DK0531310T3 - Slibekompaktering af kubisk bornitrid og en fremgangsmåde til fremstilling af samme - Google Patents
Slibekompaktering af kubisk bornitrid og en fremgangsmåde til fremstilling af sammeInfo
- Publication number
- DK0531310T3 DK0531310T3 DK91908729.6T DK91908729T DK0531310T3 DK 0531310 T3 DK0531310 T3 DK 0531310T3 DK 91908729 T DK91908729 T DK 91908729T DK 0531310 T3 DK0531310 T3 DK 0531310T3
- Authority
- DK
- Denmark
- Prior art keywords
- bonding agent
- volume percent
- cbn
- boron nitride
- cubic boron
- Prior art date
Links
- 229910052582 BN Inorganic materials 0.000 title abstract 2
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 238000005056 compaction Methods 0.000 title 1
- 239000007767 bonding agent Substances 0.000 abstract 5
- 239000013078 crystal Substances 0.000 abstract 3
- 239000011159 matrix material Substances 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 229910052581 Si3N4 Inorganic materials 0.000 abstract 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical group [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 abstract 1
- 239000011872 intimate mixture Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- 229910052726 zirconium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C26/00—Alloys containing diamond or cubic or wurtzitic boron nitride, fullerenes or carbon nanotubes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J3/00—Processes of utilising sub-atmospheric or super-atmospheric pressure to effect chemical or physical change of matter; Apparatus therefor
- B01J3/06—Processes using ultra-high pressure, e.g. for the formation of diamonds; Apparatus therefor, e.g. moulds or dies
- B01J3/062—Processes using ultra-high pressure, e.g. for the formation of diamonds; Apparatus therefor, e.g. moulds or dies characterised by the composition of the materials to be processed
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/515—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
- C04B35/58—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on borides, nitrides, i.e. nitrides, oxynitrides, carbonitrides or oxycarbonitrides or silicides
- C04B35/583—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on borides, nitrides, i.e. nitrides, oxynitrides, carbonitrides or oxycarbonitrides or silicides based on boron nitride
- C04B35/5831—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on borides, nitrides, i.e. nitrides, oxynitrides, carbonitrides or oxycarbonitrides or silicides based on boron nitride based on cubic boron nitrides or Wurtzitic boron nitrides, including crystal structure transformation of powder
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2203/00—Processes utilising sub- or super atmospheric pressure
- B01J2203/06—High pressure synthesis
- B01J2203/0605—Composition of the material to be processed
- B01J2203/0645—Boronitrides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2203/00—Processes utilising sub- or super atmospheric pressure
- B01J2203/06—High pressure synthesis
- B01J2203/065—Composition of the material produced
- B01J2203/066—Boronitrides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2203/00—Processes utilising sub- or super atmospheric pressure
- B01J2203/06—High pressure synthesis
- B01J2203/0675—Structural or physico-chemical features of the materials processed
- B01J2203/0685—Crystal sintering
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C26/00—Alloys containing diamond or cubic or wurtzitic boron nitride, fullerenes or carbon nanotubes
- C22C2026/005—Alloys containing diamond or cubic or wurtzitic boron nitride, fullerenes or carbon nanotubes with additional metal compounds being borides
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Metallurgy (AREA)
- Crystallography & Structural Chemistry (AREA)
- Mechanical Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Structural Engineering (AREA)
- Ceramic Products (AREA)
- Polishing Bodies And Polishing Tools (AREA)
- Liquid Crystal (AREA)
- Jellies, Jams, And Syrups (AREA)
- Instrument Panels (AREA)
- Liquid Crystal Display Device Control (AREA)
- Testing, Inspecting, Measuring Of Stereoscopic Televisions And Televisions (AREA)
- Control Of Indicators Other Than Cathode Ray Tubes (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AUPK029790 | 1990-05-25 | ||
| PCT/AU1991/000144 WO1991018844A1 (en) | 1990-05-25 | 1991-04-17 | Abrasive compact of cubic boron nitride and method of making same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DK0531310T3 true DK0531310T3 (da) | 1997-07-14 |
Family
ID=3774710
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK91908729.6T DK0531310T3 (da) | 1990-05-25 | 1991-04-17 | Slibekompaktering af kubisk bornitrid og en fremgangsmåde til fremstilling af samme |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US5288297A (da) |
| EP (1) | EP0531310B1 (da) |
| JP (1) | JP3091221B2 (da) |
| AT (1) | ATE151064T1 (da) |
| AU (1) | AU643280B2 (da) |
| CA (1) | CA2083693C (da) |
| DE (1) | DE69125487T2 (da) |
| DK (1) | DK0531310T3 (da) |
| IE (1) | IE911714A1 (da) |
| IN (1) | IN176315B (da) |
| WO (1) | WO1991018844A1 (da) |
| ZA (1) | ZA913464B (da) |
Families Citing this family (58)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1992017618A1 (en) * | 1991-03-26 | 1992-10-15 | The Australian National University | Abrasive compact composed mainly of cubic boron nitride and method of making same |
| US5639285A (en) * | 1995-05-15 | 1997-06-17 | Smith International, Inc. | Polycrystallline cubic boron nitride cutting tool |
| JPH10114575A (ja) * | 1996-10-04 | 1998-05-06 | Sumitomo Electric Ind Ltd | 工具用高硬度焼結体 |
| EP0852167A1 (en) * | 1997-01-07 | 1998-07-08 | General Electric Company | Coated cubic boron nitride polycrystalline superabrasive tools |
| US6170583B1 (en) | 1998-01-16 | 2001-01-09 | Dresser Industries, Inc. | Inserts and compacts having coated or encrusted cubic boron nitride particles |
| US6102140A (en) * | 1998-01-16 | 2000-08-15 | Dresser Industries, Inc. | Inserts and compacts having coated or encrusted diamond particles |
| US6138779A (en) * | 1998-01-16 | 2000-10-31 | Dresser Industries, Inc. | Hardfacing having coated ceramic particles or coated particles of other hard materials placed on a rotary cone cutter |
| JP4560604B2 (ja) * | 2000-01-25 | 2010-10-13 | 独立行政法人産業技術総合研究所 | 立方晶窒化硼素基焼結材及びその製造方法 |
| DE10315112A1 (de) * | 2003-04-02 | 2004-10-28 | Universität Hannover | Verfahren zur Kornfeinung von Magnesiumlegierungen |
| WO2004111284A2 (en) * | 2003-06-12 | 2004-12-23 | Element Six (Pty) Ltd | Composite material for drilling applications |
| US7441610B2 (en) * | 2005-02-25 | 2008-10-28 | Smith International, Inc. | Ultrahard composite constructions |
| US20070032369A1 (en) * | 2005-08-03 | 2007-02-08 | Franzen Jan M | High content CBN materials, compact incorporating the same and methods of making the same |
| JP2007142618A (ja) * | 2005-11-16 | 2007-06-07 | Hitachi Ltd | リモートコントロール装置 |
| US20100273808A1 (en) | 2008-11-21 | 2010-10-28 | Millennium Pharmaceticals, Inc. | Lactate salt of 4-[6-methoxy-7-(3-piperidin-1-yl-propoxy)quinazolin-4-yl]piperazine-1-carboxylic acid(4-isopropoxyphenyl)-amide and pharmaceutical compositions thereof for the treatment of cancer and other diseases or disorders |
| US8758461B2 (en) | 2010-12-31 | 2014-06-24 | Saint-Gobain Ceramics & Plastics, Inc. | Abrasive particles having particular shapes and methods of forming such particles |
| US8840694B2 (en) | 2011-06-30 | 2014-09-23 | Saint-Gobain Ceramics & Plastics, Inc. | Liquid phase sintered silicon carbide abrasive particles |
| CN103702800B (zh) | 2011-06-30 | 2017-11-10 | 圣戈本陶瓷及塑料股份有限公司 | 包括氮化硅磨粒的磨料制品 |
| EP2760639B1 (en) | 2011-09-26 | 2021-01-13 | Saint-Gobain Ceramics & Plastics, Inc. | Abrasive articles including abrasive particulate materials, coated abrasives using the abrasive particulate materials and methods of forming |
| EP3851248B1 (en) | 2011-12-30 | 2024-04-03 | Saint-Gobain Ceramics & Plastics, Inc. | Composite shaped abrasive particles and method of forming same |
| KR102074138B1 (ko) | 2011-12-30 | 2020-02-07 | 생-고뱅 세라믹스 앤드 플라스틱스, 인코포레이티드 | 형상화 연마입자 및 이의 형성방법 |
| EP2798032A4 (en) | 2011-12-30 | 2015-12-23 | Saint Gobain Ceramics | MANUFACTURE OF SHAPED GRINDING PARTICLES |
| KR101667943B1 (ko) | 2012-01-10 | 2016-10-20 | 생-고뱅 세라믹스 앤드 플라스틱스, 인코포레이티드 | 복잡한 형상들을 가지는 연마 입자들 및 이의 성형 방법들 |
| WO2013106602A1 (en) | 2012-01-10 | 2013-07-18 | Saint-Gobain Ceramics & Plastics, Inc. | Abrasive particles having particular shapes and methods of forming such particles |
| US8936114B2 (en) * | 2012-01-13 | 2015-01-20 | Halliburton Energy Services, Inc. | Composites comprising clustered reinforcing agents, methods of production, and methods of use |
| US9242346B2 (en) | 2012-03-30 | 2016-01-26 | Saint-Gobain Abrasives, Inc. | Abrasive products having fibrillated fibers |
| KR101813466B1 (ko) | 2012-05-23 | 2017-12-29 | 생-고뱅 세라믹스 앤드 플라스틱스, 인코포레이티드 | 형상화 연마입자들 및 이의 형성방법 |
| US10106714B2 (en) | 2012-06-29 | 2018-10-23 | Saint-Gobain Ceramics & Plastics, Inc. | Abrasive particles having particular shapes and methods of forming such particles |
| FI2906392T3 (fi) | 2012-10-15 | 2025-06-20 | Saint Gobain Abrasives Inc | Hiomahiukkasia, joilla on erityisiä muotoja, ja menetelmiä tällaisten hiukkasten muodostamiseksi |
| KR101818946B1 (ko) | 2012-12-31 | 2018-01-17 | 생-고뱅 세라믹스 앤드 플라스틱스, 인코포레이티드 | 미립자 소재 및 이의 형성방법 |
| CN107685296B (zh) | 2013-03-29 | 2020-03-06 | 圣戈班磨料磨具有限公司 | 具有特定形状的磨粒、形成这种粒子的方法及其用途 |
| TW201502263A (zh) | 2013-06-28 | 2015-01-16 | Saint Gobain Ceramics | 包含成形研磨粒子之研磨物品 |
| RU2643004C2 (ru) | 2013-09-30 | 2018-01-29 | Сен-Гобен Серэмикс Энд Пластикс, Инк. | Формованные абразивные частицы и способы их получения |
| MX380754B (es) | 2013-12-31 | 2025-03-12 | Saint Gobain Abrasives Inc | Artículo abrasivo que incluye partículas abrasivas perfiladas. |
| US9771507B2 (en) | 2014-01-31 | 2017-09-26 | Saint-Gobain Ceramics & Plastics, Inc. | Shaped abrasive particle including dopant material and method of forming same |
| CN103831737A (zh) * | 2014-02-11 | 2014-06-04 | 当涂县南方红月磨具磨料有限公司 | 一种含贝壳粉的立方氮化硼砂轮 |
| WO2015160855A1 (en) | 2014-04-14 | 2015-10-22 | Saint-Gobain Ceramics & Plastics, Inc. | Abrasive article including shaped abrasive particles |
| CA2945491C (en) | 2014-04-14 | 2023-03-14 | Saint-Gobain Ceramics & Plastics, Inc. | Abrasive article including shaped abrasive particles |
| US9902045B2 (en) | 2014-05-30 | 2018-02-27 | Saint-Gobain Abrasives, Inc. | Method of using an abrasive article including shaped abrasive particles |
| GB201412164D0 (en) * | 2014-07-08 | 2014-08-20 | Element Six Abrasives Sa | Cubic boron nitride composite material, method of using it, method of making it and tool comprising it |
| GB2531263B (en) | 2014-10-13 | 2019-01-09 | Kraft Foods R&D Inc | Filled cheese product |
| US9707529B2 (en) | 2014-12-23 | 2017-07-18 | Saint-Gobain Ceramics & Plastics, Inc. | Composite shaped abrasive particles and method of forming same |
| US9914864B2 (en) | 2014-12-23 | 2018-03-13 | Saint-Gobain Ceramics & Plastics, Inc. | Shaped abrasive particles and method of forming same |
| US9676981B2 (en) | 2014-12-24 | 2017-06-13 | Saint-Gobain Ceramics & Plastics, Inc. | Shaped abrasive particle fractions and method of forming same |
| US9827611B2 (en) | 2015-01-30 | 2017-11-28 | Diamond Innovations, Inc. | Diamond composite cutting tool assembled with tungsten carbide |
| TWI634200B (zh) | 2015-03-31 | 2018-09-01 | 聖高拜磨料有限公司 | 固定磨料物品及其形成方法 |
| EP3277459B1 (en) | 2015-03-31 | 2023-08-16 | Saint-Gobain Abrasives, Inc. | Fixed abrasive articles and methods of forming same |
| ES2819375T3 (es) | 2015-06-11 | 2021-04-15 | Saint Gobain Ceramics & Plastics Inc | Artículo abrasivo que incluye partículas abrasivas conformadas |
| CN105803248B (zh) * | 2016-03-10 | 2018-01-12 | 江苏耐尔特钻石有限公司 | 一种混合式超硬珩磨油石的制备方法 |
| KR102390844B1 (ko) | 2016-05-10 | 2022-04-26 | 생-고뱅 세라믹스 앤드 플라스틱스, 인코포레이티드 | 연마 입자 및 이의 형성 방법 |
| EP3455320A4 (en) | 2016-05-10 | 2019-11-20 | Saint-Gobain Ceramics&Plastics, Inc. | GRINDING PARTICLES AND METHOD FOR FORMING THEREOF |
| EP3519134B1 (en) | 2016-09-29 | 2024-01-17 | Saint-Gobain Abrasives, Inc. | Fixed abrasive articles and methods of forming same |
| US10759024B2 (en) | 2017-01-31 | 2020-09-01 | Saint-Gobain Ceramics & Plastics, Inc. | Abrasive article including shaped abrasive particles |
| US10563105B2 (en) | 2017-01-31 | 2020-02-18 | Saint-Gobain Ceramics & Plastics, Inc. | Abrasive article including shaped abrasive particles |
| WO2018236989A1 (en) | 2017-06-21 | 2018-12-27 | Saint-Gobain Ceramics & Plastics, Inc. | Particulate materials and methods of forming same |
| KR102765343B1 (ko) | 2019-12-27 | 2025-02-13 | 세인트-고바인 세라믹스 앤드 플라스틱스, 인크. | 연마 물품 및 이의 형성 방법 |
| EP4081609A4 (en) | 2019-12-27 | 2024-06-05 | Saint-Gobain Ceramics & Plastics Inc. | Abrasive articles and methods of forming same |
| CN114845838B (zh) | 2019-12-27 | 2024-10-25 | 圣戈本陶瓷及塑料股份有限公司 | 磨料制品及其形成方法 |
| JP2025500060A (ja) | 2021-12-30 | 2025-01-07 | サンーゴバン アブレイシブズ,インコーポレイティド | 研磨物品及びそれを形成する方法 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3767371A (en) * | 1971-07-01 | 1973-10-23 | Gen Electric | Cubic boron nitride/sintered carbide abrasive bodies |
| US3743489A (en) * | 1971-07-01 | 1973-07-03 | Gen Electric | Abrasive bodies of finely-divided cubic boron nitride crystals |
| US4224380A (en) * | 1978-03-28 | 1980-09-23 | General Electric Company | Temperature resistant abrasive compact and method for making same |
| JPS5562861A (en) * | 1978-11-06 | 1980-05-12 | Mitsubishi Metal Corp | Sintering material with tenacity and abrasion resistance |
| US4776862A (en) * | 1987-12-08 | 1988-10-11 | Wiand Ronald C | Brazing of diamond |
| US4899922A (en) * | 1988-02-22 | 1990-02-13 | General Electric Company | Brazed thermally-stable polycrystalline diamond compact workpieces and their fabrication |
| DE3923671C2 (de) * | 1988-07-22 | 1998-02-19 | Showa Denko Kk | CBN-Schleifmittelkörner aus kubischem Bornitrid und ein Verfahren zu deren Herstellung |
| US5043120A (en) * | 1988-11-10 | 1991-08-27 | The General Electric Company | Process for preparing polycrystalline CBN ceramic masses |
| US4968326A (en) * | 1989-10-10 | 1990-11-06 | Wiand Ronald C | Method of brazing of diamond to substrate |
| US5106392A (en) * | 1991-03-14 | 1992-04-21 | General Electric Company | Multigrain abrasive particles |
| AU1431992A (en) * | 1991-03-26 | 1992-11-02 | Australian National University, The | Abrasive compact composed mainly of cubic boron nitride and method of making same |
| DE4120423A1 (de) * | 1991-06-20 | 1992-12-24 | Kempten Elektroschmelz Gmbh | Verfahren zur herstellung von reaktionsgesinterten bornitrid-haltigen verbundwerkstoffen und von formkoerpern aus diesen verbundwerkstoffen sowie nach dem verfahren herstellbare bornitrid-haltige verbundwerkstoffe |
-
1991
- 1991-04-17 AU AU77538/91A patent/AU643280B2/en not_active Expired
- 1991-04-17 AT AT91908729T patent/ATE151064T1/de not_active IP Right Cessation
- 1991-04-17 DE DE69125487T patent/DE69125487T2/de not_active Expired - Lifetime
- 1991-04-17 DK DK91908729.6T patent/DK0531310T3/da not_active Application Discontinuation
- 1991-04-17 JP JP03508081A patent/JP3091221B2/ja not_active Expired - Lifetime
- 1991-04-17 CA CA002083693A patent/CA2083693C/en not_active Expired - Fee Related
- 1991-04-17 EP EP91908729A patent/EP0531310B1/en not_active Expired - Lifetime
- 1991-04-17 WO PCT/AU1991/000144 patent/WO1991018844A1/en not_active Ceased
- 1991-04-24 IN IN314CA1991 patent/IN176315B/en unknown
- 1991-05-07 ZA ZA913464A patent/ZA913464B/xx unknown
- 1991-05-20 IE IE171491A patent/IE911714A1/en not_active IP Right Cessation
-
1992
- 1992-11-18 US US07/978,386 patent/US5288297A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP0531310A4 (en) | 1993-11-18 |
| ATE151064T1 (de) | 1997-04-15 |
| DE69125487T2 (de) | 1997-10-09 |
| US5288297A (en) | 1994-02-22 |
| IN176315B (da) | 1996-04-20 |
| EP0531310A1 (en) | 1993-03-17 |
| JP3091221B2 (ja) | 2000-09-25 |
| WO1991018844A1 (en) | 1991-12-12 |
| CA2083693A1 (en) | 1991-11-26 |
| IE911714A1 (en) | 1991-12-04 |
| AU7753891A (en) | 1991-12-31 |
| ZA913464B (en) | 1992-02-26 |
| JPH05506205A (ja) | 1993-09-16 |
| AU643280B2 (en) | 1993-11-11 |
| CA2083693C (en) | 2002-01-01 |
| DE69125487D1 (de) | 1997-05-07 |
| EP0531310B1 (en) | 1997-04-02 |
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