DE925636C - Chemical contact fuse - Google Patents
Chemical contact fuseInfo
- Publication number
- DE925636C DE925636C DEW8270A DEW0008270A DE925636C DE 925636 C DE925636 C DE 925636C DE W8270 A DEW8270 A DE W8270A DE W0008270 A DEW0008270 A DE W0008270A DE 925636 C DE925636 C DE 925636C
- Authority
- DE
- Germany
- Prior art keywords
- components
- boron
- acid
- boron hydrocarbon
- solid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000126 substance Substances 0.000 title description 7
- 239000002253 acid Substances 0.000 claims description 10
- 229910052796 boron Inorganic materials 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 8
- -1 boron hydrocarbon Chemical class 0.000 claims description 7
- 229930195733 hydrocarbon Natural products 0.000 claims description 6
- 239000004215 Carbon black (E152) Substances 0.000 claims description 5
- 230000015572 biosynthetic process Effects 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- 239000002360 explosive Substances 0.000 claims description 2
- 235000019505 tobacco product Nutrition 0.000 claims 1
- 235000019504 cigarettes Nutrition 0.000 description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 235000019506 cigar Nutrition 0.000 description 4
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- FVAUCKIRQBBSSJ-UHFFFAOYSA-M sodium iodide Chemical compound [Na+].[I-] FVAUCKIRQBBSSJ-UHFFFAOYSA-M 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 206010061218 Inflammation Diseases 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 238000003776 cleavage reaction Methods 0.000 description 2
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 230000004054 inflammatory process Effects 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 230000007017 scission Effects 0.000 description 2
- 239000011973 solid acid Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 description 1
- 229940106681 chloroacetic acid Drugs 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000002757 inflammatory effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000015424 sodium Nutrition 0.000 description 1
- 235000009518 sodium iodide Nutrition 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- LALRXNPLTWZJIJ-UHFFFAOYSA-N triethylborane Chemical group CCB(CC)CC LALRXNPLTWZJIJ-UHFFFAOYSA-N 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B47/00—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase
- C06B47/02—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase the components comprising a binary propellant
- C06B47/10—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase the components comprising a binary propellant a component containing free boron, an organic borane or a binary compound of boron, except with oxygen
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06C—DETONATING OR PRIMING DEVICES; FUSES; CHEMICAL LIGHTERS; PYROPHORIC COMPOSITIONS
- C06C9/00—Chemical contact igniters; Chemical lighters
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Fireproofing Substances (AREA)
Description
Chemischer Berührungszünder Gegenstand der Erfindung .ist ein aus zwei Komponenten bestehender chemitseher Berührungszünder, dessen eine Komponente eine Boirkoh @lenwasserstoffanlagerungsverbindung ist, während die andere Komponente von einer Säure, vorwiegend in fester Form, gebildet wird.Chemical contact detonator The subject of the invention is an off two components of chemical touch detonators, one of which is a component while the other component is a Boirkoh® hydrogen addition compound is formed by an acid, mainly in solid form.
Es isst bekannt, zur Vermeidung zur Schwierigkeiten des Anzündens von Zigaretten, Zigarren od. dgl., insbesondere bei windigem und regnerischem Wetter, mit Hilfe eines Streichholzes, Feuerzeuges o,d.,dlgl. besondere Anzündungsvormiehtiungien zu verwenden. So hat man bereits das eine Endre einer Zigarre oder Zigarette mit einem Kügelchen aus feinpulverisiertem Kaliumpermanganat versehen, das,sich bei der Berührung mit einem Kissen, das mit Glycerin und Natriumjodid oder Natriumthiesulfat imprägniert war, entzündete. Die Berührung der beiden Komponenten führt zu einer Oxydation dein Glycerins unter entsprechender Wärmeentwicklung, die bis zur Flammenbildung führen kann. In der praktischen Anwendung hat esi sich aber herausgestellt, daß sich dass Glycerin infolge seiner stark hygroskopischen Eigenschaften für den Dauergebrauch wenig eignet und daß z. B. durch die Bildung von Aerolein unangenehme geruchliche und geschmackliche Beeinflusisiungen des Entzündungsgutes auftreten.It eats known to help avoid difficulties of lighting of cigarettes, cigars or the like, especially in windy and rainy weather, with the help of a match, lighter o, d., the like. special ignition devices to use. So you already have the end of a cigar or cigarette with you a bead of finely powdered potassium permanganate, which, with touching a pillow made with glycerin and sodium iodide or sodium thiesulfate was impregnated, inflamed. Touching the two components results in one Oxidation of your glycerine with corresponding heat development, which leads to the formation of a flame can lead. In practical use, however, it has been found that that glycerine is suitable for long-term use due to its highly hygroscopic properties little suitable and that z. B. due to the formation of aerolein unpleasant odor and taste influences of the inflammatory material occur.
Ferner hat man Zigaretten- und Zigarrenenden in der Weise präpariert, daß die Inbrandsetzung ohne Temperatureinwirkung von außen, insbesiondere unter der Einwirkung des vom Raucher durch Sog oder Druck erzeugten Luftstromes:, durch chemische Vorgänge erfolgte. Alls ein Mittel, das sich zur Präparierung der Zigaretten eignet, wurde pyrophores Eisen empfohlen. Aber auch dieser Vorschlag zur Inbrandsetzung weist noch gewisse Mängel auf, da pyrophores Eisen ungeeignet ist.Furthermore, the ends of cigarettes and cigars have been prepared in such a way that that the firing without exposure to temperature from outside, especially under the effect of the air flow generated by the smoker through suction or pressure :, through chemical processes took place. All a means that can be used to prepare cigarettes suitable, was Pyrophoric iron recommended. But also this suggestion there are still certain deficiencies for firing, as pyrophoric iron is unsuitable is.
Erfindungsgemäß wird vorgeschlagen, Borkohlenwasserstoffie, z. Bi Bortriäthyl, .durch Behandlung mit alkalischen Substanzen, z.. B. Ammoniak oder Aminen, in farblose, kri.stadline A.n.lagerungsverbindungen überzuführen. Die freien Borkohl@e:nwasserstoffe, die eine an der Luft sofort endzündliche Flüssigkeit darstellen, werden auf diese Weise in luftbeständige, kristalline, leicht zu handhabende Stoffe verwandelt, die durch die Einwirkung stärkerer Säuren sofort wieder in diel Ausgangsstoffe gespalten werden, wobei der frei werdende Borkohlenwasserstoffsich entzündet und eine entsprechende Trägersubstanz in Brand zu setzen vermag. Als Spaltungssäuren werden- zweckmäßig feste, kristallwassierhaltige Säuren, z. B. Oxalsäure, Chloressigsäure usw., vexwendet, es haben sich aber auch mit anorganischen Säuren imprägnierte Kieselsäurepräparate, Tonerden u. dgl. als brauchbare saure Spaltungsmittel erwiesen.According to the invention it is proposed to use boron hydrocarbons, e.g. Bi Boron triethyl, .by treatment with alkaline substances, e.g. ammonia or Amines, to be converted into colorless, critical stadline non-storage compounds. The free Borkohl @ e: nhydrogen, which is an instantly flammable liquid in the air, are in this way in air-resistant, crystalline, easy-to-use substances transforms them immediately back into the starting materials through the action of stronger acids are cleaved, whereby the released boron hydrocarbon ignites and able to set a corresponding carrier substance on fire. As cleavage acids are expediently solid acids containing water of crystallization, e.g. B. oxalic acid, chloroacetic acid etc., but there have also been found silicic acid preparations impregnated with inorganic acids, Clays and the like have been found to be useful acidic cleavage agents.
Die freien Boralkyle verbrennten an der Luft unter erheblicher Wärmeentwicklung zu Bortrioxyd, Wasserdampf und Kohlendioxyd. Die Verbrennungsprodukte sind ungiftig und geruchlos.The free boron alkyls burned in the air with considerable development of heat to boron trioxide, water vapor and carbon dioxide. The products of combustion are non-toxic and odorless.
Durch die Bildung dien kristallinen, an der Luft völlig beständigen Boralkylanlagerungsverbindungen mit Ammoniak oder Aminen und die Verwendung von festen Säuren wird es möglich, Berührungszünder zu schaffen, deren Anwendung in den mannigfaltigsten Formen möglich°ist.As a result of the formation, they are crystalline and completely stable in air Boroalkyl addition compounds with ammonia or amines and the use of solid acids it becomes possible to create touch fuses, their application in the most varied of forms is possible.
Durch die Einwirkung der trockenen Säuren werden diese Verbindungen unter dem Einfuß geringster Mengen von Luftfeuchtigkeit in ihre Ausgangsprodukte gespalten, nämlich Boralkyle und z. B. Ammoniakgas bzw. Amine, das sich mit der Säure zu dem entsprechenden Ammoniumsalz verbindet, während sich das frei gewordene Boralkyl sofort unter erheblicher ' Wärmeentwicklung oxydiert.By the action of the dry acids these compounds become under the influence of the smallest amounts of humidity in their starting products split, namely boron alkyls and z. B. ammonia gas or amines that deal with the Acid combines to form the corresponding ammonium salt, while the liberated Boroalkyl is oxidized immediately with considerable evolution of heat.
Zum Beispiel kann das Brennende von Zigaretten, Zigarren od. dgl: mit der Borkohlenwasserstoffanlagerungsverbindung präpariert werden, während die Säure als feste Substanz auf der Packung, dem Behälter oder sonst einem vom Raucher benötigten Gerät angebracht wird. Beil Berührung des: präparierten. Zigarettenendes mit der Säureschicht beginnt eich die ,Zigarette sofort zu entzünden.For example, the burning of cigarettes, cigars or the like can: be prepared with the borohydrocarbon addition compound, while the Acid as a solid substance on the packaging, the container or another from the smoker required device is attached. Hatchet touching the: groomed. End of cigarette with the acid layer the cigarette starts to ignite immediately.
In gleicher Weise ist der Gegenstand dien Erfindung geeignet, in Feuerzeugen Verwendung zu finden. Für diese Zwecke wird die betreffende BorkohlenwasserstGffanlagerungsverbindung durch ein LösurngSmittel,, z. B. Alkohol, verflüssigt und in dieser Form von Dochten u. dgl. aufgesaugt. Durch die Berührung derartig präparierter Dochtenden mixt der SäÜrekomponentetritt Entflammung ein.In the same way, the subject invention is useful in lighters To find use. For these purposes the boron hydrocarbon attachment compound in question is used by a LösurngSmittel ,, z. B. alcohol, liquefied and in this form of wicks and the like. The mixes by touching wick ends prepared in this way Acid component, inflammation occurs.
Auch für die Entzündung der bekanntfein. Feueranzünder aus, Sägemehl, Holz- und Papierabfällen hat sich-der erfindungsgemäße Berührungsentzünder als brauchbar erwiesen.Also known for inflammation of the fine. Firelighter off, sawdust, The contact igniter according to the invention has proven to be useful for waste wood and paper proven.
Er kann auch zur Entzündung von Brand-, Spreng- oder Leuchtsätzen in der Pyrotechnik Verwendung finden.It can also be used to ignite incendiaries, explosives or flares find use in pyrotechnics.
Claims (3)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEW8270A DE925636C (en) | 1952-04-04 | 1952-04-04 | Chemical contact fuse |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEW8270A DE925636C (en) | 1952-04-04 | 1952-04-04 | Chemical contact fuse |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE925636C true DE925636C (en) | 1955-03-24 |
Family
ID=7593803
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEW8270A Expired DE925636C (en) | 1952-04-04 | 1952-04-04 | Chemical contact fuse |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE925636C (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1105329B (en) * | 1955-02-05 | 1961-04-20 | Hauni Werke Koerber & Co Kg | Cigarette with lighter |
| DE19838027A1 (en) * | 1998-08-21 | 2000-03-02 | Roland Schmitt | Self lighting cigarette is fitted with a sealed patch containing material which ignites in the presence of air |
-
1952
- 1952-04-04 DE DEW8270A patent/DE925636C/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1105329B (en) * | 1955-02-05 | 1961-04-20 | Hauni Werke Koerber & Co Kg | Cigarette with lighter |
| DE19838027A1 (en) * | 1998-08-21 | 2000-03-02 | Roland Schmitt | Self lighting cigarette is fitted with a sealed patch containing material which ignites in the presence of air |
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