DE4233600C1 - Treatment of plastic wastes contg. metallic or organic impurities - involves washing with aq. alkaline medium to provide material useful as additive for building materials - Google Patents
Treatment of plastic wastes contg. metallic or organic impurities - involves washing with aq. alkaline medium to provide material useful as additive for building materialsInfo
- Publication number
- DE4233600C1 DE4233600C1 DE19924233600 DE4233600A DE4233600C1 DE 4233600 C1 DE4233600 C1 DE 4233600C1 DE 19924233600 DE19924233600 DE 19924233600 DE 4233600 A DE4233600 A DE 4233600A DE 4233600 C1 DE4233600 C1 DE 4233600C1
- Authority
- DE
- Germany
- Prior art keywords
- metallic
- plastic
- additive
- building materials
- treatment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920003023 plastic Polymers 0.000 title claims abstract description 12
- 239000004033 plastic Substances 0.000 title claims abstract description 12
- 239000012535 impurity Substances 0.000 title claims abstract description 6
- 238000005406 washing Methods 0.000 title claims description 8
- 239000000463 material Substances 0.000 title claims description 6
- 239000004566 building material Substances 0.000 title abstract description 4
- 239000002699 waste material Substances 0.000 title abstract 3
- 239000000654 additive Substances 0.000 title abstract 2
- 230000000996 additive effect Effects 0.000 title abstract 2
- 239000007788 liquid Substances 0.000 claims abstract description 6
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 5
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract 6
- 238000000034 method Methods 0.000 claims description 13
- 239000001257 hydrogen Substances 0.000 claims description 5
- 229910052739 hydrogen Inorganic materials 0.000 claims description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- 239000012670 alkaline solution Substances 0.000 claims description 4
- 239000000356 contaminant Substances 0.000 claims description 3
- 239000000243 solution Substances 0.000 claims description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
- 239000007900 aqueous suspension Substances 0.000 claims 1
- 239000011575 calcium Substances 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims 1
- 238000012545 processing Methods 0.000 abstract description 5
- 239000007789 gas Substances 0.000 abstract description 2
- 231100000206 health hazard Toxicity 0.000 abstract description 2
- 238000012432 intermediate storage Methods 0.000 abstract description 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 abstract 1
- 239000000920 calcium hydroxide Substances 0.000 abstract 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 abstract 1
- 235000011116 calcium hydroxide Nutrition 0.000 abstract 1
- 239000000383 hazardous chemical Substances 0.000 abstract 1
- 239000013502 plastic waste Substances 0.000 abstract 1
- 239000000725 suspension Substances 0.000 abstract 1
- 238000011161 development Methods 0.000 description 3
- 230000018109 developmental process Effects 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 230000003466 anti-cipated effect Effects 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000002440 industrial waste Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000012958 reprocessing Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/04—Waste materials; Refuse
- C04B18/18—Waste materials; Refuse organic
- C04B18/20—Waste materials; Refuse organic from macromolecular compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
- B29B17/02—Separating plastics from other materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2/00—Lime, magnesia or dolomite
- C04B2/02—Lime
- C04B2/04—Slaking
- C04B2/06—Slaking with addition of substances, e.g. hydrophobic agents ; Slaking in the presence of other compounds
- C04B2/063—Slaking of impure quick lime, e.g. contained in fly ash
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/14—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
- C04B28/142—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements containing synthetic or waste calcium sulfate cements
- C04B28/144—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements containing synthetic or waste calcium sulfate cements the synthetic calcium sulfate being a flue gas desulfurization product
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/30—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing magnesium cements or similar cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B30/00—Compositions for artificial stone, not containing binders
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B32/00—Artificial stone not provided for in other groups of this subclass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J11/00—Recovery or working-up of waste materials
- C08J11/04—Recovery or working-up of waste materials of polymers
- C08J11/06—Recovery or working-up of waste materials of polymers without chemical reactions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
- B29B17/02—Separating plastics from other materials
- B29B2017/0213—Specific separating techniques
- B29B2017/0286—Cleaning means used for separation
- B29B2017/0289—Washing the materials in liquids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
- B29B17/02—Separating plastics from other materials
- B29B2017/0213—Specific separating techniques
- B29B2017/0293—Dissolving the materials in gases or liquids
- B29B2017/0296—Dissolving the materials in aqueous alkaline solutions, e.g. NaOH or KOH
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2705/00—Use of metals, their alloys or their compounds, for preformed parts, e.g. for inserts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2705/00—Use of metals, their alloys or their compounds, for preformed parts, e.g. for inserts
- B29K2705/02—Aluminium
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00724—Uses not provided for elsewhere in C04B2111/00 in mining operations, e.g. for backfilling; in making tunnels or galleries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/62—Plastics recycling; Rubber recycling
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Mechanical Engineering (AREA)
- Civil Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
Description
Die Erfindung bezieht sich auf ein Verfahren zur Be handlung von Kunststoff-Restmaterial.The invention relates to a method for loading act of residual plastic material.
Es ist bekannt, daß Reststoffe, wie beispielsweise aus Siedlungs- oder Industriemüll aussortierte Kunststoffe, die für eine Wiederverarbeitung zu Gebrauchsartikeln nicht mehr verwendbar sind, als Zuschlag für Baustoffe verarbeitet werden können; derartige Verfahren sind z. B. in der DE 40 00 183 A1 und der DE 42 09 987 A1 be schrieben.It is known that residues, such as from Plastics sorted out from municipal or industrial waste, for reprocessing into consumer goods are no longer usable as a surcharge for building materials can be processed; are such procedures e.g. B. in DE 40 00 183 A1 and DE 42 09 987 A1 be wrote.
Derartige Reststoffe haben oft den Nachteil, daß sie herkunftsbedingt metallische Verunreinigungen enthalten. Soweit es sich um magnetisch abscheidbare Metalle wie Eisen, Nickel und Kobalt handelt, sind diese, insbesondere in zerkleinerter Form, leicht durch starke Magnetab scheider abtrennbar. Andere metallische Bestandteile, wie beispielsweise Kupfer, Aluminium, Zink usw., können dagegen nur in aufwendigen und recht teuren Verfahren mit Wirbelstrom magneten entfernt werden. Der Nachteil einiger metallischer Verunreinigungen besteht nun darin, daß sie, sofern es sich um amphoter reagierende Metalle wie Zink und Aluminium handelt, in basisch angemachten Baustoffen unter Freisetzung von Wasserstoff reagieren und aufgelöst werden. Ein weiterer Nachteil bei der Verarbeitung der eingangs erwähnten Rest stoffe besteht darin, daß sie organische Verunreinigungen enthalten, die über mikrobielle Zersetzungs- und Gärungs vorgänge zu Fäulnis führen, was bei der Lagerung und Ver arbeitung zu Geruchsbelästigung und Gesundheitsschädigung des Arbeitspersonals führen kann.Such residues often have the disadvantage that they due to origin contain metallic impurities. So far as it is about magnetically separable metals like Iron, nickel and cobalt, these are, in particular in shredded form, easily by strong magnet separable separator. Other metallic components, such as for example copper, aluminum, zinc etc., on the other hand, can only in complex and quite expensive processes with eddy current magnets can be removed. The disadvantage of some metallic Contamination now consists in the fact that, if it is are amphoteric reacting metals like zinc and aluminum acts, in basic made building materials with release react from hydrogen and be dissolved. Another Disadvantage in the processing of the rest mentioned above substances is that they are organic contaminants included that have microbial decomposition and fermentation processes lead to putrefaction, which in storage and ver work on odor nuisance and damage to health of the Can lead workers.
Aus der DE 41 05 368 C1 ist ein Verfahren bekannt, bei dem mit Hilfe einer starken Base eine Zellstoffschicht von einer Kunststoffschicht abgelöst wird.From DE 41 05 368 C1 a method is known in which with the help of a strong base a plastic layer is removed.
Die DE 40 23 907 A1 zeigt ein Verfahren, bei dem ein mit biologischem Material verunreinigtes Polymer in einem alkalischen Medium aufgelöst wird.DE 40 23 907 A1 shows a method in which a biologically contaminated polymer in one alkaline medium is dissolved.
Aus der EP 03 59 106 A2 ist es bekannt, verschmutzte Kunststoffprodukte zum Durchführen eines Waschvorgangs kontinuierlich auf der einen Seite eines eine Waschlösung enthaltenden Gefäßes zuzuführen und auf der gegenüber liegenden Seite auszutragen sowie die Waschflüssigkeit im Umlauf zu führen.From EP 03 59 106 A2 it is known to be soiled Plastic products for washing continuously on one side of a wash solution containing the vessel and on the opposite discharge side and the washing liquid to circulate.
Ausgehend von dem vorstehend geschilderten Stand der Technik liegt der Erfindung die Aufgabe zugrunde, ein Ver fahren zur Behandlung von metallische und organische Ver unreinigungen enthaltendem Kunststoff-Restmaterial zur Verfügung zu stellen, bei dem sowohl die bei der end gültigen Verarbeitung entstehende Gasentwicklung als auch die bei der Zwischenlagerung und Verarbeitung auftretende Geruchsbelästigung und Gesundheitsgefährdung durch die vorstehend geschilderten Fäulnisvorgänge reduziert bzw. behoben sind.Based on the status of Technology, the invention has for its object a Ver drive to treat metallic and organic ver plastic residues containing impurities To make available both those at the end gas processing as well as valid processing the one that occurs during intermediate storage and processing Odor nuisance and health hazard from the decay processes described above are reduced or are fixed.
Diese Aufgabe wird erfindungsgemäß gelöst, indem das Kunststoff-Restmaterial in einer wäßrigen, alkalischen Lösung, deren pH-Wert größer 12 beträgt, gewaschen wird, wobei die metallischen Verunreinigungen unter Wasser stoffbildung aufgelöst werden. Das Kunststoff-Restmaterial wird während des ohnehin nach der Sortierung notwendigen Waschvorgangs mit der wäßrigen, alkalischen Lösung behandelt, welche sowohl die metallische Auflösung und die damit ver bundene Wasserstoffentwicklung wie auch die mikrobiell be dingten Fäulnisvorgänge derart günstig beeinflußt, daß die zur Wasserstoffbildung führenden Metalle aufgelöst und die die Fäulnis bedingenden Mikroorganismen abgetötet werden. Wesentlich hierfür ist, daß die wäßrige, alkalische Lösung einen pH-Wert hat, der größer als 12 ist. Hierdurch wird einerseits die Wasserstoffentwicklung vorweggenommen und andererseits die Fäulnisbildung durch Abtötung der Mikro organismen vermieden.This object is achieved by the Plastic residual material in an aqueous, alkaline Solution whose pH is greater than 12 is washed, taking the metallic contaminants under water substance formation can be resolved. The plastic residual material will be necessary during the sorting anyway Treated with the aqueous alkaline solution, which both the metallic resolution and the ver bound hydrogen development as well as microbially related rotting processes so favorably influenced that the Dissolving metals leading to hydrogen formation the microorganisms causing the putrefaction are killed. It is essential that the aqueous, alkaline solution has a pH greater than 12. This will on the one hand anticipated the development of hydrogen and on the other hand, putrefaction by killing the micro organisms avoided.
Vorteilhafte Weiterbildungen der Erfindung ergeben sich aus den Unteransprüchen.Advantageous developments of the invention result from the subclaims.
Claims (5)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19924233600 DE4233600C1 (en) | 1992-10-06 | 1992-10-06 | Treatment of plastic wastes contg. metallic or organic impurities - involves washing with aq. alkaline medium to provide material useful as additive for building materials |
| DE19934323865 DE4323865C2 (en) | 1992-10-06 | 1993-07-16 | Process for the treatment of plastic residues |
| DE19934325595 DE4325595C2 (en) | 1992-10-06 | 1993-07-30 | Process for the treatment of plastic residues containing metallic and organic contaminants |
| EP19930116006 EP0591895A3 (en) | 1992-10-05 | 1993-10-04 | Building, stowing, or filling material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19924233600 DE4233600C1 (en) | 1992-10-06 | 1992-10-06 | Treatment of plastic wastes contg. metallic or organic impurities - involves washing with aq. alkaline medium to provide material useful as additive for building materials |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE4233600C1 true DE4233600C1 (en) | 1994-03-03 |
Family
ID=6469767
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19924233600 Expired - Fee Related DE4233600C1 (en) | 1992-10-05 | 1992-10-06 | Treatment of plastic wastes contg. metallic or organic impurities - involves washing with aq. alkaline medium to provide material useful as additive for building materials |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE4233600C1 (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4325595A1 (en) * | 1992-10-06 | 1995-02-02 | Hoelter Heinz | Building material with deformable properties for underground mining |
| EP0710632A1 (en) * | 1994-06-14 | 1996-05-08 | Haden Schweitzer Corporation | Process for producing building materials from paint sludge |
| DE10102554A1 (en) * | 2001-01-19 | 2002-07-25 | Heinrich Rott | Separating aluminum-containing composites, e.g. for recycling packaging materials, involves treatment with alkali solution to dissolve aluminum and precipitate other materials |
| WO2004022503A1 (en) * | 2002-09-04 | 2004-03-18 | Purcrete Limited | Polyurethane-containing building materials |
| WO2006079911A1 (en) * | 2005-01-26 | 2006-08-03 | Omya Development Ag | Method for controlling microbial contamination, mineral suspensions obtained and uses thereof |
| WO2009087079A2 (en) | 2008-01-04 | 2009-07-16 | Weingart Und Kubrat Gmbh | Process for utilizing aluminium in waste materials, in particular in combination with other substances |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0359106A2 (en) * | 1988-09-12 | 1990-03-21 | HERBOLD GMBH Maschinenfabrik | Method of recovering and recycling polluted plastics |
| DE4023907A1 (en) * | 1990-07-27 | 1992-01-30 | Belland Ag | METHOD FOR TREATING AND CLEANING SOLUBLE SOLVABLE IN ALKALINE MEDIUM, WITH BIOLOGICAL MATERIAL AND POTENTIAL. OTHER SUBSTANCES POLYSED |
| DE4105368C1 (en) * | 1991-02-21 | 1992-05-07 | Papierfabrik Schoellershammer Heinr. Aug. Schoeller Soehne Gmbh & Co Kg, 5160 Dueren, De | Handling photographic paper having plastic coating - includes dissolving cellular material from plastic using strong base |
| DE4209987A1 (en) * | 1992-03-27 | 1993-09-30 | Hoelter Heinz | Process for the disposal and economic use of solids from industrial recycling processes |
-
1992
- 1992-10-06 DE DE19924233600 patent/DE4233600C1/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0359106A2 (en) * | 1988-09-12 | 1990-03-21 | HERBOLD GMBH Maschinenfabrik | Method of recovering and recycling polluted plastics |
| DE4023907A1 (en) * | 1990-07-27 | 1992-01-30 | Belland Ag | METHOD FOR TREATING AND CLEANING SOLUBLE SOLVABLE IN ALKALINE MEDIUM, WITH BIOLOGICAL MATERIAL AND POTENTIAL. OTHER SUBSTANCES POLYSED |
| DE4105368C1 (en) * | 1991-02-21 | 1992-05-07 | Papierfabrik Schoellershammer Heinr. Aug. Schoeller Soehne Gmbh & Co Kg, 5160 Dueren, De | Handling photographic paper having plastic coating - includes dissolving cellular material from plastic using strong base |
| DE4209987A1 (en) * | 1992-03-27 | 1993-09-30 | Hoelter Heinz | Process for the disposal and economic use of solids from industrial recycling processes |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4325595A1 (en) * | 1992-10-06 | 1995-02-02 | Hoelter Heinz | Building material with deformable properties for underground mining |
| EP0710632A1 (en) * | 1994-06-14 | 1996-05-08 | Haden Schweitzer Corporation | Process for producing building materials from paint sludge |
| DE10102554A1 (en) * | 2001-01-19 | 2002-07-25 | Heinrich Rott | Separating aluminum-containing composites, e.g. for recycling packaging materials, involves treatment with alkali solution to dissolve aluminum and precipitate other materials |
| WO2004022503A1 (en) * | 2002-09-04 | 2004-03-18 | Purcrete Limited | Polyurethane-containing building materials |
| WO2006079911A1 (en) * | 2005-01-26 | 2006-08-03 | Omya Development Ag | Method for controlling microbial contamination, mineral suspensions obtained and uses thereof |
| US8877127B2 (en) | 2005-01-26 | 2014-11-04 | Omya International Ag | Process for control of microbial contamination, mineral suspensions obtained and their uses |
| US8889068B2 (en) | 2005-01-26 | 2014-11-18 | Omya International Ag | Method for controlling microbial contamination, mineral suspensions obtained and uses thereof |
| WO2009087079A2 (en) | 2008-01-04 | 2009-07-16 | Weingart Und Kubrat Gmbh | Process for utilizing aluminium in waste materials, in particular in combination with other substances |
| WO2009087079A3 (en) * | 2008-01-04 | 2010-03-04 | Weingart Und Kubrat Gmbh | Process for utilizing aluminium in waste materials, in particular in combination with other substances |
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