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DE918778C - Process for the production of polycondensation products - Google Patents

Process for the production of polycondensation products

Info

Publication number
DE918778C
DE918778C DEZ1393A DEZ0001393A DE918778C DE 918778 C DE918778 C DE 918778C DE Z1393 A DEZ1393 A DE Z1393A DE Z0001393 A DEZ0001393 A DE Z0001393A DE 918778 C DE918778 C DE 918778C
Authority
DE
Germany
Prior art keywords
production
polycondensation products
starting materials
polyamides
acids
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEZ1393A
Other languages
German (de)
Inventor
Dr Paul Voegele
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zellwolle und Kunstseide Ring GmbH
Original Assignee
Zellwolle und Kunstseide Ring GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to DEZ1386A priority Critical patent/DE901592C/en
Priority to FR879254D priority patent/FR879254A/en
Priority to BE444590A priority patent/BE444590A/en
Priority to DEZ1393A priority patent/DE918778C/en
Application filed by Zellwolle und Kunstseide Ring GmbH filed Critical Zellwolle und Kunstseide Ring GmbH
Priority to DEZ1394A priority patent/DE938396C/en
Priority to CH237400D priority patent/CH237400A/en
Priority to BE448767A priority patent/BE448767R/en
Priority to BE448769A priority patent/BE448769R/en
Priority to FR52774D priority patent/FR52774E/en
Priority to FR52927D priority patent/FR52927E/en
Priority to FR53128D priority patent/FR53128E/en
Application granted granted Critical
Publication of DE918778C publication Critical patent/DE918778C/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18—Stationary reactors having moving elements inside
    • B01J19/22—Stationary reactors having moving elements inside in the form of endless belts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0895—Manufacture of polymers by continuous processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/34—Carboxylic acids; Esters thereof with monohydroxyl compounds
    • C08G18/341—Dicarboxylic acids, esters of polycarboxylic acids containing two carboxylic acid groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/785—Preparation processes characterised by the apparatus used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/04—Preparatory processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
    • C08G69/28—Preparatory processes
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16D—COUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
    • F16D23/00—Details of mechanically-actuated clutches not specific for one distinct type
    • F16D23/02—Arrangements for synchronisation, also for power-operated clutches
    • F16D23/04—Arrangements for synchronisation, also for power-operated clutches with an additional friction clutch
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00121—Controlling the temperature by direct heating or cooling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00121—Controlling the temperature by direct heating or cooling
    • B01J2219/0013—Controlling the temperature by direct heating or cooling by condensation of reactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00761—Details of the reactor
    • B01J2219/00763—Baffles
    • B01J2219/00765—Baffles attached to the reactor wall
    • B01J2219/0077—Baffles attached to the reactor wall inclined

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Polyamides (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)

Description

Verfahren zur Herstellung von Polykondensationsprodukten Im Patent goi 592 ist ein Verfahren zur Kündensation von Aminoasäuren 'bzw. von Diaminen und Dicarbonsäuren mit ausreichend langen Ketten zu Polyamiden beschrieben worden, welches dadurch gekennzeichnet ist, daß man die Ausgangsmaterialien in feiner Verteilung bzw. in dünnen Schichten höheren Temperaturen aussetzt oder die Schmelzen der genannten Ausgangsmateriahen in dünnen Schichten, vorzugsweise in fortlaufendem Arbeitsgang, über beheizte Flächen laufen läßt. Die Schmelzen können auch durch senkrecht stehende beheizte Rohre oder Türme, die mit großoberflächigem Material gefällt sind, von oben nach untien hindurchgeleitet oder auch durch heiße poröse Wändie oder Schichten gepneßtoder gesaugt werden. In allen. Fällten kann die Beheizung des Reaktionsraumes vermittels durchströmender heißer inerter Gase oder Dämpfe erfolgen, auch können Lösungen oder Schmelzen der Awsgangsmatieralien in heißen inerten Gasen oder Dämpfen zerstäubt zur Einwirkung gebracht werden.Process for the production of polycondensation products The patent goi 592 describes a process for the termination of amino acids' resp. of diamines and dicarboxylic acids with sufficiently long chains to form polyamides, which is characterized in that the starting materials are exposed to higher temperatures in fine distribution or in thin layers or the melts of the starting materials mentioned are overheated in thin layers, preferably in a continuous operation Runs surfaces. The melts can also be passed through vertical heated pipes or towers, which are precipitated with large-surface material, from top to bottom, or they can also be pressed or sucked through hot, porous walls or layers. In all. Precipitations can be used to heat the reaction space by means of hot inert gases or vapors flowing through them; solutions or melts of the starting materials in hot inert gases or vapors can also be atomized to act.

Es wurde nun gefunden, daß, diese Maßnahmen vorteilhaft auch auf die Herstellung anderer Polykondensationsprodukte aus anderen. bifwnktionellen organischen Verbindungen, die untrer Austritt von Wasser, Alkohol usw. verlaufen, übertragen werden können. Es können auf :diese Weise Polyamide, Polyharnsboffe, Polyunethame, Polyester und Mischkondensationspinodukte derselben hergestellt werden.It has now been found that these measures are also beneficial to the Manufacture of other polycondensation products from others. bifunctional organic Compounds that leak water, alcohol, etc., are transferred will can. In this way, polyamides, polyureas, Polyunethame, polyester and mixed condensation products of the same are produced.

Als Ausgangsmaterialien kommen alle an sich hierfür bekannten Substanzen in Frage, wie z. B. Dioarbonsäuren und deren funktionelle Derivate, wie Alkyl- und Arylester, Chloride, ferner Diamine, Glykole, Duretharne, Dih arn@stoffe sowie hhiifunktioryelle Verbindungen, welche zwei verschiedene solcher Gruppen besitzen, also etwa Amnosäuren, Amnoalkohole, Aminourethane, Aminoharustoffe, Urethancarbonsäuren, Harnsboffoarbonsäur:en, Oxysäuren, sowie die homologen Verbindungen, die an Stelle des. Sauerstoffs Schwefelenthalten, ferner z. B. die Harnstoffgruppa enthaltende Dica.rbonsäuren, die unter Aufspaltung der H.arnstoffgruppe und unter Austritt von Kohlendioxyd und Wasser mit sich selbst zu Polyamiden kondensieren.All substances known per se for this are used as starting materials in question, such as B. dioarboxylic acids and their functional derivatives, such as alkyl and Aryl esters, chlorides, also diamines, glycols, Duretharne, Dih arn @ stoffe and hhiifunktioryelle Compounds that have two different such groups, such as amino acids, Amno alcohols, aminourethanes, amino ureas, urethane carboxylic acids, uric acid carboxylic acids, Oxy acids, as well as the homologous compounds which contain sulfur instead of oxygen, further z. B. the urea group containing dicarboxylic acids, with splitting of the urea group and with the escape of carbon dioxide and water with itself condense to polyamides.

Die Vorteile des vorliegenden Verfahrens sind insbesondere in der ganz wesentlichen Beschleunigung der Reaktion, mithin. also in einer bedeutenden Abkürzung der Reaktionszeit, zu erblicken. Beispielsweise lassen sich die sonst üblichen Reaktionsseiten vorn etwa i1/2 his a1/2 Stunden aufwärts bis unter Umständen 6 bis 8 Stunden auf 5 bis 15 Minuten und noch weniger abkürzen.The advantages of the present process are, in particular, the very substantial acceleration of the reaction. thus to be seen in a significant shortening of the reaction time. For example, the otherwise usual reaction pages can be shortened at the front from about 1/2 to 1/2 hours up to possibly 6 to 8 hours to 5 to 15 minutes and even less.

Au-s f ührungsbei s p iel i Mol Tetramethylenäiurethylan und i Mol Sebacinsäure werden gut gemischt und in feiner Aufteilung bzw. in dünner Schicht 5 bis 6 Minuten auf etwa z 5o bis 300° erhitzt. Man erhält ein Polyamid mit einer F,igenviskosität von i, 12.Example of one mole of tetramethylene acid ethylane and one mole Sebacic acid are mixed well and in fine division or in a thin layer Heated for 5 to 6 minutes to about z 50 to 300 °. A polyamide is obtained with a F, intrinsic viscosity of i, 12.

Claims (1)

PATENTANSPRUCH: Verfahren zur Herstellung von Polykondensationsprodukben aus bifunktionallen organischen Verbindungen durch U-msetzümg der Reaktionsteilnehmer in geschmolzenem Zustand und in dünnten Schichten, vorzugsweise in fortlaufendem Arbeitsgang, gemäß Patent goi 592, dadurch gekennzeichnet, daß man hier andere Ausgangsstoffe verwendet, die bekannroermaßen zur Bildu mg vorn Polyamiden, Polyharnstoffen, Polyurethanen, Polyestern und deren Mischkondensationsprodukten führen.PATENT CLAIM: Process for the production of polycondensation products from bifunctional organic compounds by U-msetzümg the reactants in the molten state and in thin layers, preferably in a continuous operation, according to patent goi 592, characterized in that other starting materials are used here which are known to form from polyamides, polyureas, polyurethanes, polyesters and their mixed condensation products.
DEZ1393A 1941-02-23 1942-09-06 Process for the production of polycondensation products Expired DE918778C (en)

Priority Applications (11)

Application Number Priority Date Filing Date Title
DEZ1386A DE901592C (en) 1941-02-23 1941-02-23 Process for the production of polyamides
FR879254D FR879254A (en) 1941-02-23 1942-02-11 Process for the preparation of polyamides
BE444590A BE444590A (en) 1941-02-23 1942-02-21 Polyamide manufacturing process
DEZ1393A DE918778C (en) 1941-02-23 1942-09-06 Process for the production of polycondensation products
DEZ1394A DE938396C (en) 1941-02-23 1942-10-15 Process for the continuous implementation of polycondensation
CH237400D CH237400A (en) 1941-02-23 1942-11-28 Process for the production of plastics and device for its implementation.
BE448767A BE448767R (en) 1941-02-23 1943-01-18 Polyamide manufacturing process
BE448769A BE448769R (en) 1941-02-23 1943-01-18 Polyamide manufacturing process
FR52774D FR52774E (en) 1941-02-23 1943-03-18 Process for preparing polyamides
FR52927D FR52927E (en) 1941-02-23 1943-03-19 Process for the preparation of polyamides
FR53128D FR53128E (en) 1941-02-23 1943-09-09 Process for preparing polyamides

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DEZ1386A DE901592C (en) 1941-02-23 1941-02-23 Process for the production of polyamides
DE281141X 1941-11-28
DEZ1393A DE918778C (en) 1941-02-23 1942-09-06 Process for the production of polycondensation products
DEZ1394A DE938396C (en) 1941-02-23 1942-10-15 Process for the continuous implementation of polycondensation

Publications (1)

Publication Number Publication Date
DE918778C true DE918778C (en) 1954-10-04

Family

ID=96702610

Family Applications (3)

Application Number Title Priority Date Filing Date
DEZ1386A Expired DE901592C (en) 1941-02-23 1941-02-23 Process for the production of polyamides
DEZ1393A Expired DE918778C (en) 1941-02-23 1942-09-06 Process for the production of polycondensation products
DEZ1394A Expired DE938396C (en) 1941-02-23 1942-10-15 Process for the continuous implementation of polycondensation

Family Applications Before (1)

Application Number Title Priority Date Filing Date
DEZ1386A Expired DE901592C (en) 1941-02-23 1941-02-23 Process for the production of polyamides

Family Applications After (1)

Application Number Title Priority Date Filing Date
DEZ1394A Expired DE938396C (en) 1941-02-23 1942-10-15 Process for the continuous implementation of polycondensation

Country Status (4)

Country Link
BE (3) BE444590A (en)
CH (1) CH237400A (en)
DE (3) DE901592C (en)
FR (4) FR879254A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE976174C (en) * 1953-08-04 1963-04-18 Glanzstoff Ag Process for the continuous polycondensation of diol esters of terephthalic acid in organic solvents
DE1213115B (en) * 1956-12-19 1966-03-24 Ici Ltd Device for the production of high molecular weight poly (ethylene glycol terephthalate)
DE1228417B (en) * 1963-09-19 1966-11-10 Bayer Ag Process for the production of high molecular weight thermoplastic polycondensates

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2735840A (en) * 1956-02-21 Vacuum pump
CH270844A (en) * 1948-10-01 1950-09-30 Parcofil Textil Maschinenbau A Process and device for the continuous polymerization of caprolactam.
DE1167482B (en) * 1950-05-31 1964-04-09 Toyo Rayon Co Ltd Melt spinning device for organic substances
US2735839A (en) * 1950-12-27 1956-02-21 schrenk
BE526488A (en) * 1953-02-25
US3057702A (en) * 1953-05-11 1962-10-09 Du Pont Apparatus for preparation of condensation polymers
BE531307A (en) * 1953-09-07
US2784225A (en) * 1954-06-09 1957-03-05 Eastman Kodak Co Condensing esters and amines to form amides
DE1157394B (en) * 1955-04-29 1963-11-14 Snia Viscosa Process and device for the production of polycondensates of 11-aminoundecanoic acid
NL102671C (en) * 1955-07-23
DE1222200B (en) * 1957-03-28 1966-08-04 British Nylon Spinners Ltd Device for melt-spinning polyamides
BE564576A (en) * 1957-04-06
US3130180A (en) * 1957-09-18 1964-04-21 Glanzstoff Ag Continuous method and apparatus for the production of polyhexamethylene adipamide
BE570443A (en) * 1957-09-28
DE1158419B (en) * 1958-08-28 1963-11-28 Basf Ag Process for the production of multi-layer moldings with an outer layer made of polyamides
NL266575A (en) * 1960-07-01
US5476919A (en) * 1995-02-21 1995-12-19 Minnesota Mining And Manufacturing Company Process for esterification

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE436979C (en) * 1925-03-24 1926-11-12 Joh Jacob Rieter & Cie Ag Impact machine

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE976174C (en) * 1953-08-04 1963-04-18 Glanzstoff Ag Process for the continuous polycondensation of diol esters of terephthalic acid in organic solvents
DE1213115B (en) * 1956-12-19 1966-03-24 Ici Ltd Device for the production of high molecular weight poly (ethylene glycol terephthalate)
DE1228417B (en) * 1963-09-19 1966-11-10 Bayer Ag Process for the production of high molecular weight thermoplastic polycondensates

Also Published As

Publication number Publication date
BE444590A (en) 1942-03-31
FR52927E (en) 1945-08-24
BE448769R (en) 1943-02-27
FR52774E (en) 1945-06-01
CH237400A (en) 1945-04-30
DE938396C (en) 1956-01-26
BE448767R (en) 1943-02-27
FR879254A (en) 1943-02-18
FR53128E (en) 1945-09-19
DE901592C (en) 1954-01-14

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