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DK1088012T3 - Fiberglass binder compositions and methods thereof - Google Patents

Fiberglass binder compositions and methods thereof

Info

Publication number
DK1088012T3
DK1088012T3 DK98954952.2T DK98954952T DK1088012T3 DK 1088012 T3 DK1088012 T3 DK 1088012T3 DK 98954952 T DK98954952 T DK 98954952T DK 1088012 T3 DK1088012 T3 DK 1088012T3
Authority
DK
Denmark
Prior art keywords
methods
resin binder
fiber glass
compositions
present
Prior art date
Application number
DK98954952.2T
Other languages
Danish (da)
Inventor
Clarence Helbing
Brian Lee Swift
Original Assignee
Knauf Fiber Glass Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Knauf Fiber Glass Gmbh filed Critical Knauf Fiber Glass Gmbh
Application granted granted Critical
Publication of DK1088012T3 publication Critical patent/DK1088012T3/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/0405Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres
    • C08J5/043Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres with glass fibres
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10Coating
    • C03C25/24Coatings containing organic materials
    • C03C25/26Macromolecular compounds or prepolymers
    • C03C25/32Macromolecular compounds or prepolymers obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C03C25/34Condensation polymers of aldehydes, e.g. with phenols, ureas, melamines, amides or amines
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G8/00Condensation polymers of aldehydes or ketones with phenols only
    • C08G8/04Condensation polymers of aldehydes or ketones with phenols only of aldehydes
    • C08G8/08Condensation polymers of aldehydes or ketones with phenols only of aldehydes of formaldehyde, e.g. of formaldehyde formed in situ
    • C08G8/10Condensation polymers of aldehydes or ketones with phenols only of aldehydes of formaldehyde, e.g. of formaldehyde formed in situ with phenol
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J161/00Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
    • C09J161/04Condensation polymers of aldehydes or ketones with phenols only
    • C09J161/06Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2361/00Characterised by the use of condensation polymers of aldehydes or ketones; Derivatives of such polymers
    • C08J2361/04Condensation polymers of aldehydes or ketones with phenols only
    • C08J2361/06Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2926Coated or impregnated inorganic fiber fabric
    • Y10T442/2992Coated or impregnated glass fiber fabric
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/603Including strand or fiber material precoated with other than free metal or alloy
    • Y10T442/604Strand or fiber material is glass

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Reinforced Plastic Materials (AREA)
  • Surface Treatment Of Glass Fibres Or Filaments (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Glass Compositions (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

The present invention relates to methods of preparing improved fiber glass compositions using an improved resin binder. The resin binder comprises an aqueous solution of a resole resin, a catalyst comprising an ammonia salt of an aryl sulfonic acid, and optional binder modifiers. It has been found that the use of ammonium aryl sulfonate salts in resin binder compositions, as in the present invention, provides an enhanced cure rate and also enables manufacture of a fiber glass composition exhibiting enhanced uncured storage properties, increased thermal stability, and reduced corrosiveness to metals.
DK98954952.2T 1998-05-18 1998-10-09 Fiberglass binder compositions and methods thereof DK1088012T3 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US8589098P 1998-05-18 1998-05-18
PCT/US1998/021404 WO1999060043A1 (en) 1998-05-18 1998-10-09 Fiber glass binder compositions and process therefor

Publications (1)

Publication Number Publication Date
DK1088012T3 true DK1088012T3 (en) 2010-07-19

Family

ID=22194649

Family Applications (1)

Application Number Title Priority Date Filing Date
DK98954952.2T DK1088012T3 (en) 1998-05-18 1998-10-09 Fiberglass binder compositions and methods thereof

Country Status (8)

Country Link
US (2) US6638882B1 (en)
EP (1) EP1088012B1 (en)
AT (1) ATE464334T1 (en)
CA (1) CA2315810C (en)
DE (1) DE69841616D1 (en)
DK (1) DK1088012T3 (en)
ES (1) ES2343604T3 (en)
WO (1) WO1999060043A1 (en)

Families Citing this family (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001010953A1 (en) * 1999-08-10 2001-02-15 Knauf Fiber Glass Gmbh Fiber glass binder compositions with reduced dusting
KR100708249B1 (en) * 2002-08-30 2007-04-16 아사히 유키자이 고교 가부시키가이샤 Process for producing phenolic novolak
US7323083B2 (en) 2002-10-30 2008-01-29 The Lubrizol Corporation Adhesion promoters for glass-containing systems
AU2003287448A1 (en) * 2002-10-30 2004-05-25 The Lubrizol Corporation Fiber dispersant-containing systems
US7842382B2 (en) * 2004-03-11 2010-11-30 Knauf Insulation Gmbh Binder compositions and associated methods
FR2878864B1 (en) * 2004-12-07 2007-01-26 Saint Gobain Isover Sa PROCESS FOR PRODUCING A COLORED MINERAL WOOL PRODUCT COMPRISING A SAME COLOR COATING
KR101779677B1 (en) 2005-07-26 2017-09-18 크나우프 인설레이션, 인크. Binders and materials made therewith
US7872088B2 (en) * 2006-02-16 2011-01-18 Knauf Insulation Gmbh Low formaldehyde emission fiberglass
US7989367B2 (en) * 2006-06-30 2011-08-02 Georgia-Pacific Chemicals Llc Reducing formaldehyde emissions from fiberglass insulation
US8173219B2 (en) 2006-06-09 2012-05-08 Georgia-Pacific Chemicals Llc Porous fiberglass materials having reduced formaldehyde emissions
US20070287018A1 (en) * 2006-06-09 2007-12-13 Georgia-Pacific Resins, Inc. Fibrous mats having reduced formaldehyde emissions
US20080233333A1 (en) * 2007-03-21 2008-09-25 Georgia-Pacific Chemicals Llc Fibrous products having reduced formaldehyde emissions
US20080233334A1 (en) * 2007-03-21 2008-09-25 Georgia-Pacific Chemicals Llc Fibrous products having reduced formaldehyde emissions
US8043383B2 (en) 2006-06-30 2011-10-25 Georgia-Pacific Chemicals Llc Reducing formaldehyde emissions
EP2450493B1 (en) 2007-01-25 2024-10-02 Knauf Insulation SPRL Mineral fibre board
PL2108006T3 (en) 2007-01-25 2021-04-19 Knauf Insulation Gmbh Binders and materials made therewith
US8501838B2 (en) 2007-01-25 2013-08-06 Knauf Insulation Sprl Composite wood board
CA2683706A1 (en) 2007-04-13 2008-10-23 Knauf Insulation Gmbh Composite maillard-resole binders
CA2692489A1 (en) * 2007-07-05 2009-01-08 Knauf Insulation Gmbh Hydroxymonocarboxylic acid-based maillard binder
GB0715100D0 (en) 2007-08-03 2007-09-12 Knauf Insulation Ltd Binders
US8900495B2 (en) 2009-08-07 2014-12-02 Knauf Insulation Molasses binder
PT2566904T (en) 2010-05-07 2021-08-30 Knauf Insulation Carbohydrate polyamine binders and materials made therewith
KR101835899B1 (en) 2010-05-07 2018-03-07 크나우프 인설레이션, 인크. Carbohydrate binders and materials made therewith
WO2011154368A1 (en) 2010-06-07 2011-12-15 Knauf Insulation Fiber products having temperature control additives
US20130174758A1 (en) * 2010-09-17 2013-07-11 Knauf Insulation Gmbh Organic acid carbohydrate binders and materials made therewith
US20140186635A1 (en) * 2011-05-07 2014-07-03 Knauf Insulation Liquid high solids binder composition
GB201206193D0 (en) 2012-04-05 2012-05-23 Knauf Insulation Ltd Binders and associated products
GB201214734D0 (en) 2012-08-17 2012-10-03 Knauf Insulation Ltd Wood board and process for its production
US20150315339A1 (en) 2012-12-05 2015-11-05 Knauf Insulation Sprl Binder
WO2015120252A1 (en) 2014-02-07 2015-08-13 Knauf Insulation, Llc Uncured articles with improved shelf-life
GB201408909D0 (en) 2014-05-20 2014-07-02 Knauf Insulation Ltd Binders
GB201412709D0 (en) 2014-07-17 2014-09-03 Knauf Insulation And Knauf Insulation Ltd Improved binder compositions and uses thereof
GB201517867D0 (en) 2015-10-09 2015-11-25 Knauf Insulation Ltd Wood particle boards
GB201610063D0 (en) 2016-06-09 2016-07-27 Knauf Insulation Ltd Binders
GB201701569D0 (en) 2017-01-31 2017-03-15 Knauf Insulation Ltd Improved binder compositions and uses thereof
GB201804908D0 (en) 2018-03-27 2018-05-09 Knauf Insulation Ltd Binder compositions and uses thereof
GB201804907D0 (en) 2018-03-27 2018-05-09 Knauf Insulation Ltd Composite products
SI3561166T1 (en) * 2018-04-27 2021-08-31 Ursa Insulation, S.A. Method for the manufacture of mineral wool products

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Publication number Priority date Publication date Assignee Title
US3616179A (en) 1968-01-18 1971-10-26 Owens Corning Fiberglass Corp Glass fiber product bonded with terpolymer comprising phenol formaldehyde-urea formaldehyde condensation product
US3944703A (en) 1971-07-21 1976-03-16 Union Carbide Corporation Fibrous batts impregnated with aqueous dispersions based on heat-hardenable phenolic resins
US4067829A (en) 1973-03-19 1978-01-10 The Dow Chemical Company Preparation of a cured resole resin
US4076873A (en) 1974-07-29 1978-02-28 Shea Lawrence E Resorcinol-aldehyde resins used to bind reinforcing materials such as glass fibers in shaped object form
US4045398A (en) 1975-11-24 1977-08-30 Monsanto Company Resole resin binder composition
US4373062A (en) 1981-04-20 1983-02-08 Brown Gordon E Phenol-resorcinol-formaldehyde resin
US4461859A (en) 1981-11-16 1984-07-24 Ppg Industries, Inc. Method of preparing a phenolic aldehyde resin and resin composition for an adhesive system to be applied to glass fibers
US4476191A (en) 1981-11-16 1984-10-09 Ppg Industries, Inc. Resorcinol-aldehyde resin composition for an adhesive system to be applied to glass fibers
US4525492A (en) 1982-06-04 1985-06-25 Fiberglas Canada Inc. Modified phenolic foams
DE3504339A1 (en) 1985-02-08 1986-08-14 Rütgerswerke AG, 6000 Frankfurt METHOD FOR THE PRODUCTION OF PHENOL RESIN-BONDED GLASS AND MINERAL FIBER PRODUCTS
US4904753A (en) 1988-03-23 1990-02-27 Ashland Oil, Inc. Acid/oxidizer catalyst system for storage stable, quick-cure phenolic resins of the resole or benzylic ether resole type
US5043175A (en) 1990-10-01 1991-08-27 California Pellet Mill Company Method and apparatus for sterilization of animal feed
US5243015A (en) * 1992-06-25 1993-09-07 Georgia-Pacific Resins, Inc. Latent catalyzed phenolic resole resin composition
US5324337A (en) * 1992-12-29 1994-06-28 Knauf Fiber Glass Gmbh Method for producing fiber product
US5578371A (en) 1995-08-25 1996-11-26 Schuller International, Inc. Phenol/formaldehyde fiberglass binder compositions exhibiting reduced emissions
US5952440A (en) * 1997-11-03 1999-09-14 Borden Chemical, Inc. Water soluble and storage stable resole-melamine resin

Also Published As

Publication number Publication date
CA2315810C (en) 2007-01-09
DE69841616D1 (en) 2010-05-27
ATE464334T1 (en) 2010-04-15
WO1999060043A1 (en) 1999-11-25
US6555616B1 (en) 2003-04-29
EP1088012A1 (en) 2001-04-04
EP1088012A4 (en) 2002-10-23
CA2315810A1 (en) 1999-11-25
ES2343604T3 (en) 2010-08-04
EP1088012B1 (en) 2010-04-14
US6638882B1 (en) 2003-10-28

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