DK0538571T3 - - Google Patents
Info
- Publication number
- DK0538571T3 DK0538571T3 DK92113798.0T DK92113798T DK0538571T3 DK 0538571 T3 DK0538571 T3 DK 0538571T3 DK 92113798 T DK92113798 T DK 92113798T DK 0538571 T3 DK0538571 T3 DK 0538571T3
- Authority
- DK
- Denmark
- Prior art keywords
- monomers
- free
- total amount
- polyvinyl alcohol
- dispersions
- Prior art date
Links
- 239000000178 monomer Substances 0.000 abstract 4
- 238000000034 method Methods 0.000 abstract 3
- 239000004372 Polyvinyl alcohol Substances 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- 239000000084 colloidal system Substances 0.000 abstract 2
- 239000006185 dispersion Substances 0.000 abstract 2
- 229920002451 polyvinyl alcohol Polymers 0.000 abstract 2
- 230000001681 protective effect Effects 0.000 abstract 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract 1
- 239000011230 binding agent Substances 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- 239000004570 mortar (masonry) Substances 0.000 abstract 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 239000003973 paint Substances 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/30—Emulsion polymerisation with the aid of emulsifying agents non-ionic
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polymerization Catalysts (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to a process for the preparation of emulsifier-free, aqueous polymer dispersions stabilised by protective colloids, based on > 50% by weight of styrene and/or (C1- to C8-alkyl) (meth)acrylate, based on the total amount of monomers. The process comprises the semicontinuous, free-radical polymerisation of the monomers by the monomer feed method in the presence of a water-soluble polyvinyl alcohol as protective colloid, where the total amount of polyvinyl alcohol is introduced at the beginning. The dispersions have a very low residual monomer content. They are suitable as binders in emulsion paints and in hydraulically setting mortars.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4134672A DE4134672A1 (en) | 1991-10-19 | 1991-10-19 | METHOD FOR PRODUCING PROTECTIVE COLLOID-STABILIZED, EMULSIFIER-FREE, AQUEOUS PLASTIC DISPERSIONS |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DK0538571T3 true DK0538571T3 (en) | 1997-02-10 |
| DK0538571T4 DK0538571T4 (en) | 2002-02-11 |
Family
ID=6443061
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK92113798T DK0538571T4 (en) | 1991-10-19 | 1992-08-13 | Process for Preparation of Protective Colloid-Stabilized Emulsifier-Free Aqueous Plastic Dispersions |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP0538571B2 (en) |
| AT (1) | ATE143380T1 (en) |
| DE (2) | DE4134672A1 (en) |
| DK (1) | DK0538571T4 (en) |
| ES (1) | ES2091986T5 (en) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4337264A1 (en) * | 1993-11-02 | 1995-05-04 | Upat Max Langensiepen Kg | Mortar for two-component systems |
| DE4427480A1 (en) * | 1994-08-03 | 1996-02-08 | Schienenfahrzeuge Consulting U | Goods wagon for accepting freight on double or multiple levels |
| DE4446539A1 (en) * | 1994-12-24 | 1996-06-27 | Hoechst Ag | Process for the preparation of plastic dispersions |
| DE19502435A1 (en) * | 1995-01-26 | 1996-08-01 | Elotex Ag | Chemical composition containing a) a copolymer based on styrene and / or alkyl (meth) acrylate and at least one further comonomer and b) a protective colloid, its aqueous polymer dispersion, process for its preparation and its use |
| US5741871A (en) * | 1996-06-14 | 1998-04-21 | Air Products And Chemicals, Inc. | Acrylic emulsions prepared in the presence of fully hydrolyzed poly (vinyl alcohol) |
| DE19629948A1 (en) * | 1996-07-25 | 1998-01-29 | Polymer Latex Gmbh & Co Kg | Process for the preparation of sterically stabilized, emulsifier-free, aqueous polymer dispersions and powders prepared therefrom for use in building materials |
| US5753036A (en) * | 1997-04-21 | 1998-05-19 | Air Products And Chemicals, Inc. | Poly(vinyl alcohol) stabilized acrylic polymer modified hydraulic cement systems |
| DK1023331T3 (en) | 1997-09-26 | 2001-09-17 | Wacker Chemie Gmbh | Process for Preparation of Protective Colloid-Stabilized Polymers |
| KR100354450B1 (en) | 1997-12-02 | 2002-09-28 | 와커-헤미 게엠베하 | Method for producing protective colloid-stabilised vinyl aromatic-1,3-diene-copolymers |
| DE10132614A1 (en) | 2001-07-05 | 2003-01-16 | Polymerlatex Gmbh & Co Kg | Process for the preparation of protective colloid-stabilized, emulsifier-free, aqueous dispersions |
| DE10333623A1 (en) * | 2003-07-24 | 2005-02-24 | Celanese Emulsions Gmbh | Coating composition and process for its preparation |
| DE102004030358A1 (en) | 2004-06-23 | 2006-01-19 | Celanese Emulsions Gmbh | Food coating composition comprising protective colloid-stabilized polyacrylate dispersions, their use and coated foods prepared therewith |
| US8524822B2 (en) | 2005-01-11 | 2013-09-03 | W. R. Grace & Co.—Conn. | Vapor permeable liquid-applied membrane |
| WO2007124142A2 (en) | 2006-04-19 | 2007-11-01 | Hercules Incorporated | Stabilizers for improved open time of aqueous coatings |
| CN104031210B (en) * | 2014-06-23 | 2016-08-17 | 中国科学院化学研究所 | The preparation method of the monodisperse polystyrene microsphere emulsion of quaternary ammonium salt surface modification |
| US11912901B1 (en) | 2021-01-05 | 2024-02-27 | Swimc Llc | Polymer latex for matte films |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3111602A1 (en) * | 1981-03-24 | 1982-10-07 | Wacker-Chemie GmbH, 8000 München | COPOLYMERISATE OF INCREASED WATER RESISTANCE, METHOD FOR THEIR PRODUCTION AND THEIR USE |
| DE3128448C2 (en) * | 1981-07-18 | 1983-09-29 | Chemische Werke Hüls AG, 4370 Marl | Process for the preparation of aqueous dispersions of carboxylated styrene / ester copolymers |
-
1991
- 1991-10-19 DE DE4134672A patent/DE4134672A1/en not_active Withdrawn
-
1992
- 1992-08-13 AT AT92113798T patent/ATE143380T1/en active
- 1992-08-13 DK DK92113798T patent/DK0538571T4/en active
- 1992-08-13 ES ES92113798T patent/ES2091986T5/en not_active Expired - Lifetime
- 1992-08-13 EP EP92113798A patent/EP0538571B2/en not_active Expired - Lifetime
- 1992-08-13 DE DE59207240T patent/DE59207240D1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE59207240D1 (en) | 1996-10-31 |
| ES2091986T5 (en) | 2002-06-16 |
| DE4134672A1 (en) | 1993-04-22 |
| DK0538571T4 (en) | 2002-02-11 |
| EP0538571A1 (en) | 1993-04-28 |
| EP0538571B1 (en) | 1996-09-25 |
| EP0538571B2 (en) | 2001-12-12 |
| ES2091986T3 (en) | 1996-11-16 |
| ATE143380T1 (en) | 1996-10-15 |
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