DE4420880A1 - Firming hair cleanser - Google Patents

Description

The subject of the present invention is a liquid Hair cleanser containing a combination nation of at least one cationic polymer, min at least one particular anionic polymer, minde at least one anionic surfactant and at least one in the medium insoluble solid, in addition to a good hair-cleaning effect a good hair-firming Has effect.

Hair cleansers usually contain in addition to the for the cleaning effect causal surfactants hair caring additives to ensure that the Hair is good in both wet and dry conditions is combinable, showing a diminished static charge and has a soft natural feel.

After the hair washing next to the cleaning a good Hairability of the hair and a possible duration Adhere to the seat of the hairstyle to be sure Hair washing usually hair fixative in the form alko holischer or aqueous-alcoholic polymer solutions the hair is applied, not rinsed out again become.

This procedure is time and time for the user costly, since he has two remedies, a hair cleanser medium and a hair fixer, needed.

From US-PS 4,299,817 is a hair shampoo on the  Base of a water-soluble polyelectrolyte complex, in addition to a hair-cleansing and a hair-fixation should have a corresponding effect known. That from the However, US-PS 4,299,817 known hair shampoo can be down obviously not full of its strengthening effect to satisfy.

It was therefore the task of a liquid Haarreini to make available, in addition to a good hair-cleansing effect, a good hair-firming Has effect.

It has now been found that a liquid hair cleansing Means, characterized in that it

• (A) 1 to 20% by weight of at least one ionic surfactant,
• (B) 0.1 to 2% by weight of at least one cat ionic polymer,
• (C) 0.1 to 5 percent by weight of at least one in 50 up to 100 percent neutralized anio niche polymer, which is selected acrylate / acrylamide copolymers, Vinyl acetate / crotonic acid copolymers, vinyl acetate / crotonic acid / Vinylneodeca noate copolymers, anionic chitosan derivatives and shellac and
• (D) 0.1 to 5% by weight of at least one im Agent of insoluble solid with a mean grain size of 1 to 200 μm, which is selected from nylon  powder, polyethylene powder and poly methylmethacrylatpulver,

contains and free of silicone oils and cationic Is surfactants.

The hair-cleaning composition according to the invention preferably contains 10 to 20 percent by weight of component (A). The anionic surfactant of component (A) is preferably selected from the alkali or alkaline earth metal salts of C₁₀- to C₁₈-alkyl sulfates, the C₁₀- to C₁₈-Alkylsulfo nate, the C₁₀- to C₁₈-alkylbenzenesulfonates, the C₁₀- to C₁₈-xylenesulfonates and the ethoxylated with 1 to 10 ethylene units C₁₀- to C₁₈-alkyl ether sulfate,
the ethoxylated sulfosuccinic monoesters of the general formula (I)

where R¹ is a C₁₀ to C₁₈ alkyl radical, M is an alkali metal or alkaline earth metal cation and m is an integer from 1 to 10,
and the alkyl ether carboxylates of the general formula (II)

R² (OCH₂CH₂) _n OCH₂COOM (II),

wherein R² is a C₁₀ to C₁₈ alkyl radical, M is a Alkali or alkaline earth is and n is a whole Number from 1 to 20 means the alkali and earth  alkali salts of from 1 to 10 ethylene oxide units ethoxylated C₁₀ to C₁₈ alkyl ether sulfates especially are preferred.

Of the as component (A) of the invention By means of suitable alkyl sulfates is sodium lauryl sulfate, which is available, for example, from Henkel KGaA, Düsseldorf, Germany in the form of a solid under the Trade name Texapon K 12 is sold, prefers.

Of the suitable as component (A) alkyl sulfonates is the mixture of the sodium salts of the secondary C₁₂- to C₁₆ alkanesulfonates, for example, from the Company Hoechst AG, Frankfurt, Germany under the Handelsbe drawing Hostapur® SAS 30 in the form of a 30 percent Solution is sold, preferably.

Of the as component (A) of the hair of the invention cleaning agent suitable alkylbenzenesulfonates the sodium salt of linear dodecylbenzenesulfonate, for example in the form of a 55% paste under the trade name Maranil® Paste A 55 of Henkel KGaA, Dusseldorf, Germany, prefers.

Of the suitable as component (A) xylenesulfonates is the sodium salt of xylenesulfonate which for example, from Albright & Wilson Ltd., Cumbria, UK in the form of a solid below the trade name Eltesol® SX 93 is sold, prefers.  

Of the suitable as component (A) Alkylethersul faten is that which has a C₁₂-alkyl radical and ethoxylated with 3 ethylene oxide units. One for use as component (A) of the invention agent according to the invention suitable with 3 ethylene oxide A ethoxylated lauryl ether sulfate example in the form of a 70 percent aqueous solution the trade name Texapon® N 70 from the company Henkel KGaA, Düsseldorf, Germany.

Of the suitable as component (A) ethoxylated Sulfosuccinic monoesters is the preferred one which is ethoxylated with 3 ethylene oxide units and has an alkyl group with 12 carbon atoms.

A lauryl ethoxylated with 3 ethylene oxide units For example, sulfo-succinic acid semi-ester is described in Form of a 40 percent aqueous solution of his di sodium salt under the trade name Texapon® SB3 sold by the company Henkel KGaA, Dusseldorf, Germany.

Of the alkyl ether carboxylates which are used as component (A) may be contained in the agent according to the invention, the one preferred is that with 10 ethylene oxide units is ethoxylated and an alkyl group with 12 carbon atoms. One with 10 ethylene oxide units ethoxylated lauryl ether carboxylate is in the form of a 22 percent aqueous solution of its sodium salt for example, by the company Huls AG, Marl, Germany under the trade name Marlinat® CM 105/80 distributed.

The hair cleanser according to the invention contains preferably 0.5 to 1.2 percent by weight of the component (B). The cationic polymer of component (B) is  preferably selected from diallyldimethylammonium chloride / acrylamide copolymers, with dimethyl sulfate quaternized vinylpyrrolidone / dimethylaminoethyl methacrylate copolymers, polymeric quaternaries Ammonium salts of hydroxyethyl cellulose and vinyl pyrrolidone / methacrylamidopropyltrimethylammonium chloride copolymers.

As component (B) suitable diallyldimethylammonium For example, chloride / acrylamide copolymers are used by the company Calgon, Pittsburgh, USA in the form of a 8 percent aqueous solution, under the trade name Merguat® 550. As component (B) suitable dimethyl quaternized vinyl pyrrolidone / dimethylaminoethyl methacrylate copolymers are for example in the form of a 20prozentigen aqueous solution under the trade name Gafquat® 755 sold by the company Gaf, New York, USA.

As component (B) suitable polymeric quaternary Ammonium salts of hydroxyethyl cellulose are added For example, from the company Union Carbide Europa S.A., Geneva, Switzerland under the trade name Polymer JR® distributed.

As component (B) suitable vinylpyrrolidone / methacryl amidopropyltrimethylammonium chloride copolymers for example, under the trade name Gafquat® HS-100 in the form of a 20 percent aqueous solution of sold by Gaf, New York, USA.

The hair cleanser according to the invention contains as Component (B) particularly preferably a polymeric quaternary ammonium salt of hydroxyethylcellulose.  

Component (C) is in the hair of the invention cleaning agent preferably in an amount of 0.3 to 3 Weight percent included.

The anionic polymer of component (C) of the invention Hair cleanser according to the invention is according to the Invention in a 50 to 100 percent neutrali Siert form, wherein the neutralization is preferably selected from alkali metal hydroxides, organic amines and alkanolamines.

Suitable amines or alkanolamines for neutralization are, for example:
2-amino-2-methyl-1,3-propanediol,
2-amino-2-ethyl-1,3-propanediol,
2-amino-2-methyl-1-propanol,
2-amino-2-methyl-2-pentanol
1-amino-2-methyl-2-propanol,
2-amino-1-butanol,
3-amino-2-pentanol,
2-amino-1-phenyl-1-butanol,
2-dimethylamino-2-methyl-1-propanol,
2-dimethylamino-2-methyl-1,3-propanediol,
tris (hydroxymethyl) aminomethane,
triisopropylamine
tris- (hydroxymethyl) -dimethylaminomethane, and
N¹- (2-hydroxyethyl) -2-methyl-1,2-propanediamine.

The anionic polymer of component (C) is especially preferably with sodium hydroxide to 50 to 100 percent neutralized.  

As component (C) suitable acrylate / acrylamide copoly For example, mers are sold under the trade name Ultrahold 8® from BASF AG, Ludwigshafen, Germany distributed. Suitable as component (C) vinyl acetate / Crotonic acid copolymers are used, for example, by the Company Hoechst AG, Frankfurt, Germany in the form of a 60pro solution in aqueous isopropanol under the Trade name Aristoflex A and from the company Delft-National GmbH, Frankfurt, Germany under the trade term Resyn® 28-1310.

Vinyl acetate / crotonic acid suitable as component (C) Vinyl neodecanoate copolymers are used, for example, by National Starch and Chem. Ltd., New Jersey, USA under the trade name Resyn® 28-2930 in the form a solid sold.

The hair cleanser according to the invention contains as Component (C) preferably has from 50 to 100 percent neutralized vinyl acetate / crotonic acid copolymer.

The agent according to the invention contains the components (B) and (C) preferably in a weight ratio of (B): (C) of 1: 2.

The agent according to the invention contains component (D) preferably in an amount of 0.1 to 2 percent by weight.

The as component (D) in the agent according to the invention solid contained preferably has an average Grain size from 2 to 40 microns (microns).  

As component (D) suitable nylon powder is at For example, under the trade name Orgasol® of sold by Atochem, Paris, France.

As component (D) suitable polyethylene powder is for example under the trade name Lupolen® 1800 SP 15 from BASF AG, Ludwigshafen, Germany distributed.

As component (D) of the agent according to the invention suitable polymethyl methacrylate powder is exemplified example of the company Ziegler & Co., Wunsiedel, Germany the trade name Jurymer distributed.

The hair cleanser according to the invention contains as Component (D) prefers nylon powder with a grain size of 2 to 40 μm (microns).

The agent according to the invention can be used in addition to inventive combination of components (A) to (D) 0.1 to 20% by weight of at least one for Hair cleanser suitable amphoteric surfactant contain. Of those suitable for hair cleansers Amphoteric surfactants are for example the C₈- to C₁₈-alkylbetaines, the C₈ to C₁₈-alkyl sulfobetaines, the carboxyl derivatives of imidazole, the C₈ to C₁₈- Alkyldimethylammonium acetates containing C₈ to C₁₈- Alkyldimethylcarboxylmethylammonium salts and the C₈- to C₁₈-Fettsäurealkylamidobetaine called.

As C₈- to C₁₈-Fettsäurealkylamidobetain comes For example, the Kokosfettsäureamidopropylbetain, which, for example, in the form of a 30prozentigen aqueous solution under the trade name  Tego Betain® L7 from Goldschmidt AG, Essen, Germany Germany and the N-Kokosfettsäureamidoethyl- N- [2- (carboxymethoxy) ethyl] glycine (CTFA name: Coco amphocarboxyglycinate), which, for example, in the form a 50% aqueous solution under the trade term Miranol® C2M from Miranol Chemical Co. Inc., New Jersey, USA.

However, the agent according to the invention is preferably free of amphoteric surfactants.

Of course, the Haarreini invention Means for hair cleansers usual addition substances, for example nonionic surfactants in one Amount of 0.1 to 5 weight percent, such as Oxyethylated fatty alcohols with 12 to 18 carbon atoms, for example with up to 40 moles of ethylene oxide per Mole fatty alcohol ethoxylated lauryl, tetradecyl, Cetyl, oleyl and stearyl alcohol, alone or in the Mixture; the fatty alcohols of ethoxylated lanolin or ethoxylated lanolin: polyglyceryl ether of saturated or unsaturated fatty alcohols and alkyl phenols having 8 to 30 carbon atoms in the alkyl radical and 1 to 10 glyceryl units in the molecule; fatty acid alkanolamides, and ethoxylated sorbitan fatty acid esters; Perfume oils in an amount of about 0.5 to 5.0 weight percent; Opacifiers, such as ethylene glycol Koldistearat, in an amount of about 0.5 to 5.0 Ge weight percent; Pearlescing agents, such as a Mixture of fatty acid monoalkylolamide / ethylene glycol distearate, in an amount of about 1.0 to 10.0 Ge weight percent; bactericidal or fungicidal active substances, such as 2,4,4-trichloro-2-hydroxy-diphenyl ether or methylchloroisothiazolinone, in an amount of about  0.01 to 1.0 weight percent; Thickener, like for example, glycerol monolaurate, coconut fatty acid di ethanolamide, in an amount of about 0.5 to 3.0 Weight percent; Diluents, such as 1,2-propylene glycol or ethoxylated Sorbitan monolaurate, in an amount of about 0.5 to 5.0 Weight percent; Buffer substances, such as Sodium citrate or sodium phosphate, in an amount of about 0.1 to 1.0 weight percent; Solubilizers, such as ethoxylated, optionally hydrogenated castor oil, in an amount of about 0.1 to 1.0 percent by weight and staining substances, such as Example fluorescein sodium salt, in an amount of about 0.1 to 1.0 weight percent.

The water content of the hair cleansing according to the invention means is preferably between 30 and 90 weight percent.

The agent according to the invention has a pH of 4 to 9, preferably from 4.5 to 7.5.

The adjustment of the pH of the inventive By means of, for example, citric acid, Phos phosphoric acid, hydrochloric acid or sodium hydroxide.

The composition of the invention has a good hair clean good effect in combination with a good hair firmness effect on.

The hair cleaned with the composition according to the invention have a good wet and dry combability, a good Manageability and an attractive volume. The Composition according to the invention gives the hair a firm and  at the same time flexible but without the natural Affect the hair's grip.

The following examples are intended to form the subject of the invention explain in more detail:

Examples example 1 Hair detergent 11.20 g ethoxylated sodium lauryl ether sulfate ethoxylated with 3 units of ethylene oxide 1.00 g polymeric quaternary ammonium salt of hydroxyethyl cellulose (Polymer JR® from Union Carbide Europe S.A, Switzerland) 0.50 g Vinyl acetate / crotonic acid / vinyl neodecanoate copolymer (Resyn® 28-2930 from National Starch Chem. Ltd, USA) 0.50 g Nylon powder (Orgasol® 2002 UD Nat Cos from Atochem, France) 0.20 g sodium hydroxide 0.10 g citric acid 86.50 g water 100.00 g

Example 2 Hair detergent 11.20 g ethoxylated sodium lauryl ether sulfate ethoxylated with 3 units of ethylene oxide 1.00 g polymeric quaternary ammonium salt of hydroxyethylcellulose (Polymer JR® from Union Carbide Europe SA, Switzerland) 0.50 g Acrylate / acrylamide copolymer (Ultra hold 8® from BASF AG, FRG) 0.50 g Nylon powder (Orgasol® 2002 UD Nat Cos from Atochem, France) 0.20 g sodium hydroxide 0.20 g citric acid 86.40 g water 100.00 g

Example 3 Hair detergent 11.20 g ethoxylated sodium lauryl ether sulfate ethoxylated with 3 units of ethylene oxide 1.00 g polymeric quaternary ammonium salt of hydroxyethyl cellulose (Polymer JR® from Union Carbide Europe S.A, Switzerland) 0.50 g Vinyl acetate / crotonic acid copolymer (Resyn® 28-1310 from National Starch Chem Ltd., USA) 0.50 g Nylon powder (Orgasol® 2002 UD Nat Cos from Atochem, France) 0.10 g sodium hydroxide 0.10 g citric acid 86.60 g water 100.00 g

Example 4 Hair detergent 11.20 g ethoxylated sodium lauryl ether sulfate ethoxylated with 3 units of ethylene oxide 1.00 g polymeric quaternary ammonium salt of hydroxyethyl cellulose (Polymer JR® from Union Carbide Europe S.A, Switzerland) 0.50 g Vinyl acetate / crotonic acid copolymer (Resyn® 28-1310 from National Starch Chem. Ltd, USA) 0.50 g Polymethylmethacrylate powder (Jurymer® from Ziegler & Co., FRG 0.10 g sodium hydroxide 0.10 g citric acid 86.60 g water 100.00 g

Example 5 Hair detergent 2.40 g Disodium salt of the ethoxylated with 3 ethylene oxide Laurylsulfobernsteinsäurehalbesters 8.40 g ethoxylated sodium lauryl ether sulfate ethoxylated with 5 units of ethylene oxide 1.00 g polymeric quaternary ammonium salt of hydroxyethyl cellulose (Polymer JR® from Union Carbide Europe S.A, Switzerland) 0.50 g Vinyl acetate / crotonic acid copolymer (Resyn® 28-1310 from National Starch Chem Ltd, USA) 0.50 g Nylon powder (Orgasol® 2002 UD Nat Cos from Atochem, France) 0.10 g sodium hydroxide 0.10 g citric acid 87.00 g water 100.00 g

Example 6 Hair detergent 0.88 g Sodium salt of a lauryl ether carboxylate ethoxylated with 10 units of ethylene oxide 8.40 g ethoxylated sodium lauryl ether sulfate ethoxylated with 5 units of ethylene oxide 1.00 g polymeric quaternary ammonium salt of hydroxyethyl cellulose (Polymer JR® from Union Carbide Europe S.A, Switzerland) 0.50 g Vinyl acetate / crotonic acid copolymer (Resyn® 28-1310 from National Starch Chem. Ltd, USA)   0.50 g Nylon powder (Orgasol® 2002 UD Nat Cos from Atochem, France) 0.10 g sodium hydroxide 0.10 g citric acid 88.52 g water 100.00 g

Example 7 Hair detergent 11.2 g ethoxylated sodium lauryl ether sulfate ethoxylated with 3 units of ethylene oxide 1.00 g polymeric quaternary ammonium salt of hydroxyethyl cellulose (Polymer JR® from Union Carbide Europe S.A, Switzerland) 0.50 g Vinyl acetate / crotonic acid copolymer (Resyn® 28-1310 from National Starch Chem Ltd, USA) 0.50 g Polyethylene powder (Lupolen® 1800 SP 15 from BASF AG, FRG) 0.10 g sodium hydroxide 0.10 g citric acid 86.60 g water 100.00 g

Comparative tests Comparative experiment A

An inventive hair cleanser according to Example 3 was regarding his attachment Schaften with Example II, Composition II of Table V of U.S. Patent 4,299,817.

Composition II of Example II of US Pat 4,299, 817 (hereinafter referred to as Example II) has the following composition:

5,000 g triethanolamine 0.100 g polymeric quaternary ammonium salt of hydroxyethyl cellulose (Polymer JR® from Union Carbide Europe S.A, Switzerland) 0.025 g Sodium carboxymethylcellulose (Blanose® 7 from Herkules GmbH, Germany) 3,900 g N-coconut fatty acid amidoethyl-N- [2- (carboxyethoxy) ethyl] alanine (Miranol® C2M SF from Miranol Inc., USA) 90.975 g water 100,000 g

For comparison concerning the strengthening effect was the hair of 10 subjects whose hair undamaged to moderately damaged, in parallel trial (half-side test) with the invention Example 3 and non-inventive Example II treated US Patent 4,299,817.  

To get clear results and from trial Person to subject deviating hair qualities turn off, the hair of the subject became moistened next with water and then in the middle parted. The right half of the hair was, in Dependence on the hair fullness of the subject, with 5 to 15 g of Example 3 of the invention in the usual Way washed (shampooed) while the left Half of the hair each with the same amount of the hair Non-inventive Example II of the US-PS 4,299,817 was washed.

After a hair wash of about 5 minutes, the Hair on both sides of the head of the experiment person rinsed with water, taking care of it Care was taken to flush the hair with water completely separated.

Then each hair half was taken with a Towel dried, combed and then ge dries.

The cleansing action of the hair of the invention cleaning agent according to Example 3 and the Haarreini agent according to Example II of US Patent 4,299,817 was chosen by the hairdressing expert group as equally good, while the combability of the with the Agents of the invention treated hair as better was assessed.

Then the firming effect of the two hair detergent from the hairdressing experts group assessed. The in Table 1 below  given ratings make the individual evaluation obtained mean.

Table 1

The comparative experiment proves that the inventive Hair cleanser according to Example 3 with the same good Cleaning effect a significantly better consolidation of Hair and a better durability of the hairstyle causes as the Haarreini known from US-PS 4,299,817 Means according to Example II.

Comparative experiment B

For comparison concerning the strengthening effect the hair of 10 subjects whose hair was un damaged to moderately damaged, in the Parallelver Such (half-page attempt) each with the invention Hair cleansers according to Examples 1, 2 or 3 on one half side and one of each non-inventive hair cleanser A, B or C on the other half side treated. The non-invented According to the invention hair cleanser A, B and C showed the following compositions:

To get clear results and from trial Person to subject deviating hair qualities turn off, became the hair of the subjects first moistened with water and then in the Parted middle. The right half of the hair became, depending on the hair fullness of the subject,  with 5 to 15 g each one of the invention Hair cleanser according to Examples 1, 2 or 3 washed in the usual way, while the left half of the hair each with the same amount of one of Non-inventive examples A, B or C washed has been.

After a period of shampooing of about 5 minutes The hairs were on both sides of the head of the hair Subject rinsed with water, taking care Care was taken that the rinsing of the hair with Water was completely separated. Subsequently was each half dried with a towel, combed through and then dried, so could the Firming effect of the hair cleanser of one hairdressing expert group become.

An assessment of the strengthening effect was made after the scheme:

rating:
0 no consolidation
- low consolidation
+ good consolidation

The evaluations given in Table 2 below represent the average of the individual weights.

example 1 + Example 2 + Example 3 + Example A 0 Example B 0 Example C 0

The half-side tests according to Comparative Experiment B show that only by the inventive examples 1, 2 and 3 a good setting effect is achieved. Neither the non-inventive hair cleanser according to Example A, which is a combination of anionic Does not contain surfactant and anionic polymer Inventive hair cleanser according to Example B, a combination of anionic surfactant contains ionic polymer and cationic polymer, nor the non-inventive hair cleanser according to Example C, which is a combination of anionic Contains surfactant and average insoluble solid, have a hair-firming effect. The Comparative experiment B shows that, surprisingly only by the inventive combination of the compo (A) to (D) a synergistic effect occurs, which causes a good consolidation of the hair.

All percentages in this application provide as far as Unless otherwise noted, is weight percent.

Claims (12)

1. Liquid hair cleanser, characterized in that it

• (A) 1 to 20% by weight of at least one ionic surfactant,
• (B) 0.1 to 2% by weight of at least one cationic polymer,
• (C) 0.1 to 5 weight percent of at least one 50 to 100 percent neutralized anionic polymer selected from acrylate / acrylamide copolymers, vinyl acetate / crotonic acid copolymers, vinyl acetate / crotonic acid / vinyl neodecanoate copolymers, anionic chitosan derivatives, and Shellac and
• (D) 0.1 to 5% by weight of at least one medium-insoluble solid having a mean grain size of 1 to 200 μm, which is selected from nylon powder, polyethylene powder and polymethyl methacrylate powder,

contains and free of silicone oils and cationic Is surfactants. 2. Composition according to claim 1, characterized that it is 10 to 20 percent by weight of the component (A) contains.   3. Composition according to claim 1 or 2, characterized in that the anionic surfactant of component (A) is selected from

• - The alkali or alkaline earth metal salts of C₁₀- to C₁₈-alkyl sulfates, the C₁₀- to C₁₈-Alkylsulfo nate, the C₁₀- to C₁₈-alkylbenzenesulfonates, the C₁₀- to C₁₈-Xylenesulfonate and ethoxylated with 1 to 10 ethylene oxide units C₁₀- to C₁₈ alkyl ether,
• the ethoxylated sulfosuccinic acid esters of the general formula (I)

wherein R¹ is a C₁₀ to C₁₈ alkyl radical, M is an alkali or alkaline earth metal and m is an integer from 1 to 10, and the Alkylethercarboxylaten of the general formula (II) R² (OCH₂CH₂) _n OCH₂COOM (II), wherein R² a C₁₀ to C₁₈ alkyl radical, M is an alkali or alkaline earth metal and n is an integer from 1 to 20. 4. Composition according to one of claims 1 to 3, characterized characterized in that it is 0.5 to 1.2 weight percent component (B).   5. Composition according to one of claims 1 to 4, characterized characterized in that the cationic polymer of Component (B) is selected from diallyldimethyl ammonium chloride / acrylamide copolymers, with Di methyl sulfate quaternized vinylpyrrolidone / di methylaminoethyl methacrylate copolymers, polymeric quaternary ammonium salts of hydroxyethylcellu Loose and vinylpyrrolidone / methylacrylamidopropyl trimethyl ammonium chloride copolymers. 6. Composition according to one of claims 1 to 5, characterized characterized in that it is 0.3 to 3 weight percent component (C). 7. Composition according to one of claims 1 to 6, characterized characterized in that the anionic polymer of Component (C) to 50 to 100 percent with a Neutralizing agent selected from alkali hydroxide iden, organic amines and alkanolamines neutra is lisiert. 8. Composition according to one of claims 1 to 7, characterized characterized in that it comprises the components (B) and (C) in a weight ratio of (B) :( C) of 1: 2 contains. 9. Composition according to one of claims 1 to 8, characterized characterized in that it is 0.1 to 2 weight percent component (D).   10. Composition according to one of claims 1 to 9, characterized characterized in that the solid of the component (D) a mean grain size of 2 to 40 microns has.