DE4015555A1 - Synthetic active carbon e.g. for water purificn. - prepd. by introducing fine pored carbon into coarse pores of inert matrix material - Google Patents
Synthetic active carbon e.g. for water purificn. - prepd. by introducing fine pored carbon into coarse pores of inert matrix materialInfo
- Publication number
- DE4015555A1 DE4015555A1 DE19904015555 DE4015555A DE4015555A1 DE 4015555 A1 DE4015555 A1 DE 4015555A1 DE 19904015555 DE19904015555 DE 19904015555 DE 4015555 A DE4015555 A DE 4015555A DE 4015555 A1 DE4015555 A1 DE 4015555A1
- Authority
- DE
- Germany
- Prior art keywords
- carbon
- active carbon
- prepd
- inert matrix
- matrix material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 12
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 7
- 239000011159 matrix material Substances 0.000 title claims abstract description 7
- 239000011148 porous material Substances 0.000 title claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title description 3
- 239000004927 clay Substances 0.000 claims abstract description 4
- 239000008187 granular material Substances 0.000 claims abstract description 3
- 150000004760 silicates Chemical class 0.000 claims abstract description 3
- 239000000203 mixture Substances 0.000 claims description 4
- 239000010457 zeolite Substances 0.000 claims description 4
- 238000004061 bleaching Methods 0.000 claims description 2
- 239000011505 plaster Substances 0.000 claims description 2
- 238000000034 method Methods 0.000 claims 3
- 239000000463 material Substances 0.000 abstract description 3
- 238000005299 abrasion Methods 0.000 abstract description 2
- 229910052793 cadmium Inorganic materials 0.000 abstract description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical class O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract description 2
- 239000003651 drinking water Substances 0.000 abstract description 2
- 235000020188 drinking water Nutrition 0.000 abstract description 2
- 239000000975 dye Substances 0.000 abstract description 2
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 2
- 229910052753 mercury Inorganic materials 0.000 abstract description 2
- 239000000575 pesticide Substances 0.000 abstract description 2
- 230000002285 radioactive effect Effects 0.000 abstract description 2
- 239000000356 contaminant Substances 0.000 abstract 1
- 239000010440 gypsum Substances 0.000 abstract 1
- 229910052602 gypsum Inorganic materials 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 229910010272 inorganic material Inorganic materials 0.000 abstract 1
- 239000011147 inorganic material Substances 0.000 abstract 1
- 229910052745 lead Inorganic materials 0.000 abstract 1
- 231100000331 toxic Toxicity 0.000 abstract 1
- 230000002588 toxic effect Effects 0.000 abstract 1
- 239000003245 coal Substances 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 231100000816 toxic dose Toxicity 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Water Treatment By Sorption (AREA)
- Carbon And Carbon Compounds (AREA)
Abstract
Synthetic active carbon is prepd. by introducing a fine pored form of the carbon into the coarse pores of an inert matrix material. The matrix is e.g. of a mixt. of clay, gypsum, porous silicates, fuller's earth, natural or synthetic zeolites with montmorrilonites in a ratio of 10-70%. Pref. the mixt. is formed into spheres or granules and activated by heating to 700 deg.C under an inert atmos. USE/ADVANTAGE - Prods. have better abrasion resistance than conventional active carbon. Esp. useful for purificn. of drinking water e.g. to remove contaminants e.g. toxic concns. of Pb, Cd and Hg and other adsorbable materials e.g. pesticides and dyes and inorganic materials e.g. heavy metals and radioactive elements.
Description
Die Verwendung von feinporigen Erscheinungsformen der Kohlenstoffe innerhalb der groben Poren einer inerten Matrix wurde schon in der Patentanmeldung P 39 19 567.8 beschrieben. Es wurde jetzt festgestellt, daß die grobporige inerte Matrix aus Mischungen von Bleicherde, Zeolithen (natürlicher oder synthetischer Art), mit Ton, Gips, porösen Silikaten oder grobporiger Holzkohle, Steinkohle, porösen Kunststoffen jeder Art, oder jeder Sorte Ruß, bestehen kann. Erhebliche Verbesserungen der Adsorptionskraft solcher künstlicher aktiver Kohle wurde festgestellt. Im Falle von Mischungen von Zeolithen z. B. sind zusätzliche Ionenaustauscheigenschaften anwesend. Der Erfindung liegt daher die Aufgabe zugrunde, die Entfernung nicht nur von adsorbierbaren Stoffen aus Wasser, sondern auch die Adsorption von anorganischen Giften, wie z. B. Schwermetalle oder radioaktive Elemente.The use of fine-pored forms of carbon within the Coarse pores of an inert matrix have already been described in patent application P 39 19 567.8 described. It has now been found that the coarse pore inert matrix is made up of mixtures of bleaching earth, zeolites (natural or synthetic), with clay, plaster, porous Silicates or coarse-pored charcoal, hard coal, porous plastics of any kind, or any kind of soot can exist. Significant improvements in the adsorption power of such Artificial active coal has been found. In the case of mixtures of zeolites z. B. additional ion exchange properties are present. The invention is therefore the Task, the removal not only of adsorbable substances from water, but also the adsorption of inorganic poisons, such as. B. heavy metals or radioactive elements.
Durchfeuchteter Ton (50 g) wurde mit 3 g Ruß und 10 g synthetischem Zeolith, wie z. B. "Wessalith P", der Firma Degussa, vermischt. Aus dieser Masse wurden Kügelchen oder Granulat geformt. Nach Verbrennung bei 700° Celsius in Stickstoff-Atmosphäre erhält man das gewünschte Material, welches abriebfest, und daher besser geeignet, als gewöhnliche Aktivkohle ist. Das Material entfernt z. B. giftige Konzentrationen von Blei, Cadmium und Quecksilber aus Trinkwasser. Ferner wurde eine Senkung des Härtegrades des Wassers beobachtet. Pestizide und andere adsorbierbare Stoffe, sowie Farbstoffe, wurden auch grundsätzlich entfernt.Moistened clay (50 g) was treated with 3 g of carbon black and 10 g of synthetic zeolite, such as. B. "Wessalith P" from Degussa. From this mass, beads or Shaped granules. After combustion at 700 ° Celsius in a nitrogen atmosphere, one obtains the desired material, which is abrasion-resistant and therefore more suitable than ordinary Activated carbon is. The material removes e.g. B. toxic concentrations of lead, cadmium and Mercury from drinking water. There was also a decrease in the hardness of the water observed. Pesticides and other adsorbable substances, as well as dyes, have also been basically removed.
Claims (3)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19893919567 DE3919567C2 (en) | 1989-06-15 | 1989-06-15 | Process for the preparation of an adsorbent |
| DE19904015555 DE4015555A1 (en) | 1989-06-15 | 1990-05-15 | Synthetic active carbon e.g. for water purificn. - prepd. by introducing fine pored carbon into coarse pores of inert matrix material |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19893919567 DE3919567C2 (en) | 1989-06-15 | 1989-06-15 | Process for the preparation of an adsorbent |
| DE19904015555 DE4015555A1 (en) | 1989-06-15 | 1990-05-15 | Synthetic active carbon e.g. for water purificn. - prepd. by introducing fine pored carbon into coarse pores of inert matrix material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE4015555A1 true DE4015555A1 (en) | 1991-11-21 |
Family
ID=25881968
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19893919567 Expired - Fee Related DE3919567C2 (en) | 1989-06-15 | 1989-06-15 | Process for the preparation of an adsorbent |
| DE19904015555 Withdrawn DE4015555A1 (en) | 1989-06-15 | 1990-05-15 | Synthetic active carbon e.g. for water purificn. - prepd. by introducing fine pored carbon into coarse pores of inert matrix material |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19893919567 Expired - Fee Related DE3919567C2 (en) | 1989-06-15 | 1989-06-15 | Process for the preparation of an adsorbent |
Country Status (1)
| Country | Link |
|---|---|
| DE (2) | DE3919567C2 (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4238142A1 (en) * | 1992-11-12 | 1994-05-19 | Hasso Von Bluecher | Self-supporting porous bodies with adsorbent properties - contain spherical adsorber particles, e.g. active carbon, linked with bridges, e.g. of clay, carbon etc, with voids between particles |
| WO1994016811A1 (en) * | 1993-01-27 | 1994-08-04 | Syracuse University | Activated carbons molecularly engineered |
| FR2718126A1 (en) * | 1994-03-30 | 1995-10-06 | Heidenreich Hans | Clay and carbon prod. for treatment of aq. effluents |
| WO1998036830A1 (en) * | 1997-02-21 | 1998-08-27 | Engelhard Corporation | Composite material based on zeolite and active carbon, preparation and use thereof in water treatment |
| WO1998036831A1 (en) * | 1997-02-21 | 1998-08-27 | Engelhard Corporation | Composite material based on zeolite and active carbon, preparation and use thereof in water treatment |
| CN105170094A (en) * | 2015-07-31 | 2015-12-23 | 广西壮族自治区环境保护科学研究院 | Modification method for active carbon and applications |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL7203046A (en) * | 1972-03-08 | 1973-09-11 |
-
1989
- 1989-06-15 DE DE19893919567 patent/DE3919567C2/en not_active Expired - Fee Related
-
1990
- 1990-05-15 DE DE19904015555 patent/DE4015555A1/en not_active Withdrawn
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4238142A1 (en) * | 1992-11-12 | 1994-05-19 | Hasso Von Bluecher | Self-supporting porous bodies with adsorbent properties - contain spherical adsorber particles, e.g. active carbon, linked with bridges, e.g. of clay, carbon etc, with voids between particles |
| WO1994016811A1 (en) * | 1993-01-27 | 1994-08-04 | Syracuse University | Activated carbons molecularly engineered |
| US5385876A (en) * | 1993-01-27 | 1995-01-31 | Syracuse University | Activated carbons molecularly engineered |
| AU673902B2 (en) * | 1993-01-27 | 1996-11-28 | Syracuse University | Activated carbons molecularly engineered |
| FR2718126A1 (en) * | 1994-03-30 | 1995-10-06 | Heidenreich Hans | Clay and carbon prod. for treatment of aq. effluents |
| WO1998036830A1 (en) * | 1997-02-21 | 1998-08-27 | Engelhard Corporation | Composite material based on zeolite and active carbon, preparation and use thereof in water treatment |
| WO1998036831A1 (en) * | 1997-02-21 | 1998-08-27 | Engelhard Corporation | Composite material based on zeolite and active carbon, preparation and use thereof in water treatment |
| US6107354A (en) * | 1997-02-21 | 2000-08-22 | Engelhard Corporation | Composite material, preparation and use thereof |
| CN105170094A (en) * | 2015-07-31 | 2015-12-23 | 广西壮族自治区环境保护科学研究院 | Modification method for active carbon and applications |
Also Published As
| Publication number | Publication date |
|---|---|
| DE3919567A1 (en) | 1990-12-20 |
| DE3919567C2 (en) | 1997-07-31 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| AF | Is addition to no. |
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| 8127 | New person/name/address of the applicant |
Owner name: AFFONSO, ALVARO, PROF. DR., 61348 BAD HOMBURG, DE |
|
| 8181 | Inventor (new situation) |
Free format text: AFFONSO, BETTINA, 61348 BAD HOMBURG, DE |
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| AF | Is addition to no. |
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| 8141 | Disposal/no request for examination |