DE870002C - Effect paints - Google Patents
Effect paintsInfo
- Publication number
- DE870002C DE870002C DEB14636A DEB0014636A DE870002C DE 870002 C DE870002 C DE 870002C DE B14636 A DEB14636 A DE B14636A DE B0014636 A DEB0014636 A DE B0014636A DE 870002 C DE870002 C DE 870002C
- Authority
- DE
- Germany
- Prior art keywords
- oil
- parts
- drying
- effect
- mixed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 230000000694 effects Effects 0.000 title claims description 10
- 239000003973 paint Substances 0.000 title claims description 9
- 239000003921 oil Substances 0.000 claims description 15
- 238000001035 drying Methods 0.000 claims description 9
- 229920005989 resin Polymers 0.000 claims description 8
- 239000011347 resin Substances 0.000 claims description 7
- 239000002023 wood Substances 0.000 claims description 7
- 229920000642 polymer Polymers 0.000 claims description 6
- 239000002966 varnish Substances 0.000 claims description 6
- 239000004922 lacquer Substances 0.000 claims description 5
- 229920001577 copolymer Polymers 0.000 claims description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 15
- 239000000203 mixture Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 4
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 3
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 239000002274 desiccant Substances 0.000 description 2
- 239000011133 lead Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 230000037303 wrinkles Effects 0.000 description 2
- OZCMOJQQLBXBKI-UHFFFAOYSA-N 1-ethenoxy-2-methylpropane Chemical class CC(C)COC=C OZCMOJQQLBXBKI-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 235000004347 Perilla Nutrition 0.000 description 1
- 244000124853 Perilla frutescens Species 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- GIWKOZXJDKMGQC-UHFFFAOYSA-L lead(2+);naphthalene-2-carboxylate Chemical compound [Pb+2].C1=CC=CC2=CC(C(=O)[O-])=CC=C21.C1=CC=CC2=CC(C(=O)[O-])=CC=C21 GIWKOZXJDKMGQC-UHFFFAOYSA-L 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- SGGOJYZMTYGPCH-UHFFFAOYSA-L manganese(2+);naphthalene-2-carboxylate Chemical compound [Mn+2].C1=CC=CC2=CC(C(=O)[O-])=CC=C21.C1=CC=CC2=CC(C(=O)[O-])=CC=C21 SGGOJYZMTYGPCH-UHFFFAOYSA-L 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/04—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C09D127/06—Homopolymers or copolymers of vinyl chloride
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Description
Effektlacke Es ist bekannt, au,s trocl<neniden Ölen: und Polymeri,saten oder Mischpolymerisaten des Vinylch:lorids. Lacke herzustjellem Dabei werdeni nach den bekannten. Verfahren, die Polymerisate in der Regel im überschuß verwendiet; weil die ölreichen @Iischun:gen bei mehrmaligem Auftragendes Lackes t.eilw-eise gelöst werden, wodurch Inhomogernitäten in den Lackschichten entsteheni, die als sorg: Hochziehen bekannt sind.Effect lacquers It is known to use synthetic oils: and polymers or copolymers of vinyl chloride. Varnishes to be manufactured the known. Processes which use polymers as a rule in excess; because the oil-rich mixtures sometimes occur when the paint is applied several times be solved, whereby inhomogernities arise in the lacquer layers, which as Sorg: pulling up are known.
Es ist-,auch. bekannt, aus Mischungen von: rohem Holzöl und, öllöslichen; Harzen Effektlacke, d. h. Runzel- oder Eisblumenilaclse herzustellen. Um mit diesen Holzöl-Harz-Miechunigen den. Runzel- oder Eisbdcu.meneffekt zu erzielen;, müssen die au:tge;triagenen i Lacke bei, höherer Temperatur ini besonders konstruierten Öfen, den sog. Gasöfen,, entwickelt werden.It is also. known from mixtures of: crude wood oil and, oil-soluble; Resins effect paints, d. H. To make wrinkled or ice flower silaclse. To deal with this Wood oil resin Miechunigen. To achieve a wrinkle or Eisbdcu.menffekt ;, must The applied varnishes contribute to higher temperature in specially designed Ovens, the so-called gas ovens, are developed.
Es wurde nun überraschend. gefunden., diaß Lacke aus Holzöl oder ähnlichen trocknenden Ölen, z. B. Oiticicaöl, Perillaöl, und ölverträglichen Mischpolymerisaten des Vinylchlorids, die auf t Teil Polymerisat mindestens 2 Teile, vorzugsweise aber 3 bis 4. Teile Öl enthalten, bereits bei gewöhnlicher Temperatur unter Ausbildung von sehr gleichmäßigen Runzel- oder Eisblumeneffekten trocknen.It was now surprising. found., lacquers made from wood oil or the like drying oils, e.g. B. Oiticica oil, perilla oil, and oil-compatible copolymers of vinyl chloride, which is at least 2 parts per part of polymer, but preferably Contains 3 to 4 parts of oil, even at normal temperature with formation dry from very even wrinkle or ice flower effects.
Ale ölverträgliche Mischpolyrnerisate- des Vi.nylch:lori.ds können beispielsweise Mischpolymerisate aus Vin:ylchJ.ori,d undl Vinyllisobutyläthe"r und bzw. oder Acrylsäurebutyles:ter ve -xvendet werden. Man kann diesen Lackmnischungen auch öllösl.ich,e Harze, beispielsweise Harze. aus Cycloh"-:xanon, oder- aus Kolophonium, Maleinsäure und Glycerin oder P"nit@aerytriti, zusetzen.Ale oil-compatible mixed polymers- des Vi.nylch: lori.ds can for example copolymers from Vin: ylchJ.ori, d andl vinyl isobutyl ethers and respectively. or acrylic acid butyls: can be used. You can do this Paint mixtures also oil-soluble resins, for example resins. from Cycloh "-: xanone, or from rosin, maleic acid and glycerine or P "nit @ aerytriti, add.
Dite aus ,diesen Mischunigen, hergestellten Effektlacke z@eichrien; sich durch einfache Verarbeibbarkeit, schnelle Antrocknung und hohe Härte aufs. Hinzu kommrt noch eine gleichmäßige Ausbildung der Runzel- oder Eisb lumene ffektei, besonders. an, unr ebenen Flächenr, wie sie mit dien, bisher bekannten, Effektlacken. nicht zu erzielen ihst.Dite from, these mixed, produced effect lacquers z @ eichrien; easy processing, quick drying and high hardness. In addition, there is a uniform formation of the wrinkled or ice-flowered ffektei, particularly. on, uneven surfaces, as with the previously known effect paints. cannot be achieved.
Die, durch Mischung von Vinylch,lori-dmischpolymerisaten, Holzöl, und öllöslichen Harzen hergestel.ltien; Lacke Ussenh sich wie üblich pigmenti@eren, z. B. mit Ruß. je nach dem Mischungsverhältnis, .der Komponenten, der Schichtdicke d!er aufgetragenen Lacke, dien Art unid Menge an, gegebeniendalls zugesetzten Trockenstoffen, dem Pi:gm-enitgehalt und dein anigewanidten Lösungsmitteln, erhält man tiefschwar ze; matte Überzüge, die einen Sammet-, Kränsel- bis Eisblumeneffekt zeigen. Derartige Überzüge sind für die optische Indusitrie, für die Photoindustrie, ausgezeichnet geeignet; auch als Dekorationslacke können, sie. Verwendung finden. Beispiel i 2o T"-;il,--- einer 2oo/oigen. Lösung eines Mischpolyrüerisatras aus -7(5! Teilen, Vinylch@lho,riid und 2r5 Teilen Vin:ylisobutyläthe@r in Toluol werdfen: mit 24 Teilen einer 5:ao/oiigen: Lösung von rohem Holzöl in, Toiluol versetzt und mit 6- Teilen Toluol: verdünnit. Hierzu werden 2.o, Teile einer 5%igen@ Lösung eines Cyclohexanonharzes in Toluol gegeb@en. Nachdem- Auftragen auf Glas, Metall aderandere Träger bildet sich bei Lufttrockniung schone nach wenigen Stunden eine eisblu,meniartige Struktur aus.The, by mixing vinylch, lori-dmischpolymerisaten, wood oil, and oil-soluble resins manufactured; Ussenh varnishes are pigmented as usual, z. B. with soot. depending on the mixing ratio, the components, the layer thickness the varnishes applied, the type and amount of any drying agents added, the Pi: gm-enite content and your used solvents, you get deep black ze; matt coatings that show a velvet, pebble to ice flower effect. Such Coatings are excellent for the optical industry, for the photo industry suitable; They can also be used as decorative varnishes. Find use. Example i 2o T "-; il, --- a 2oo per cent. Solution of a mixed polymer of -7 (5! Parts, Vinylch @ lho, riid and 2r5 parts of Vin: ylisobutyläthe @ r in toluene: with 24 parts a 5: ao / oigen: solution of crude wood oil in, toiluene added and with 6 parts Toluene: dilute. For this purpose, 2.o, parts of a 5% solution of a cyclohexanone resin given in toluene. After application on glass, metal forms other supports When air-dried, an ice-blooming, menial structure is preserved after a few hours the end.
Zur Erzielung schnellerer Durchtrocknung könrnen Trockenstoffe, z. B. Blei-, Kobalt- oder Manganiniaphth"eniaree; b:zw. ihre--Mischungen zuggesetzt werden. Hierdurch wird außerdem ein; Eisblum@enr bl,d mit stärkerem Glanz, erzielt.To achieve faster through-drying, drying agents, e.g. B. lead, cobalt or manganese naphtha "eniaree; b: between their - mixtures added will. This is also a; Eisblum @ enr bl, d with a stronger shine.
Beispiele i2,5 Teile ein°r 4Po/ogen Lösung eines. Mischpolym:erisates aus -goi Teilen Vinylcblarid und io Teilen Acrylsäurebutyl,ester in, einer Lösung aus i Teil Äthylglykol.acetat und 2 Teilen Xylo:l: werden mit 3,o Teilen einer 5p°/oige:n, Lösung von rohem Holzöl in Toluol gemischt und, mit. 7,.5 Teilen Toluol verdünnet. Hierzu werden 2,oi Tei:l@e einer 51oP/aigen Xyloldösung eines Cy clohex:anonharzes@ gegeben.Examples 2.5 parts of a 4% solution of a. Mixed polymer: erisates from -goi parts of vinyl chloride and 10 parts of butyl acrylate in a solution from i part of ethylglycol acetate and 2 parts of xylo: l: are mixed with 3, o parts of a 5p%: n, Solution of crude wood oil mixed in toluene and, with. 7.5 parts of toluene diluted. For this purpose, 2, oi parts: l @ e of a 51oP / aigen xylene solution of a cyclohex: anon resin @ given.
Das Gemisch wird 24, Stunidien@ mit, ob75, Teilen Gasruß in der Kugeilmühle gemahlen unidi schließlich mit 0,3 Teilen eines Blei-, Kobalt- oder Manganniaphth!enates bzw. deren Mischjung versetzt. Man erhalt einen spritzbaren: Lack.The mixture is ground 24, Stunidien® with, ob75, parts of carbon black in a ball mill and finally mixed with 0.3 parts of a lead, cobalt or manganese naphthenate or a mixture of these. You get a sprayable: paint.
In dünnen Schichten aufgetragen; ergibt dieser Lack totmatte Überzüge, in dicker Schicht einen samm:etartig,-n Effekt. Die Trocknung erfolgt bei normaler Temperatur. Zur schne lzren Durcnrtrocknu,ng kann nach dem Wrdunsben der Lösungsmittel bei höheren Temperaturen (bis. etwa i5p°) niachrgetrrcckn°,t werden. Die bei höheren; Temperaturen nachg@etrockneten, Überzüge weisen, einen. erhöhten Glanz und höhere Härte auf.Applied in thin layers; this paint results in dead matt coatings, in a thick layer a collectively, -n effect. Drying takes place at normal Temperature. For quicker drying, the solvent can be used after drying At higher temperatures (up to approx. 15 p °) they will not be dried. Those at higher; Temperatures after drying, coatings show a. increased gloss and higher Hardness on.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEB14636A DE870002C (en) | 1951-04-20 | 1951-04-20 | Effect paints |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEB14636A DE870002C (en) | 1951-04-20 | 1951-04-20 | Effect paints |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE870002C true DE870002C (en) | 1953-03-09 |
Family
ID=6958072
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEB14636A Expired DE870002C (en) | 1951-04-20 | 1951-04-20 | Effect paints |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE870002C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1115868B (en) * | 1958-03-07 | 1961-10-26 | Vinyl Products Ltd | Coating agents with a content of copolymers of vinyl acetate and process for their preparation |
-
1951
- 1951-04-20 DE DEB14636A patent/DE870002C/en not_active Expired
Non-Patent Citations (1)
| Title |
|---|
| None * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1115868B (en) * | 1958-03-07 | 1961-10-26 | Vinyl Products Ltd | Coating agents with a content of copolymers of vinyl acetate and process for their preparation |
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