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DK3011004T3 - Blegning- og oxideringskatalysator - Google Patents

Blegning- og oxideringskatalysator Download PDF

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Publication number
DK3011004T3
DK3011004T3 DK14732322.4T DK14732322T DK3011004T3 DK 3011004 T3 DK3011004 T3 DK 3011004T3 DK 14732322 T DK14732322 T DK 14732322T DK 3011004 T3 DK3011004 T3 DK 3011004T3
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DK
Denmark
Prior art keywords
silicate
bleaching
catalyst
experiment
alkaline earth
Prior art date
Application number
DK14732322.4T
Other languages
English (en)
Inventor
Ronald Hage
Fabien Pierre Guy Gaulard
Original Assignee
Chemsenti Ltd
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Publication of DK3011004T3 publication Critical patent/DK3011004T3/da

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/395—Bleaching agents
    • C11D3/3955—Organic bleaching agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/16—Clays or other mineral silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32—Manganese, technetium or rhenium
    • B01J23/34—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
    • B01J31/182—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine comprising aliphatic or saturated rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B01J31/2239—Bridging ligands, e.g. OAc in Cr2(OAc)4, Pt4(OAc)8 or dicarboxylate ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B08—CLEANING
    • B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/04—Cleaning involving contact with liquid
    • B08B3/08—Cleaning involving contact with liquid the liquid having chemical or dissolving effect
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0034—Fixed on a solid conventional detergent ingredient
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/168—Organometallic compounds or orgometallic complexes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3905—Bleach activators or bleach catalysts
    • C11D3/3935—Bleach activators or bleach catalysts granulated, coated or protected
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0213—Complexes without C-metal linkages
    • B01J2531/0216—Bi- or polynuclear complexes, i.e. comprising two or more metal coordination centres, without metal-metal bonds, e.g. Cp(Lx)Zr-imidazole-Zr(Lx)Cp
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0258—Flexible ligands, e.g. mainly sp3-carbon framework as exemplified by the "tedicyp" ligand, i.e. cis-cis-cis-1,2,3,4-tetrakis(diphenylphosphinomethyl)cyclopentane
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
    • B01J2531/72—Manganese

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Dispersion Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Detergent Compositions (AREA)
  • Catalysts (AREA)

Claims (15)

  1. BLEGNING- OG OXIDERINGSKATALYSATOR
    1. Fremgangsmåde, der omfaller etablering al kontakt mellem et jordalkalimelalsilical og el sail, der omfatter et mononukleart eller dinukleart Mn- (ill) og/eller Μη- (IV) kompleks af en ligand med formlen
    (I): hvor: p er 3; R er uafhængigt udvalgt fra gruppen bestående af hydrogen, Ci-C24-alkyl, CH2CH2OH og CH2COOH; eller ét R er bundet til nitrogenatomet af et andet Q af en anden ring med formlen (I) via en C2-Cg-alkylenbro, en Cg-Ciø-arylenbro eller en bro, der omfatter én eller to Ci-C3-alkylenenheder og én Cg-Cm -arylenenhed, hvilken bro eventuelt kan være substitueret én eller flere gange med uafhængigt udvalgte Cr C24-alkylgrupper; og Ri, R2, R3 og R4 uafhængigt er udvalgt fra H, CrC4-alkyl og CrC4-alkylhydroxy.
  2. 2. Fremgangsmåde ifølge krav 1, hvor R er uafhængigt udvalgt fra gruppen bestående af hydrogen, Ci-Cg-alkyl, CH2CH2OH og CH2COOH; eller ét R er bundet til nitrogenatomet af et andet Q af en anden ring med formlen (I) via en ethylenbro.
  3. 3. Fremgangsmåde ifølge krav 1, hvor liganden med formlen (I) er l,4,7-trimethyl-l,4,7-triazacyclononan (Me3-TACN) eller l,2,-bis(4,7,-dimethyl-l,4,7,-triazacyclonon-l-yl)-ethan (Me4-DTNE), for eksempel hvor komplekset er [MnIVMnIV(p-0)3(Me3-TACN)2]2+ eller [ΜηΠΙΜηιν(μ-0)2(μ-CH3COO)(Me4-DTNE)]2+.
  4. 4. Fremgangsmåde ifølge et hvilket som helst foregående krav, hvor saltet omfatter én eller flere ikke-koordinerende modioner, der ikke er silicationer.
  5. 5. Fremgangsmåde ifølge krav 4, hvor den ene eller flere ikke-koordinerende modioner er udvalgt fra gruppen bestående af CT, Br\ Γ, N03", C104\ PF6", S042", R5S03\ R5S04", CF3S03", tosylat og R5COO", hvor R5 er H, Ci_i2-alkyl og eventuelt Ci_6-alkyl-substitueret C6H5.
  6. 6. Fremgangsmåde ifølge krav 5, hvor den ene eller flere ikke-koordinerende modioner er udvalgt fra gruppen bestående af Cl", N03", S042" og acetat.
  7. 7. Fremgangsmåde ifølge et hvilket som helst foregående krav, hvor jordalkalimetalsilicatet er et calcium- eller magnesiumsilicat.
  8. 8. Fremgangsmåde ifølge et hvilket som helst foregående krav, hvor saltet bringes i kontakt med jordalkalimetalsilicatet i en væske, for eksempel en vandig væske.
  9. 9. Fremgangsmåde ifølge et hvilket som helst foregående krav, der endvidere omfatter tørring af den resulterende sammensætning.
  10. 10. Sammensætning, der kan opnås ved hjælp af en fremgangsmåde som defineret i et hvilket som helst foregående krav.
  11. 11. Sammensætning ifølge krav 10, hvis faststofindhold omfatter mellem ca. 0,1 og ca. 20 vægt-% af det mononukleare eller dinukleare Μη- (III) og/eller Μη- (IV) kompleks.
  12. 12. Blegningsformulering, der omfatter en sammensætning, der kan opnås ved hjælp af fremgangsmåden ifølge et hvilket som helst af kravene 1 til 9; og eventuelt en peroxyforbindelse.
  13. 13. Fremgangsmåde, der omfatter, at et substrat bringes i kontakt med vand og en blegningsformulering som defineret i krav 12.
  14. 14. Fremgangsmåde ifølge krav 13, der er en fremgangsmåde til vask af service i en mekanisk opvaskemaskine, hvilken fremgangsmåde omfatter at bringe service i kontakt med vand og blegningsformuleringen.
  15. 15. Fremgangsmåde ifølge krav 13, der er en fremgangsmåde til vask af tekstiler eller ikke-vævede stoffer, hvilken fremgangsmåde omfatter at bringe et tekstil eller et ikke-vævet stof i kontakt med vand og blegningsformuleringen.
DK14732322.4T 2013-06-20 2014-06-13 Blegning- og oxideringskatalysator DK3011004T3 (da)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP13173074 2013-06-20
PCT/GB2014/051819 WO2014202954A1 (en) 2013-06-20 2014-06-13 Bleach and oxidation catalyst

Publications (1)

Publication Number Publication Date
DK3011004T3 true DK3011004T3 (da) 2017-10-30

Family

ID=48672442

Family Applications (1)

Application Number Title Priority Date Filing Date
DK14732322.4T DK3011004T3 (da) 2013-06-20 2014-06-13 Blegning- og oxideringskatalysator

Country Status (14)

Country Link
US (1) US20160102276A1 (da)
EP (1) EP3011004B2 (da)
CN (1) CN105473700B (da)
AR (1) AR096655A1 (da)
AU (1) AU2014283027B2 (da)
BR (1) BR112015031941A2 (da)
CA (1) CA2916083A1 (da)
DK (1) DK3011004T3 (da)
ES (1) ES2643483T5 (da)
HU (1) HUE036889T2 (da)
NO (1) NO3011004T3 (da)
PL (1) PL3011004T3 (da)
PT (1) PT3011004T (da)
WO (1) WO2014202954A1 (da)

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EP3967742A1 (en) 2020-09-15 2022-03-16 WeylChem Performance Products GmbH Compositions comprising bleaching catalyst, manufacturing process thereof, and bleaching and cleaning agent comprising same
EP4008765A1 (en) * 2020-12-07 2022-06-08 WeylChem Performance Products GmbH Compositions comprising protonated triazacyclic compounds and bleaching agent and cleaning agent comprising same

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Also Published As

Publication number Publication date
HUE036889T2 (hu) 2018-08-28
ES2643483T5 (es) 2021-05-04
PL3011004T3 (pl) 2018-01-31
PT3011004T (pt) 2017-10-19
CN105473700B (zh) 2021-11-02
ES2643483T3 (es) 2017-11-23
AU2014283027B2 (en) 2017-08-24
AU2014283027A1 (en) 2016-02-11
CA2916083A1 (en) 2014-12-24
EP3011004A1 (en) 2016-04-27
AR096655A1 (es) 2016-01-27
EP3011004B1 (en) 2017-07-26
US20160102276A1 (en) 2016-04-14
EP3011004B2 (en) 2020-07-01
CN105473700A (zh) 2016-04-06
BR112015031941A2 (pt) 2020-01-14
WO2014202954A1 (en) 2014-12-24
NO3011004T3 (da) 2017-12-23

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