DE402616C - Siccatives, linseed oil substitute and substitute for oxidizing linseed oils - Google Patents
Siccatives, linseed oil substitute and substitute for oxidizing linseed oilsInfo
- Publication number
- DE402616C DE402616C DEJ20922D DEJ0020922D DE402616C DE 402616 C DE402616 C DE 402616C DE J20922 D DEJ20922 D DE J20922D DE J0020922 D DEJ0020922 D DE J0020922D DE 402616 C DE402616 C DE 402616C
- Authority
- DE
- Germany
- Prior art keywords
- substitute
- linseed
- linseed oil
- siccatives
- oxidizing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000944 linseed oil Substances 0.000 title claims description 26
- 235000021388 linseed oil Nutrition 0.000 title claims description 21
- 230000001590 oxidative effect Effects 0.000 title claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 7
- 239000002184 metal Substances 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 239000002966 varnish Substances 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 150000002739 metals Chemical class 0.000 claims description 3
- 230000001603 reducing effect Effects 0.000 claims description 3
- 150000001642 boronic acid derivatives Chemical class 0.000 claims description 2
- 150000002894 organic compounds Chemical class 0.000 claims description 2
- 239000003960 organic solvent Substances 0.000 claims 1
- 238000001035 drying Methods 0.000 description 7
- 150000002736 metal compounds Chemical class 0.000 description 7
- 239000002253 acid Substances 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910021538 borax Inorganic materials 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000004328 sodium tetraborate Substances 0.000 description 3
- 235000010339 sodium tetraborate Nutrition 0.000 description 3
- RSWGJHLUYNHPMX-UHFFFAOYSA-N 1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylic acid Chemical compound C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000002274 desiccant Substances 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- HKOOXMFOFWEVGF-UHFFFAOYSA-N phenylhydrazine Chemical compound NNC1=CC=CC=C1 HKOOXMFOFWEVGF-UHFFFAOYSA-N 0.000 description 2
- 229940067157 phenylhydrazine Drugs 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000001293 FEMA 3089 Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 235000004431 Linum usitatissimum Nutrition 0.000 description 1
- 240000006240 Linum usitatissimum Species 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- SVMCDCBHSKARBQ-UHFFFAOYSA-N acetic acid;cobalt Chemical compound [Co].CC(O)=O SVMCDCBHSKARBQ-UHFFFAOYSA-N 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 150000001868 cobalt Chemical class 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 235000004426 flaxseed Nutrition 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000000320 mechanical mixture Substances 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09F—NATURAL RESINS; FRENCH POLISH; DRYING-OILS; OIL DRYING AGENTS, i.e. SICCATIVES; TURPENTINE
- C09F9/00—Compounds to be used as driers, i.e. siccatives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Fats And Perfumes (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Description
Sikkative, Leinölfirnisersatz und Ersatz für oxydierende Leinöle. Bisher wurden Sikkative unter Zuhilfenahme harzsaurer, leinölsaurer, borsaurer usw. Verbindungen hergestellt. Diese Trockner übernehmen dann bei der Herstellung von Sikkativen usw. die Rolle von Katalysatoren, und die Oxydation der trocknenden Olsäure besteht nicht nur in der Sättigung der freien Valenzen durch Sauerstoff, sondern es schiebt sich noch Sauerstoff zwischen Kohlenstoff und Wasserstoff ein (vgl. Chemie der trocknenden Öle Dr. M. Fahrion S. 164, 1g6). Bis jetzt ist kein Verfahren bekannt geworden, welches ohne die obenerwähnten Zwischenträger, wie Harz, Leinöl, Borax usw., praktisch arbeiten könnte.Siccatives, linseed oil substitute and substitute for oxidizing linseed oils. So far, siccatives have been used with the help of resinous, linseed, boric, etc. Connections made. These dryers then take over in the manufacture of Siccatives, etc., the role of catalysts, and the oxidation of drying oleic acid consists not only in the saturation of the free valences with oxygen, but there is still oxygen between carbon and hydrogen (see chemistry of the drying oils Dr. M. Fahrion p. 164, 1g6). No method is known up to now become, which without the above-mentioned intermediate carriers, such as resin, linseed oil, borax etc., could work practically.
Es ist bekannt, daß mit Hilfe von Ölen und Aluminiumchlorid factisähnliche Massen hergestellt werden können, die höchstens als mechanisches Verdickungsmittel, aber nicht als Sikkative Verwendung finden können, da ihnen eine Trockenfähigkeit nicht zukommt.It is known that factis-like with the help of oils and aluminum chloride Masses can be produced that are at most used as mechanical thickeners, but cannot be used as siccatives, as they have a drying capacity does not apply.
Nun sind zwar durch die Patentschrift 201966 Massen bekannt geworden, die als Unterlage für Lacke und Kitte sozusagen in Form eines festen Sikkaiivs Verwendung finden können. Die nach diesem Patent erhaltenen Produkte stellen jedoch keine einheitlich zusammengesetzten Körper dar, sondern sie sind mechanische Gemengsel von fein verteilten und großen Metallmengen, in denen das Metall die Rolle eines Substrates spielt. Das Vorgesagte gilt auch für die in dem Werke von Bott 1 e r »Die Trockenmittel« erwähnten festen Sikkativ-Extrakte. Die in dem gleichen Werke erwähnte Verwendung von essigsaurem Cobalt zur Fabrikation wasserheller Firnisse hat insofern für die Praxis keine Bedeutung erlangt, als die Ausnutzung dieser Metallverbindungen bei der beschriebenen Arbeitsweise eine sehr schlechte ist und die Hauptmenge der Metallverbindung in Form verschiedentlich oxydierter Produkte als Bodensatz sich der gewünschten Reaktion entzieht, so daß stark verunreinigte Firnisse erhalten werden, die hinsichtlich ihrer Trockenfähigkeit zu den angewandten Metallsalzmengen in keinem Verhältnis stehen.Now masses have become known through the patent specification 201966, which are used as a base for paints and putties, so to speak, in the form of a solid Sikkaiiv can find. However, the products obtained according to this patent are not uniform composite bodies, but they are mechanical mixtures of finely divided bodies and large amounts of metal in which the metal plays the role of a substrate. The foregoing also applies to the in the work of Bott 1 e r "The drying agents" mentioned solid siccative extracts. The use mentioned in the same work of acetic acid cobalt for the manufacture of water-white varnishes has so far for the Practice has no significance other than taking advantage of these metal compounds the procedure described is a very poor one and the bulk of the metal compound in the form of variously oxidized products as sediments Removes reaction, so that highly contaminated varnishes are obtained, which in terms of their drying ability to the applied metal salt amounts in no relation stand.
Es wurde nun demgegenüber die bemerkenswerte Beobachtung gemacht, daß Sikkative, Leinölfirnisersatz und Ersatz für oxydierende Leinöle von stark trocknenden Eigenschaften in bequemer Weise durch Überführung von Metallen oder deren Verbindungen in eine fein verteilte bzw. kolloidale Form direkt in Leinöl usw. unter vollkommener Ausschaltung eines Zwischenkörpers erhalten werden können.On the other hand, the remarkable observation was made, that siccatives, linseed oil varnish substitute and substitute for oxidizing linseed oils of strongly drying ones Properties in a convenient way by converting metals or their compounds in a finely divided or colloidal form directly in linseed oil etc. under perfect Elimination of an intermediate body can be obtained.
Das Verfahren besteht darin, daß z. B. Metallverbindungen in Leinöl usw. aufgeschwemmt mit Spuren von reduzierend wirkenden organischen Verbindungen versetzt erhitzt werden. Die Feuchtigkeit des Leinöls bzw. der Kristallwassergehalt der Metallverbindungen genügen meist, um deren stark reduzierende Eigenschaften bzw. ihre Fähigkeit, kolloidale Lösungen zu erzeugen, auszunutzen. Auch können solche fein verteilte bzw. kolloidale Verbindungen unter Zuhilfenahme des elektrischen Stromes durch direkte Zerstäubung in Leinöl usw. erhalten werden.The method consists in that e.g. B. Metal compounds in linseed oil etc. bloated with traces of reducing organic compounds be heated offset. The moisture of the linseed oil or the water of crystallization of the metal compounds are usually sufficient to reduce their strongly reducing properties or their ability to generate colloidal solutions. Such finely divided or colloidal compounds can also be used with the aid of the electric current can be obtained by direct atomization in linseed oil, etc.
Die auftretenden chemischen und physikalischen Vorgänge beeinflussen das Leinöl für den späteren Trockenprozeß in denkbar bester `'eise. Die fein verteilten Metallverbindungen bzw. Kolloide werden sofort im Entstehungszustand von dem Leinöl eingehüllt, vor der Oxydation geschützt und machen nachher das Leinöl sozusagen porös und schwammartig. Dem Sauerstoff werden dann bei dünnen Schichten große Angriffsflächen geboten. Die so hergestellten Verbindungen stellen das Ideal eines Trockners dar, in dem die beste Sauerstoffübertragung unter Vermeidung der üblichen Zwischenträger, wie Harz, Leinöl, Borax usw., gewährleistet ist. Dadurch werden gewisse unangenehme Eigenschaften, wie z. B. das Nachkleben harzsaurer Trockner hei wesentlicher Ersparnis an Chemikalien, Energie und Arbeitskraft behoben. Des weiteren können diese neuartigen Trockner in beliebig hochkonzentrierter Form (Extrakten) erhalten werden, was bei den harzsauren, leinölsauren, barsauren usw. Verbindungen nicht möglich ist, wo das Metall nur befähigt erscheint, sich in molekularem Verhältnis mit dem Zwischenträger umzusetzeig und die Löslichkeit dieser Verbindungen in Leinöl eine beschränkte ist.Influence the occurring chemical and physical processes the linseed oil for the subsequent drying process in the best possible way. The finely divided Metal compounds or colloids are immediately removed from the linseed oil as it is formed enveloped, protected from oxidation and afterwards make the linseed oil, so to speak porous and spongy. In the case of thin layers, the oxygen then becomes large areas of attack commanded. The connections made in this way represent the ideal of a dryer, in which the best oxygen transfer while avoiding the usual intermediate carriers, such as resin, linseed oil, borax, etc., is guaranteed. This makes certain uncomfortable Properties such as B. re-gluing resin-acid dryers hot substantial savings fixed in chemicals, energy and manpower. Furthermore, these can be novel Dryer in any highly concentrated form (extracts) can be obtained, which is at the resin acid, linseed oil acid, bar acid etc. compounds are not possible where the metal only appears capable of being in molecular relationship with the intermediate carrier and the solubility of these compounds in linseed oil is limited.
Natürlich können diese neuen - keinen Zwischenträger enthaltenden - Trockenstoffe allein oder in Mischungen mit Oleaten, Resinaten, Boraten usw. ohne oder unter Zuhilfenahme von geeigneten Lösungsmitteln als Sikkative, Leinölfirnisersatz oder Ersatz für oxydierende Leinöle verwendet werden. Die daraus hergestellten Aufstriche, Drucklacke, Films usw., können bezüglich ihrer Trockenfähigkeit den harzsauren, leinölsauren, barsauren usw. Metallverbindungen, wie diese durch Umsetzung von Harzseife, Leinölseife, Borax usw. mit Metallverbindungen erhalten werden, nicht nur gleichgestellt werden, sondern sind diesen überlegen.Of course, these can be new - not containing an intermediate carrier - Drying agents alone or in mixtures with oleates, resinates, borates etc. without or with the aid of suitable solvents as siccatives or as a substitute for linseed oil or as a substitute for oxidising linseed oils. The spreads made from it, In terms of their drying properties, printing varnishes, films, etc. linoleum acid, bar acid, etc. metal compounds, such as these by conversion of resin soap, Linseed oil soap, borax, etc. with metal compounds are obtained, not just assimilated but are superior to them.
Die Erfindung wird in nachstehenden Beispielen näher beschrieben: Beispiel i.The invention is described in more detail in the following examples: Example i.
o,6 g eines Cobaltsalzes werden in ioo g Leinöl aufgeschwemmt mit o,2 g Phenylhydrazin versetzt und am besten unter Rühren eine Stunde auf i2o° C erhitzt.0.6 g of a cobalt salt are suspended in 100 g of linseed oil 0.2 g of phenylhydrazine are added and it is best to keep stirring for one hour at 130 ° C heated.
Beispiel 2.Example 2.
Metalle bzw. deren Verbindungen werden unter Zuhilfenahme des elektrischen Stromes in Leinöl zerstäubt und in fein verteilte kolloidale Form gebracht.Metals or their compounds are made with the help of the electrical Stromes atomized in linseed oil and brought into finely divided colloidal form.
Beispiel 3. Example 3.
Eine Mischung von ioo Teilen Terpentinöl und ioo Teilen Leinöl wird unter gutem Rühren mit i g Zinksulfat versetzt und o,2 g Phenylhydrazin zugefügt und etwa eine Stunde auf 120' C erhitzt.A mixture of 100 parts turpentine oil and 100 parts linseed oil will be used i g of zinc sulfate are added with thorough stirring and 0.2 g of phenylhydrazine is added and heated to 120 ° C for about an hour.
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEJ20922D DE402616C (en) | 1920-11-06 | 1920-11-06 | Siccatives, linseed oil substitute and substitute for oxidizing linseed oils |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEJ20922D DE402616C (en) | 1920-11-06 | 1920-11-06 | Siccatives, linseed oil substitute and substitute for oxidizing linseed oils |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE402616C true DE402616C (en) | 1924-09-17 |
Family
ID=7200395
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEJ20922D Expired DE402616C (en) | 1920-11-06 | 1920-11-06 | Siccatives, linseed oil substitute and substitute for oxidizing linseed oils |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE402616C (en) |
-
1920
- 1920-11-06 DE DEJ20922D patent/DE402616C/en not_active Expired
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