DK2376663T3 - Fremgangsmåde til fremstilling af en gasformig atmosfære til behandling af metaller - Google Patents
Fremgangsmåde til fremstilling af en gasformig atmosfære til behandling af metaller Download PDFInfo
- Publication number
- DK2376663T3 DK2376663T3 DK09797083.4T DK09797083T DK2376663T3 DK 2376663 T3 DK2376663 T3 DK 2376663T3 DK 09797083 T DK09797083 T DK 09797083T DK 2376663 T3 DK2376663 T3 DK 2376663T3
- Authority
- DK
- Denmark
- Prior art keywords
- furnace
- atmosphere
- ethanol
- nitrogen
- zone
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 20
- 238000011282 treatment Methods 0.000 title claims description 20
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 47
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 45
- 239000000203 mixture Substances 0.000 claims description 25
- 229910052757 nitrogen Inorganic materials 0.000 claims description 23
- 238000002347 injection Methods 0.000 claims description 11
- 239000007924 injection Substances 0.000 claims description 11
- 238000006243 chemical reaction Methods 0.000 claims description 10
- 238000010438 heat treatment Methods 0.000 claims description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 6
- 239000001257 hydrogen Substances 0.000 claims description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 49
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 28
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 21
- 229910002091 carbon monoxide Inorganic materials 0.000 description 21
- 235000019441 ethanol Nutrition 0.000 description 20
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 15
- 229910052799 carbon Inorganic materials 0.000 description 15
- 229910002092 carbon dioxide Inorganic materials 0.000 description 14
- 230000015572 biosynthetic process Effects 0.000 description 8
- 239000012071 phase Substances 0.000 description 8
- 239000007789 gas Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 6
- 230000003647 oxidation Effects 0.000 description 6
- 238000007254 oxidation reaction Methods 0.000 description 6
- 239000000470 constituent Substances 0.000 description 4
- 238000003786 synthesis reaction Methods 0.000 description 4
- LBPGGVGNNLPHBO-UHFFFAOYSA-N [N].OC Chemical compound [N].OC LBPGGVGNNLPHBO-UHFFFAOYSA-N 0.000 description 3
- 238000005256 carbonitriding Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 239000003345 natural gas Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000012159 carrier gas Substances 0.000 description 1
- 239000010730 cutting oil Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 238000009313 farming Methods 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000007792 gaseous phase Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/74—Methods of treatment in inert gas, controlled atmosphere, vacuum or pulverulent material
- C21D1/76—Adjusting the composition of the atmosphere
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/74—Methods of treatment in inert gas, controlled atmosphere, vacuum or pulverulent material
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/02—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working in inert or controlled atmosphere or vacuum
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C8/06—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
- C23C8/08—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases only one element being applied
- C23C8/20—Carburising
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C8/06—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
- C23C8/08—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases only one element being applied
- C23C8/20—Carburising
- C23C8/22—Carburising of ferrous surfaces
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C8/06—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
- C23C8/28—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases more than one element being applied in one step
- C23C8/30—Carbo-nitriding
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C8/06—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
- C23C8/28—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases more than one element being applied in one step
- C23C8/30—Carbo-nitriding
- C23C8/32—Carbo-nitriding of ferrous surfaces
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)
- Furnace Details (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Claims (4)
1
1. Fremgangsmåde til frembringelse af en atmosfære beregnet til varmebehandling af metaldele i en ovn, ifølge hvilken en blanding, der indeholder gasformigt CO2 og ethanol i form affine smådråber eller damp, indføres i mindst 5 en fase i behandlingscyklussen eller i mindst en zone i varmebehandlingsovnen, således at der inde i ovnen gennemføres en reaktion mellem CO2 og ethanol til dannelse af en blanding af hydrogen og CO ifølge reaktionen: CO2 + C2H5OH 3 CO + 3 H2 10 og kendetegnet ved, at indsprøjtningen gennemføres i en fase i behandlingscyklussen eller en zone i varmebehandlingsovnen, hvis temperatur overstiger 750°C, medens der i den eller de faser i behandlingscyklussen eller i den eller de zoner i ovnen, hvis temperatur er lavere end 750°C, indsprøjtes CO2 15 alene eller eventuelt i blanding med nitrogen.
2. Fremgangsmåde ifølge krav 1, kendetegnet ved, at den indsprøjtede blanding i en fase af behandlingscyklussen eller en zone i varmebehandlingsovnen, hvis temperatur overstiger 750°C, også indeholder 20 gasformigt nitrogen.
3. Fremgangsmåde ifølge et af de foregående krav, kendetegnet ved, at ethanolen opvarmes og/eller fordampes inden indsprøjtningen i ovnen.
4. Fremgangsmåde ifølge et af de foregående krav, kendetegnet ved, at indsprøjtningen af blandingen, der indeholder gasformigt CO2 og ethanol i form af fine smådråber eller damp, gennemføres i en fase i behandlingscyklussen eller en zone i varmebehandlingsovnen, hvis temperatur befinder sig i en området fra 850°C til 1000°C. 30
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0858379A FR2939448B1 (fr) | 2008-12-09 | 2008-12-09 | Procede de production d'une atmosphere gazeuse pour le traitement des metaux. |
| PCT/FR2009/052290 WO2010066979A1 (fr) | 2008-12-09 | 2009-11-25 | Procede de production d'une atmosphere gazeuse pour le traitement des metaux |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DK2376663T3 true DK2376663T3 (da) | 2019-04-08 |
Family
ID=40427563
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK09797083.4T DK2376663T3 (da) | 2008-12-09 | 2009-11-25 | Fremgangsmåde til fremstilling af en gasformig atmosfære til behandling af metaller |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US8679264B2 (da) |
| EP (1) | EP2376663B1 (da) |
| JP (1) | JP5529158B2 (da) |
| DK (1) | DK2376663T3 (da) |
| ES (1) | ES2715925T3 (da) |
| FR (1) | FR2939448B1 (da) |
| PL (1) | PL2376663T3 (da) |
| PT (1) | PT2376663T (da) |
| TR (1) | TR201903521T4 (da) |
| WO (1) | WO2010066979A1 (da) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2985508B1 (fr) * | 2012-01-06 | 2015-05-01 | Air Liquide | Procede de generation d'un melange de gaz contenant du monoxyde de carbone et de l'hydrogene en proportions sensiblement egales |
| EP3243585A1 (de) * | 2016-05-13 | 2017-11-15 | Linde Aktiengesellschaft | Verfahren und vorrichtung zum kodieren bei der wärmebehandlung eines bauteils sowie ein kodierungsgas zum kodieren von bauteilen bei der wärmebehandlung eines bauteils |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2037816B (en) * | 1978-11-30 | 1982-10-27 | Boc Ltd | Heat treatment method |
| US4306919A (en) * | 1980-09-04 | 1981-12-22 | Union Carbide Corporation | Process for carburizing steel |
| BR8504616A (pt) * | 1985-09-20 | 1987-04-28 | Aichelin Ind E Comercio De For | Processo para o enriquecimento da atmosfera de fornos de tratamentos termoquimicos de pecas metalicas |
| US5221369A (en) * | 1991-07-08 | 1993-06-22 | Air Products And Chemicals, Inc. | In-situ generation of heat treating atmospheres using non-cryogenically produced nitrogen |
| DE4340060C1 (de) * | 1993-11-24 | 1995-04-20 | Linde Ag | Verfahren zum Gasaufkohlen |
| JP3505690B2 (ja) * | 1994-08-18 | 2004-03-08 | 関東冶金工業株式会社 | 金属の加熱処理方法 |
| JP3409236B2 (ja) * | 1997-02-18 | 2003-05-26 | 同和鉱業株式会社 | 熱処理炉の雰囲気制御方法 |
| DE19819042A1 (de) * | 1998-04-28 | 1999-11-04 | Linde Ag | Verfahren und Anlage zum Gasaufkohlen |
| JP3531736B2 (ja) * | 2001-01-19 | 2004-05-31 | オリエンタルエンヂニアリング株式会社 | 浸炭方法及び浸炭装置 |
-
2008
- 2008-12-09 FR FR0858379A patent/FR2939448B1/fr not_active Expired - Fee Related
-
2009
- 2009-11-25 DK DK09797083.4T patent/DK2376663T3/da active
- 2009-11-25 TR TR2019/03521T patent/TR201903521T4/tr unknown
- 2009-11-25 PT PT09797083T patent/PT2376663T/pt unknown
- 2009-11-25 PL PL09797083T patent/PL2376663T3/pl unknown
- 2009-11-25 JP JP2011540154A patent/JP5529158B2/ja not_active Expired - Fee Related
- 2009-11-25 US US13/133,538 patent/US8679264B2/en active Active
- 2009-11-25 WO PCT/FR2009/052290 patent/WO2010066979A1/fr not_active Ceased
- 2009-11-25 EP EP09797083.4A patent/EP2376663B1/fr active Active
- 2009-11-25 ES ES09797083T patent/ES2715925T3/es active Active
Also Published As
| Publication number | Publication date |
|---|---|
| JP2012511633A (ja) | 2012-05-24 |
| EP2376663A1 (fr) | 2011-10-19 |
| PL2376663T3 (pl) | 2019-07-31 |
| FR2939448A1 (fr) | 2010-06-11 |
| US8679264B2 (en) | 2014-03-25 |
| JP5529158B2 (ja) | 2014-06-25 |
| US20110272637A1 (en) | 2011-11-10 |
| FR2939448B1 (fr) | 2011-05-06 |
| EP2376663B1 (fr) | 2019-01-02 |
| PT2376663T (pt) | 2019-04-01 |
| ES2715925T3 (es) | 2019-06-07 |
| WO2010066979A1 (fr) | 2010-06-17 |
| TR201903521T4 (tr) | 2019-04-22 |
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