DK3234224T3 - Filterpresse fotoelektrokemisk celle til vandoxidering og co2-reduktion - Google Patents
Filterpresse fotoelektrokemisk celle til vandoxidering og co2-reduktion Download PDFInfo
- Publication number
- DK3234224T3 DK3234224T3 DK15830783.5T DK15830783T DK3234224T3 DK 3234224 T3 DK3234224 T3 DK 3234224T3 DK 15830783 T DK15830783 T DK 15830783T DK 3234224 T3 DK3234224 T3 DK 3234224T3
- Authority
- DK
- Denmark
- Prior art keywords
- cathode
- anode
- photoelectrochemical
- filter press
- press cell
- Prior art date
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Classifications
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/50—Processes
- C25B1/55—Photoelectrolysis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/50—Carbon dioxide
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/70—Assemblies comprising two or more cells
- C25B9/73—Assemblies comprising two or more cells of the filter-press type
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/133—Renewable energy sources, e.g. sunlight
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- Chemical & Material Sciences (AREA)
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- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Electrochemistry (AREA)
- Metallurgy (AREA)
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- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
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Claims (15)
1. Fotoelektrokemisk filterpressecelle omfattende: a) et katodekammer (1), der omfatter en katodestøtteramme (150) omfattende et katodisk materiale (4), der virker som en katode; en første flydende og gasformig CO2-fordelingsramme (6) og en anden flydende og gasformig CO2-fordelingsramme (7); en eller flere katodepakninger (81, 82, 83 og 84), hvor katodepakningerne er placeret mellem katodestøtterammen (150) og fordelingsrammerne (6, 7), og som laterale ender af katodekammeret; hvor katodestøtterammen (150) er anbragt mellem den første og anden fordelingsramme (6; 7); b) et anodekammer (2), der omfatter en anodestøtteramme (250) omfattende et anodisk materiale (5), der virker som en anode; en fluidfordelingsramme (8) anbragt således at fluidfordelingsrammen (8) er på en del af anodekammeret tættere på membranen (3) end anodestøtterammen (250); og en eller flere anodepakninger (85 og 86), hvor anodepakningerne er placeret mellem anodestøtterammen (250) og fordelingsrammen (8), og som laterale ender af anodekammeret; og c) en ionbyttermembran (3) anbragt mellem katodekammeret (1) og anodekammeret (2); hvor i) det katodiske materiale (4) er en ledende porøs elektrode med immobiliseret CO2-elektrokatalysatormateriale; ii) den første og anden flydende og gasformige CO2-fordelingsramme (6, 7) og katodepakningerne (81, 82, 83 og 84) er anbragt således at de i brug tillader indføring afen katolyt og gasformig CO2 separat ind i katodekammeret (1) igennem forskellige indløbsåbninger (11a, 11b) og de tillader at katolytten, de flydende og gasformige produkter og/eller ikke-reageret CO2 sammen forlader kammeret igennem en udløbsåbning (12); iii) fluidfordelingsrammen (8), anodestøtterammen (250) og anodepakninger (85 og 86) er anbragt på sådan en måde, at de i brug tillader indføring af en anolyt i anodekammeret (2) igennem en indløbsåbning (13), og de tillader at anolytten og oxidationsprodukter sammen forlader kammeret igennem en udløbsåbning (14); iv) det anodiske materiale (5), er et fotokatalytisk anodisk materiale, og er placeret i en side, som vender mod membranen (3) af et optisk vindue (15) af anodestøtterammen (250); og er anbragt således at det i brug er i stand til at være i kontakt med anolytten, som indføres i anodekammeret via indløbsåbningen (13) og, er i stand til at blive aktiveret, når strålingen anvendt til at bestråle anodekammeret (2) når det optiske vindue (15) med sin modsatte side, som ikke vender mod membranen (3); og v) det fotokatalytiske anodiske materiale (5) og det katodiske gasdiffusionsmateriale (4) har et overfladearealforhold omfattet fra 1:1 til 1:0,1.
2. Den fotoelektrokemiske filterpressecelle ifølge krav 1, hvor det immobiliserede CO2-elektrokatalysatormateriale af det katodiske materiale (4) er valgt fra a) et metal med et højt overpotentiale til hydrogenevolution, lav CO-adsorption og højt overpotentiale for CO2 til CO2 radikal ion; valgt fra gruppen bestående af Pb, Hg, In, Sn, Cd, TI og Bi; b) et metal med et mellem overpotentiale til hydrogenevolution og lav CO-adsorption; valgt fra gruppen bestående af Au, Ag, Zn, Pd og Ga; c) et metal med en høj CO-adsorption og et mellem overpotentiale til hydrogenevolution; valgt fra gruppen bestående af Cu; d) et metal med et relativt lav overpotentiale til hydrogenevolution og en høj CO-adsorption, valgt fra gruppen bestående af Ni, Fe, Pt, Ti; e) et oxid af et hvilket som helst af metallerne af type a), b), c) eller d); og f) kombinationer deraf; hvor materialet er aflejret på en meget porøs og ledende bærer.
3. Den fotoelektrokemiske filterpressecelle ifølge et hvilket som helst af kravene 1-2, hvor det immobiliserede CO2-elektrokatalysatormateriale af det katodiske materiale (4) er valgt fra gruppen bestående af Sn, Pb, Hg, Bi, In, Cd, TI, Cu, CuO, CU2O, Au, Ag, Zn, Pd, Ga og kombinationer deraf, hvor materialerne er aflejret på en meget porøs og ledende bærer.
4. Den fotoelektrokemiske filterpressecelle ifølge et hvilket som helst af kravene 1- 3, hvor det immobiliserede CO2-elektrokatalysatormateriale af det katodiske materiale (4) er valgt fra gruppen bestående af Pb, Hg, In, Sn, Cd, TI, Bi og kombinationer deraf, hvor materialerne er aflejret på en meget porøs og ledende bærer.
5. Den fotoelektrokemiske filterpressecelle ifølge et hvilket som helst af kravene 2- 4, hvor den meget porøse og ledende bærer er valgt fra carbonpapir, carbon-baserede nanofibre, metalnet, og metalskum.
6. Den fotoelektrokemiske filterpressecelle ifølge et hvilket som helst af kravene 1-5, hvor det fotokatalytiske anodiske materiale (5) er valgt fra halvledermaterialer med en båndgab mellem 1,1 og 3,4 eV og valensbåndkant lig med eller højere end 1,23V vs RHE.
7. Den fotoelektrokemiske filterpressecelle ifølge krav 6, hvor det fotokatalytiske anodiske materiale (5) er valgt fra gruppen bestående af T1O2, WO3, BiVCU, Fe2C>3, SrTiCH, Si, amorf Si, GaAs, GaN, M0S2, WSe2, MoSe2 og kombinationer deraf.
8. Den fotoelektrokemiske filterpressecelle ifølge et hvilket som helst af kravene 1-7 hvor anolytten omfatter a) mindst et polært protisk solvent omfattende mindst en bærerelektrolyt, og b) eventuelt en bufferopløsning; idet bærerelektrolytten er et salt af formlen MmYn i hvilken M er valgt fra lithium, kalium, natrium, magnesium, calcium, og strontium; Y er enten en hydroxidion eller en modion kommende fra mineralsyrer valgt fra halider, sulfater, nitrater, chlorater eller phosphater.
9. Den fotoelektrokemiske filterpressecelle ifølge krav 8, hvor saltet inkluderet som en bærerelektrolyt er valgt fra NaOH, KOH, H2SO4, KCI, HCI, H3PO4, NaHCC>3, K2HPO4, K2SO4, Na2SO4.
10. Den fotoelektrokemiske filterpressecelle ifølge et hvilket som helst af kravene 1-7 hvor katolytten omfatter a) mindst et polært protisk solvent omfattende mindst en bærerelektrolyt, og b) eventuelt en bufferopløsning; idet bærerelektrolytten er et salt af formlen MmXn i hvilken: M er valgt fra magnesium, calcium, lithium, kalium og natrium; X er valgt fra anioner af svage eller stærke syrer valgt fra carbonater, bicarbonater, sulfater, hydroxider og halider.
11. Den fotoelektrokemiske filterpressecelle ifølge krav 10, hvor saltet inkluderet som en bærerelektrolyt er valgt fra NaHCC>3, KHCO3, K2CO3, Na2SC>4, K2SO4, KCI, KCIO4.
12. Den fotoelektrokemiske filterpressecelle ifølge et hvilket som helst af kravene 1-11, hvor ionbyttermembranen er en ionbyttermembran, som tillader valgte ioner at krydse membranen for at afbalancere processtøkiometrien.
13. Den fotoelektrokemiske filterpressecelle ifølge et hvilket som helst af kravene 1-12, hvor ionbyttermembranen er en kationbyttermembran.
14. Fremgangsmåde til at reducere kuldioxid omfattende trinnene: i) at tilvejebringe en fotoelektrokemisk filterpressecelle som defineret i et hvilket som helst af kravene 1-13; ii) at tilføre den fotoelektrokemiske filterpressecelle en anolyt igennem en indløbsåbning (13) til anodekammeret (2), en katolyt igennem en indløbsåbning (11a) til katodekammeret (1) og en gas indeholdende CO2 igennem en anden indløbsåbning (11b) til katodekammeret (1); iii) at anvende på cellen et eksternt elektrisk potentiale mellem katode (4) og anode (5) med forspændingskapacitet i området fra 0 til 4 volt; iv) at bestråle fotoanoden med en stråling, hvorved stråling rammer det optiske vindue (15), som aktiverer det fotokatalytiske anodiske materiale (5) med sin modsatte side, som ikke vender mod membranen (3); og v) at indsamle produkterne af den katodiske reaktion fra katodekammerudløbet (12) til identificering og kvantificering.
15. Fremgangsmåden ifølge krav 14, hvor bestrålingstrinnet udføres under anvendelse af solstråling eller en kunstig UV-Vis-strålingskilde.
Applications Claiming Priority (2)
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| EP14382541 | 2014-12-19 | ||
| PCT/EP2015/080402 WO2016097247A1 (en) | 2014-12-19 | 2015-12-18 | Filter-press photoelectrochemical water oxidation and co2 reduction cell |
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| DK3234224T3 true DK3234224T3 (da) | 2018-09-03 |
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| PT (1) | PT3234224T (da) |
| SA (1) | SA517381727B1 (da) |
| WO (1) | WO2016097247A1 (da) |
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| DE102016211824A1 (de) * | 2016-06-30 | 2018-01-18 | Siemens Aktiengesellschaft | Anordnung für die Kohlendioxid-Elektrolyse |
| DE102016211822A1 (de) * | 2016-06-30 | 2018-01-04 | Siemens Aktiengesellschaft | Anordnung und Verfahren für die Kohlendioxid-Elektrolyse |
| KR102679547B1 (ko) * | 2017-12-19 | 2024-07-01 | 렙솔, 에스.에이. | 전기화학적 프로세스 |
| CN108193225B (zh) * | 2018-01-09 | 2020-01-24 | 大连理工大学 | 一种膜电极构型co2电还原电解池 |
| MY203263A (en) * | 2018-04-17 | 2024-06-20 | Repsol Sa | Photovoltaic-electrochemical (pv-ec) system |
| EP3656892B1 (en) * | 2018-11-21 | 2023-06-07 | Paris Sciences et Lettres | Method for co2 reduction into hydrocarbons |
| CN109839416B (zh) * | 2019-03-12 | 2021-02-19 | 青岛科技大学 | 纳米二硒化钨修饰金电极光致电化学传感器检测多巴胺的方法 |
| CN110867601A (zh) * | 2019-11-19 | 2020-03-06 | 东华大学 | 一种连续式多隔室类燃料电池膜电极结构二氧化碳电化学还原反应器 |
| CN111304672B (zh) * | 2020-03-18 | 2022-03-29 | 大连理工大学 | 一种h型固定床二氧化碳还原电解池及应用 |
| CN111733425B (zh) * | 2020-07-08 | 2025-01-10 | 福建师范大学 | 一种多功能电催化二氧化碳还原的电解池装置 |
| EP4189142A4 (en) * | 2020-07-28 | 2025-01-22 | Électro Carbone Inc. | Electrochemical cell for carbon dioxide reduction towards liquid chemicals |
| CN113061923B (zh) * | 2021-03-12 | 2022-08-02 | 华中科技大学 | 一种高活性电化学自掺杂TiO2纳米管基材料及其制备与应用 |
| JP7441194B2 (ja) * | 2021-03-19 | 2024-02-29 | 出光興産株式会社 | 電極用材料、膜－電極接合体、ｃｏ２電解装置およびｃｏ２電解生成物の製造方法 |
| EP4071274B1 (en) | 2021-04-07 | 2023-09-27 | Toyota Jidosha Kabushiki Kaisha | Photoelectrochemical device for the capture, concentration and collection of atmospheric carbon dioxide |
| WO2022243845A1 (en) * | 2021-05-18 | 2022-11-24 | Green Independence S.R.L. | Photo-electrochemical cell and corresponding apparatus |
| CN113502493B (zh) * | 2021-06-08 | 2022-11-04 | 东南大学 | 一种光电催化有机固废氧化耦合二氧化碳还原系统及方法 |
| CN113522318A (zh) * | 2021-06-23 | 2021-10-22 | 景德镇陶瓷大学 | 一种析氢和析氧用双功能钨钴双金属电解水催化剂及其制备方法 |
| CN113884446B (zh) * | 2021-09-27 | 2024-04-26 | 西南石油大学 | 一种可用于超快光谱工况实验的三相反应池 |
| CN114280026B (zh) * | 2021-11-22 | 2024-01-30 | 合肥原位科技有限公司 | 一种气体扩散电极的原位拉曼检测装置及其方法 |
| US12247281B2 (en) | 2022-10-24 | 2025-03-11 | King Fahd University Of Petroleum And Minerals | Method for coating a substrate with a Co-PI modified BiVO4/WO3 heterostructure film |
| KR20240070816A (ko) * | 2022-11-15 | 2024-05-22 | 한국과학기술원 | 연속 유동식 광촉매 반응기 및 가스의 광화학적 연속식 전환방법 |
| KR102751657B1 (ko) * | 2022-12-23 | 2025-01-10 | 한국에너지기술연구원 | 광전기화학전지 모듈 및 이를 이용한 어레이 시스템 |
| CN115951008B (zh) * | 2023-01-15 | 2024-09-06 | 西安交通大学 | 一种用于电催化连续流动co2还原反应的自动测试系统及测试方法 |
| CN116621280A (zh) * | 2023-07-11 | 2023-08-22 | 重庆大学 | 一种电吸附耦合双极膜处理含铊废水的装置 |
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- 2015-12-18 DK DK15830783.5T patent/DK3234224T3/da active
- 2015-12-18 CN CN201580067935.4A patent/CN107406993B/zh active Active
- 2015-12-18 PT PT15830783T patent/PT3234224T/pt unknown
-
2017
- 2017-06-15 SA SA517381727A patent/SA517381727B1/ar unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US20180023203A1 (en) | 2018-01-25 |
| CN107406993B (zh) | 2019-06-25 |
| CN107406993A (zh) | 2017-11-28 |
| SA517381727B1 (ar) | 2021-02-01 |
| US10626510B2 (en) | 2020-04-21 |
| PT3234224T (pt) | 2018-10-18 |
| WO2016097247A1 (en) | 2016-06-23 |
| ES2685279T3 (es) | 2018-10-08 |
| EP3234224A1 (en) | 2017-10-25 |
| EP3234224B1 (en) | 2018-06-13 |
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