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DE60311399D1 - Feuerfestes System für Glassschmelzöfen - Google Patents

Feuerfestes System für Glassschmelzöfen

Info

Publication number
DE60311399D1
DE60311399D1 DE60311399T DE60311399T DE60311399D1 DE 60311399 D1 DE60311399 D1 DE 60311399D1 DE 60311399 T DE60311399 T DE 60311399T DE 60311399 T DE60311399 T DE 60311399T DE 60311399 D1 DE60311399 D1 DE 60311399D1
Authority
DE
Germany
Prior art keywords
glass melting
refractory
melting furnaces
refractory system
silica
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE60311399T
Other languages
English (en)
Other versions
DE60311399T3 (de
DE60311399T2 (de
Inventor
Michael W Anderson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Magneco Metrel Inc
Original Assignee
Magneco Metrel Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=32326659&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=DE60311399(D1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Magneco Metrel Inc filed Critical Magneco Metrel Inc
Application granted granted Critical
Publication of DE60311399D1 publication Critical patent/DE60311399D1/de
Publication of DE60311399T2 publication Critical patent/DE60311399T2/de
Publication of DE60311399T3 publication Critical patent/DE60311399T3/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D1/00Casings; Linings; Walls; Roofs
    • F27D1/0003Linings or walls
    • F27D1/0006Linings or walls formed from bricks or layers with a particular composition or specific characteristics
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B5/00Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
    • C03B5/16Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
    • C03B5/42Details of construction of furnace walls, e.g. to prevent corrosion; Use of materials for furnace walls
    • C03B5/43Use of materials for furnace walls, e.g. fire-bricks
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/10Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on aluminium oxide
    • C04B35/111Fine ceramics
    • C04B35/117Composites
    • C04B35/119Composites with zirconium oxide
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/63Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
    • C04B35/6303Inorganic additives
    • C04B35/6316Binders based on silicon compounds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/66Monolithic refractories or refractory mortars, including those whether or not containing clay
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B17/00Furnaces of a kind not covered by any of groups F27B1/00 - F27B15/00
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3206Magnesium oxides or oxide-forming salts thereof
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3217Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3244Zirconium oxides, zirconates, hafnium oxides, hafnates, or oxide-forming salts thereof
    • C04B2235/3248Zirconates or hafnates, e.g. zircon
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3418Silicon oxide, silicic acids or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427Silicates other than clay, e.g. water glass
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427Silicates other than clay, e.g. water glass
    • C04B2235/3463Alumino-silicates other than clay, e.g. mullite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/40Metallic constituents or additives not added as binding phase
    • C04B2235/402Aluminium
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/50Glass production, e.g. reusing waste heat during processing or shaping

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Structural Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Composite Materials (AREA)
  • Furnace Housings, Linings, Walls, And Ceilings (AREA)
  • Ceramic Products (AREA)
  • Glass Melting And Manufacturing (AREA)
  • Vertical, Hearth, Or Arc Furnaces (AREA)
  • Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
  • Glass Compositions (AREA)
DE60311399T 2002-12-10 2003-12-10 Feuerfestes System für Glassschmelzöfen Expired - Lifetime DE60311399T3 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US43250302P 2002-12-10 2002-12-10
US432503P 2002-12-10

Publications (3)

Publication Number Publication Date
DE60311399D1 true DE60311399D1 (de) 2007-03-15
DE60311399T2 DE60311399T2 (de) 2007-10-31
DE60311399T3 DE60311399T3 (de) 2010-07-01

Family

ID=32326659

Family Applications (1)

Application Number Title Priority Date Filing Date
DE60311399T Expired - Lifetime DE60311399T3 (de) 2002-12-10 2003-12-10 Feuerfestes System für Glassschmelzöfen

Country Status (15)

Country Link
US (1) US7176153B2 (de)
EP (1) EP1428807B2 (de)
KR (1) KR101146003B1 (de)
CN (1) CN100408495C (de)
AT (1) ATE352529T1 (de)
AU (1) AU2003268817B2 (de)
BR (1) BR0305414B1 (de)
CA (1) CA2452886C (de)
DE (1) DE60311399T3 (de)
DK (1) DK1428807T4 (de)
ES (1) ES2279072T5 (de)
MX (1) MXPA03011323A (de)
PT (1) PT1428807E (de)
SI (1) SI1428807T1 (de)
ZA (1) ZA200309168B (de)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1810956A4 (de) * 2003-05-14 2007-11-28 Asahi Glass Ceramics Co Ltd Monolithischer feuerfester stoff auf zirconiumoxidbasis
ZA200507296B (en) * 2004-09-10 2006-09-27 Magneco Metrel Inc Converter repair method
EP1739356A1 (de) * 2005-07-01 2007-01-03 Siemens Aktiengesellschaft Formmasse zum Herstellen einer feuerfesten Auskleidung
US20060236722A1 (en) * 2005-04-26 2006-10-26 Robert Delia Forming apparatus with extensions attached thereto used in a glass manufacturing system
RU2359942C2 (ru) * 2007-01-25 2009-06-27 Юлия Алексеевна Щепочкина Шихта для изготовления огнеупорных изделий
US8505335B2 (en) * 2007-06-19 2013-08-13 Magneco/Metrel, Inc. Refractoy composition for glass melting furnaces
US8505336B2 (en) * 2007-06-19 2013-08-13 Magneco/Metrel, Inc. AZS refractory composition
BRPI0722149A2 (pt) * 2007-10-17 2014-04-15 Compania Vidreira S A De C V Forno para fundição de vidro construído inteiramente com concreto refratário
FR2937636B1 (fr) * 2008-10-29 2010-11-12 Saint Gobain Ct Recherches Beton frais auto-nivelant
US8464555B2 (en) 2009-07-27 2013-06-18 Vidrio Plano De Mexico, S.A. De C.V. Monolithic float glass forming chamber and method of construction
US8408029B2 (en) * 2009-11-17 2013-04-02 Corning Incorporated Method for thermally conditioning molten glass
CA2880812C (en) 2012-08-01 2020-10-27 Allied Mineral Products, Inc. Reinforced refractory containers
DE102013204276A1 (de) * 2013-03-12 2014-09-18 Hug Engineering Ag Verfahren zur Herstellung eines Formkörpers und Formkörper
FR3008967B1 (fr) * 2013-07-26 2016-12-30 Saint-Gobain Centre De Rech Et D'Etudes Europeen Produit a haute teneur en alumine
KR102053603B1 (ko) 2015-06-01 2019-12-09 생-고뱅 세라믹스 앤드 플라스틱스, 인코포레이티드 내화성 물품 및 이의 형성 방법
JP6498546B2 (ja) * 2015-06-30 2019-04-10 AvanStrate株式会社 ガラス板の製造方法、および、熔解槽
US10590283B2 (en) 2016-08-12 2020-03-17 Magneco/Metrel, Inc. Method of providing a protective coating composition for molten aluminum and alkali metal environments
US10233335B2 (en) 2016-08-12 2019-03-19 Magneco/Metrel, Inc. Protective coating composition for molten aluminum and alkali metal environments
US9994486B1 (en) 2017-03-16 2018-06-12 Magneco/Metrel, Inc. Refractory composition resistant to high temperature shock and creep
US10494305B2 (en) 2017-03-16 2019-12-03 Magneco/Metrel, Inc. Method of making refractory article resistant to high temperature shock and creep
US10429130B2 (en) 2017-03-16 2019-10-01 Magneco/Metrel, Inc. Refractory kiln car resistant to high temperature shock and creep
IT201800010817A1 (it) * 2018-12-05 2020-06-05 Danieli Off Mecc Recipiente per contenere ferro di riduzione diretta (dri)
EP3815767B1 (de) 2019-10-31 2023-07-19 Foseco International Limited Feuerfester filter
US20250346518A1 (en) * 2024-05-09 2025-11-13 Owens-Brockway Glass Container Inc. Composite material for a glass melting apparatus

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FR1288045A (fr) 1960-10-20 1962-03-24 Agglomérant pour matières réfractaires
FR1307299A (fr) 1961-09-11 1962-10-26 Creusot Forges Ateliers Procédé de fabrication de moules réfractaires pour fonderie de précision
SE317026B (de) * 1966-10-05 1969-11-03 Amsted Ind Inc
GB1194158A (en) 1967-06-20 1970-06-10 Nalco Chemical Co Refractory Coating Compositions.
GB1283692A (en) 1968-09-25 1972-08-02 Foseco Int Refractory heat insulating materials
US3885005A (en) 1973-08-20 1975-05-20 Taylors Sons Co Chas Production of refractory articles by a freezecast process
US4119472A (en) 1976-09-01 1978-10-10 Corning Glass Works Rebonded fusion-cast AZS refractory grain
US4212680A (en) * 1979-04-30 1980-07-15 Nalco Chemical Co. Thixotropic refractory binder based upon aluminum phosphate gelled silica sols
DE3507876A1 (de) 1985-03-06 1986-09-11 Didier-Werke Ag, 6200 Wiesbaden Verwendung von zementfreien vibriermassen auf basis von aluminiumoxid und/oder zirkoniumdioxid zur herstellung von verschleissteilen
FR2617835B1 (fr) 1987-07-07 1989-11-10 Vesuvius Sa Composition refractaire pour plaques-tiroirs et son procede de fabrication
US5657607A (en) * 1989-08-23 1997-08-19 University Of Sydney Thermally insulating glass panel and method of construction
DD294702A5 (de) 1990-05-31 1991-10-10 Feuerfestwerke Wetro,De Hoeherwertiger moertel mit kieselsol- bindung
US5403794A (en) * 1994-04-14 1995-04-04 Vesuvius Crucible Company Alumina-zirconia refractory material and articles made therefrom
JPH0952769A (ja) * 1995-08-11 1997-02-25 Toshiba Ceramics Co Ltd 窒化アルミニウム質固形体の製造方法
GB9617010D0 (en) * 1996-08-13 1996-09-25 Shaw Richard D Improved refractory binder
JPH10212158A (ja) * 1997-01-30 1998-08-11 Toshiba Ceramics Co Ltd ガラス溶解窯用耐火物
EP0939065B1 (de) * 1998-02-26 2002-05-15 Asahi Glass Company Ltd. Schmelzgegossenes Aluminiumoxid-Zirkonoxid-Siliziumoxid-Feuerfestmaterial und Glasschmelzofen, in den dieses eingesetzt wird
DE19845761A1 (de) 1998-10-05 2000-04-20 Morgan Crucible Company Plc Wi Hochtemperaturfester, hochbelastbarer, feinkeramischer, gesinterter Konstruktionswerkstoff, Verfahren zu seiner Herstellung und ein Bauteil aus einem Keramikwerkstoff
FR2810315B1 (fr) * 2000-06-20 2002-08-16 Produits Refractaires Produits azs fondus et coules de cout reduit et leurs utilisations
FR2832403B1 (fr) * 2001-11-20 2004-07-23 Saint Gobain Ct Recherches Composition refractaire non faconnee, destinee notamment a la realisation de soles d'un four de verrerie

Also Published As

Publication number Publication date
DK1428807T4 (da) 2010-04-19
CA2452886A1 (en) 2004-06-10
CN100408495C (zh) 2008-08-06
CA2452886C (en) 2008-05-06
EP1428807A3 (de) 2004-12-15
ES2279072T3 (es) 2007-08-16
DK1428807T3 (da) 2007-05-29
DE60311399T3 (de) 2010-07-01
KR20040050844A (ko) 2004-06-17
EP1428807A2 (de) 2004-06-16
DE60311399T2 (de) 2007-10-31
PT1428807E (pt) 2007-02-28
AU2003268817A1 (en) 2004-06-24
EP1428807B1 (de) 2007-01-24
US20040138048A1 (en) 2004-07-15
BR0305414A (pt) 2004-08-31
ZA200309168B (en) 2004-07-22
CN1532155A (zh) 2004-09-29
US7176153B2 (en) 2007-02-13
ATE352529T1 (de) 2007-02-15
MXPA03011323A (es) 2004-10-15
KR101146003B1 (ko) 2012-05-15
BR0305414B1 (pt) 2012-10-02
AU2003268817B2 (en) 2010-05-20
ES2279072T5 (es) 2010-04-23
SI1428807T1 (sl) 2007-06-30
EP1428807B2 (de) 2009-12-02

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Legal Events

Date Code Title Description
8363 Opposition against the patent
8366 Restricted maintained after opposition proceedings