DE560916C - Soap-like products - Google Patents
Soap-like productsInfo
- Publication number
- DE560916C DE560916C DEST45142D DEST045142D DE560916C DE 560916 C DE560916 C DE 560916C DE ST45142 D DEST45142 D DE ST45142D DE ST045142 D DEST045142 D DE ST045142D DE 560916 C DE560916 C DE 560916C
- Authority
- DE
- Germany
- Prior art keywords
- soap
- water
- products
- acidic
- fatty alcohols
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 230000002378 acidificating effect Effects 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 4
- 239000007795 chemical reaction product Substances 0.000 claims description 3
- 150000007513 acids Chemical class 0.000 claims description 2
- -1 aliphatic fatty alcohols Chemical class 0.000 claims description 2
- 230000007935 neutral effect Effects 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 238000000926 separation method Methods 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 235000002639 sodium chloride Nutrition 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 230000008961 swelling Effects 0.000 description 2
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- ZUVCYFMOHFTGDM-UHFFFAOYSA-N hexadecyl dihydrogen phosphate Chemical compound CCCCCCCCCCCCCCCCOP(O)(O)=O ZUVCYFMOHFTGDM-UHFFFAOYSA-N 0.000 description 1
- 239000010446 mirabilite Substances 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- RSIJVJUOQBWMIM-UHFFFAOYSA-L sodium sulfate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]S([O-])(=O)=O RSIJVJUOQBWMIM-UHFFFAOYSA-L 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 239000010698 whale oil Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/34—Derivatives of acids of phosphorus
- C11D1/345—Phosphates or phosphites
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Description
Seifenartig wirkende Produkte Die Fettsäuren der tierischen und pflanzlichen Fette sind bislang hauptsächlich die einzigen chemischen Körper, welche als Alkaliverbindungen den Begriff der Seifen ausmachen.Soap-like products The fatty acids of animal and vegetable So far, fats are mainly the only chemical bodies that act as alkali compounds make up the concept of soaps.
Die wesentlichen Eigenschaften dieser sind, mit- Wasser Quellkörper zu bilden, welche ein erhebliches Schaumvermögen der kolloidalen wässerigen Lösungen aufweisen und ein hohes Ernulsionsvermögen bzw. Lösungsvermögen für viele andere Substanzen besitzen.The main properties of these are, with- water swelling bodies to form, which has a considerable foaming power of the colloidal aqueous solutions have and a high emulsifying power or dissolving power for many others Own substances.
Es wurde nun gefunden, daß die gleichen seifenartigen Eigenschaften auch den Produkten zukommen, welche durch Einwirkung von wasserentziehenden, nicht sulfonierenden Säuren auf einwertige aliphatische Fettalkohole entstehen und sauren oder neutralen Charakter haben können, indem erstere mit basischen Substanzen neutralisiert werden, wodurch der seifenartige Charakter noch erhöht wird.It has now been found that the same soap-like properties also come to the products, which by the action of dehydrating, not Sulphonating acids on monohydric aliphatic fatty alcohols are formed and acidic or can have a neutral character by neutralizing the former with basic substances which increases the soap-like character.
Die Herstellung der beanspruchten Verbindungen erfolgt nach allgemein bekannten Veresterungsmethoden. Beispiel i roo kg der aus Walratöl nach bekannten Verfahren gewonnenen einwertigen Fettalkohole werden bei Zimmertemperatur unter ständigem Rühren und langsamem Zulauf mit 25 °1o sirupöser Phosphorsäure versetzt. Darauf wird die Masse etwa 24 Stunden .der Ruhe überlassen und alsdann Wasser in Mengen von etwa 30 % des Öles zugegeben. Bei schwachem Erwärmen erfolgt bald eine Trennung des Säurewassers vom Reaktionsprodukt. Nach Abziehen des ersteren wird erneut Wasser zugegeben, gut durchgemischt und erwärmt.The compounds claimed are produced according to general known esterification methods. Example i roo kg of whale oil according to known Process obtained monohydric fatty alcohols are taken at room temperature constant stirring and slow inflow with 25 ° 1o syrupy phosphoric acid. The mass is then left to rest for about 24 hours and then water is poured in Amounts of about 30% of the oil are added. If the warming is weak, one will soon follow Separation of the acid water from the reaction product. After peeling off the former becomes again added water, mixed well and warmed up.
Erfolgt hierbei keine Trennung mehr, so gibt man zwecks Erhöhung des spezifischen Gewichts des Säurewassers Salz, Glaubersalz, Kochsalz o. dgl., zu, wodurch die Trennung der Schichten dann herbeigeführt wird. Es erfolgt ein erneutes Abziehen des Säurewassers und evtl. eine dritte Waschung, wie vor angegben.If there is no longer any separation, in order to increase the specific gravity of the acidic water salt, Glauber's salt, table salt or the like, to, whereby the separation of the layers is then brought about. There is another Remove the acidic water and possibly a third wash, as indicated above.
Das so' gewonnene Reaktionsprodukt ist eine fettähnliche Masse von salbenartiger Konsistenz, welche sowohl in saurem wie auch in alkalisch-neutralisiertem Zustand ein hohes Queliungsvermögen in Wasser sowie auch ausgesprochenen Seifencharakter in bezug auf Emulgierfähigkeit usw. zeigt, so daB es sich in der Lumpenreißerei mit Vorteil verwenden läBt. Beispiel e ioo kg Cetylalkohol, gelöst in einem indifferenten organischen Lösungsmittel, werden in der Kälte unter Rühren mit 50 °% pulverförmigem Phosphorsäureanhydrid versetzt, welches sich unter Erwärmen mit dem Alkohol zu einer homogenen Masse verbindet. Nach 24stündigem Stehen, gegebenenfalls unter Zufuhr von Wärme; wird mit Wasser gewaschen und der gebildete Phosphorsäurecetylester durch Abdestillieren des Lösungsmittels erhalten. Zur Verwendung als Seifenbad wird der _gebildete Ester mit Alkali oder einer organischen Base neutralisiert und in einer Menge von 5 bis io g pro Liter der Waschflotte zugefügt.The reaction product obtained in this way is a fat-like mass of ointment-like consistency, which is available in both acidic and alkaline-neutralized State a high swelling capacity in water as well as pronounced soap character with regard to emulsifiability etc. shows that it is in rags can be used with advantage. Example e 100 kg of cetyl alcohol dissolved in an inert organic solvents, are in the cold with stirring with 50 °% powdery Phosphoric anhydride added, which when heated with the alcohol to a homogeneous mass. After standing for 24 hours, if necessary with feeding of warmth; is washed with water and the phosphoric acid cetyl ester formed by Obtained distilling off the solvent. For use as a soap bath, the _ formed esters neutralized with alkali or an organic base and in a Amount of 5 to 10 g per liter of the wash liquor added.
Beispiel 3 Um Kunstseide, die nach dem Viscoseverfahren gewonnen ist, einen weichen und angenehmen Griff zu verleihen, wird die Ware mit einem Bade, das etwa 4 bis 5 g des Natriumsalzes des sauren Oleylmetaborsäureesters pro Liter Waschflotte enthält, während 2o bis 30 Minuten behandelt.EXAMPLE 3 In order to give rayon obtained by the viscose process a soft and pleasant feel, the goods are treated for 20 to 30 minutes with a bath containing about 4 to 5 g of the sodium salt of the acidic oleylmetaboric acid ester per liter of wash liquor.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEST45142D DE560916C (en) | 1928-12-06 | 1928-12-06 | Soap-like products |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEST45142D DE560916C (en) | 1928-12-06 | 1928-12-06 | Soap-like products |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE560916C true DE560916C (en) | 1932-10-08 |
Family
ID=7464820
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEST45142D Expired DE560916C (en) | 1928-12-06 | 1928-12-06 | Soap-like products |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE560916C (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE954009C (en) * | 1953-12-30 | 1956-12-13 | Huels Chemische Werke Ag | Use of phosphoric acid esters as emulsifiers for the emulsion polymerization of polymerizable chlorine-containing organic compounds |
| US3000750A (en) * | 1953-03-06 | 1961-09-19 | Dehydag Dentsche Hydrierwerke | Process of preparing dispersions of pulverulent material and preparations obtained thereby |
| DE1230956B (en) * | 1955-12-01 | 1966-12-22 | J G Mouson & Co | Perfuming normally prepared soap masses by means of solutions of alkali-sensitive fragrances |
-
1928
- 1928-12-06 DE DEST45142D patent/DE560916C/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3000750A (en) * | 1953-03-06 | 1961-09-19 | Dehydag Dentsche Hydrierwerke | Process of preparing dispersions of pulverulent material and preparations obtained thereby |
| DE954009C (en) * | 1953-12-30 | 1956-12-13 | Huels Chemische Werke Ag | Use of phosphoric acid esters as emulsifiers for the emulsion polymerization of polymerizable chlorine-containing organic compounds |
| DE1230956B (en) * | 1955-12-01 | 1966-12-22 | J G Mouson & Co | Perfuming normally prepared soap masses by means of solutions of alkali-sensitive fragrances |
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