DK0541604T3 - Overtræksmidler på basis af hydroxygruppeholdige polykondensations- og polyadditionsprodukter samt anvendelse deraf - Google Patents
Overtræksmidler på basis af hydroxygruppeholdige polykondensations- og polyadditionsprodukter samt anvendelse derafInfo
- Publication number
- DK0541604T3 DK0541604T3 DK91913342.1T DK91913342T DK0541604T3 DK 0541604 T3 DK0541604 T3 DK 0541604T3 DK 91913342 T DK91913342 T DK 91913342T DK 0541604 T3 DK0541604 T3 DK 0541604T3
- Authority
- DK
- Denmark
- Prior art keywords
- koh
- pct
- coating agents
- weight
- agents based
- Prior art date
Links
- 238000006068 polycondensation reaction Methods 0.000 title abstract 4
- 239000011248 coating agent Substances 0.000 title abstract 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 title abstract 2
- 239000002253 acid Substances 0.000 abstract 4
- 239000011230 binding agent Substances 0.000 abstract 3
- 229920005989 resin Polymers 0.000 abstract 3
- 239000011347 resin Substances 0.000 abstract 3
- 229920000058 polyacrylate Polymers 0.000 abstract 2
- 150000007513 acids Chemical class 0.000 abstract 1
- 229920000180 alkyd Polymers 0.000 abstract 1
- 239000003431 cross linking reagent Substances 0.000 abstract 1
- 239000012948 isocyanate Substances 0.000 abstract 1
- 150000002513 isocyanates Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 229920000728 polyester Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4063—Mixtures of compounds of group C08G18/62 with other macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
- C08G18/423—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing cycloaliphatic groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/63—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers
- C08G18/631—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers onto polyesters and/or polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/08—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Paints Or Removers (AREA)
- Polyesters Or Polycarbonates (AREA)
- Polyurethanes Or Polyureas (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4024204A DE4024204A1 (de) | 1990-07-31 | 1990-07-31 | Ueberzugsmittel auf der basis hydroxylgruppen enthaltender polykondensations- und polyadditionsprodukte sowie deren verwendung |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DK0541604T3 true DK0541604T3 (da) | 1995-05-08 |
Family
ID=6411327
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK91913342.1T DK0541604T3 (da) | 1990-07-31 | 1991-07-24 | Overtræksmidler på basis af hydroxygruppeholdige polykondensations- og polyadditionsprodukter samt anvendelse deraf |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US5326820A (da) |
| EP (1) | EP0541604B1 (da) |
| JP (1) | JPH0733496B2 (da) |
| AT (1) | ATE115171T1 (da) |
| BR (1) | BR9106715A (da) |
| CA (1) | CA2087338A1 (da) |
| DE (2) | DE4024204A1 (da) |
| DK (1) | DK0541604T3 (da) |
| ES (1) | ES2067946T3 (da) |
| WO (1) | WO1992002590A1 (da) |
Families Citing this family (66)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4209035A1 (de) * | 1992-03-20 | 1993-09-23 | Bayer Ag | Verfahren zur herstellung von hydroxyfunktionellen copolymerisaten |
| JPH06163423A (ja) * | 1992-11-18 | 1994-06-10 | Fujitsu Ltd | 半導体製造装置 |
| DE4317792A1 (de) * | 1993-05-28 | 1994-12-01 | Herberts Gmbh | Emulgatorfreies Überzugsmittel, dessen Herstellung und Verwendung |
| DE4317861C1 (de) * | 1993-05-28 | 1994-11-24 | Herberts Gmbh | Verfahren zur Mehrschichtlackierung von Substraten und Anwendung des Verfahrens |
| EP0688840A3 (de) * | 1994-06-20 | 1996-08-07 | Herberts & Co Gmbh | Überzugsmittel und deren Verwendung bei Verfahren zur Herstellung von Mehrschichtüberzügen |
| US5498783A (en) * | 1994-08-22 | 1996-03-12 | Basf Corporation | Powder coating composition resistant to overspray incompatibility defects |
| US6107403A (en) * | 1995-02-28 | 2000-08-22 | Basf Corporation | Coating composition containing hydroxyl groups, and its use in processes for the production of coatings |
| DE19525375A1 (de) * | 1995-07-12 | 1997-01-16 | Herberts Gmbh | Überzugsmittel, deren Verwendung und Verfahren zur Herstellung von Mehrschichtüberzügen |
| DE19535603A1 (de) * | 1995-09-25 | 1997-03-27 | Basf Lacke & Farben | 3-Komponenten-Beschichtungsmittel mit hoher Lösemittelbeständigkeit und hoher Abklebfestigkeit |
| DE19649394B4 (de) * | 1996-11-29 | 2007-01-11 | Synthopol Chemie Dr.Rer.Pol. Koch Gmbh & Co Kg | Bindemittel auf Polyester-Acrylatbasis, Verfahren zu dessen Herstellung und seine Verwendung |
| DE19544737C1 (de) * | 1995-12-01 | 1996-12-12 | Synthopol Chemie Dr Koch | Bindemittel auf Polyester-Acrylatbasis, Verfahren zu dessen Herstellung und seine Verwendung |
| US6184332B1 (en) * | 1996-02-29 | 2001-02-06 | Synthopol Chemie Dr. Rer. Pol. Koch Gmbh & Co. Kg | Polyester polyols and their use as the polyol component in two-component polyurethane paints |
| DE19623371A1 (de) | 1996-06-12 | 1997-12-18 | Herberts Gmbh | Bindemittel- und Überzugsmittelzusammensetzung und deren Verwendung bei der Mehrschichtlackierung |
| US6018013A (en) * | 1996-09-03 | 2000-01-25 | Nkk Corporation | Coating composition and method for producing precoated steel sheets |
| DE19637970A1 (de) | 1996-09-18 | 1998-03-19 | Basf Lacke & Farben | Beschichtungsmittel, Verfahren zu seiner Herstellung sowie die Verwendung des Beschichtungsmittels, insbesondere zur Außenlackierung von Emballagen |
| DE19711410A1 (de) | 1997-03-19 | 1998-09-24 | Beck & Co Ag Dr | Tränk-, Verguß- und Überzugsmassen für elektrotechnische und/oder elektronische Bauteile sowie für Trägermaterialien für flächige Isolierstoffe |
| DE19723504C1 (de) | 1997-06-05 | 1998-10-15 | Basf Coatings Ag | Beschichtungsmittel, Verfahren zu seiner Herstellung und seine Verwendung als Decklack oder Klarlack, insbesondere zur Beschichtung von Kunststoffen |
| EP0885908A1 (en) * | 1997-06-19 | 1998-12-23 | Basf Corporation | Coating composition based on a polyacrylate resin containing hydroxyl groups, and its use in processes for the production of coatings |
| EP0885907A1 (en) * | 1997-06-19 | 1998-12-23 | Basf Corporation | Coating composition based on a polyacrylate resin containing hydroxyl groups, and its use in processes for the production of coatings |
| DE19728411C2 (de) | 1997-07-03 | 2001-09-27 | Basf Coatings Ag | Polyurethanharz, Verfahren zu seiner Herstellung und seine Verwendung in wäßrigen Zweikomponenten-Klarlacken |
| AT405518B (de) * | 1997-08-07 | 1999-09-27 | Vianova Kunstharz Ag | Neue acrylatpolymerisate, deren grundlage polyesterharze oder polyester-oligomere sind, deren herstellung und verwendung in beschichtungsmitteln |
| DE19845740A1 (de) | 1998-10-05 | 2000-04-13 | Basf Coatings Ag | Beschichtungsmittel, Verfahren zu seiner Herstellung und seine Verwendung als Effekt-Klarlack, insbesondere zur Beschichtung von Kunststoffen |
| DE19846971A1 (de) * | 1998-10-12 | 2000-04-20 | Basf Coatings Ag | Beschichtungsmittel, Verfahren zu seiner Herstellung und seine Verwendung als Decklack oder Klarlack, insbesondere zur Beschichtung von Kunststoffen |
| DE19904330A1 (de) | 1999-01-28 | 2000-08-10 | Basf Coatings Ag | Wäßriger Beschichtungsstoff und Modulsystem zu seiner Herstellung |
| DE19910492A1 (de) | 1999-03-10 | 2000-09-21 | Basf Coatings Ag | Polyurethan und seine Verwendung zur Herstellung lösemittelfreier Beschichtungsstoffe |
| DE19921457B4 (de) | 1999-05-08 | 2006-05-04 | Basf Coatings Ag | Modulsystem zur Herstellung wäßriger Beschichtungsstoffe, Verfahren zu deren Herstellung und Verwendung sowie damit hergestellte Lackierungen |
| DE19938758A1 (de) * | 1999-08-16 | 2001-02-22 | Basf Coatings Ag | Oligomere und Polymere auf der Basis von Diethyloctandiolen, Verfahren zu ihrer Herstellung und ihre Verwendung |
| US6172159B1 (en) * | 2000-01-18 | 2001-01-09 | Accures Corporation | Water-reducible polyester resins and urethane coatings produced therefrom |
| US6326059B1 (en) | 2000-08-07 | 2001-12-04 | E.I. Du Pont De Nemours And Company | Two-stage cure coating compositions |
| US6410147B1 (en) | 2000-08-24 | 2002-06-25 | E. I. Du Pont De Nemours And Company | Low gloss crosslinkable coating compositions |
| US7230048B1 (en) * | 2000-08-25 | 2007-06-12 | Basf Corporation | Process for continuous production of reactive polymers with in-line post-modification and products thereof |
| DE10044670C1 (de) | 2000-09-09 | 2002-06-13 | Basf Coatings Ag | Thermisch oder thermisch und mit aktinischer Strahlung härtbarer, nicht wäßriger Beschichtungsstoff, Verfahren zu seiner Herstellung und seine Verwendung |
| TW200307733A (en) * | 2002-02-01 | 2003-12-16 | Natoco Co Ltd | Composition curable with actinic energy ray and use thereof |
| US6984693B2 (en) * | 2003-08-01 | 2006-01-10 | E. I. Du Pont De Nemours And Company | Two stage cure two component coating composition containing hydroxylbutyl acrylate polymers |
| DE10335491A1 (de) * | 2003-08-02 | 2005-02-24 | Basf Coatings Ag | Thermisch härtender, transparenter Beschichtungsstoff, Verfahren zu seiner Herstellung und seine Verwendung |
| US20050209433A1 (en) * | 2004-03-22 | 2005-09-22 | Barsotti Robert J | Orthoester-protected polyols for low VOC coatings |
| WO2005092976A1 (en) * | 2004-03-22 | 2005-10-06 | E.I. Dupont De Nemours And Company | Ketal-protected polyols for low voc coatings |
| DE102005045228A1 (de) | 2005-09-22 | 2007-04-05 | Basf Coatings Ag | Verwendung von Phosphonsäurediestern und Diphosphonsäurediestern sowie silangruppenhaltige, härtbare Gemische, enthaltend Phosphonsäurediester und Diphosphonsäurediester |
| DE102005045150A1 (de) | 2005-09-22 | 2007-04-05 | Basf Coatings Ag | Verwendung von Phosphonsäurediestern und Diphosphonsäurediestern sowie thermisch härtbare Gemische, enthaltend Phosphonsäurediester und Diphosphonsäurediester |
| CN101421014B (zh) * | 2006-02-13 | 2013-01-02 | 唐纳森公司 | 包括细纤维和反应、吸附或吸收颗粒的过滤网 |
| US20070269661A1 (en) * | 2006-05-16 | 2007-11-22 | Graham William F | Ultraproductive coating composition using a chemically mixed isocyanate system |
| WO2007136645A2 (en) * | 2006-05-16 | 2007-11-29 | E. I. Du Pont De Nemours And Company | Highly productive coating composition for automotive refinishing |
| DE102006024823A1 (de) | 2006-05-29 | 2007-12-06 | Basf Coatings Ag | Verwendung von härtbaren Gemischen, enthaltend silangruppenhaltige Verbindungen sowie Phosphonsäurediester oder Diphosphonsäurediester, als Haftvermittler |
| CN101517019B (zh) * | 2006-09-22 | 2012-04-11 | 关西涂料株式会社 | 涂料组合物和用于形成多层面漆膜的方法 |
| JP5156212B2 (ja) * | 2006-09-27 | 2013-03-06 | 日産自動車株式会社 | 2液型クリヤ塗料組成物及び複層塗膜形成方法 |
| US7867617B2 (en) * | 2006-09-29 | 2011-01-11 | E.I. Du Pont De Nemours And Company | Low temperature curable melamine containing coating composition and the use thereof |
| US8568888B2 (en) | 2007-03-15 | 2013-10-29 | Nanovere Technologies, Inc. | Dendritic polyurethane coating |
| US8206827B2 (en) * | 2007-03-15 | 2012-06-26 | Nanovere Technologies, Llc | Dendritic polyurethane coating |
| DE102007014720A1 (de) | 2007-03-23 | 2008-09-25 | Basf Coatings Japan Ltd., Yokohama | Phosphonat-haltiges Zweikomponenten-Lacksystem, dessen Herstellung und Verwendung |
| US8163850B2 (en) * | 2009-02-06 | 2012-04-24 | Eastman Chemical Company | Thermosetting polyester coating compositions containing tetramethyl cyclobutanediol |
| US9029460B2 (en) * | 2009-02-06 | 2015-05-12 | Stacey James Marsh | Coating compositions containing acrylic and aliphatic polyester blends |
| US9029461B2 (en) * | 2009-02-06 | 2015-05-12 | Eastman Chemical Company | Aliphatic polyester coating compositions containing tetramethyl cyclobutanediol |
| US8168721B2 (en) * | 2009-02-06 | 2012-05-01 | Eastman Chemical Company | Coating compositions containing tetramethyl cyclobutanediol |
| JP5991822B2 (ja) * | 2012-02-10 | 2016-09-14 | Basfジャパン株式会社 | 1液型クリヤー塗料組成物及びそれを用いた複層塗膜形成方法 |
| TWI619740B (zh) * | 2012-08-16 | 2018-04-01 | 迪愛生股份有限公司 | 纖維素酯樹脂組成物、纖維素酯光學膜及偏光板用保護膜 |
| JP6014903B2 (ja) * | 2013-02-07 | 2016-10-26 | ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツングBASF Coatings GmbH | 2液型水系1コート塗料組成物 |
| US20150175836A1 (en) | 2013-12-19 | 2015-06-25 | Axalta Coating Systems Ip Co., Llc | Low bake temperature curable coating compositions and processes for producing coatings at low bake temperatures |
| WO2016055128A1 (en) * | 2014-10-06 | 2016-04-14 | Siniat International | Improved mat and related gypsum boards suitable for wet or humid areas |
| US9598602B2 (en) | 2014-11-13 | 2017-03-21 | Eastman Chemical Company | Thermosetting compositions based on phenolic resins and curable poleyester resins made with diketene or beta-ketoacetate containing compounds |
| US9650539B2 (en) | 2014-10-27 | 2017-05-16 | Eastman Chemical Company | Thermosetting compositions based on unsaturated polyesters and phenolic resins |
| US9487619B2 (en) | 2014-10-27 | 2016-11-08 | Eastman Chemical Company | Carboxyl functional curable polyesters containing tetra-alkyl cyclobutanediol |
| US20160340471A1 (en) | 2015-05-19 | 2016-11-24 | Eastman Chemical Company | Aliphatic polyester coating compositions containing tetramethyl cyclobutanediol |
| US20170088665A1 (en) | 2015-09-25 | 2017-03-30 | Eastman Chemical Company | POLYMERS CONTAINING CYCLOBUTANEDIOL AND 2,2 BIS(HYDROXYMETHYL) AlKYLCARBOXYLIC ACID |
| US9988553B2 (en) | 2016-02-22 | 2018-06-05 | Eastman Chemical Company | Thermosetting coating compositions |
| US10011737B2 (en) | 2016-03-23 | 2018-07-03 | Eastman Chemical Company | Curable polyester polyols and their use in thermosetting soft feel coating formulations |
| WO2022147004A1 (en) * | 2020-12-28 | 2022-07-07 | Ppg Industries Ohio, Inc. | Polyester polymer |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA987808A (en) * | 1971-06-28 | 1976-04-20 | E.I. Du Pont De Nemours And Company | Air-drying coating composition of an acrylic enamel and an isocyanate cross-linking agent modified with an acid phosphate catalyst |
| AT309627B (de) | 1971-11-26 | 1973-08-27 | Vianova Kunstharz Ag | Verfahren zur Herstellung von Bindemitteln für luft- und ofentrocknende Überzugsmittel |
| DE3010719A1 (de) * | 1980-03-20 | 1981-09-24 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von metalleffektlackierungen und witterungsbestaendige metalleffekt-mehrschichtlackierungen aufweisende flaechengebilde |
| DE3213160A1 (de) | 1982-04-08 | 1983-10-13 | Herberts Gmbh, 5600 Wuppertal | Waessriges, waermehaertbares ueberzugsmittel und dessen verwendung |
| DE3314777A1 (de) * | 1983-04-23 | 1984-10-25 | Herberts Gmbh, 5600 Wuppertal | Verfahren zur lackierung |
| DE3322830A1 (de) * | 1983-06-24 | 1985-01-03 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von ueberzuegen |
-
1990
- 1990-07-31 DE DE4024204A patent/DE4024204A1/de not_active Withdrawn
-
1991
- 1991-07-24 DE DE59103830T patent/DE59103830D1/de not_active Expired - Fee Related
- 1991-07-24 BR BR919106715A patent/BR9106715A/pt not_active Application Discontinuation
- 1991-07-24 CA CA002087338A patent/CA2087338A1/en not_active Abandoned
- 1991-07-24 DK DK91913342.1T patent/DK0541604T3/da active
- 1991-07-24 US US07/969,276 patent/US5326820A/en not_active Expired - Fee Related
- 1991-07-24 EP EP91913342A patent/EP0541604B1/de not_active Expired - Lifetime
- 1991-07-24 ES ES91913342T patent/ES2067946T3/es not_active Expired - Lifetime
- 1991-07-24 AT AT91913342T patent/ATE115171T1/de not_active IP Right Cessation
- 1991-07-24 WO PCT/EP1991/001379 patent/WO1992002590A1/de not_active Ceased
- 1991-07-24 JP JP3512521A patent/JPH0733496B2/ja not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE59103830D1 (de) | 1995-01-19 |
| JPH0733496B2 (ja) | 1995-04-12 |
| BR9106715A (pt) | 1993-07-13 |
| WO1992002590A1 (de) | 1992-02-20 |
| US5326820A (en) | 1994-07-05 |
| JPH05507959A (ja) | 1993-11-11 |
| DE4024204A1 (de) | 1992-02-06 |
| EP0541604B1 (de) | 1994-12-07 |
| CA2087338A1 (en) | 1992-02-01 |
| ES2067946T3 (es) | 1995-04-01 |
| ATE115171T1 (de) | 1994-12-15 |
| EP0541604A1 (de) | 1993-05-19 |
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