DK1088012T3 - Fiberglass binder compositions and methods thereof - Google Patents
Fiberglass binder compositions and methods thereofInfo
- Publication number
- DK1088012T3 DK1088012T3 DK98954952.2T DK98954952T DK1088012T3 DK 1088012 T3 DK1088012 T3 DK 1088012T3 DK 98954952 T DK98954952 T DK 98954952T DK 1088012 T3 DK1088012 T3 DK 1088012T3
- Authority
- DK
- Denmark
- Prior art keywords
- methods
- resin binder
- fiber glass
- compositions
- present
- Prior art date
Links
- 239000011230 binding agent Substances 0.000 title abstract 5
- 239000000203 mixture Substances 0.000 title abstract 4
- 239000011152 fibreglass Substances 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- 229920005989 resin Polymers 0.000 abstract 4
- 239000011347 resin Substances 0.000 abstract 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical class N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- -1 aryl sulfonic acid Chemical compound 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 230000001747 exhibiting effect Effects 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 239000003607 modifier Substances 0.000 abstract 1
- 229920003987 resole Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/0405—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres
- C08J5/043—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres with glass fibres
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/26—Macromolecular compounds or prepolymers
- C03C25/32—Macromolecular compounds or prepolymers obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
- C03C25/34—Condensation polymers of aldehydes, e.g. with phenols, ureas, melamines, amides or amines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G8/00—Condensation polymers of aldehydes or ketones with phenols only
- C08G8/04—Condensation polymers of aldehydes or ketones with phenols only of aldehydes
- C08G8/08—Condensation polymers of aldehydes or ketones with phenols only of aldehydes of formaldehyde, e.g. of formaldehyde formed in situ
- C08G8/10—Condensation polymers of aldehydes or ketones with phenols only of aldehydes of formaldehyde, e.g. of formaldehyde formed in situ with phenol
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J161/00—Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
- C09J161/04—Condensation polymers of aldehydes or ketones with phenols only
- C09J161/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2361/00—Characterised by the use of condensation polymers of aldehydes or ketones; Derivatives of such polymers
- C08J2361/04—Condensation polymers of aldehydes or ketones with phenols only
- C08J2361/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2926—Coated or impregnated inorganic fiber fabric
- Y10T442/2992—Coated or impregnated glass fiber fabric
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/603—Including strand or fiber material precoated with other than free metal or alloy
- Y10T442/604—Strand or fiber material is glass
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Geochemistry & Mineralogy (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Reinforced Plastic Materials (AREA)
- Surface Treatment Of Glass Fibres Or Filaments (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Glass Compositions (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The present invention relates to methods of preparing improved fiber glass compositions using an improved resin binder. The resin binder comprises an aqueous solution of a resole resin, a catalyst comprising an ammonia salt of an aryl sulfonic acid, and optional binder modifiers. It has been found that the use of ammonium aryl sulfonate salts in resin binder compositions, as in the present invention, provides an enhanced cure rate and also enables manufacture of a fiber glass composition exhibiting enhanced uncured storage properties, increased thermal stability, and reduced corrosiveness to metals.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US8589098P | 1998-05-18 | 1998-05-18 | |
| PCT/US1998/021404 WO1999060043A1 (en) | 1998-05-18 | 1998-10-09 | Fiber glass binder compositions and process therefor |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DK1088012T3 true DK1088012T3 (en) | 2010-07-19 |
Family
ID=22194649
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK98954952.2T DK1088012T3 (en) | 1998-05-18 | 1998-10-09 | Fiberglass binder compositions and methods thereof |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US6638882B1 (en) |
| EP (1) | EP1088012B1 (en) |
| AT (1) | ATE464334T1 (en) |
| CA (1) | CA2315810C (en) |
| DE (1) | DE69841616D1 (en) |
| DK (1) | DK1088012T3 (en) |
| ES (1) | ES2343604T3 (en) |
| WO (1) | WO1999060043A1 (en) |
Families Citing this family (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001010953A1 (en) * | 1999-08-10 | 2001-02-15 | Knauf Fiber Glass Gmbh | Fiber glass binder compositions with reduced dusting |
| KR100708249B1 (en) * | 2002-08-30 | 2007-04-16 | 아사히 유키자이 고교 가부시키가이샤 | Process for producing phenolic novolak |
| US7323083B2 (en) | 2002-10-30 | 2008-01-29 | The Lubrizol Corporation | Adhesion promoters for glass-containing systems |
| AU2003287448A1 (en) * | 2002-10-30 | 2004-05-25 | The Lubrizol Corporation | Fiber dispersant-containing systems |
| US7842382B2 (en) * | 2004-03-11 | 2010-11-30 | Knauf Insulation Gmbh | Binder compositions and associated methods |
| FR2878864B1 (en) * | 2004-12-07 | 2007-01-26 | Saint Gobain Isover Sa | PROCESS FOR PRODUCING A COLORED MINERAL WOOL PRODUCT COMPRISING A SAME COLOR COATING |
| KR101779677B1 (en) | 2005-07-26 | 2017-09-18 | 크나우프 인설레이션, 인크. | Binders and materials made therewith |
| US7872088B2 (en) * | 2006-02-16 | 2011-01-18 | Knauf Insulation Gmbh | Low formaldehyde emission fiberglass |
| US7989367B2 (en) * | 2006-06-30 | 2011-08-02 | Georgia-Pacific Chemicals Llc | Reducing formaldehyde emissions from fiberglass insulation |
| US8173219B2 (en) | 2006-06-09 | 2012-05-08 | Georgia-Pacific Chemicals Llc | Porous fiberglass materials having reduced formaldehyde emissions |
| US20070287018A1 (en) * | 2006-06-09 | 2007-12-13 | Georgia-Pacific Resins, Inc. | Fibrous mats having reduced formaldehyde emissions |
| US20080233333A1 (en) * | 2007-03-21 | 2008-09-25 | Georgia-Pacific Chemicals Llc | Fibrous products having reduced formaldehyde emissions |
| US20080233334A1 (en) * | 2007-03-21 | 2008-09-25 | Georgia-Pacific Chemicals Llc | Fibrous products having reduced formaldehyde emissions |
| US8043383B2 (en) | 2006-06-30 | 2011-10-25 | Georgia-Pacific Chemicals Llc | Reducing formaldehyde emissions |
| EP2450493B1 (en) | 2007-01-25 | 2024-10-02 | Knauf Insulation SPRL | Mineral fibre board |
| PL2108006T3 (en) | 2007-01-25 | 2021-04-19 | Knauf Insulation Gmbh | Binders and materials made therewith |
| US8501838B2 (en) | 2007-01-25 | 2013-08-06 | Knauf Insulation Sprl | Composite wood board |
| CA2683706A1 (en) | 2007-04-13 | 2008-10-23 | Knauf Insulation Gmbh | Composite maillard-resole binders |
| CA2692489A1 (en) * | 2007-07-05 | 2009-01-08 | Knauf Insulation Gmbh | Hydroxymonocarboxylic acid-based maillard binder |
| GB0715100D0 (en) | 2007-08-03 | 2007-09-12 | Knauf Insulation Ltd | Binders |
| US8900495B2 (en) | 2009-08-07 | 2014-12-02 | Knauf Insulation | Molasses binder |
| PT2566904T (en) | 2010-05-07 | 2021-08-30 | Knauf Insulation | Carbohydrate polyamine binders and materials made therewith |
| KR101835899B1 (en) | 2010-05-07 | 2018-03-07 | 크나우프 인설레이션, 인크. | Carbohydrate binders and materials made therewith |
| WO2011154368A1 (en) | 2010-06-07 | 2011-12-15 | Knauf Insulation | Fiber products having temperature control additives |
| US20130174758A1 (en) * | 2010-09-17 | 2013-07-11 | Knauf Insulation Gmbh | Organic acid carbohydrate binders and materials made therewith |
| US20140186635A1 (en) * | 2011-05-07 | 2014-07-03 | Knauf Insulation | Liquid high solids binder composition |
| GB201206193D0 (en) | 2012-04-05 | 2012-05-23 | Knauf Insulation Ltd | Binders and associated products |
| GB201214734D0 (en) | 2012-08-17 | 2012-10-03 | Knauf Insulation Ltd | Wood board and process for its production |
| US20150315339A1 (en) | 2012-12-05 | 2015-11-05 | Knauf Insulation Sprl | Binder |
| WO2015120252A1 (en) | 2014-02-07 | 2015-08-13 | Knauf Insulation, Llc | Uncured articles with improved shelf-life |
| GB201408909D0 (en) | 2014-05-20 | 2014-07-02 | Knauf Insulation Ltd | Binders |
| GB201412709D0 (en) | 2014-07-17 | 2014-09-03 | Knauf Insulation And Knauf Insulation Ltd | Improved binder compositions and uses thereof |
| GB201517867D0 (en) | 2015-10-09 | 2015-11-25 | Knauf Insulation Ltd | Wood particle boards |
| GB201610063D0 (en) | 2016-06-09 | 2016-07-27 | Knauf Insulation Ltd | Binders |
| GB201701569D0 (en) | 2017-01-31 | 2017-03-15 | Knauf Insulation Ltd | Improved binder compositions and uses thereof |
| GB201804908D0 (en) | 2018-03-27 | 2018-05-09 | Knauf Insulation Ltd | Binder compositions and uses thereof |
| GB201804907D0 (en) | 2018-03-27 | 2018-05-09 | Knauf Insulation Ltd | Composite products |
| SI3561166T1 (en) * | 2018-04-27 | 2021-08-31 | Ursa Insulation, S.A. | Method for the manufacture of mineral wool products |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3616179A (en) | 1968-01-18 | 1971-10-26 | Owens Corning Fiberglass Corp | Glass fiber product bonded with terpolymer comprising phenol formaldehyde-urea formaldehyde condensation product |
| US3944703A (en) | 1971-07-21 | 1976-03-16 | Union Carbide Corporation | Fibrous batts impregnated with aqueous dispersions based on heat-hardenable phenolic resins |
| US4067829A (en) | 1973-03-19 | 1978-01-10 | The Dow Chemical Company | Preparation of a cured resole resin |
| US4076873A (en) | 1974-07-29 | 1978-02-28 | Shea Lawrence E | Resorcinol-aldehyde resins used to bind reinforcing materials such as glass fibers in shaped object form |
| US4045398A (en) | 1975-11-24 | 1977-08-30 | Monsanto Company | Resole resin binder composition |
| US4373062A (en) | 1981-04-20 | 1983-02-08 | Brown Gordon E | Phenol-resorcinol-formaldehyde resin |
| US4461859A (en) | 1981-11-16 | 1984-07-24 | Ppg Industries, Inc. | Method of preparing a phenolic aldehyde resin and resin composition for an adhesive system to be applied to glass fibers |
| US4476191A (en) | 1981-11-16 | 1984-10-09 | Ppg Industries, Inc. | Resorcinol-aldehyde resin composition for an adhesive system to be applied to glass fibers |
| US4525492A (en) | 1982-06-04 | 1985-06-25 | Fiberglas Canada Inc. | Modified phenolic foams |
| DE3504339A1 (en) | 1985-02-08 | 1986-08-14 | Rütgerswerke AG, 6000 Frankfurt | METHOD FOR THE PRODUCTION OF PHENOL RESIN-BONDED GLASS AND MINERAL FIBER PRODUCTS |
| US4904753A (en) | 1988-03-23 | 1990-02-27 | Ashland Oil, Inc. | Acid/oxidizer catalyst system for storage stable, quick-cure phenolic resins of the resole or benzylic ether resole type |
| US5043175A (en) | 1990-10-01 | 1991-08-27 | California Pellet Mill Company | Method and apparatus for sterilization of animal feed |
| US5243015A (en) * | 1992-06-25 | 1993-09-07 | Georgia-Pacific Resins, Inc. | Latent catalyzed phenolic resole resin composition |
| US5324337A (en) * | 1992-12-29 | 1994-06-28 | Knauf Fiber Glass Gmbh | Method for producing fiber product |
| US5578371A (en) | 1995-08-25 | 1996-11-26 | Schuller International, Inc. | Phenol/formaldehyde fiberglass binder compositions exhibiting reduced emissions |
| US5952440A (en) * | 1997-11-03 | 1999-09-14 | Borden Chemical, Inc. | Water soluble and storage stable resole-melamine resin |
-
1998
- 1998-10-09 WO PCT/US1998/021404 patent/WO1999060043A1/en not_active Ceased
- 1998-10-09 DE DE69841616T patent/DE69841616D1/en not_active Expired - Lifetime
- 1998-10-09 EP EP98954952A patent/EP1088012B1/en not_active Expired - Lifetime
- 1998-10-09 US US09/169,719 patent/US6638882B1/en not_active Expired - Fee Related
- 1998-10-09 AT AT98954952T patent/ATE464334T1/en not_active IP Right Cessation
- 1998-10-09 CA CA002315810A patent/CA2315810C/en not_active Expired - Fee Related
- 1998-10-09 DK DK98954952.2T patent/DK1088012T3/en active
- 1998-10-09 US US09/601,419 patent/US6555616B1/en not_active Expired - Lifetime
- 1998-10-09 ES ES98954952T patent/ES2343604T3/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| CA2315810C (en) | 2007-01-09 |
| DE69841616D1 (en) | 2010-05-27 |
| ATE464334T1 (en) | 2010-04-15 |
| WO1999060043A1 (en) | 1999-11-25 |
| US6555616B1 (en) | 2003-04-29 |
| EP1088012A1 (en) | 2001-04-04 |
| EP1088012A4 (en) | 2002-10-23 |
| CA2315810A1 (en) | 1999-11-25 |
| ES2343604T3 (en) | 2010-08-04 |
| EP1088012B1 (en) | 2010-04-14 |
| US6638882B1 (en) | 2003-10-28 |
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