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DE69911765D1 - Verfahren zur herstellung von styrolen - Google Patents

Verfahren zur herstellung von styrolen

Info

Publication number
DE69911765D1
DE69911765D1 DE69911765T DE69911765T DE69911765D1 DE 69911765 D1 DE69911765 D1 DE 69911765D1 DE 69911765 T DE69911765 T DE 69911765T DE 69911765 T DE69911765 T DE 69911765T DE 69911765 D1 DE69911765 D1 DE 69911765D1
Authority
DE
Germany
Prior art keywords
producing styrene
styrene
producing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69911765T
Other languages
English (en)
Other versions
DE69911765T2 (de
Inventor
Hendrik Dirkzwager
Zwienen Marinus Van
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHELL INT RESEARCH
Shell Internationale Research Maatschappij BV
Original Assignee
SHELL INT RESEARCH
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHELL INT RESEARCH, Shell Internationale Research Maatschappij BV filed Critical SHELL INT RESEARCH
Application granted granted Critical
Publication of DE69911765D1 publication Critical patent/DE69911765D1/de
Publication of DE69911765T2 publication Critical patent/DE69911765T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/40—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals
    • C07C15/42—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic
    • C07C15/44—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic the hydrocarbon substituent containing a carbon-to-carbon double bond
    • C07C15/46—Styrene; Ring-alkylated styrenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/31—Density
    • B01J35/32—Bulk density
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE69911765T 1998-05-11 1999-04-27 Verfahren zur herstellung von styrolen Expired - Lifetime DE69911765T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP98201527 1998-05-11
EP98201527 1998-05-11
PCT/EP1999/003018 WO1999058480A1 (en) 1998-05-11 1999-04-27 Process for the preparation of styrenes

Publications (2)

Publication Number Publication Date
DE69911765D1 true DE69911765D1 (de) 2003-11-06
DE69911765T2 DE69911765T2 (de) 2004-08-05

Family

ID=8233704

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69911765T Expired - Lifetime DE69911765T2 (de) 1998-05-11 1999-04-27 Verfahren zur herstellung von styrolen

Country Status (11)

Country Link
US (1) US6437207B1 (de)
EP (1) EP1077916B1 (de)
JP (1) JP2002514613A (de)
KR (1) KR100598728B1 (de)
CN (1) CN1160286C (de)
AU (1) AU3826799A (de)
BR (1) BR9910328B1 (de)
CA (1) CA2331580C (de)
DE (1) DE69911765T2 (de)
ES (1) ES2207212T3 (de)
WO (1) WO1999058480A1 (de)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0998976A1 (de) * 1998-11-04 2000-05-10 Engelhard Corporation Sternförmige Aluminiumoxid Extrudaten und darauf basierender Katalysator
US6844454B2 (en) * 2002-04-12 2005-01-18 Shell Oil Company Process
JP4400120B2 (ja) * 2002-12-24 2010-01-20 住友化学株式会社 クメンの製造方法
JP2006518723A (ja) * 2003-02-25 2006-08-17 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー スチレンの調製方法
WO2005028405A1 (ja) 2003-09-18 2005-03-31 Sumitomo Chemical Company, Limited クメンの製造方法
KR100572473B1 (ko) 2003-10-13 2006-04-18 주식회사 엘지화학 스티렌계 올레핀의 새로운 제조 방법
US20050085677A1 (en) * 2003-10-15 2005-04-21 Fina Technology, Inc. Method for improved production of cyclohexenyl and alkenyl aromatic compounds
US7288688B2 (en) 2003-12-02 2007-10-30 Shell Oil Company Process for preparing styrene
JP4885469B2 (ja) * 2005-03-31 2012-02-29 広栄化学工業株式会社 キヌクリジン類の製造方法
CN100348558C (zh) * 2005-04-29 2007-11-14 北京金源化学集团有限公司 生产苯乙烯类化合物的新工艺
WO2009074461A1 (en) * 2007-12-10 2009-06-18 Shell Internationale Research Maatschappij B.V. Process for the preparation of styrene and/or a substituted styrene
CN103922902B (zh) * 2013-01-11 2016-12-28 南京科技职业学院 对甲氧基苯乙醇合成对甲氧基苯乙烯的工艺
US20160046554A1 (en) * 2013-04-12 2016-02-18 Shell Oil Company Process for producing styrene
CN108057432A (zh) * 2017-12-15 2018-05-22 常州瑞华化工工程技术股份有限公司 一种适合α-苯乙醇脱水催化剂的制备方法
CN111689827B (zh) * 2019-03-14 2023-01-03 中国石化工程建设有限公司 一种制备苯乙烯的装置及方法
US12371382B2 (en) 2020-02-07 2025-07-29 Basf Se Star-shaped ceramic body for use as catalyst
CN112452319A (zh) * 2020-12-11 2021-03-09 山东齐鲁华信高科有限公司 一种α-苯乙醇脱水催化剂及其制备方法
CN113336612A (zh) * 2021-06-18 2021-09-03 山东齐鲁华信高科有限公司 一种α-苯乙醇气相脱水制苯乙烯的方法

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3526674A (en) * 1968-08-05 1970-09-01 Halcon International Inc Process for the dehydration of aralkanols
US3658928A (en) * 1970-09-21 1972-04-25 Shell Oil Co Dehydration of alpha-methylbenzyl alcohol

Also Published As

Publication number Publication date
EP1077916A1 (de) 2001-02-28
CA2331580A1 (en) 1999-11-18
KR20010043450A (ko) 2001-05-25
BR9910328A (pt) 2001-01-30
JP2002514613A (ja) 2002-05-21
BR9910328B1 (pt) 2012-02-22
CN1160286C (zh) 2004-08-04
CA2331580C (en) 2007-11-13
AU3826799A (en) 1999-11-29
ES2207212T3 (es) 2004-05-16
WO1999058480A1 (en) 1999-11-18
KR100598728B1 (ko) 2006-07-13
US6437207B1 (en) 2002-08-20
CN1300272A (zh) 2001-06-20
EP1077916B1 (de) 2003-10-01
DE69911765T2 (de) 2004-08-05

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Legal Events

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