DE4431577A1 - Non-corrosive aerosol compsn. for hair bleach, brightener or fixative - Google Patents
Non-corrosive aerosol compsn. for hair bleach, brightener or fixativeInfo
- Publication number
- DE4431577A1 DE4431577A1 DE19944431577 DE4431577A DE4431577A1 DE 4431577 A1 DE4431577 A1 DE 4431577A1 DE 19944431577 DE19944431577 DE 19944431577 DE 4431577 A DE4431577 A DE 4431577A DE 4431577 A1 DE4431577 A1 DE 4431577A1
- Authority
- DE
- Germany
- Prior art keywords
- aerosol preparation
- ethoxylated
- hydrogen peroxide
- preparation according
- aerosol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000443 aerosol Substances 0.000 title claims abstract description 33
- 230000009972 noncorrosive effect Effects 0.000 title claims abstract description 7
- 239000000834 fixative Substances 0.000 title description 2
- 239000007844 bleaching agent Substances 0.000 title 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 59
- 239000000839 emulsion Substances 0.000 claims abstract description 17
- 150000002191 fatty alcohols Chemical class 0.000 claims abstract description 12
- 239000003380 propellant Substances 0.000 claims abstract description 6
- 150000001335 aliphatic alkanes Chemical class 0.000 claims abstract description 5
- 238000002360 preparation method Methods 0.000 claims description 28
- 239000000203 mixture Substances 0.000 claims description 16
- -1 fatty acid esters Chemical class 0.000 claims description 12
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical group CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 claims description 12
- 229920000847 nonoxynol Polymers 0.000 claims description 9
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 8
- 239000002736 nonionic surfactant Substances 0.000 claims description 8
- CSNINPBUICSTHD-UHFFFAOYSA-N 2-[2-[2-[2-(2-hydroxyethoxy)ethoxy]ethoxy]ethoxy]ethyl octanoate Chemical compound CCCCCCCC(=O)OCCOCCOCCOCCOCCO CSNINPBUICSTHD-UHFFFAOYSA-N 0.000 claims description 6
- 150000001298 alcohols Chemical class 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 239000001273 butane Substances 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 claims description 4
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims description 4
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 4
- 239000001294 propane Substances 0.000 claims description 4
- 229920006395 saturated elastomer Polymers 0.000 claims description 3
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- 239000000194 fatty acid Substances 0.000 claims description 2
- 229930195729 fatty acid Natural products 0.000 claims description 2
- 239000007789 gas Substances 0.000 claims description 2
- 239000001282 iso-butane Substances 0.000 claims description 2
- 235000013847 iso-butane Nutrition 0.000 claims description 2
- 229960002163 hydrogen peroxide Drugs 0.000 claims 6
- 150000002500 ions Chemical class 0.000 claims 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 6
- 230000007797 corrosion Effects 0.000 description 6
- 238000005260 corrosion Methods 0.000 description 6
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 6
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 5
- 238000000354 decomposition reaction Methods 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- CXIISRLRZRAKST-UHFFFAOYSA-N 29‐(4‐nonylphenoxy)‐3,6,9,12,15,18,21,24,27‐ nonaoxanonacosan‐1‐ol Chemical compound CCCCCCCCCC1=CC=C(OCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO)C=C1 CXIISRLRZRAKST-UHFFFAOYSA-N 0.000 description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 229940073555 nonoxynol-10 Drugs 0.000 description 3
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 3
- 150000002978 peroxides Chemical class 0.000 description 3
- 229960004889 salicylic acid Drugs 0.000 description 3
- VYMFQAYLNYQHER-UHFFFAOYSA-N 2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-(2-hydroxyethoxy)ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO VYMFQAYLNYQHER-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- KDQPSPMLNJTZAL-UHFFFAOYSA-L disodium hydrogenphosphate dihydrate Chemical compound O.O.[Na+].[Na+].OP([O-])([O-])=O KDQPSPMLNJTZAL-UHFFFAOYSA-L 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 229940094512 nonoxynol-12 Drugs 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 125000005474 octanoate group Chemical class 0.000 description 2
- JLFNLZLINWHATN-UHFFFAOYSA-N pentaethylene glycol Chemical compound OCCOCCOCCOCCOCCO JLFNLZLINWHATN-UHFFFAOYSA-N 0.000 description 2
- PWVUXRBUUYZMKM-UHFFFAOYSA-N 2-(2-hydroxyethoxy)ethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOCCO PWVUXRBUUYZMKM-UHFFFAOYSA-N 0.000 description 1
- CBLFQQQLPYAQCP-UHFFFAOYSA-N 2-hydroxyethyl octanoate Chemical compound CCCCCCCC(=O)OCCO CBLFQQQLPYAQCP-UHFFFAOYSA-N 0.000 description 1
- 239000004264 Petrolatum Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical class [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 230000003766 combability Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 239000008406 cosmetic ingredient Substances 0.000 description 1
- 238000004042 decolorization Methods 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 229940077412 peg-12 laurate Drugs 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 229940066842 petrolatum Drugs 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- UWHCKJMYHZGTIT-UHFFFAOYSA-N tetraethylene glycol Chemical compound OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 1
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 1
- REZOIPSCCRVWNN-UHFFFAOYSA-N tetratriacontan-17-ol Chemical compound CCCCCCCCCCCCCCCCCC(O)CCCCCCCCCCCCCCCC REZOIPSCCRVWNN-UHFFFAOYSA-N 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/30—Materials not provided for elsewhere for aerosols
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/046—Aerosols; Foams
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/22—Peroxides; Oxygen; Ozone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/08—Preparations for bleaching the hair
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/01—Hydrogen peroxide
- C01B15/037—Stabilisation by additives
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Public Health (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Cosmetics (AREA)
Abstract
Description
Gegenstand der Erfindung ist ein nicht-korrosives, lagerstabiles, wasserstoffperoxidhaltiges Aerosolprä parat.The subject of the invention is a non-corrosive, storage-stable, hydrogen peroxide-containing Aerosolprä ready.
Es ist bekannt, daß Wasserstoffperoxid enthaltende Präparate schwer zu stabilisieren sind und zudem bei Verwendung von Metallbehältern Probleme bezüglich der Korrosion der Metallbehälter auftreten. Bei der Korro sion können zusätzlich Verbindungen entstehen, durch die der Zerfall des Wasserstoffperoxids beschleunigt wird. Dieser Zerfall des Wasserstoffperoxids führt zu einem Überdruck, wodurch die Produktsicherheit erheb lich beeinträchtigt wird. Durch die Korrosionsprobleme wird zudem das durch den Überdruck bestehende Risiko einer Explosion des Behältnisses erheblich vergrößert, da das korrodierte Behältnis keine ausreichende Druck stabilität mehr aufweist.It is known that hydrogen peroxide-containing Preparations are difficult to stabilize and also at Use of metal containers problems regarding the Corrosion of metal containers occur. At the Korro Additional connections can be created through which accelerates the decomposition of the hydrogen peroxide becomes. This decomposition of the hydrogen peroxide leads to overpressure, which raises product safety is adversely affected. Due to the corrosion problems is also the risk posed by the overpressure an explosion of the container considerably increased, because the corroded container does not have sufficient pressure stability has more.
Aufgabe der vorliegenden Erfindung ist es daher, ein stabiles, nicht-korrosives, wasserstoffperoxidhaltiges Aerosolpräparat zur Verfügung zu stellen.Object of the present invention is therefore, a stable, non-corrosive, hydrogen peroxide-containing Aerosol preparation to provide.
Es wurde überraschenderweise gefunden, daß die ge stellte Aufgabe durch ein nicht-korrosives, wasser stoffperoxidhaltiges Aerosolpräparat, welches dadurch gekennzeichnet ist, daß es aus einer Wasserstoffper oxidemulsion auf der Basis eines Fettalkoholes und eines nichtionischen Tensides sowie einem Treibgas, das ausgewählt ist aus gasförmigen oder unter, Druck ver flüssigbaren niederen Alkanen, besteht in hervorra gender Weise gelöst wird.It was surprisingly found that the ge Set task by a non-corrosive, water peroxide-containing aerosol preparation, which thereby characterized in that it consists of a Wasserstoffper oxide emulsion based on a fatty alcohol and a nonionic surfactant and a propellant, the is selected from gaseous or under, pressure ver liquid lower alkanes, consists in hervorra gender way is solved.
In der Wasserstoffperoxidemulsion gemäß der vor liegenden Erfindung sind 0,5 bis 18 Gewichtsprozent, vorzugsweise 1 bis 6 Gewichtsprozent, Wasserstoff peroxid enthalten.In the hydrogen peroxide emulsion according to the before 0.5 to 18 weight percent, preferably 1 to 6 percent by weight, hydrogen contained peroxide.
Als Fettalkohol können gemäß der vorliegenden Erfindung aliphatische, geradkettige oder verzweigtkettige, gesättigte Alkohole mit 8 bis 30 Kohlenstoffatomen im Molekül sowie Gemische dieser Alkohole eingesetzt werden. Vorzugsweise werden in dem erfindungsgemäßen Aerosolpräparat als Fettalkohol Laurylalkohol, Cetyl alkohol und Stearylalkohol oder Gemische dieser Alko hole verwendet.As the fatty alcohol, according to the present invention aliphatic, straight-chain or branched-chain, saturated alcohols having 8 to 30 carbon atoms in the Molecule and mixtures of these alcohols used become. Preferably, in the inventive Aerosol preparation as fatty alcohol lauryl alcohol, cetyl alcohol and stearyl alcohol or mixtures of this alcohol hole used.
Die Einsatzmenge des Fettalkoholes in dem erfindungs gemäßen Aerosolpräparat beträgt vorzugsweise 0,1 bis 5 Gewichtsprozent, bezogen auf die Gesamtmenge der Wasserstoffperoxidemulsion.The amount of fatty alcohol used in the invention According to the aerosol preparation is preferably 0.1 to 5 Percent by weight, based on the total amount of Hydrogen peroxide emulsion.
Als nichtionisches Tensid werden in dem erfindungs gemäßen Aerosolpräparat insbesondere mit 2 bis 200 Mol Ethylenoxid oxethylierte Nonylphenole und oxethylierte Fettsäureester (mit 2 bis 500 Mol Ethylenoxid um Mole kül und 6 bis 30 Kohlenstoffatomen in der Alkylkette) oder deren Gemische verwendet.As a nonionic surfactant in the invention according to the aerosol preparation, in particular with 2 to 200 mol Ethylene oxide ethoxylated nonylphenols and ethoxylated Fatty acid esters (with 2 to 500 moles of ethylene oxide to mol and 6 to 30 carbon atoms in the alkyl chain) or mixtures thereof used.
Geeignete nichtionische Tenside werden im CTFA Inter national Cosmetic Ingredient Dictionary; 4th Edition (1991); The Cosmetic, Toiletry and Fragrance Associa tion; Washington DC/USA auf den Seiten 341 bis 345 und 403 bis 428 beschrieben.Suitable nonionic surfactants are described in the CTFA Inter national Cosmetic Ingredient Dictionary; 4th Edition (1991); The Cosmetic, Toiletry and Fragrance Associa tion; Washington DC / USA on pages 341-345 and 403 to 428 described.
Als Beispiele für gemäß der vorliegenden Erfindung geeignete nichtionische Tenside können insbesondere Diethylenglykolmonostearat (PEG-2-Stearate), Dodeca ethylenglykolmonolaurat (PEG-12-Laurate), Tetraethylen glykoloctanoat (PEG-4-Octanoate), Pentaethylenglykol octanoat (PEG-5-Octanoate) und mit 2 bis 200 Mol Ethylenoxid oxethylierte Nonylphenole genannt werden. Bevorzugt sind hierbei Mischungen der genannten oxethylierten Nonylphenole mit Pentaethylenglykolocta noat, wobei die Mischungen aus mit 10 bis 14 Mol ox ethylierten Nonylphenolen und Pentaethylenglykolocta noat besonders bevorzugt sind.As examples of according to the present invention suitable nonionic surfactants may in particular Diethylene glycol monostearate (PEG-2 stearates), dodeca ethylene glycol monolaurate (PEG-12 laurate), tetraethylene glycoloctanoate (PEG-4-octanoate), pentaethylene glycol octanoate (PEG-5-octanoate) and with 2 to 200 moles Ethylene oxide be called ethoxylated nonylphenols. Preference is given to mixtures of said ethoxylated nonylphenols with pentaethylene glycol octa noate, the mixtures of 10 to 14 mol ox ethylated nonylphenols and pentaethylene glycol octa noate are particularly preferred.
Das nichtionische Tensid ist in der Wasserstoffperoxid emulsion vorzugsweise in einer Menge von 0,05 bis 5 Ge wichsprozent enthalten.The nonionic surfactant is in the hydrogen peroxide preferably in an amount of 0.05 to 5 Ge weight percent included.
Die Wasserstoffperoxidemulsion kann weiterhin für wasserstoffperoxidhaltige Zubereitungen übliche Ver bindungen, wie zum Beispiel anorganische oder organische Säuren, beispielsweise Phosphorsäure oder Salicylsäure, Mineralöle, Vaseline (Petrolatum), Lösungsvermittler, anionische Tenside, beispielsweise Alkylsulfate und Alkylethersulfate, Parfümöle, Farb stoffe und Geruchsverbesserer enthalten.The hydrogen peroxide emulsion may further be used for hydrogen peroxide-containing preparations usual Ver bonds, such as inorganic or organic acids, for example phosphoric acid or Salicylic acid, mineral oils, Vaseline (petrolatum), Solubilizers, anionic surfactants, for example Alkyl sulfates and alkyl ether sulfates, perfume oils, color contain substances and odor improvers.
Diese Zusatzstoffe werden in den für solche Zwecke üblichen Mengen verwendet.These additives are used for such purposes usual amounts used.
Der pH-Wert des erfindungsgemäßen Aerosolpräparates beträgt 1 bis 5, vorzugsweise 1,4 bis 4,5. The pH of the aerosol preparation according to the invention is 1 to 5, preferably 1.4 to 4.5.
Weiterhin enthält das erfindungsgemäße Aerosolpräparat ein Treibgas, welches ausgewählt ist aus gasförmigen oder unter Druck verflüssigbaren niederen Alkanen, wobei Propan, Butan und iso-Butan sowie deren Gemische besonders bevorzugt sind.Furthermore, the aerosol preparation according to the invention contains a propellant, which is selected from gaseous or under pressure liquefiable lower alkanes, wherein propane, butane and iso-butane and mixtures thereof are particularly preferred.
Das Gewichtsverhältnis von Wasserstoffperoxidemulsion zu Treibgas beträgt in dem erfindungsgemäßen Aerosol präparat vorzugsweise 80 : 20 bis 97 : 3, wobei ein Ge wichtsverhältnis von 90 : 10 bis 95 : 5 besonders bevorzugt ist.The weight ratio of hydrogen peroxide emulsion to propellant gas is in the aerosol according to the invention preparation preferably 80: 20 to 97: 3, wherein a Ge weight ratio of 90: 10 to 95: 5 particularly preferred is.
Das erfindungsgemäße Aerosolpräparat wird aus einem Aerosolbehälter mittels eines geeigneten Ventils auf das Haar aufgebracht und kann sowohl für die Entfärbung beziehungsweise Aufhellung der Haare als auch als Fixiermittel bei der dauerhaften Haarverformung ver wendet werden. Es verbleibt je nach Anwendungszweck für einen Zeitraum von 5 Minuten bis zu 10 Tagen im Haar, wobei für die Entfärbung von Haaren ein Zeitraum von 30 Minuten bis 36 Stunden und für die Verwendung als Fixiermittel ein Zeitraum von 5 bis 30 Minuten bevor zugt ist.The aerosol preparation according to the invention is made from a Aerosol container by means of a suitable valve The hair is applied and can be used both for decolorization or whitening the hair as well as Fixative in permanent hair deformation ver be used. It remains depending on the application for a period of 5 minutes to 10 days in the hair, for the discoloration of hair a period of 30 Minutes to 36 hours and for use as Fixer a period of 5 to 30 minutes before is awarded.
Als Aerosolbehälter können sowohl Aluminium- oder Weiß blechbehälter als auch Kunststoffbehälter verwendet werden, wobei innenlackierte Aluminiumbehälter bevor zugt sind.As aerosol container can be both aluminum or white Sheet metal container as well as plastic container used be, with interior painted aluminum container before are awarded.
Das erfindungsgemäße Aerosolpräparat zeichnet sich durch eine hohe Stabilität aus und ist nicht-korrosiv. So tritt auch nach einer zweÿährigen Lagerung bei 40 Grad Celsius weder eine Zersetzung des Wasserstoff peroxids noch eine Korrosion des Aerosolbehälters auf.The aerosol preparation according to the invention is characterized due to high stability and is non-corrosive. So occurs even after a two-year storage at 40 Celsius degrees neither a decomposition of hydrogen peroxide still a corrosion of the aerosol container.
Weiterhin wird die Kämmbarkeit der Haare trotz der Abwesenheit kationischer Tenside verbessert und das Fönen der Haare erleichtert. Das erfindungsgemäße Aerosolpräparat wirkt zudem auf das Haar antistatisch.Furthermore, the combability of the hair despite the Absence of cationic surfactants improved and the Blow dry the hair. The invention Aerosol preparation also has an antistatic effect on the hair.
Ein weiterer Gegenstand der vorliegenden Erfindung ist die Verwendung einer Fettalkohole sowie ein Gemisch von oxethylierten gesättigten Fettsäureestern und oxethy lierten Nonylphenolen enthaltenden Wasserstoffperoxid emulsion zur Vermeidung von Korrosionen in wasserstoff peroxidhaltige Mittel enthaltenden Aerosolbehältern aus Metall.Another object of the present invention is the use of a fatty alcohols and a mixture of Oxyethylated saturated fatty acid esters and oxethy lated nonylphenol-containing hydrogen peroxide emulsion to prevent corrosion in hydrogen containing peroxide-containing agent aerosol containers Metal.
Als Fettalkohole können die bereits genannten Fettalko hole verwendet werden, wobei die Einsatzmenge etwa 0,1 bis 5 Gewichtsprozent beträgt.As fatty alcohols, the already mentioned fatty alcohol be used, wherein the amount used about 0.1 to 5 percent by weight.
Als Beispiel für geeignete oxethylierte gesättigte Fettsäureester können Verbindungen mit 2 bis 500 Mol Ethylenoxid im Molekül und einer Alkylkettenlänge von 6 bis 30 Kohlenstoffatomen, beispielsweise Diethylengly kolmonostearat, Dodecaethylenglykolmonolaurat, Tetra ethylenglykoloctanoat oder Pentaethylenglykoloctanoat, genannt werden.As an example of suitable ethoxylated saturated Fatty acid esters can be compounds having 2 to 500 moles Ethylene oxide in the molecule and an alkyl chain length of 6 to 30 carbon atoms, for example diethylene glycol colmonostearate, dodecaethylene glycol monolaurate, tetra ethylene glycol octanoate or pentaethylene glycol octanoate, to be named.
Als geeignete oxethylierte Nonylphenole können mit 2 bis 200 Mol Ethylenoxid oxethylierte Nonylphenole genannt werden.Suitable ethoxylated Nonylphenole can with 2 to 200 moles of ethylene oxide ethoxylated nonylphenols to be named.
Die Gesamteinsatzmenge an oxethylierten gesättigten Fettsäureestern und oxethylierten Nonylphenolen beträgt etwa 0,05 bis 5 Gewichtsprozent, wobei der pH-Wert der Zubereitung vorzugsweise auf 1,5 bis 4,5 eingestellt wird.The total amount of ethoxylated saturated Fatty acid esters and ethoxylated nonylphenols about 0.05 to 5 weight percent, wherein the pH of the Preparation preferably adjusted to 1.5 to 4.5 becomes.
Besonders bevorzugt ist die Verwendung eines Gemisches aus mit 10 bis 14 Mol Ethylenoxid oxethylierten Nonyl phenolen (Nonoxynol-10; Nonoxynol-12 oder Nonoxynol-14) und Pentaethylenglykoloctanoat (PEG-5-Octanoate).Particularly preferred is the use of a mixture from with 10 to 14 moles of ethylene oxide ethoxylated nonyl phenols (nonoxynol-10, nonoxynol-12 or nonoxynol-14) and pentaethylene glycol octanoate (PEG-5 octanoates).
Die nachfolgenden Beispiele sollen den Gegenstand der vorliegenden Erfindung näher erläutern, ohne diesen auf die Beispiele zu beschränken.The following examples are intended to illustrate the subject matter of explain this invention in more detail, without this on to limit the examples.
Der pH-Wert der vorstehenden Wasserstoffperoxidemulsion wird mit Phosphorsäure auf 3,0 eingestellt. Anschließend wird die Wasserstoffperoxidemulsion zu sammen mit einem Propan/Butan-Gemisch im Verhältnis von 92 : 8 in einen innenlackierten Aluminiumbehälter abge füllt.The pH of the above hydrogen peroxide emulsion is adjusted to 3.0 with phosphoric acid. Subsequently, the hydrogen peroxide emulsion is added together with a propane / butane mixture in the ratio of 92: 8 abge in an internally painted aluminum container crowded.
Das auf diese Weise hergestellte Aerosolpräparat ist völlig stabil und weist auch nach einer längeren Lager zeit keinerlei Zersetzung des Wasserstoffperoxids oder Korrosion des Aerosolbehälters auf.The aerosol preparation prepared in this way is completely stable and also points to a longer bearing no decomposition of the hydrogen peroxide or Corrosion of the aerosol container on.
Der pH-Wert der vorstehenden Wasserstoffperoxidemulsion wird mit Phosphorsäure auf 2,8 eingestellt.The pH of the above hydrogen peroxide emulsion is adjusted to 2.8 with phosphoric acid.
Anschließend werden 95 g dieser Wasserstoffperoxid emulsion mit 5 g eines Propan/Butan-Gemisches in einen innenlackierten Aluminiumbehälter abgefüllt. Subsequently, 95 g of this hydrogen peroxide emulsion with 5 g of a propane / butane mixture in one internally painted aluminum container bottled.
Das erhaltene Aerosolpräparat weist nach einer Lagerung von 6 Monaten bei Raumtemperatur bzw. 40 Grad Celsius weder eine auf einer Wasserstoffperoxidzersetzung beruhende Druckerhöhung noch Korrosionserscheinungen auf.The resulting aerosol preparation shows after storage 6 months at room temperature or 40 degrees Celsius neither on hydrogen peroxide decomposition based pressure increase nor corrosion phenomena on.
Die Anwendung des Aerosolpräparates zur Haaraufhellung erfolgt in einfacher Weise, indem das Aerosolpräparat kurz geschüttelt wird, sodann eine für die Haarauf hellung ausreichende Menge auf das Haar aufgetragen wird, anschließend in das Haar eingearbeitet wird und nach der gewünschten Einwirkungszeit (je nach Auf hellungsgrad 6 bis 36 Stunden) aus dem Haar wieder ausgespült wird.The use of the aerosol preparation for hair lightening takes place in a simple manner by the aerosol preparation shaken briefly, then one for the hair sufficient amount applied to the hair is then incorporated into the hair and after the desired exposure time (depending on degree of lightening 6 to 36 hours) from the hair again is rinsed out.
Claims (10)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19944431577 DE4431577A1 (en) | 1994-09-05 | 1994-09-05 | Non-corrosive aerosol compsn. for hair bleach, brightener or fixative |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19944431577 DE4431577A1 (en) | 1994-09-05 | 1994-09-05 | Non-corrosive aerosol compsn. for hair bleach, brightener or fixative |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE4431577A1 true DE4431577A1 (en) | 1996-03-07 |
Family
ID=6527453
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19944431577 Withdrawn DE4431577A1 (en) | 1994-09-05 | 1994-09-05 | Non-corrosive aerosol compsn. for hair bleach, brightener or fixative |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE4431577A1 (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0861656A1 (en) * | 1997-02-01 | 1998-09-02 | Wella Aktiengesellschaft | Hair bleaching composition |
| WO1999006518A1 (en) * | 1997-07-30 | 1999-02-11 | Cognis Deutschland Gmbh | Thickened aqueous tenside solutions |
| WO2007002044A1 (en) * | 2005-06-20 | 2007-01-04 | The Procter & Gamble Company | Product release system for atomizing compositions containing hair-keratin-reducing or oxidative active ingredients |
| WO2014094911A1 (en) * | 2012-12-21 | 2014-06-26 | Ecolab Inc. | Enhancement of the sporicidal efficacy of alcohol and peroxide compositions |
| US9986809B2 (en) | 2013-06-28 | 2018-06-05 | The Procter & Gamble Company | Aerosol hairspray product comprising a spraying device |
| US10131488B2 (en) | 2015-06-01 | 2018-11-20 | The Procter And Gamble Company | Aerosol hairspray product comprising a spraying device |
| US10426979B2 (en) | 2011-09-15 | 2019-10-01 | The Procter And Gamble Company | Aerosol hairspray product for styling and/or shaping hair |
| US12128118B2 (en) | 2021-07-29 | 2024-10-29 | The Procter & Gamble Company | Aerosol dispenser containing a hairspray composition and a nitrogen propellant |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3434886A1 (en) * | 1984-09-22 | 1986-03-27 | Wella Ag, 6100 Darmstadt | Stabilisers for alkyl halides and their use in aerosol preparations |
| DE3732147A1 (en) * | 1987-09-24 | 1989-04-06 | Henkel Kgaa | EMULSION-SHAPED HYDROGEN PEROXIDE PREPARATIONS FOR BLONDING AND OXIDATIVE COLORING OF THE HAIR |
| DE4018259A1 (en) * | 1990-06-07 | 1991-12-12 | Henkel Kgaa | HYDROGEN-PREPARATIONS |
-
1994
- 1994-09-05 DE DE19944431577 patent/DE4431577A1/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3434886A1 (en) * | 1984-09-22 | 1986-03-27 | Wella Ag, 6100 Darmstadt | Stabilisers for alkyl halides and their use in aerosol preparations |
| DE3732147A1 (en) * | 1987-09-24 | 1989-04-06 | Henkel Kgaa | EMULSION-SHAPED HYDROGEN PEROXIDE PREPARATIONS FOR BLONDING AND OXIDATIVE COLORING OF THE HAIR |
| DE4018259A1 (en) * | 1990-06-07 | 1991-12-12 | Henkel Kgaa | HYDROGEN-PREPARATIONS |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0861656A1 (en) * | 1997-02-01 | 1998-09-02 | Wella Aktiengesellschaft | Hair bleaching composition |
| WO1999006518A1 (en) * | 1997-07-30 | 1999-02-11 | Cognis Deutschland Gmbh | Thickened aqueous tenside solutions |
| WO2007002044A1 (en) * | 2005-06-20 | 2007-01-04 | The Procter & Gamble Company | Product release system for atomizing compositions containing hair-keratin-reducing or oxidative active ingredients |
| US10426979B2 (en) | 2011-09-15 | 2019-10-01 | The Procter And Gamble Company | Aerosol hairspray product for styling and/or shaping hair |
| US11311749B2 (en) | 2011-09-15 | 2022-04-26 | The Procter And Gamble Company | Aerosol hairspray for styling and/or shaping hair |
| WO2014094911A1 (en) * | 2012-12-21 | 2014-06-26 | Ecolab Inc. | Enhancement of the sporicidal efficacy of alcohol and peroxide compositions |
| US9820489B2 (en) | 2012-12-21 | 2017-11-21 | Ecolab Usa Inc. | Enhancement of the sporicidal efficacy of alcohol and peroxide compositions |
| US9986809B2 (en) | 2013-06-28 | 2018-06-05 | The Procter & Gamble Company | Aerosol hairspray product comprising a spraying device |
| US10131488B2 (en) | 2015-06-01 | 2018-11-20 | The Procter And Gamble Company | Aerosol hairspray product comprising a spraying device |
| US12128118B2 (en) | 2021-07-29 | 2024-10-29 | The Procter & Gamble Company | Aerosol dispenser containing a hairspray composition and a nitrogen propellant |
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