DE9112264U1 - Hairspray composition - Google Patents
Hairspray compositionInfo
- Publication number
- DE9112264U1 DE9112264U1 DE9112264U DE9112264U DE9112264U1 DE 9112264 U1 DE9112264 U1 DE 9112264U1 DE 9112264 U DE9112264 U DE 9112264U DE 9112264 U DE9112264 U DE 9112264U DE 9112264 U1 DE9112264 U1 DE 9112264U1
- Authority
- DE
- Germany
- Prior art keywords
- weight
- hairspray
- total composition
- vinylpyrrolidone
- composition according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims description 33
- 239000008266 hair spray Substances 0.000 title claims description 19
- 229920001577 copolymer Polymers 0.000 claims description 18
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 15
- 125000002252 acyl group Chemical group 0.000 claims description 15
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 9
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims description 9
- 239000003380 propellant Substances 0.000 claims description 9
- 150000003839 salts Chemical class 0.000 claims description 8
- 239000007921 spray Substances 0.000 claims description 8
- 235000019441 ethanol Nutrition 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 239000004215 Carbon black (E152) Substances 0.000 claims description 5
- 229920006317 cationic polymer Polymers 0.000 claims description 5
- 239000007789 gas Substances 0.000 claims description 5
- 229930195733 hydrocarbon Natural products 0.000 claims description 5
- 150000002430 hydrocarbons Chemical class 0.000 claims description 5
- 229920000642 polymer Polymers 0.000 claims description 5
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 4
- 150000001447 alkali salts Chemical class 0.000 claims description 2
- 125000003342 alkenyl group Chemical group 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 150000003863 ammonium salts Chemical class 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 125000003696 stearoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 239000003513 alkali Substances 0.000 claims 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 9
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 6
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 6
- 239000002537 cosmetic Substances 0.000 description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 5
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 5
- 239000002304 perfume Substances 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- SNPLKNRPJHDVJA-ZETCQYMHSA-N D-panthenol Chemical compound OCC(C)(C)[C@@H](O)C(=O)NCCCO SNPLKNRPJHDVJA-ZETCQYMHSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000001273 butane Substances 0.000 description 3
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 3
- 229940101267 panthenol Drugs 0.000 description 3
- 235000020957 pantothenol Nutrition 0.000 description 3
- 239000011619 pantothenol Substances 0.000 description 3
- 239000001294 propane Substances 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
- 239000000443 aerosol Substances 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 229940008099 dimethicone Drugs 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- 239000003906 humectant Substances 0.000 description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 2
- 239000001282 iso-butane Substances 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical group CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- CGIHFIDULQUVJG-UHFFFAOYSA-N phytantriol Chemical compound CC(C)CCCC(C)CCCC(C)CCCC(C)(O)C(O)CO CGIHFIDULQUVJG-UHFFFAOYSA-N 0.000 description 2
- CGIHFIDULQUVJG-VNTMZGSJSA-N phytantriol Natural products CC(C)CCC[C@H](C)CCC[C@H](C)CCC[C@@](C)(O)[C@H](O)CO CGIHFIDULQUVJG-VNTMZGSJSA-N 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 239000002453 shampoo Substances 0.000 description 2
- ODFAPIRLUPAQCQ-UHFFFAOYSA-M sodium stearoyl lactylate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC(=O)OC(C)C(=O)OC(C)C([O-])=O ODFAPIRLUPAQCQ-UHFFFAOYSA-M 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 2
- AOHBGMDQHXJADT-UHFFFAOYSA-N 2-(2-dodecanoyloxypropanoyloxy)propanoic acid Chemical compound CCCCCCCCCCCC(=O)OC(C)C(=O)OC(C)C(O)=O AOHBGMDQHXJADT-UHFFFAOYSA-N 0.000 description 1
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 description 1
- BEWCNXNIQCLWHP-UHFFFAOYSA-N 2-(tert-butylamino)ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCNC(C)(C)C BEWCNXNIQCLWHP-UHFFFAOYSA-N 0.000 description 1
- XVTDINVUVOXJIY-UHFFFAOYSA-N 2-hydroxypropanoyl hexanoate Chemical compound CCCCCC(=O)OC(=O)C(C)O XVTDINVUVOXJIY-UHFFFAOYSA-N 0.000 description 1
- ZKYCLDTVJCJYIB-UHFFFAOYSA-N 2-methylidenedecanamide Chemical compound CCCCCCCCC(=C)C(N)=O ZKYCLDTVJCJYIB-UHFFFAOYSA-N 0.000 description 1
- MXRGSJAOLKBZLU-UHFFFAOYSA-N 3-ethenylazepan-2-one Chemical compound C=CC1CCCCNC1=O MXRGSJAOLKBZLU-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- 229920001661 Chitosan Polymers 0.000 description 1
- -1 Dimethylsiloxane Chemical class 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical class OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- NJSSICCENMLTKO-HRCBOCMUSA-N [(1r,2s,4r,5r)-3-hydroxy-4-(4-methylphenyl)sulfonyloxy-6,8-dioxabicyclo[3.2.1]octan-2-yl] 4-methylbenzenesulfonate Chemical compound C1=CC(C)=CC=C1S(=O)(=O)O[C@H]1C(O)[C@@H](OS(=O)(=O)C=2C=CC(C)=CC=2)[C@@H]2OC[C@H]1O2 NJSSICCENMLTKO-HRCBOCMUSA-N 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- KYKAJFCTULSVSH-UHFFFAOYSA-N chloro(fluoro)methane Chemical compound F[C]Cl KYKAJFCTULSVSH-UHFFFAOYSA-N 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 125000003074 decanoyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C(*)=O 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- FYUWIEKAVLOHSE-UHFFFAOYSA-N ethenyl acetate;1-ethenylpyrrolidin-2-one Chemical compound CC(=O)OC=C.C=CN1CCCC1=O FYUWIEKAVLOHSE-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 230000003760 hair shine Effects 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 125000001419 myristoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 229940080352 sodium stearoyl lactylate Drugs 0.000 description 1
- 235000010956 sodium stearoyl-2-lactylate Nutrition 0.000 description 1
- 239000003724 sodium stearoyl-2-lactylate Substances 0.000 description 1
- AMJZVHHOVFFTOM-UHFFFAOYSA-M sodium;2-(2-hexanoyloxypropanoyloxy)propanoate Chemical compound [Na+].CCCCCC(=O)OC(C)C(=O)OC(C)C([O-])=O AMJZVHHOVFFTOM-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
- A61K8/8182—Copolymers of vinyl-pyrrolidones. Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
Description
Die vorliegende Erfindung betrifft eine neuartige Haarspray-Zusammensetzung, die zur Abgabe aus einer mechanischen Sprühvorrichtung oder mit verflüssigten Kohlenwasserstoff-Treibmitteln bzw. komprimierten Gasen vorgesehen ist und bei der Aufbringung auf das Haar die Frisur festigt, ihr einen elastischen Halt verleiht und zusätzlich den Haaren Glanz gibt.The present invention relates to a novel hairspray composition, which is intended for delivery from a mechanical spray device or with liquefied hydrocarbon propellants or compressed gases and, when applied to the hair, sets the hairstyle, gives it an elastic hold and additionally gives the hair shine.
Haarsprays, die mit Hilfe von verflüssigten Chlorfluorkohlenwasserstoff-Treibmitteln aus Aerosoldosen auf das Haar aufgebracht werden, sind seit langem bekannt.Hairsprays that are applied to the hair from aerosol cans using liquefied chlorofluorocarbon propellants have been known for a long time.
Diese unter Druck verflüssigten Treibmittel wurden aufgrund ihrer vermuteten Umweltschädlichkeit bereits seit längerer Zeit durch Haarsprays abgelöst, die mit Hilfe von Kohlenwasserstoff-Treibmitteln, insbesondere Propan, Butan bzw. Isobutan und deren Gemischen oder komprimierter Gase, insbesondere Dimethylether, Kohlendioxid, Stickstoff oder Stickstoffoxid versprüht werden, oder durch aus mechanischen Sprühvorrichtungen abgegebene Haarspray-Zusammensetzungen ersetzt. Obwohl die heute eingesetzten Haarsprays bereits einen hohen Entwicklungsstand erreicht haben, erfüllen sie häufig doch nicht alle an sie gestellten Forderungen.Due to their presumed environmental impact, these pressurized propellants have long been replaced by hairsprays that are sprayed using hydrocarbon propellants, in particular propane, butane or isobutane and mixtures thereof or compressed gases, in particular dimethyl ether, carbon dioxide, nitrogen or nitrogen oxide, or by hairspray compositions dispensed from mechanical spray devices. Although the hairsprays used today have already reached a high level of development, they often do not meet all the requirements placed on them.
Ziel der Erfindung ist es daher, eine Haarspray-Zusammensetzung zur Abgabe aus einer mechanischen Sprühvorrichtung oder mit verflüssigten Kohlenwasserstoff-Treibmitteln bzw. komprimierten Gasen zu schaffen, die dem Haar eine hohe Festigung vermittelt, ohne gleichzeitig dieses starr bzw. hart zu verformen, sondern dem Haar ein flexibles Volumen gibt und darüber hinaus auch Glanz verleiht.The aim of the invention is therefore to create a hairspray composition for delivery from a mechanical spray device or with liquefied hydrocarbon propellants or compressed gases, which gives the hair a high level of hold, without at the same time making it rigid or hard, but gives the hair a flexible volume and also gives it shine.
Diese Aufgabe wird dadurch gelöst, daß man eine Haarspray-Zusammensetzung
auf wäßriger Basis, die etwa 30 bis 90 Gew.-%,
insbesondere etwa 40 bis etwa 75 Gew Gew.-%, bezogen auf die
Gesamtzusammensetzung, eines niedrigen Alkohols der Gruppe
Ethylalkohol,n-Propylalkohol und/oder Isopropylalkohol und etwa 1 bis 15 Gew.-%, bezogen auf die Gesamtzusammensetzung,
mindestens eines filmbildenden Polymeren enthält, noch etwa
0,1 bis etwa 5 Gew.-% mindestens eines Cfi-C-fl-Acyllactylats
bzw. ein wasserlösliches Salz desselben zusetzt.This object is achieved by using a water-based hairspray composition containing about 30 to 90% by weight,
in particular about 40 to about 75 wt.%, based on the
Total composition, a low alcohol of the group
Ethyl alcohol, n-propyl alcohol and/or isopropyl alcohol and about 1 to 15% by weight, based on the total composition,
at least one film-forming polymer, or about
0.1 to about 5 wt.% of at least one C fi -C fl acyl lactylate
or adding a water-soluble salt thereof.
Die angegebenen Mengenanteile beziehen sich jeweils auf die Gesamtzusammensetzung ohne einen etwaigen Treibmittel-Anteil.The stated proportions refer to the total composition without any propellant content.
Acyllactylate der allgemeinen StrukturAcyl lactylates of the general structure
R-C - (-O-CH- C) - OH
H I H n
0 CH3 0,RC - (-O-CH- C) - OH
HIH n
0 CH3 0,
wobei R eine gerad- oder verzweigtkettige Alkyl- oder Alkenylgruppe mit 6 bis 18 Kohlenstoffatomen bedeutet, und &eegr; für eine Zahl zwischen 1 und 5 steht, und ihre Anwendung in kosmetischen Mitteln, insbesondere als Feuchthaltemittel, sind seit langem bekannt.where R is a straight- or branched-chain alkyl or alkenyl group having 6 to 18 carbon atoms, and η is a number between 1 and 5, and their use in cosmetic products, in particular as humectants, have been known for a long time.
Es wird hierzu auf einen Artikel von L. J. Murphy und F. Baiocchi, Drug Cosmetic Industry 122/5 (May 1978), 35, "The Role of Acyl Lactylates in Cosmetics and Toiletries" verwiesen, wonach sie insbesondere als Feuchthaltemittel eingesetzt werden.Reference is made to an article by LJ Murphy and F. Baiocchi, Drug Cosmetic Industry 122/5 (May 1978), 35, "The Role of Acyl Lactylates in Cosmetics and Toiletries", according to which they are used in particular as humectants.
Aus der US-PS 3 275 503 ist die Verwendung dieser Substanzen, insbesondere von Natriumcaproyllactylat, als antimikrobielle Wirkstoffe beschrieben.US Patent No. 3,275,503 describes the use of these substances, particularly sodium caproyl lactylate, as antimicrobial agents.
Aus der US-PS 3 472 940 ist weiterhin die Verwendung von Acyllactylaten, beispielsweise Natriumstearoyl-2-lactylat, in Deodorant-Stiften bekannt.The use of acyl lactylates, for example sodium stearoyl-2-lactylate, in deodorant sticks is also known from US Pat. No. 3,472,940.
Die US-PS 3 728 447 schließlich beschreibt die Verwendung von
Fettsäurelactylaten und -glycolaten in Konditionierungs-Shampoos.
Finally, US-PS 3 728 447 describes the use of
Fatty acid lactylates and glycolates in conditioning shampoos.
Ebenso ist aus der EP-A 278 370 die Verwendung vonEP-A 278 370 also discloses the use of
verzweigtkettigen Acyllactylaten und deren Salzen inbranched-chain acyl lactylates and their salts in
kosmetischen Mitteln, insbesondere auch Shampoos und Haarspülungen, bekannt.cosmetic products, especially shampoos and hair conditioners.
Alle diese Druckschriften enthalten jedoch keinerlei Hinweis auf die überraschende Wirkung dieser Verbindungsklasse in Kombination mit filmbildenden Polymeren bei Anwendung in Haarspray-Zusammensetzungen zur Verbesserung der Elastizität und des Volumens sowie der Erhöhung des Glanzes des Haares.However, all these publications contain no reference to the surprising effect of this class of compounds in combination with film-forming polymers when used in hairspray compositions to improve the elasticity and volume as well as to increase the shine of the hair.
Wie bereits ausgeführt, werden als im Rahmen der Erfindung geeignete Acyllactylate sowohl gerad- als auch verzweigtkettige Verbindungen eingesetzt. Besonders bevorzugt sind hierbei Stearoyl- und Isostearoyllactylat; die Herstellung des letzteren und anderer verzweigtkettiger Acyllactylate ist in der bereits erwähnten EP-A 278 370 beschrieben, auf die in diesem Zusammenhang ausdrücklich Bezug genommen wird. ...As already stated, both straight-chain and branched-chain compounds are used as acyl lactylates suitable for the purposes of the invention. Stearoyl and isostearoy lactylate are particularly preferred; the preparation of the latter and other branched-chain acyl lactylates is described in the aforementioned EP-A 278 370, to which express reference is made in this context. ...
Weitere geeignete Acyllactylate sind das Caproyllactylat und dessen Salze, Decanoyllactylat, Lauroyllactylat, Myristoyllactylat, etc. Die bevorzugte Zahl der Milchsäuregruppen liegt bei &eegr; = 1 bis 2, jedoch sind auch höhere Zahlen zwischen 3 und 5 möglich.Other suitable acyl lactylates are caproyl lactylate and its salts, decanoyl lactylate, lauroyl lactylate, myristoyl lactylate, etc. The preferred number of lactic acid groups is η = 1 to 2, but higher numbers between 3 and 5 are also possible.
Die Zahl der Milchsäuregruppen im Acyllactylat wird durch die eingesetzten Mengenanteile und die Reaktionsbedingungen bestimmt; es wird hierzu auch auf die US-PS 2 7 33 2 52 verwiesen.The number of lactic acid groups in the acyl lactylate is determined by the amounts used and the reaction conditions; reference is also made to US Pat. No. 2,733,252.
Eine Gruppe von Acyllactylaten, die zum Einsatz in denA group of acyl lactylates used in the
erfindungsgemäßen Haarsprays geeignet sind, werden von dersuitable for the hairsprays according to the invention are
Firma Patco Cosmetic Products, CJ. Patterson Co., unter der Bezeichnung "Pationic" vertrieben.Patco Cosmetic Products, CJ. Patterson Co., sold under the name "Pationic".
Wie bereits ausgeführt, können neben den Acyllactylaten selbst auch ihre wasserlöslichen Salze verwendet werden. Bevorzugt sind hierbei die Alkalisalze wie das Natrium-, Kalium- und Ammoniumsalz sowie Erdalkalisalze, beispielsweise Calciumacyllactylate; jedoch können auch Alkanolaminsalze zum Einsatz gelangen.As already mentioned, in addition to the acyl lactylates themselves, their water-soluble salts can also be used. Alkali salts such as sodium, potassium and ammonium salts as well as alkaline earth salts, for example calcium acyl lactylates, are preferred; however, alkanolamine salts can also be used.
Auch ungesättigte Acyllactylate, wie sie z.B. in der EP-A 443 956 beschrieben sind, können im Rahmen der Erfindung verwendet werden.Unsaturated acyl lactylates, as described, for example, in EP-A 443 956, can also be used within the scope of the invention.
Der bevorzugte Anteil an Acyllactylat liegt zwischen etwa 0,1 bis 5 Gew.-%, vorzugsweise 0,25 bis 2,5 Gew-%, insbesondere 0,5 bis 1,5 Gew.%, jeweils berechnet auf die Gesamtzusammensetzung.The preferred proportion of acyl lactylate is between about 0.1 to 5 wt.%, preferably 0.25 to 2.5 wt.%, in particular 0.5 to 1.5 wt.%, each calculated on the total composition.
Bei den erfindungsgemäß mit den Acyllactylaten bzw. deren wasserlöslichen Salzen zum Einsatz gelangenden filmbildenden Polymeren handelt es sich in der Regel um bekannte Produkte.The film-forming polymers used according to the invention with the acyl lactylates or their water-soluble salts are generally known products.
So sind die bekannten Vinylacetat/Vinylpyrrolidon-Copolymeren ebenso geeignet wie jene aus Acrylsäure/Vinylacetat,
Terpolymerisate aus Vinylpyrrolidon, Acrylsäureestern und
(Meth) Acrylsäure sowie Copolymerisate aus Vinylethern und
Maleinsäureanhydrid, die in wässrigem Medium hydrolysieren, kationische Polymere, beispielsweise Copolymere aus
Vinylpyrrolidon und Dialkylaminoalkylfmethjacrylaten, die
quaternisiert sein können, Homo- und Copolymere des Dimethyldiallylammoniumchlorids, beispielsweise mit Acrylamid,
Copolymere aus Hydroxyethylcellulose und Diallyldimethylammoniumchlorid,
mit Epichlorhydrin vernetzte Hydroxyethylcellulose, die anschließend mit Trimethylamin quaterniert
wurde, natürliche Filmbildner wie Chitosan, etc.The well-known vinyl acetate/vinylpyrrolidone copolymers are just as suitable as those made from acrylic acid/vinyl acetate, terpolymers made from vinylpyrrolidone, acrylic acid esters and
(Meth) acrylic acid and copolymers of vinyl ethers and
Maleic anhydride, which hydrolyze in aqueous medium, cationic polymers, for example copolymers of vinylpyrrolidone and dialkylaminoalkylmethacrylates, which may be quaternized, homo- and copolymers of dimethyldiallylammonium chloride, for example with acrylamide,
Copolymers of hydroxyethylcellulose and diallyldimethylammonium chloride, hydroxyethylcellulose cross-linked with epichlorohydrin and subsequently quaternized with trimethylamine, natural film formers such as chitosan, etc.
Besonders bevorzugt als Filmbildner in den erfindungsgemäßen
Haarspray-Zusammensetzungen wird ein Vinylpyrrolidon/ Vinylacetat-Copolymer, beispielsweise ein solches unter dem
Handelsnamen "LUVISKOL VA 28 " erhältliches in einer Menge von
1 bis 15 Gew.-%, vorzugsweise 2,5 bis 10 Gew.-%,insbesondere
5 bis 8 Gew.-%, berechnet auf die Gesamtzusammensetzung.Particularly preferred as a film former in the hairspray compositions according to the invention is a vinylpyrrolidone/vinyl acetate copolymer, for example one under the
Trade name "LUVISKOL VA 28 " available in a quantity of
1 to 15 wt.%, preferably 2.5 to 10 wt.%, in particular
5 to 8 wt.%, calculated on the total composition.
Gemäß einer weiteren bevorzugten Ausführungsform der Erfindung liegt dieses Vinylacetat/Vinylpyrrolidon-Copolymerisat im Gemisch mit einem kationischen Polymeren, beispielsweise einem quaternisierten Vinylpyrrolidon/Dialkylaminoalkylmethacrylat-Copolymerisat, vor, wobei der Anteil des kationischen Polymeren bei etwa 0,1 bis etwa 2,5 Gew.-% derAccording to a further preferred embodiment of the invention, this vinyl acetate/vinylpyrrolidone copolymer is present in a mixture with a cationic polymer, for example a quaternized vinylpyrrolidone/dialkylaminoalkyl methacrylate copolymer, the proportion of the cationic polymer being about 0.1 to about 2.5% by weight of the
Gesamtzusammensetzung, vorzugsweise zwischen etwa 0,5 und
1,5 Gew.-%, liegt.Total composition, preferably between about 0.5 and
1.5% by weight.
Die erfindungsgemäßen Zusammensetzungen können alle in solchen
Mitteln üblichen Stoffe enthalten, beispielsweise weitere Lösungsmittel wie niedere Alkane, beispielsweise n-Pentan oder
Isopentan in Mengenanteilen zwischen etwa 2,5 und etwa
10 Gew.-% der Gesamtzusammensetzung, Aceton, Polyalkohole und deren Ether, beispielsweise Glycerin, Propylenglykol und dessen
Monomethylether, Weichmacher, haarpflegende Wirkstoffe, wie beispielsweise Panthenol oder Phytantriol, Parfüms,
oberflächenaktive Substanzen, etc.The compositions according to the invention can contain all substances customary in such agents, for example further solvents such as lower alkanes, for example n-pentane or isopentane in proportions between about 2.5 and about
10% by weight of the total composition, acetone, polyalcohols and their ethers, for example glycerin, propylene glycol and its monomethyl ether, plasticizers, hair care ingredients such as panthenol or phytantriol, perfumes, surface-active substances, etc.
Art und Menge solcher Zusatzstoffe sind dem Fachmann hinreichend bekannt und finden sich in jedem kosmetischen Handbuch.The type and amount of such additives are well known to the expert and can be found in every cosmetic manual.
Obwohl erfindungsgemäß aus mechanischen Sprühvorrichtungen abzugebende Haarsprays, sog. Pumpsprays, bevorzugt sind, kann auch mit komprimierten Gasen, vorzugsweise Dimethylether, Kohlendioxid, Stickstoff oder Stickstoffoxid (N2^) oder Kohlenwasserstoff-Treibgasen wie Propan und Butan bzw. Isobutan und deren handelsüblichen Gemischen gearbeitet werden.Although hairsprays dispensed from mechanical spray devices, so-called pump sprays, are preferred according to the invention, it is also possible to work with compressed gases, preferably dimethyl ether, carbon dioxide, nitrogen or nitrogen oxide ( N 2^) or hydrocarbon propellants such as propane and butane or isobutane and their commercially available mixtures.
Im folgenden werden Ausführungsbeispiele für erfindungsgemäße Zusammensetzungen gegeben.In the following, exemplary embodiments of compositions according to the invention are given.
Ethanol 75,0 (Gew.-%)Ethanol 75.0 (wt.%)
Vinylacetat / Vinylpyrrolidon (80:20)-Vinyl acetate / vinylpyrrolidone (80:20)-
Copolymerisat 7,0Copolymer 7.0
Quaterniertes Vinylpyrrolidon/
Dimethylaminoethylmetharcylat-Copolymerisat 0,5Quaternized vinylpyrrolidone/
Dimethylaminoethyl methacrylate copolymer 0.5
Dimethylsiloxan - Glycol-Copolymer (Dimethicone
Copolyol) 0,5Dimethylsiloxane - Glycol Copolymer (Dimethicone
Copolyol) 0.5
Panthenol 0,1Panthenol 0.1
Natriumisostearoyllactylat (n =1-2) 0,5Sodium isostearoylactylate (n =1-2) 0.5
Parfüm 0,1Perfume 0.1
Wasser ad 100,0Water ad 100.0
Bei Anwendung aus einer bekannten mechanischen Pumpsprühvorrichtung auf das Haar wird eine Frisur mit vollem Griff, gutem Halt und natürlichem Glanz erhalten.When applied to the hair from a well-known mechanical pump spray device, a hairstyle with full grip, good hold and natural shine is achieved.
Die Weglassung des Natriumisostearoyllactylats in der gleichen Rezeptur ergab einen wesentlich starreren, harten Film auf dem Haar mit stumpfem Aussehen.The omission of sodium isostearoylactylate in the same formulation resulted in a much more rigid, hard film on the hair with a dull appearance.
Isopropylalkohol 7 3,5 (Gew.-%)Isopropyl alcohol 7 3.5 (wt.%)
Vinylacetat / Crotonsäure-Copolymerisat 6,0Vinyl acetate / crotonic acid copolymer 6.0
NatriumstearoylIactylat (n = 2) 1,0Sodium stearoyl lactylate (n = 2) 1.0
Phytantriol 0,3Phytantriol 0.3
Panthenol 0,5Panthenol 0.5
Parfüm 0,3Perfume 0.3
Wasser ad 100,0Water ad 100.0
Die Zusammensetzung wird als Pumpspray abgegeben.The composition is dispensed as a pump spray.
Ethanol 51,5 (Gew.-%)Ethanol 51.5 (wt.%)
Vinylcaprolactam/Vinylpyrrolidon / Dimethylaminoethylmethacrylat - Copolymerisat 7,2Vinylcaprolactam/vinylpyrrolidone / dimethylaminoethyl methacrylate - copolymer 7.2
Vinylpyrrolidon/Vinylacetat -Vinylpyrrolidone/vinyl acetate -
Copolymerisat 1,5Copolymer 1.5
Natrium-n-caproyllactylatSodium n-caproyl lactylate
(n = 2) 1,0(n = 2) 1.0
Parfüm 0,2Perfume 0.2
Dimethylether 25,0Dimethyl ether 25.0
Wasser ad 100,0Water ad 100.0
Die Abfüllung der Lösung mit Dimethylether in eine Aerosoldose erfolgt auf übliche Weise.The solution containing dimethyl ether is filled into an aerosol can in the usual way.
Es wird ein Haarspray erhalten, das dem Haar festen, aber elastischen Halt und Glanz verleiht.The result is a hairspray that gives the hair a firm but elastic hold and shine.
Ethanol 50,50 (Gew.-%)Ethanol 50.50 (wt.%)
Copolymerisat aus Octylacrylamid/Copolymer of octylacrylamide/
t-Butylaminoethylmethacrylat/Acrylsäuret-Butylaminoethyl methacrylate/acrylic acid
(Amphomer ) 4,50(Amphomer) 4.50
Quaterniertes CopolymerisatQuaternized copolymer
aus Vinylpyrrolidon/Dimethylaminooethyl-from vinylpyrrolidone/dimethylaminoethyl
methacrylat 1,00methacrylate 1.00
Aminomethylpropanol 0,75Aminomethylpropanol 0.75
Dimethicone Copolyol 0,50Dimethicone Copolyol 0.50
Natriumisostearoyllactylat (n = 1-2) 1,50Sodium isostearoylactylate (n = 1-2) 1.50
Parfüm 0,15Perfume 0.15
Wasser 11,10Water 11.10
abgefüllt mit einem Treibmittelgemischfilled with a propellant mixture
Propan/Butan (35:65) 30,00Propane/Butane (35:65) 30.00
Claims (5)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE9112264U DE9112264U1 (en) | 1991-10-02 | 1991-10-02 | Hairspray composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE9112264U DE9112264U1 (en) | 1991-10-02 | 1991-10-02 | Hairspray composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE9112264U1 true DE9112264U1 (en) | 1993-02-04 |
Family
ID=6871862
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE9112264U Expired - Lifetime DE9112264U1 (en) | 1991-10-02 | 1991-10-02 | Hairspray composition |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE9112264U1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2908297A1 (en) * | 2006-11-10 | 2008-05-16 | Oreal | Cosmetic eyelash coating composition, useful for makeup or non-therapeutic care of eyelashes and to obtain a uniform makeup and/or volume in eyelashes, comprises aqueous phase, emulsifier and wax |
| EP1920757A3 (en) * | 2006-11-10 | 2009-10-28 | L'Oréal | Cosmetic composition containing lactic acid derivatives and/or citric acid derivatives |
-
1991
- 1991-10-02 DE DE9112264U patent/DE9112264U1/en not_active Expired - Lifetime
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2908297A1 (en) * | 2006-11-10 | 2008-05-16 | Oreal | Cosmetic eyelash coating composition, useful for makeup or non-therapeutic care of eyelashes and to obtain a uniform makeup and/or volume in eyelashes, comprises aqueous phase, emulsifier and wax |
| EP1920757A3 (en) * | 2006-11-10 | 2009-10-28 | L'Oréal | Cosmetic composition containing lactic acid derivatives and/or citric acid derivatives |
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