DE670813C - Aids for mercerising liquor - Google Patents
Aids for mercerising liquorInfo
- Publication number
- DE670813C DE670813C DEG89001D DEG0089001D DE670813C DE 670813 C DE670813 C DE 670813C DE G89001 D DEG89001 D DE G89001D DE G0089001 D DEG0089001 D DE G0089001D DE 670813 C DE670813 C DE 670813C
- Authority
- DE
- Germany
- Prior art keywords
- liquor
- aids
- mercerizing
- mercerising
- lye
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000009992 mercerising Methods 0.000 title description 2
- 239000000654 additive Substances 0.000 claims description 6
- 150000003512 tertiary amines Chemical class 0.000 claims description 3
- -1 hydrogen peroxide tertiary amine Chemical class 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 4
- 229930003836 cresol Natural products 0.000 description 4
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- AEFTZVMBNWKTMT-UHFFFAOYSA-N 1-benzyl-1-oxidopiperidin-1-ium Chemical compound C=1C=CC=CC=1C[N+]1([O-])CCCCC1 AEFTZVMBNWKTMT-UHFFFAOYSA-N 0.000 description 1
- AXWLKJWVMMAXBD-UHFFFAOYSA-N 1-butylpiperidine Chemical compound CCCCN1CCCCC1 AXWLKJWVMMAXBD-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- MQWCXKGKQLNYQG-UHFFFAOYSA-N 4-methylcyclohexan-1-ol Chemical compound CC1CCC(O)CC1 MQWCXKGKQLNYQG-UHFFFAOYSA-N 0.000 description 1
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 description 1
- LKQUDAOAMBKKQW-UHFFFAOYSA-N N,N-dimethylaniline N-oxide Chemical compound CN(C)(=O)C1=CC=CC=C1 LKQUDAOAMBKKQW-UHFFFAOYSA-N 0.000 description 1
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 229960000583 acetic acid Drugs 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 150000001983 dialkylethers Chemical class 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 239000010685 fatty oil Substances 0.000 description 1
- 239000012362 glacial acetic acid Substances 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N hydrogen peroxide Substances OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- 238000005517 mercerization Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/152—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen having a hydroxy group bound to a carbon atom of a six-membered aromatic ring
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/388—Amine oxides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
- Y10S516/01—Wetting, emulsifying, dispersing, or stabilizing agents
- Y10S516/07—Organic amine, amide, or n-base containing
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Fats And Perfumes (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Paper (AREA)
- Detergent Compositions (AREA)
Description
Es wurde gefunden, daß Gemische von einem oder mehreren aus tertiären Aminen durch Behandeln mit Oxydationsmitteln, wie Wasserstoffsuperoxyd, gewonnenen sogenannten tertiären Aminoxyden und üblichen Mercerisierlaugenzusatzmitteln, wie Phenolen oder Phenolgemischen, z. B. Rohkresol oder sulfonierten fetten Ölen, z. B. hochsulfonierten Rizinusölen, gegebenenfalls unter Zusatz von Ätheralkoholen, z. B. von Glykolmonobutyläther, oder von Glycerinmono- oder -dialkyläthern, Mercerisierlaugen ein hervorragendes Netzvermögen verleihen.It has been found that mixtures of one or more of tertiary amines so-called obtained by treatment with oxidizing agents such as hydrogen peroxide tertiary amine oxides and customary mercerizing liquor additives, such as phenols or phenol mixtures, e.g. B. raw cresol or sulfonated fatty oils, e.g. B. highly sulfonated castor oils, optionally with addition of ether alcohols, e.g. B. of glycol monobutyl ether, or of glycerol mono- or dialkyl ethers, mercerizing liquors an excellent one Lend network power.
Alkohole, wie Butyl- oder Amylalkohol, carbocyclische Alkohole, wie Terpenalkohol, hydrierte Phenole, wie Cyclohexanol oder Methylcyclohexanol oder Amine, wie Anilin oder Pyridin, sind bereits als Mercerisierzusätze empfohlen worden. Gegenüber diesen Verbindungen besitzen die tertiären Aminoxyde den wesentlichen Vorteil der Geruchlosigkeit und der NichtfLüchtigkeit, so daß die Mercerisierlaugen nach ' Zusatz des Netzmittels längere Zeit beständig sind.Alcohols such as butyl or amyl alcohol, carbocyclic alcohols such as terpene alcohol, hydrogenated phenols such as cyclohexanol or methylcyclohexanol or amines such as aniline or pyridine, have already been recommended as mercerizing additives. Compared to these Compounds, the tertiary amine oxides have the essential advantage of being odorless and the non-volatility, so that the mercerising liquors after 'addition of the Wetting agents are stable for a long time.
Gegenüber bekannten schwerfiüchtigen Zusätzen, wie Benzylalkohol oder Triäthanolamin, sind die Aminoxyde wesentlich wirksamer. Compared to known volatile additives such as benzyl alcohol or triethanolamine, the amine oxides are much more effective.
Einer Mercerisierlauge von 300 Be werden 5 g je Liter eines Gemisches aus 25 °/o Butyldimethylaminoxyd und 75 °/0 Rohkresol- zugesetzt. Es entsteht eine wasserklare Lösung. Die Prüfung der Schrumpffähigkeit der Lauge nach dem in »Melliands Textilberichte«, 1928, Seite 763, angegebenen Verfahren ergibt folgende Schrumpf werte:A mercerization of 30 Be 0 to 5 g per liter of a mixture of 25 ° / o Butyldimethylaminoxyd and 75 ° / 0 Rohkresol- added. A clear solution is created. The test of the shrinkability of the lye according to the method given in "Melliand's Textile Reports," 1928, page 763, gives the following shrinkage values:
Die mit dem Zusatz versetzte Lauge bleibt auch bei längerem Stehen völlig klar; sie ergibt z. B. nach 72stündigem Stehen dieselben Schrumpfwerte wie die frische Lauge. Eine stabile, klare Lauge erhält man auch, wenn man das Rohkresol durch 65 % Rohkresol und 10 °/0 Eisessig ersetzt.The lye to which the additive has been added remains completely clear even when standing for a long time; it gives z. B. the same shrinkage values as the fresh liquor after standing for 72 hours. A stable, clear liquor is also obtained by replacing the crude cresol by 65% crude cresol and 10 ° / 0 of glacial acetic acid.
Als Zusatz zur Mercerisierflotte werden 5 g je Liter eines Gemisches aus 38,5 °/0 As an additive to be mercerizing liquor 5 g per liter of a mixture of 38.5 ° / 0
Dimethylanilinoxyd und 61,5 °/0 Rohkresol verwendet. Es bildet sich ebenfalls eine völlig klare Lösung. Die Bestimmung der Schrumpfung ergibt folgende Werte:Dimethylanilinoxyd and 61.5 ° / 0 crude cresol used. A completely clear solution also forms. The determination of the shrinkage gives the following values:
ohne ZusatzLye
without addition
mit ZusatzLye
with addition
Die gleiche Mischung, die statt des Dimethylanilinoxydes Dimethylanilin enthält, ist infolge sofortiger Abscheidung der Base ,völlig unbrauchbar.The same mixture that was used instead of the dimethylaniline oxide Contains dimethylaniline is due to immediate deposition of the base , completely useless.
«i Ähnlich verhalten sich Dimethylaminocyclohexanoxyd, N-Butylpiperidin- oder Benzylpiperidinoxyd. «I Dimethylaminocyclohexanoxide behave similarly, N-butylpiperidine or benzylpiperidine oxide.
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH449209X | 1934-06-23 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE670813C true DE670813C (en) | 1939-01-25 |
Family
ID=4515425
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEG89001D Expired DE670813C (en) | 1934-06-23 | 1934-10-19 | Aids for mercerising liquor |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US2060568A (en) |
| CH (1) | CH177545A (en) |
| DE (1) | DE670813C (en) |
| FR (1) | FR792239A (en) |
| GB (1) | GB449209A (en) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE622461A (en) * | 1959-04-20 | |||
| DE1185756B (en) * | 1959-04-22 | |||
| US2999068A (en) * | 1959-04-27 | 1961-09-05 | Procter & Gamble | Personal use detergent lotion |
| US3001945A (en) * | 1959-04-29 | 1961-09-26 | Procter & Gamble | Liquid detergent composition |
| BE622463A (en) * | 1959-06-10 | |||
| NL264464A (en) * | 1960-05-05 | |||
| DE1163850B (en) * | 1960-07-14 | 1964-02-27 | Henkel & Cie Gmbh | Process for the production of new, non-ionic, skin-friendly derivatives of capillary-active tertiary amines |
| NL280455A (en) * | 1961-07-03 | |||
| NL280446A (en) * | 1961-07-03 | |||
| BE623038A (en) * | 1961-09-29 | |||
| NL286242A (en) * | 1961-12-04 | |||
| US3441611A (en) * | 1961-12-04 | 1969-04-29 | Procter & Gamble | Hydroxyalkylamine oxide detergent compounds |
| US3194840A (en) * | 1961-12-18 | 1965-07-13 | Procter & Gamble | N, n-diloweralkyl, 1, 1-dihydrogen perfluoroalkyl amine oxides |
| US3197509A (en) * | 1961-12-21 | 1965-07-27 | Procter & Gamble | Diamine dioxide compounds |
| US3447939A (en) * | 1966-09-02 | 1969-06-03 | Eastman Kodak Co | Compounds dissolved in cyclic amine oxides |
| US3447956A (en) * | 1966-09-02 | 1969-06-03 | Eastman Kodak Co | Process for strengthening swellable fibrous material with an amine oxide and the resulting material |
| BR8008793A (en) * | 1979-08-15 | 1981-06-23 | Sherex Chem | PROCESS OF FLOTATION AND PERFECTED WATER AMINIC MIXTURE |
| JP3445865B2 (en) * | 1995-04-06 | 2003-09-08 | 花王株式会社 | Cellulosic fiber modification method |
| US6500215B1 (en) | 2000-07-11 | 2002-12-31 | Sybron Chemicals, Inc. | Utility of selected amine oxides in textile technology |
-
1934
- 1934-06-23 CH CH177545D patent/CH177545A/en unknown
- 1934-10-19 DE DEG89001D patent/DE670813C/en not_active Expired
-
1935
- 1935-06-20 FR FR792239D patent/FR792239A/en not_active Expired
- 1935-06-20 US US27609A patent/US2060568A/en not_active Expired - Lifetime
- 1935-06-24 GB GB18070/35A patent/GB449209A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| CH177545A (en) | 1935-06-15 |
| US2060568A (en) | 1936-11-10 |
| GB449209A (en) | 1936-06-23 |
| FR792239A (en) | 1935-12-26 |
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