиеся межплоскостными расстояниями 3.2 и 2.8 A, с углом между ними 53.8°. Катализатор имеет удельную поверхность 130-180 м/г, объем пор 0,35-0,65 см/г, средний диаметр пор 7-12 нм и представляет собой частицы с сечением в виде круга, трилистника или четырехлистника. После сульфидирования по известным методикам катализатор содержит, мас.%: Mo - 10,0-14,0; Co - 3,0-4,3; S - 6,7-9,4; носитель - остальное. Технический результат - получение катализатора, имеющего максимальную активность в целевых реакциях, протекающих при гидроочистке углеводородного сырья.The invention relates to catalysts for the production of low sulfur oil distillates. The described catalyst containing, in wt.%: [Co (HO) (CHO)] [MoO (CHO)] - 33.0-43.0; the carrier is the rest; wherein the carrier contains, wt.%: aluminum borate AlBO with the structure of norbergite - 5.0-25.0; sodium - not more than 0.03; γ-AlO - the rest. The aluminum borate AlBO catalyst included in the structure with norbergite is a particle with sizes from 10 to 200 nm, characterized by interplanar distances of 3.2 and 2.8 A, with an angle between them of 53.8 °. The catalyst has a specific surface area of 130-180 m / g, a pore volume of 0.35-0.65 cm / g, an average pore diameter of 7-12 nm and is a particle with a cross section in the form of a circle, shamrock or tetrafoil. After sulfidation by known methods, the catalyst contains, wt.%: Mo - 10.0-14.0; Co - 3.0-4.3; S 6.7-9.4; the carrier is the rest. EFFECT: obtaining a catalyst having maximum activity in target reactions occurring during hydrotreatment of hydrocarbon feedstocks.

EA201900237A 2016-11-09 2017-10-25 Catalyst for hydrotreatment of hydrocarbon feedstocks EA037191B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
RU2016143886A RU2626398C1 (en) 2016-11-09 2016-11-09 Catalyst for hydrotreating hydrocarbon raw materials
PCT/RU2017/000778 WO2018088934A1 (en) 2016-11-09 2017-10-25 A catalyst for hydrotreatment of hydrocarbon feedstocks

Publications (2)

Publication Number Publication Date
EA201900237A1 true EA201900237A1 (en) 2019-09-30
EA037191B1 EA037191B1 (en) 2021-02-17

Family

ID=59495897

Family Applications (1)

Application Number Title Priority Date Filing Date
EA201900237A EA037191B1 (en) 2016-11-09 2017-10-25 Catalyst for hydrotreatment of hydrocarbon feedstocks

Country Status (3)

Country Link
EA (1) EA037191B1 (en)
RU (1) RU2626398C1 (en)
WO (1) WO2018088934A1 (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2663903C1 (en) * 2017-09-25 2018-08-13 Акционерное общество "Газпромнефть - Омский НПЗ" (АО "Газпромнефть - ОНПЗ") Method of preparing catalyst for hydrotreating hydrocarbon feedstock
RU2663904C1 (en) * 2017-09-25 2018-08-13 Акционерное общество "Газпромнефть - Омский НПЗ" (АО "Газпромнефть - ОНПЗ") Catalyst for hydrotreating hydrocarbon feedstock
RU2663902C1 (en) * 2017-09-25 2018-08-13 Акционерное общество "Газпромнефть - Омский НПЗ" (АО "Газпромнефть - ОНПЗ") Method for hydrofining hydrocarbon feedstock
RU2688155C1 (en) * 2018-12-17 2019-05-20 Акционерное Общество "Газпромнефть - Московский Нпз" (Ао "Газпромнефть - Мнпз") Hydrotreating method of catalytic cracking gasoline
RU2687734C1 (en) * 2018-12-17 2019-05-16 Акционерное Общество "Газпромнефть - Московский Нпз" (Ао "Газпромнефть - Мнпз") Method of catalytically cracking gasoline hydrotreating catalyst preparation
RU2724773C1 (en) * 2020-01-17 2020-06-25 Акционерное общество "Газпромнефть - Омский НПЗ" (АО "Газпромнефть - ОНПЗ") Hydrofining catalyst for diesel fuel

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4033249B2 (en) * 1996-12-18 2008-01-16 財団法人石油産業活性化センター Heavy hydrocarbon oil hydrotreating catalyst and hydrotreating method using the same
RU2313392C1 (en) * 2006-10-13 2007-12-27 Институт Катализа Им. Г.К. Борескова Сибирского Отделения Российской Академии Наук Diesel fraction hydrodesulfurization catalyst and a method for preparation thereof
RU2335457C2 (en) * 2006-11-13 2008-10-10 Институт Катализа Им. Г.К. Борескова Сибирского Отделения Российской Академии Наук Method of aluminium hydroxide production with pseudoboehmite structure and aluminium gamma-oxide on its basis
RU2472585C1 (en) * 2011-09-23 2013-01-20 Учреждение Российской академии наук Институт катализа им. Г.К. Борескова Сибирского отделения РАН Catalyst, method of producing support, method of producing catalyst and method of hydrofining hydrocarbon material
MY173817A (en) * 2013-03-25 2020-02-24 Cosmo Oil Co Ltd Hydrodesulfurization catalyst for diesel oil and hydrotreating method for diesel oil
RU2534998C1 (en) * 2013-09-27 2014-12-10 Федеральное государственное бюджетное учреждение науки Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук Catalyst for hydropurification of hydrocarbon raw material

Also Published As

Publication number Publication date
RU2626398C1 (en) 2017-07-27
WO2018088934A1 (en) 2018-05-17
EA037191B1 (en) 2021-02-17

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