DE29923520U1 - Oxidation hair dye - Google Patents
Oxidation hair dyeInfo
- Publication number
- DE29923520U1 DE29923520U1 DE29923520U DE29923520U DE29923520U1 DE 29923520 U1 DE29923520 U1 DE 29923520U1 DE 29923520 U DE29923520 U DE 29923520U DE 29923520 U DE29923520 U DE 29923520U DE 29923520 U1 DE29923520 U1 DE 29923520U1
- Authority
- DE
- Germany
- Prior art keywords
- component
- weight
- percent
- agent according
- glycol ether
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000118 hair dye Substances 0.000 title description 12
- 230000003647 oxidation Effects 0.000 title description 9
- 238000007254 oxidation reaction Methods 0.000 title description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 27
- 239000000126 substance Substances 0.000 claims description 25
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 21
- 239000000975 dye Substances 0.000 claims description 20
- 239000007788 liquid Substances 0.000 claims description 20
- 229920001451 polypropylene glycol Polymers 0.000 claims description 20
- 229920001223 polyethylene glycol Polymers 0.000 claims description 18
- 229920001577 copolymer Polymers 0.000 claims description 15
- 239000007800 oxidant agent Substances 0.000 claims description 15
- 239000002202 Polyethylene glycol Substances 0.000 claims description 14
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 14
- 238000004043 dyeing Methods 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 13
- 150000001875 compounds Chemical class 0.000 claims description 11
- 230000001590 oxidative effect Effects 0.000 claims description 11
- 150000001413 amino acids Chemical class 0.000 claims description 10
- NLMKTBGFQGKQEV-UHFFFAOYSA-N 2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-(2-hexadecoxyethoxy)ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethanol Chemical compound CCCCCCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO NLMKTBGFQGKQEV-UHFFFAOYSA-N 0.000 claims description 8
- ICIDSZQHPUZUHC-UHFFFAOYSA-N 2-octadecoxyethanol Chemical compound CCCCCCCCCCCCCCCCCCOCCO ICIDSZQHPUZUHC-UHFFFAOYSA-N 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- 229940056318 ceteth-20 Drugs 0.000 claims description 8
- 239000000839 emulsion Substances 0.000 claims description 8
- 229940100459 steareth-20 Drugs 0.000 claims description 8
- 125000000129 anionic group Chemical group 0.000 claims description 7
- 150000002191 fatty alcohols Chemical class 0.000 claims description 6
- 150000003839 salts Chemical class 0.000 claims description 6
- 229920002125 Sokalan® Polymers 0.000 claims description 4
- 238000010168 coupling process Methods 0.000 claims description 4
- 238000005859 coupling reaction Methods 0.000 claims description 4
- 239000002243 precursor Substances 0.000 claims description 4
- 239000000982 direct dye Substances 0.000 claims description 3
- 239000004480 active ingredient Substances 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims 2
- 238000004040 coloring Methods 0.000 claims 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 25
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 16
- -1 5-Amino-saücylsäure Chemical compound 0.000 description 13
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 12
- 239000007864 aqueous solution Substances 0.000 description 8
- 239000000047 product Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 235000001014 amino acid Nutrition 0.000 description 6
- 229910021529 ammonia Inorganic materials 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 5
- 108010009736 Protein Hydrolysates Proteins 0.000 description 5
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 239000003531 protein hydrolysate Substances 0.000 description 5
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 5
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- GUQPDKHHVFLXHS-UHFFFAOYSA-M sodium;2-(2-dodecoxyethoxy)ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOS([O-])(=O)=O GUQPDKHHVFLXHS-UHFFFAOYSA-M 0.000 description 4
- CWLKGDAVCFYWJK-UHFFFAOYSA-N 3-aminophenol Chemical compound NC1=CC=CC(O)=C1 CWLKGDAVCFYWJK-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 102000011782 Keratins Human genes 0.000 description 3
- 108010076876 Keratins Proteins 0.000 description 3
- LUSZGTFNYDARNI-UHFFFAOYSA-N Sesamol Chemical compound OC1=CC=C2OCOC2=C1 LUSZGTFNYDARNI-UHFFFAOYSA-N 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- XGNXYCFREOZBOL-UHFFFAOYSA-N 1,3-benzodioxol-5-amine Chemical compound NC1=CC=C2OCOC2=C1 XGNXYCFREOZBOL-UHFFFAOYSA-N 0.000 description 2
- FBMQNRKSAWNXBT-UHFFFAOYSA-N 1,4-diaminoanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(N)=CC=C2N FBMQNRKSAWNXBT-UHFFFAOYSA-N 0.000 description 2
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 2
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- SBUMIGFDXJIPLE-UHFFFAOYSA-N 2-(3-amino-4-methoxyanilino)ethanol Chemical compound COC1=CC=C(NCCO)C=C1N SBUMIGFDXJIPLE-UHFFFAOYSA-N 0.000 description 2
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- HCPJEHJGFKWRFM-UHFFFAOYSA-N 2-amino-5-methylphenol Chemical compound CC1=CC=C(N)C(O)=C1 HCPJEHJGFKWRFM-UHFFFAOYSA-N 0.000 description 2
- ALQKEYVDQYGZDN-UHFFFAOYSA-N 2-amino-6-methylphenol Chemical compound CC1=CC=CC(N)=C1O ALQKEYVDQYGZDN-UHFFFAOYSA-N 0.000 description 2
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical compound NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 2
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 2
- 229940018563 3-aminophenol Drugs 0.000 description 2
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 2
- GPJJASIJVRXZFI-UHFFFAOYSA-N 4-methoxybenzene-1,3-diol Chemical compound COC1=CC=C(O)C=C1O GPJJASIJVRXZFI-UHFFFAOYSA-N 0.000 description 2
- SNPLKNRPJHDVJA-ZETCQYMHSA-N D-panthenol Chemical compound OCC(C)(C)[C@@H](O)C(=O)NCCCO SNPLKNRPJHDVJA-ZETCQYMHSA-N 0.000 description 2
- JSFUMBWFPQSADC-UHFFFAOYSA-N Disperse Blue 1 Chemical compound O=C1C2=C(N)C=CC(N)=C2C(=O)C2=C1C(N)=CC=C2N JSFUMBWFPQSADC-UHFFFAOYSA-N 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 description 2
- KZSNJWFQEVHDMF-BYPYZUCNSA-N L-valine Chemical compound CC(C)[C@H](N)C(O)=O KZSNJWFQEVHDMF-BYPYZUCNSA-N 0.000 description 2
- XUMBMVFBXHLACL-UHFFFAOYSA-N Melanin Chemical compound O=C1C(=O)C(C2=CNC3=C(C(C(=O)C4=C32)=O)C)=C2C4=CNC2=C1C XUMBMVFBXHLACL-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- KZSNJWFQEVHDMF-UHFFFAOYSA-N Valine Natural products CC(C)C(N)C(O)=O KZSNJWFQEVHDMF-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 125000005396 acrylic acid ester group Chemical group 0.000 description 2
- 235000004279 alanine Nutrition 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- POJWUDADGALRAB-UHFFFAOYSA-N allantoin Chemical compound NC(=O)NC1NC(=O)NC1=O POJWUDADGALRAB-UHFFFAOYSA-N 0.000 description 2
- 235000010323 ascorbic acid Nutrition 0.000 description 2
- 229960005070 ascorbic acid Drugs 0.000 description 2
- 239000011668 ascorbic acid Substances 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- 239000000413 hydrolysate Substances 0.000 description 2
- PYIDGJJWBIBVIA-UYTYNIKBSA-N lauryl glucoside Chemical compound CCCCCCCCCCCCO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O PYIDGJJWBIBVIA-UYTYNIKBSA-N 0.000 description 2
- 229940048848 lauryl glucoside Drugs 0.000 description 2
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 229940101267 panthenol Drugs 0.000 description 2
- 235000020957 pantothenol Nutrition 0.000 description 2
- 239000011619 pantothenol Substances 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- 230000002028 premature Effects 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- 229960001755 resorcinol Drugs 0.000 description 2
- 230000035943 smell Effects 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 2
- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 description 2
- MGSRCZKZVOBKFT-UHFFFAOYSA-N thymol Chemical compound CC(C)C1=CC=C(C)C=C1O MGSRCZKZVOBKFT-UHFFFAOYSA-N 0.000 description 2
- 235000014393 valine Nutrition 0.000 description 2
- 239000004474 valine Substances 0.000 description 2
- NKNCGBHPGCHYCQ-UHFFFAOYSA-N (2,5-diaminophenyl)methanol Chemical compound NC1=CC=C(N)C(CO)=C1 NKNCGBHPGCHYCQ-UHFFFAOYSA-N 0.000 description 1
- WVOAPRDRMLHUMI-UHFFFAOYSA-N (2-methylnaphthalen-1-yl) acetate Chemical compound C1=CC=C2C(OC(=O)C)=C(C)C=CC2=C1 WVOAPRDRMLHUMI-UHFFFAOYSA-N 0.000 description 1
- VIXBPSTZNCRCJE-UHFFFAOYSA-N 1,3-bis[4-amino-n-(2-hydroxyethyl)anilino]propan-2-ol Chemical compound C1=CC(N)=CC=C1N(CCO)CC(O)CN(CCO)C1=CC=C(N)C=C1 VIXBPSTZNCRCJE-UHFFFAOYSA-N 0.000 description 1
- WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 description 1
- FRASJONUBLZVQX-UHFFFAOYSA-N 1,4-dioxonaphthalene Natural products C1=CC=C2C(=O)C=CC(=O)C2=C1 FRASJONUBLZVQX-UHFFFAOYSA-N 0.000 description 1
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 1
- BOKGTLAJQHTOKE-UHFFFAOYSA-N 1,5-dihydroxynaphthalene Chemical compound C1=CC=C2C(O)=CC=CC2=C1O BOKGTLAJQHTOKE-UHFFFAOYSA-N 0.000 description 1
- ICVRBKCRXNVOJC-UHFFFAOYSA-N 1-amino-4-(methylamino)anthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(N)=CC=C2NC ICVRBKCRXNVOJC-UHFFFAOYSA-N 0.000 description 1
- AQXYVFBSOOBBQV-UHFFFAOYSA-N 1-amino-4-hydroxyanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(O)=CC=C2N AQXYVFBSOOBBQV-UHFFFAOYSA-N 0.000 description 1
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 1
- FDCJDKXCCYFOCV-UHFFFAOYSA-N 1-hexadecoxyhexadecane Chemical compound CCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCC FDCJDKXCCYFOCV-UHFFFAOYSA-N 0.000 description 1
- HBXWUCXDUUJDRB-UHFFFAOYSA-N 1-octadecoxyoctadecane Chemical compound CCCCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCCCC HBXWUCXDUUJDRB-UHFFFAOYSA-N 0.000 description 1
- XAWPKHNOFIWWNZ-UHFFFAOYSA-N 1h-indol-6-ol Chemical compound OC1=CC=C2C=CNC2=C1 XAWPKHNOFIWWNZ-UHFFFAOYSA-N 0.000 description 1
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- SYEYEGBZVSWYPK-UHFFFAOYSA-N 2,5,6-triamino-4-hydroxypyrimidine Chemical compound NC1=NC(N)=C(N)C(O)=N1 SYEYEGBZVSWYPK-UHFFFAOYSA-N 0.000 description 1
- KZTWOUOZKZQDMN-UHFFFAOYSA-N 2,5-diaminotoluene sulfate Chemical compound OS(O)(=O)=O.CC1=CC(N)=CC=C1N KZTWOUOZKZQDMN-UHFFFAOYSA-N 0.000 description 1
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- MQMMMSDSVNOFJM-UHFFFAOYSA-N 2-[3-amino-n-(2-hydroxyethyl)anilino]ethanol Chemical compound NC1=CC=CC(N(CCO)CCO)=C1 MQMMMSDSVNOFJM-UHFFFAOYSA-N 0.000 description 1
- ISCYHXYLVTWDJT-UHFFFAOYSA-N 2-[4-amino-n-(2-hydroxyethyl)anilino]ethanol Chemical compound NC1=CC=C(N(CCO)CCO)C=C1 ISCYHXYLVTWDJT-UHFFFAOYSA-N 0.000 description 1
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- KJTXCKZBFHBRQT-UHFFFAOYSA-N 2-amino-5-ethoxyphenol Chemical compound CCOC1=CC=C(N)C(O)=C1 KJTXCKZBFHBRQT-UHFFFAOYSA-N 0.000 description 1
- 125000000022 2-aminoethyl group Chemical group [H]C([*])([H])C([H])([H])N([H])[H] 0.000 description 1
- BMTSZVZQNMNPCT-UHFFFAOYSA-N 2-aminopyridin-3-ol Chemical compound NC1=NC=CC=C1O BMTSZVZQNMNPCT-UHFFFAOYSA-N 0.000 description 1
- SWZVJOLLQTWFCW-UHFFFAOYSA-N 2-chlorobenzene-1,3-diol Chemical compound OC1=CC=CC(O)=C1Cl SWZVJOLLQTWFCW-UHFFFAOYSA-N 0.000 description 1
- HGUYBLVGLMAUFF-UHFFFAOYSA-N 2-methoxybenzene-1,4-diamine Chemical compound COC1=CC(N)=CC=C1N HGUYBLVGLMAUFF-UHFFFAOYSA-N 0.000 description 1
- OBCSAIDCZQSFQH-UHFFFAOYSA-N 2-methyl-1,4-phenylenediamine Chemical compound CC1=CC(N)=CC=C1N OBCSAIDCZQSFQH-UHFFFAOYSA-N 0.000 description 1
- ZTMADXFOCUXMJE-UHFFFAOYSA-N 2-methylbenzene-1,3-diol Chemical compound CC1=C(O)C=CC=C1O ZTMADXFOCUXMJE-UHFFFAOYSA-N 0.000 description 1
- WNYJRJRHKRZXEO-UHFFFAOYSA-N 2-propan-2-ylbenzene-1,4-diamine Chemical compound CC(C)C1=CC(N)=CC=C1N WNYJRJRHKRZXEO-UHFFFAOYSA-N 0.000 description 1
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
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- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
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- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
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Description
Beschreibung OxidationshaarfärbemittelDescription Oxidation hair dye
Gegenstand der Erfindung ist ein Mittel zum oxidativen Färben von Haaren mit haarschonenden und haarpflegenden Eigenschaften, das durch Vermischen einer speziellen flüssigen Farbstoffträgermasse auf der Basis einer Entwicklersubstanz-Kupplersubstanz-Kombination mit einer speziellen Oxidationsmittelzubereitung erhalten wird.The invention relates to an agent for the oxidative dyeing of hair with hair-protecting and hair-care properties, which is obtained by mixing a special liquid dye carrier mass based on a developer substance-coupler substance combination with a special oxidizing agent preparation.
Oxidationshaarfarben sind ein zentraler Bestandteil eines jeden der Haarbehandlung dienenden, kosmetischen Produktsortiments. Sie bestehen aus zwei Komponenten, die kurz vor dem Gebrauch miteinander vermischt und dann auf das zu färbende Haar aufgetragen werden.Oxidation hair dyes are a central component of any cosmetic product range used for hair treatment. They consist of two components that are mixed together shortly before use and then applied to the hair to be dyed.
Die erste Komponente, wird als Farbstoffträgermasse bezeichnet und enthält die Farbstoffe. Sie kann als Flüssigkeit, Gel oder auch als Emulsion vorliegen. Die zweite Komponente ist eine wäßrige, flüssige,-cremeförmiges oder pulverförmige Oxidationsmittelzubereitung.The first component is called the dye carrier and contains the dyes. It can be in the form of a liquid, gel or emulsion. The second component is an aqueous, liquid, cream or powdered oxidizing agent preparation.
Die Färbung entsteht durch die Reaktion bestimmter Entwicklersubstanzen mit bestimmten Kupplersubstanzen in Gegenwart eines geeigneten Oxidationsmittels, zum Beispiel Wasserstoffperoxid.The coloration is caused by the reaction of certain developing substances with certain coupler substances in the presence of a suitable oxidizing agent, for example hydrogen peroxide.
Aus der DE-OS 40 05 008 ist ein Mittel zum oxidativen Färben von Haaren bekannt, welches durch Vermischen einer flüssigen Farbträgermasse mit einer emulsionsförmigen, einen C10- bis C24-Fettalkohol enthaltenden Wasserstoffperoxid-Zubereitungerhalten wird.From DE-OS 40 05 008 an agent for the oxidative dyeing of hair is known, which is obtained by mixing a liquid dye carrier mass with an emulsion-like hydrogen peroxide preparation containing a C 10 to C 24 fatty alcohol.
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Die Verwendung von anionischen Polymeren, welche jedoch eine andere Struktur als die erfindungsgemäß verwendeten Polymeren aufweisen, in Oxidationsmittelzubereitungen ist aus der EP-OS O 308 825, EP-OS O 640 334 und EP-OS 0 640 335 bekannt.The use of anionic polymers, which, however, have a different structure than the polymers used according to the invention, in oxidizing agent preparations is known from EP-OS O 308 825, EP-OS O 640 334 and EP-OS 0 640 335.
In der Färbepraxis wird die flüssige Farbträgermasse vor der Anwendung mit einer wäßrigen Wasserstoffperoxidlösung vermischt, beispielsweise in einem Mischungsverhältnis von 1 : 1 bis 1 : 2, wobei die Vermischung der flüssigen Farbträgermasse mit der Wasserstoffperoxid-Lösung zum Beispiel in einer Auftrageflasche, mit der das gebrauchsfertige Oxidationshaarfärbemittel nach dem Mischen auf das zu färbende Haar aufgebracht wird, erfolgen kann.In dyeing practice, the liquid dye carrier mass is mixed with an aqueous hydrogen peroxide solution before use, for example in a mixing ratio of 1:1 to 1:2, whereby the mixing of the liquid dye carrier mass with the hydrogen peroxide solution can take place, for example, in an application bottle with which the ready-to-use oxidation hair dye is applied to the hair to be dyed after mixing.
Die bisher bekannten flüssigen Farbträgermassen haben jedoch eine Reihe von Nachteilen. So färben sich diese Farbträgermassen nach dem Zumischen der Wasserstoffperoxid-Lösung sehr rasch dunkel und das mit dem nun gebrauchsfertigen Oxidationshaarfärbemittel in Kontakt gebrachte Haar nimmt die Färbung deutlich langsamer an. Die vorzeitige Dunkelfärbung des Oxidationshaarfärbemittels hat zudem den nachteiligen Effekt, daß das Färbemittel zu früh ausgespült wird, so daß häufig die beabsichtigte Farbintensität durch eine zu kurze Einwirkzeit auf dem Haar nicht erreicht wird. Weiterhin geben übliche flüssige Farbträgermassen den in ihnen enthaltenen Ammoniak sehr leicht an die Umgebung abgeben, was eine unerwünschte Geruchsbelästigung zur Folge hat. Darüber hinaus kann der häufige Gebrauch derartiger Färbemittel zu Hautirritationen oder einer Versprödung beziehungsweiseHowever, the liquid color carrier masses known to date have a number of disadvantages. For example, these color carrier masses turn dark very quickly after the hydrogen peroxide solution has been added, and the hair that has come into contact with the now ready-to-use oxidation hair dye absorbs the color much more slowly. The premature darkening of the oxidation hair dye also has the disadvantageous effect that the dye is rinsed out too soon, so that the intended color intensity is often not achieved because the hair is not allowed to react for long enough. Furthermore, conventional liquid color carrier masses release the ammonia they contain very easily into the environment, which results in an undesirable odor nuisance. In addition, the frequent use of such dyes can cause skin irritation or brittleness or
Austrocknung der Haare sowie einer Verschlechterung der Kämmbarkeit führen.This can lead to hair drying out and deterioration in combability.
Aufgabe der vorliegenden Erfindung ist es daher, ein Mittel zum oxidativen Färben von Haaren auf der Basis einer flüssigen Farbträgermasse zur Verfügung zu stellen, das die vorstehend beschriebenen Nachteile von auf flüssigen Farbträgermassen basierenden Mitteln zum oxidativen Färben von Haaren nicht aufweist.The object of the present invention is therefore to provide an agent for the oxidative dyeing of hair based on a liquid dye carrier mass, which does not have the above-described disadvantages of agents for the oxidative dyeing of hair based on liquid dye carrier masses.
Es wurde nunmehr gefunden, daß sich Mittel zum oxidativen Färben von Haaren, die gut hautverträglich sind, bei denen das das Färbeergebnis nachteilig beeinflussende, vorzeitige Nachdunkeln nach dem Zumischen des Oxidationsmittels weitgehend vermieden wird sowie bei denen im Vergleich zu bekannten Mitteln eine weitaus geringere Geruchsbelästigung durch aus dem Mittel entweichenden Ammoniak entsteht und bei denen das Haar deutlich weniger geschädigt wird, durch Vermischen einer speziellen flüssigen Farbträgermasse und einer speziellen emulsionsförmigen Oxidationsmittel-Zubereitung herstellen lassen.It has now been found that agents for the oxidative dyeing of hair which are well tolerated by the skin, in which the premature darkening after the oxidizing agent is added, which has a detrimental effect on the dyeing result, is largely avoided and in which, in comparison with known agents, a far lower odor nuisance is caused by ammonia escaping from the agent and in which the hair is significantly less damaged, can be produced by mixing a special liquid color carrier mass and a special emulsion-like oxidizing agent preparation.
Gegenstand der vorliegenden Erfindung ist daher ein Mittel zum oxidativen Färben von Haaren, erhalten durch Vermischen einer Komponente (A) mit einer Komponente (B), welches dadurch gekennzeichnet ist, daß die Komponente (A) eine (a) eine Entwicklersubstanz-Kupplersubstanz-Kombination, (b) eine Kombination von nichtionischen und anionischen oberflächenaktiven Verbindungen, (c) eine Aminosäure und/oder deren Salze und (d) einen 1-oder 2wertigen Alkohol enthaltende flüssige Farbträgermasse mit einer Viskosität von weniger als 100 mPa.s ist, und die Komponente (B) eine (a) einThe present invention therefore relates to an agent for the oxidative dyeing of hair, obtained by mixing a component (A) with a component (B), which is characterized in that component (A) is (a) a developer substance-coupler substance combination, (b) a combination of non-ionic and anionic surface-active compounds, (c) an amino acid and/or salts thereof and (d) a mono- or dihydric alcohol-containing liquid dye carrier mass with a viscosity of less than 100 mPa.s, and component (B) is (a) a
Oxidationsmittel, (b) 2 bis 15 Gewichtsprozent mindestens eines C10- bis C24- Fettalkohols natürlicher oder synthetischer Herkunft und (c) einen Polypropylenglykolether („PPG-Ether"), Polyethylenglykolether („PEG-Ether") oder Polyethylenglykol/Polypropylenglykolether („PEG-PPG-Ether" bzw. „PPG-PEG-Ether") sowie (d) ein Acrylsäurepolymerisat aus der Gruppe bestehend aus Acrylates/Steareth-20 Itaconate Copolymer und Acrylates/Ceteth-20 Itaconate Copolymer enthaltende emulsionsförmige Zusammensetzung darstellt.oxidizing agent, (b) 2 to 15 percent by weight of at least one C 10 to C 24 fatty alcohol of natural or synthetic origin and (c) a polypropylene glycol ether ("PPG ether"), polyethylene glycol ether ("PEG ether") or polyethylene glycol/polypropylene glycol ether ("PEG-PPG ether" or "PPG-PEG ether") and (d) an acrylic acid polymer selected from the group consisting of Acrylates/Steareth-20 Itaconate Copolymer and Acrylates/Ceteth-20 Itaconate Copolymer.
„Acrylates/Steareth-20 Itaconate Copolymer" steht hierbei für aus dem Halbester der Itaconsäure, dem Polyoxyethylen(20)stearylether und einem oder mehreren Monomeren der Acrylsäure, Methacrylsäure oder einem Acrylsäuresester oder Methacrylsäureester gebildete Copolymere „Acrylates/Ceteth-20 Itaconate Copolymer" steht hierbei für aus dem Halbester der Itaconsäure, dem Polyoxyethylen(20)cetylether und einem oder mehreren Monomeren der Acrylsäure, Methacrylsäure oder einem Acrylsäuresester oder Methacrylsäureester gebildete Copolymere"Acrylates/Steareth-20 Itaconate Copolymer" stands for copolymers formed from the half ester of itaconic acid, the polyoxyethylene(20) stearyl ether and one or more monomers of acrylic acid, methacrylic acid or an acrylic acid ester or methacrylic acid ester. "Acrylates/Ceteth-20 Itaconate Copolymer" stands for copolymers formed from the half ester of itaconic acid, the polyoxyethylene(20) cetyl ether and one or more monomers of acrylic acid, methacrylic acid or an acrylic acid ester or methacrylic acid ester.
Die Komponente (A) enthält mindestens eine Kupplersubstanz und mindestens eine Entwicklersubstanz sowie gegebenenfalls zusätzlich mit sich selbst kuppelnde Farbvorstufen und direkt auf das Haar aufziehende Farbstoffe.Component (A) contains at least one coupler substance and at least one developer substance and optionally additional self-coupling color precursors and dyes which are absorbed directly onto the hair.
Die Entwicklersubstanzen und Kupplersubstanzen werden in den Haarfärbemitteln entweder in Form der freien Base oder in Form ihrer physiologisch unbedenklichen Salze mit anorganischen oder organischen Säuren, wie zum Beispiel als Chlorid, Sulfat, Phosphat, Acetat, Propionat, Lactat oder Citrat, eingesetzt.The developer substances and coupler substances are used in hair dyes either in the form of the free base or in the form of their physiologically harmless salts with inorganic or organic acids, such as chloride, sulfate, phosphate, acetate, propionate, lactate or citrate.
Die Kupplersubstanzen und Entwicklersubstanzen werden vorzugsweise in etwa equimolarer Menge eingesetzt. Es ist jedoch nicht nachteilig, wenn die Kupplersubstanzen gegenüber den Entwicklersubstanzen in einem Überschuß oder Unterschuß verwendet werden, wobei sowohl die Entwicklerkomponente ein Gemisch von bekannten Entwicklersubstanzen als auch die Kupplerkomponente ein Gemisch von bekannten Kupplersubstanzen darstellen kann.The coupler substances and developer substances are preferably used in approximately equimolar amounts. However, it is not disadvantageous if the coupler substances are used in excess or in deficit compared to the developer substances, whereby both the developer component can be a mixture of known developer substances and the coupler component can be a mixture of known coupler substances.
Als geeignete Entwicklersubstanzen sind beispielsweise zu nennen: 1,4-Diamino-benzol (p-Phenylendiamin), 1 ^-Diamino^-methyl-benzol (p-Toluylendiamin), 2,5-Diaminoanisol, 2,5-Diaminobenzylalkohol, 1 ,^-Diamino^.e-dimethyl-benzol, 1 ^-Diamino^.S-dimethyl-benzol, 1 ^-Diamino^.S-dimethyl-benzol^-Chlor-i ,4-diaminobenzol, 4-Phenylamino-anilin, 4-Dimethylamino-anilin,4-Diethylamino-anilin, 4-[Di(2-hydroxyethyl)amino]-anilin,4-[(2-Methoxyethyl)amino]-anilin, 4-[(3-Hydroxypropyl)amino]-anilin, 1,4-Diamino-2-(2-hydroxyethyl)-benzol, 1,4-Diamino-2-(1-methylethyl)-benzol, 1,3-Bis[(4-aminophenyl)-(2-hydroxyethyl)amino]-2-propanol, 1,8-Bis(2,5-diaminophenoxy)-3,6-dioxaoctan, 4-Amino-phenol, 4-Amino-3-methyl-phenol, 4-Methylaminophenol, 4-Amino-2-(aminomethyl)-phenol, 4-Amino-2-[(2-hydroxyethyl)-aminojmethyl-phenol, 4-Amino-2-(methoxymethyl)-phenol, 4-Amino-2-(2-hydroxyethyl)-phenol, 5-Amino-saücylsäure, 2,5-Diamino-pyridin, 2,4,5,6-Tetraamino-pyrimidin, 2,5,6-Triamino-4-(1 H)-pyrimidon, 4,5-Diamino-1-(2-hydroxyethyl)-1H-pyrazol, 4,5-Diamino-1-(1-methylethyl)-1 H-pyrazol, 4,5-Diamino-1 -[(4-methylphenyl)methyl]-1 H-pyrazol, 1-[(4-Chlorphenyl)methyl]-4,5-diamino-1 H-pyrazol, 4,5-Diamino-1-Examples of suitable developing substances are: 1,4-diaminobenzene (p-phenylenediamine), 1 ^-diamino^-methylbenzene (p-toluenediamine), 2,5-diaminoanisole, 2,5-diaminobenzyl alcohol, 1 ,^-diamino^.e-dimethylbenzene, 1 ^-diamino^.S-dimethylbenzene, 1 ^-diamino^.S-dimethylbenzene^-chloro-i ,4-diaminobenzene, 4-phenylaminoaniline, 4-dimethylaminoaniline, 4-diethylaminoaniline, 4-[di(2-hydroxyethyl)amino]aniline, 4-[(2-methoxyethyl)amino]aniline, 4-[(3-hydroxypropyl)amino]aniline, 1,4-diamino-2-(2-hydroxyethyl)benzene, 1,4-Diamino-2-(1-methylethyl)-benzol, 1,3-Bis[(4-aminophenyl)-(2-hydroxyethyl)amino]-2-propanol, 1,8-Bis(2,5-diaminophenoxy)-3,6-dioxaoctan, 4-Amino-phenol, 4-Amino-3-methyl-phenol, 4-Methylaminophenol, 4-Amino-2-(aminomethyl)-phenol, 4-Amino-2-[(2-hydroxyethyl)-aminojmethyl-phenol, 4-Amino-2-(methoxymethyl)-phenol, 4-Amino-2-(2-hydroxyethyl)-phenol, 5-Amino-saücylsäure, 2,5-Diamino-pyridin, 2,4,5,6-Tetraamino-pyrimidin, 2,5,6-Triamino-4-(1 H)-pyrimidon, 4,5-diamino-1-(2-hydroxyethyl)-1H-pyrazole, 4,5-diamino-1-(1-methylethyl)-1 H-pyrazole, 4,5-diamino-1 -[(4-methylphenyl)methyl]-1 H-pyrazole, 1-[(4-chlorophenyl)methyl]-4,5-diamino-1 H-pyrazole, 4,5-diamino-1-
methyl-1H-pyrazol( 2-Amino-phenol, 2-Amino-6-methyl-phenol und 2-Amino-5-methyl-phenol, allein oder im Gemisch miteinander.methyl-1H-pyrazole ( 2-amino-phenol, 2-amino-6-methyl-phenol and 2-amino-5-methyl-phenol, alone or in admixture with each other.
Als geeignete Kupplersubstanzen sind beispielsweise zu nennen: N-(3-Dimethylamino-phenyl)-hamstoff, 2,6-Diamino-pyridin, 2-Amino-4-[(2-hydroxyethyl)amino]-anisol, 2,4-Diamino-1-fluor-5-methyl-benzol, 2,4-Diamino-1-methoxy-5-methyl-benzol, 2,4-Diamino-1-ethoxy-5-methylbenzol, 2,4-Diamino-1-(2-hydroxyethoxy)-5-methyl-benzol, 2,4-Di[(2-hydroxyethyl)amino]-1,5-dimethoxy-benzol, 2,3-Diamino-6-methoxypyridin, 3-Amino-6-methoxy-2-(methylamino)-pyridin, 2,6-Diamino-3,5-dimethoxy-pyridin, 3,5-Diamino-2,6-dimethoxy-pyridin, 1,3-Diaminobenzol, 2,4-Diamino-1-(2-hydroxyethoxy)-benzol, 1-(2-Aminoethoxy)-2,4-diamino-benzol, 2-Amino-1-(2-hydroxyethoxy)-4-methylamino-benzol, 2,4-Diaminophenoxy-essigsäure, 3-[Di(2-hydroxyethyl)amino]-anilin, 4-Amino-2-di[(2-hydroxyethyl)amino]-1-ethoxy-benzol, 5-Methyl-2-(1-methylethyl)-phenol, 3-[(2-Hydroxyethyl)amino]-anilin, 3-[(2-Aminoethyl)öamino]-anilin, 1,3-Di(2,4-diaminophenoxy)-propan, Di(2,4-diaminophenoxy)-methan, 1,3-Diamino-2,4-dimethoxy-benzol, 2,6-Bis(2-hydroxyethyl)amino-toluol, 4-Hydroxyindol, 3-Dimethylamino-phenol, 3-Diethylamino-phenol, 5-Amino-2-methyl-phenol, 5-Amino-4-fluor-2-methyl-phenol, 5-Amino-4-methoxy-2-methyl-phenol, 5-Amino-4-ethoxy-2-methyl-phenol, 3-Amino-2,4-dichlor-phenol, 5-Amino-2,4-dichlor-phenol, 3-Amino-2-methyl-phenol, 3-Amino-2-chlor-6-methyl-phenol, 3-Aminophenol, 2-[(3-Hydroxyphenyl)amino]-acetamid, 5-[(2-Hydroxyethyl)amino]-2-methyl-phenol, 3-[(2-Hydroxyethyl)amino]-phenol, 3-[(2-Methoxyethyl)-amino]-phenol, 5-Amino-2-ethyl-phenol, 2-(4-Amino-2-hydroxyphenoxy)-ethanol, 5-[(3-Hydroxypropyl)amino]-2-methyl-phenol, 3-[(2,3-Dihydroxy-Examples of suitable coupler substances include: N-(3-dimethylamino-phenyl)-urea, 2,6-diaminopyridine, 2-amino-4-[(2-hydroxyethyl)amino]-anisole, 2,4-diamino -1-fluoro-5-methyl-benzene, 2,4-diamino-1-methoxy-5-methyl-benzene, 2,4-diamino-1-ethoxy-5-methylbenzene, 2,4-diamino-1-( 2-hydroxyethoxy)-5-methyl-benzene, 2,4-di[(2-hydroxyethyl)amino]-1,5-dimethoxy-benzene, 2,3-diamino-6-methoxypyridine, 3-amino-6-methoxy -2-(methylamino)-pyridine, 2,6-diamino-3,5-dimethoxy-pyridine, 3,5-diamino-2,6-dimethoxy-pyridine, 1,3-diaminobenzene, 2,4-diamino-1-(2-hydroxyethoxy)-benzene, 1-(2-aminoethoxy)-2,4-diaminobenzene, 2-amino-1-(2-hydroxyethoxy)- 4-methylamino-benzene, 2,4-diaminophenoxy-acetic acid, 3-[di(2-hydroxyethyl)amino]-aniline, 4-amino-2-di[(2-hydroxyethyl)amino]-1-ethoxy-benzene, 5-Methyl-2-(1-methylethyl)-phenol, 3-[(2-hydroxyethyl)amino]-aniline, 3-[(2-aminoethyl)öamino]-aniline, 1,3-di(2,4- diaminophenoxy)-propane, di(2,4-diaminophenoxy)-methane, 1,3-diamino-2,4-dimethoxy-benzene, 2,6-Bis(2-hydroxyethyl)amino-toluene, 4-hydroxyindole, 3-dimethylamino-phenol, 3-diethylamino-phenol, 5-amino-2-methyl-phenol, 5-amino-4-fluoro-2- methyl-phenol, 5-amino-4-methoxy-2-methyl-phenol, 5-amino-4-ethoxy-2-methyl-phenol, 3-amino-2,4-dichloro-phenol, 5-amino-2, 4-dichlorophenol, 3-amino-2-methyl-phenol, 3-amino-2-chloro-6-methyl-phenol, 3-aminophenol, 2-[(3-hydroxyphenyl)amino]-acetamide, 5-[ (2-Hydroxyethyl)amino]-2-methyl-phenol, 3-[(2-hydroxyethyl)amino]-phenol, 3-[(2-methoxyethyl)-amino]-phenol, 5-amino-2-ethyl-phenol , 2-(4-Amino-2-hydroxyphenoxy)-ethanol, 5-[(3-Hydroxypropyl)amino]-2-methyl-phenol, 3-[(2,3-Dihydroxy-
propyl)amino]-2-methyl-phenol, 3-[(2-Hydroxyethyl)amino]-2-methylphenol, 2-Amino-3-hydroxy-pyridin, S-Amino^-chlor^-methyl-phenol, 1-Naphthol, 1,5-Dihydroxy-naphthalin, 1,7-Dihydroxy-naphthalin, 2,3-Dihydroxy-naphthalin, 2,7-Dihydroxy-naphthalin, 2-Methyl-1 -naphtholacetat, 1,3-Dihydroxy-benzol, 1-Chlort,4-dihydroxy-benzol, 2-Chlor-1,3-dihydroxy-benzol, 1,2-DiChIOr-S, S-dihydroxy^-methyl-benzol, 1,5-Dichlor-2,4-dihydroxy-benzol, 1 ,S-Dihydroxy^-methyl-benzol, 3,4-Methylendioxyphenol, 4-(ß-Hydroxyethylamino)-1,2-methylendioxybenzol, 3,4-Methylendioxy-anilin, 5-[(2-Hydroxyethyl)amino]-1,3-benzodioxol, 5-Hydroxy-1,3-benzodioxol, 5-Amino-1,3-benzodioxol, 4-Methoxy-1-naphthol, 2-Methyl-1,3-dihydroxy-benzol, 6-Brom-1-hydroxy-3,4-methylendioxy-benzol, 3,4-Diamino-benzoesäure, 3,4-Dihydro-6-hydroxy-1,4(2H)-benzoxazin, 6-Amino-3,4-dihydro-1,4(2H)-benzoxazin, 3-Methyl-1-phenyl-5-pyrazolon, 5,6-Dihydroxy-indol, 5,6-Dihydroxy-indolin, 5-Hydroxy-indol, 6-Hydroxy-indol, 7-Hydroxy-indol, 2,3-lndolindion, 2,4-Dihydroxyphenolether wie 2,4-Dihydroxyanisol und 2,4-Dihydroxyphenoxyethanol.propyl)amino]-2-methyl-phenol, 3-[(2-hydroxyethyl)amino]-2-methylphenol, 2-amino-3-hydroxy-pyridine, S-amino^-chloro^-methyl-phenol, 1- Naphthol, 1,5-dihydroxy-naphthalene, 1,7-dihydroxy-naphthalene, 2,3-dihydroxy-naphthalene, 2,7-dihydroxy-naphthalene, 2-methyl-1-naphthol acetate, 1,3-dihydroxy-benzene, 1-chloro,4-dihydroxy-benzene, 2-chloro-1,3-dihydroxy-benzene, 1,2-DiChIOr-S, S-dihydroxy^-methyl-benzene, 1,5-dichloro-2,4-dihydroxy -benzene, 1,S-dihydroxy^-methyl-benzene, 3,4-methylenedioxyphenol, 4-(ß-Hydroxyethylamino)-1,2-methylenedioxybenzene, 3,4-methylenedioxyaniline, 5-[(2-hydroxyethyl)amino]-1,3-benzodioxole, 5-hydroxy-1,3-benzodioxole, 5 -Amino-1,3-benzodioxole, 4-methoxy-1-naphthol, 2-methyl-1,3-dihydroxy-benzene, 6-bromo-1-hydroxy-3,4-methylenedioxy-benzene, 3,4-diamino -benzoic acid, 3,4-dihydro-6-hydroxy-1,4(2H)-benzoxazine, 6-amino-3,4-dihydro-1,4(2H)-benzoxazine, 3-methyl-1-phenyl-5 -pyrazolone, 5,6-dihydroxy-indole, 5,6-dihydroxy-indoline, 5-hydroxy-indole, 6-hydroxy-indole, 7-hydroxy-indole, 2,3-indolindione, 2,4-dihydroxyphenol ethers such as 2,4-dihydroxyanisole and 2,4-dihydroxyphenoxyethanol.
Die Gesamtmenge der in der Komponente (A) enthaltenen Entwicklersubstanz-Kupplersubstanz-Kombination beträgt etwa 0,01 bis 12,0 Gewichtsprozent, insbesondere etwa 0,2 bis 4,0 Gewichtsprozent.The total amount of the developer substance-coupler substance combination contained in component (A) is about 0.01 to 12.0 percent by weight, in particular about 0.2 to 4.0 percent by weight.
Zur Erzielung bestimmter Farbnuancen können ferner auch übliche direktziehende Farbstoffe, beispielsweise Triphenylmethanfarbstoffe wie Diamond Fuchsine (Cl. 42 510) und Leather Ruby HF (C.I. 42 520), aromatische Nitrofarbstoffe wie 2-Amino-4,6-din'itro-phenol, 2-Nitro-4-(n-hydroxyethylamino)-anilin, 2-N-ß,-Dihydroxypropylamino-5-(N-methyl,N-hydroxyethyl)amino-nitrobenzol und 2-Amino-4-nitrophenol,In order to achieve certain colour nuances, conventional direct dyes can also be used, for example triphenylmethane dyes such as Diamond Fuchsine (Cl. 42 510) and Leather Ruby HF (C.I. 42 520), aromatic nitro dyes such as 2-amino-4,6-din'itro-phenol, 2-nitro-4-(n-hydroxyethylamino)-aniline, 2-N-ß,-dihydroxypropylamino-5-(N-methyl,N-hydroxyethyl)amino-nitrobenzene and 2-amino-4-nitrophenol,
Azofarbstofte wie Acid Brown 4 (C.I. 14 805) und Acid Blue 135 (C.I. 13 385), Anthrachinonfarbstoffe wie Disperse Violet 4 (C.I. 61 105), Disperse Blue 1 (C.I. 64 500), Disperse Red 15 (C.I. 60 710), Disperse Violet 1 (C.I. 61 100), 1,4,5,8-Tetraaminoanthrachinon und 1,4-Diaminoanthrachinon, in der Komponente (A) enthalten sein.Azo dyes such as Acid Brown 4 (C.I. 14 805) and Acid Blue 135 (C.I. 13 385), anthraquinone dyes such as Disperse Violet 4 (C.I. 61 105), Disperse Blue 1 (C.I. 64 500), Disperse Red 15 (C.I. 60 710), Disperse Violet 1 (C.I. 61 100), 1,4,5,8-tetraaminoanthraquinone and 1,4-diaminoanthraquinone may be contained in component (A).
Die Komponente (A) kann weiterhin auch mit sich selbstkuppelnde Farbvorstufen, wie zum Beispiel 2-Amino-5-methylphenol, 2-Amino-6-methylphenol, 2-Amino-5-ethoxyphenol oder auch 2-Propyl-amino-5-aminopyridin, enthalten.Component (A) may also contain self-coupling dye precursors, such as 2-amino-5-methylphenol, 2-amino-6-methylphenol, 2-amino-5-ethoxyphenol or 2-propyl-amino-5-aminopyridine.
Die Gesamtmenge der direktziehenden Farbstoffe und der mit sich selbst kuppelnden Farbstoffvorstufen beträgt in der Komponente (A) etwa 0,01 bis 7,0 Gewichtsprozent, vorzugsweise etwa 0,2 bis 4,0 Gewichtsprozent.The total amount of direct dyes and self-coupling dye precursors in component (A) is about 0.01 to 7.0 percent by weight, preferably about 0.2 to 4.0 percent by weight.
Die Komponente (A) enthält weiterhin eine Kombination von nichtionischen und anionischen oberflächenaktiven Verbindungen (sogenannten Tensiden oder Emulgatoren), vorzugsweise in einer Gesamtmenge von etwa 0,1 bis 25 Gewichtsprozent, insbesondere etwa 1,0 bis 20 Gewichtsprozent. Als nichtionische oberflächenaktive Verbindungen können insbesondere oxethylierte C10- bis C20-Fettalkohole, oxethylierte Sorbitanfettsäure- (C12 bis C18)-partialester, oxethylierte Glycerinfettsäure- (C12 bis C18)-partialester oder Gemische dieser Verbindungen, wobei ein Oxethylierungsgrad von 1 bis 30, insbesondere von 2 bis 6, bevorzugt ist, oder (C12- bis C18-Alkyl)glucoside eingesetzt werden. Als anionische oberflächenaktive Verbindungen können insbesondere Alkylsulfate, Alkylethersulfate mit einem C10- bis C20-Component (A) further contains a combination of nonionic and anionic surface-active compounds (so-called surfactants or emulsifiers), preferably in a total amount of about 0.1 to 25 percent by weight, in particular about 1.0 to 20 percent by weight. Nonionic surface-active compounds which can be used are in particular ethoxylated C 10 - to C 20 - fatty alcohols, ethoxylated sorbitan fatty acid (C12 to C18) partial esters, ethoxylated glycerol fatty acid (C12 to C18) partial esters or mixtures of these compounds, with a degree of ethoxylation of 1 to 30, in particular 2 to 6, being preferred, or (C12- to C18-alkyl)glucosides. Anionic surface-active compounds which can be used are in particular alkyl sulfates, alkyl ether sulfates with a C 10 - to C 20 -
• ft ·■·• ft ·■·
Alkylrest oder Gemische derselben eingesetzt werden, wobei ein Oxethylierungsgrad von 1 bis 8, insbesondere von 1 bis 6, bevorzugt ist.Alkyl radical or mixtures thereof, with a degree of oxyethylation of 1 to 8, in particular 1 to 6, being preferred.
Als Aminosäure können sowohl neutrale als auch saure oder basische Aminosäuren verwendet werden. Beispiele für geeignete Aminosäuren sind Glycin, Alanin, Valin, Leucin, Glutaminsäure und Arginin. Die Gesamtmenge an Aminosäuren beträgt in dem erfindungsgemäßen Mittel vorzugsweise 0,01 bis 5 Gewichtsprozent.Neutral, acidic or basic amino acids can be used as amino acids. Examples of suitable amino acids are glycine, alanine, valine, leucine, glutamic acid and arginine. The total amount of amino acids in the agent according to the invention is preferably 0.01 to 5 percent by weight.
In der Komponente (A) sind ferner 1- oder 2wertige Alkohole, beispielsweise niedermolekulare C1- bis C4-Alkohole oder C2- bis C6-Glykole, wie zum Beispiel Ethanol, Propanol, Isopropanol, Ethylenglykol, 1,2-Propylenglykol oder Butylenglykol, beziehungsweise deren Gemische enthalten, wobei die Einsatzmenge dieser Alkohole vorzugsweise gleich etwa 1 bis 40 Gewichtsprozent, insbesondere etwa 5 bis 30 Gewichtsprozent, ist.Component (A) also contains monohydric or dihydric alcohols, for example low molecular weight C 1 to C 4 alcohols or C 2 to C 6 glycols, such as ethanol, propanol, isopropanol, ethylene glycol, 1,2-propylene glycol or butylene glycol, or mixtures thereof, the amount of these alcohols used preferably being about 1 to 40 percent by weight, in particular about 5 to 30 percent by weight.
Gegebenenfalls können der Komponente (A) spezielle Pflegestoffe und/oder Wirkstoffe, wie zum Beispiel Proteinhydrolysate, beispielsweise Keratinhydrolysate, Elastinhydrolysate, Kollagenhydrolysate, Seidenproteinhydrolysate, Milcheiweißhydrolysate, Sojaproteinhydrolysate oder Weizenproteinhydrolysate; Panthenol; Allantoin; Pyrolidoncarbonsäuren oder deren Salze; Pflanzenextrakte oder Vitamine; oder kationische Polymere; alleine oder in Kombination miteinander, zugesetzt werden, wobei diese Verbindungen vorzugsweise in einer Gesamtkonzentration von etwa 0,01 bis 5 Gewichtsprozent, insbesondere etwa 0,01 bis 1 Gewichtsprozent, in der Komponente (A) enthalten sind.If necessary, special care substances and/or active ingredients, such as protein hydrolysates, for example keratin hydrolysates, elastin hydrolysates, collagen hydrolysates, silk protein hydrolysates, milk protein hydrolysates, soy protein hydrolysates or wheat protein hydrolysates; panthenol; allantoin; pyrolidone carboxylic acids or their salts; plant extracts or vitamins; or cationic polymers; alone or in combination with one another, can be added to component (A), wherein these compounds are preferably contained in a total concentration of about 0.01 to 5 percent by weight, in particular about 0.01 to 1 percent by weight, in component (A).
# · »«I * * ·■·-■♦» ft· «&bgr;1 # · »«I * * ·■·-■♦» ft· «&bgr; 1
Darüberhinaus können in der Komponente (A) Antioxidantien, wie zum Beispiel Ascorbinsäure, Thioglykolsäure oder Natriumsulfit, oder Komplexbildner für Schwermetalle, beispielsweise Ethylendiaminotetraacetat oder Nitriloessigsäure, in einer Menge von bis zu etwa 0,5 Gewichtsprozent enthalten sein. Parfümöle können in der Komponente (A) in einer Menge von bis zu etwa 1 Gewichtsprozent enthalten sein.In addition, antioxidants, such as ascorbic acid, thioglycolic acid or sodium sulfite, or complexing agents for heavy metals, for example ethylenediaminotetraacetate or nitriloacetic acid, can be contained in component (A) in an amount of up to about 0.5 percent by weight. Perfume oils can be contained in component (A) in an amount of up to about 1 percent by weight.
Die Komponente (B) enthält als Oxidationsmittel zur Entwicklung der Haarfärbung insbesondere Wasserstoffperoxid oder dessen Additionsverbindungen an Harnstoff, Melanin und Natriumborat, wobei das Oxidationsmittel vorzugsweise in einer Menge von etwa 1 bis 18 Gewichtsprozent, insbesondere etwa 4 bis 14 Gewichtsprozent eingesetzt wird. Besonders bevorzugt ist hierbei die Verwendung von etwa 1 bis 18 Gewichtsprozent WasserstoffperoxidComponent (B) contains, as an oxidizing agent for developing the hair color, in particular hydrogen peroxide or its addition compounds with urea, melanin and sodium borate, the oxidizing agent preferably being used in an amount of about 1 to 18 percent by weight, in particular about 4 to 14 percent by weight. The use of about 1 to 18 percent by weight of hydrogen peroxide is particularly preferred.
Der in der emulsionsförmigen, oxidationsmittelhaltigen Komponente (B) enthaltene Fettalkohol kann sowohl natürlicher als auch synthetischer Herkunft sein, wobei C14- bis C20-Fettalkohole, insbesondere Cetylalkohol und Stearylalkohol oder deren Gemische, bevorzugt sind. Die Einsatzmenge des Fettalkohols in der Komponente (B) beträgt etwa 2 bis 15 Gewichtsprozent, vorzugsweise 5 bis 12 Gewichtsprozent.The fatty alcohol contained in the emulsion-like, oxidizing agent-containing component (B) can be of either natural or synthetic origin, with C 14 to C 20 fatty alcohols, in particular cetyl alcohol and stearyl alcohol or mixtures thereof, being preferred. The amount of fatty alcohol used in component (B) is about 2 to 15 percent by weight, preferably 5 to 12 percent by weight.
Die Komponente (B) enthält vorzugsweise etwa 0,1 bis 5 Gewichtsprozent, insbesondere etwa 0,3 bis 3 Gewichtsprozent, eines Polypropylenglykolethers, Polyethylenglykolethers oder Polyethylenglykol/Polypropylenglykolethers. Als Polypropylenglykolether, Polyethylenglykolether oder Polyethylenglykol/Polypropylenglykolether können beispielsweise genannt werden: PPG-16 Butyl Ether, der PPG-1-Component (B) preferably contains about 0.1 to 5% by weight, in particular about 0.3 to 3% by weight, of a polypropylene glycol ether, polyethylene glycol ether or polyethylene glycol/polypropylene glycol ether. Examples of polypropylene glycol ether, polyethylene glycol ether or polyethylene glycol/polypropylene glycol ether are: PPG-16 Butyl Ether, PPG-1-
PEG-9 Lauryl Glykol Ether, PPG-38 Buteth-37 oder PPG-1-PEG-9 Lauryl Ether.PEG-9 Lauryl Glycol Ether, PPG-38 Buteth-37 or PPG-1-PEG-9 Lauryl Ether.
Die Komponente (B) enthält etwa 0,5 bis 10 Gewichtsprozent, vorzugsweise jedoch etwa 1 bis 7 Gewichtsprozent an Acrylates/Steareth-20 Itaconate Copolymer oder Acrylates/Ceteth-20 Itaconate.Component (B) contains about 0.5 to 10 weight percent, but preferably about 1 to 7 weight percent, of Acrylates/Steareth-20 Itaconate Copolymer or Acrylates/Ceteth-20 Itaconate.
Die vorstehenden Gewichtsprozentangaben beziehen sich jeweils auf die Gesamtmenge der Komponente (A) beziehungsweise auf die Gesamtmenge der Komponente (B).The above percentages by weight refer to the total amount of component (A) or to the total amount of component (B).
Ein weiterer Gegenstand der vorliegenden Erfindung ist ein 2-Komponenten-Mittel zum oxidativen Färben von Haaren bestehend aus 2 unmittelbar vor der Anwendung zu vermischenden Komponenten (A) und (B), welches dadurch gekennzeichnet ist, daß die Komponente (A) eine (a) eine Entwicklersubstanz-Kupplersubstanz-Kombination, (b) eine Kombination von nichtionogenen und anionischen oberflächenaktiven Verbindungen, (c) eine Aminosäure und/oder deren Salze und (d) einen 1-oder 2wertigen Alkohol enthaltende flüssige Farbträgermasse mit einer Viskosität von weniger als 100 mPa.s ist, und die Komponente (B) eine (a) ein Oxidationsmittel, (b) 2,5 bis 12 Gewichtsprozent mindestens eines C10- bis C24- Fettalkohols natürlicher oder synthetischer Herkunft und (c) einen Polypropylenglykolether („PPG-Ether") Polyethylenglykolether („PEG-Ether") oder Polyethylenglykol/ Polypropylenglykolether („PEG-PPG-Ether" bzw. „PPG-PEG-Ether") sowie (d) ein Acrylsäurepolymerisat aus der Gruppe bestehend aus Acrylates/Steareth-20 Itaconate Copolymer und Acrylates/Ceteth-20 Itaconate Copolymer enthaltende emulsionsförmige Zusammensetzung darstellt.Another subject of the present invention is a 2-component agent for oxidatively dyeing hair, consisting of 2 components (A) and (B) to be mixed immediately before use, which is characterized in that component (A) is (a) a developer substance-coupler substance combination, (b) a combination of non-ionic and anionic surface-active compounds, (c) an amino acid and/or salts thereof and (d) a liquid color carrier mass containing a monohydric or dihydric alcohol and having a viscosity of less than 100 mPa.s, and component (B) is (a) an oxidizing agent, (b) 2.5 to 12 percent by weight of at least one C 10 - to C 24 - fatty alcohol of natural or synthetic origin and (c) a polypropylene glycol ether ("PPG ether"), polyethylene glycol ether ("PEG ether") or polyethylene glycol/polypropylene glycol ether. ("PEG-PPG ether" or "PPG-PEG ether") and (d) an acrylic acid polymer selected from the group consisting of Acrylates/Steareth-20 Itaconate Copolymer and Acrylates/Ceteth-20 Itaconate Copolymer.
Das durch Mischen der Komponente (A) mit der Komponente (B) erhaltene gebrauchsfertige Mittel zum oxidativen Färben der Haare kann sowohl schwach sauer als auch alkalisch eingestellt sein; vorzugsweise liegt der pH-Wert des erfindungsgemäßen Mittels bei etwa 6,5 bis 12.The ready-to-use agent for oxidative hair dyeing obtained by mixing component (A) with component (B) can be either slightly acidic or alkaline; the pH of the agent according to the invention is preferably about 6.5 to 12.
Die Anwendung des erfindungsgemäßen Oxidationshaarfärbemittels erfolgt indem man die flüssige Farbträgermasse (Komponente (A)) unmittelbar vor dem Gebrauch mit der Wasserstoffperoxidemulsion (Komponente (B)) in einem Gewichtsverhältnis von 1 : 1 bis 1 : 4 , vorzugsweise in einem Gewichtsverhältnis von 1 : 1 bis 1 : 3, vermischt, und sodann eine für die Haarfärbung ausreichende Menge des so erhaltenen Färbemittels, je nach Haarfülle im allgemeinen 60 bis 160 g, auf das Haar aufträgt. Nach einer Einwirkungszeit von etwa 5 bis 60 Minuten, vorzugsweise etwa 20 bis 30 Minuten, bei 15 bis 50 Grad Celsius wird das Haar mit Wasser ausgespült, gegebenenfalls mit einem Shampoo gewaschen und getrocknet. Falls erforderlich kann das Haar vor dem Trocknen zur Frisur gelegt werden.The oxidation hair dye according to the invention is used by mixing the liquid dye carrier mass (component (A)) with the hydrogen peroxide emulsion (component (B)) immediately before use in a weight ratio of 1:1 to 1:4, preferably in a weight ratio of 1:1 to 1:3, and then applying a sufficient amount of the dye thus obtained to dye the hair, generally 60 to 160 g depending on the thickness of the hair, to the hair. After an exposure time of about 5 to 60 minutes, preferably about 20 to 30 minutes, at 15 to 50 degrees Celsius, the hair is rinsed with water, washed with a shampoo if necessary and dried. If necessary, the hair can be styled before drying.
Die nachfolgenden Beispiele sollen den Gegenstand der Erfindung näher erläutern, ohne den Gegenstand auf diese Beispiele zu beschränken.The following examples are intended to illustrate the subject matter of the invention in more detail without restricting the subject matter to these examples.
13 Beispiele13 Examples
Beispiel 1: Oxidationshaarfärbemittel zur Hellerfärbung Example 1 : Oxidation hair dye for lightening
10,0 g Cetylstearylalkohol10.0 g cetylstearyl alcohol
1,5 g Acrylates/Steareth-20 Itaconate Coploymer (Structure 2001 der National Starch & Chemical Company/USA) 4,0 g Polyoxyethylen(37)polyoxypropylen(38)butylether1.5 g Acrylates/Steareth-20 Itaconate Coploymer (Structure 2001 from National Starch & Chemical Company/USA) 4.0 g polyoxyethylene (37) polyoxypropylene (38) butyl ether
(PPG-38 Buteth-37)
4,0 g Natriumlaurylalkohol-diglykolethersulfat,(PPG-38 Buteth-37)
4.0 g sodium lauryl alcohol diglycol ether sulfate,
28 %ige wäßrige Lösung28% aqueous solution
35,0 g Wasserstoffperoxid, 35 %ige wäßrige Lösung ad 100,0 g Wasser35.0 g hydrogen peroxide, 35 % aqueous solution ad 100.0 g water
Man vermischt vor dem Gebrauch 40 g der flüssigen Farbträgermasse (A) mit 80 g der Wasserstoffperoxid-Emulsion (B). Der pH-Wert des durch Vermischen von (A) und (B) erhaltenen gebrauchsfertigen Mittels beträgt 9,5.Before use, 40 g of the liquid color carrier mass (A) are mixed with 80 g of the hydrogen peroxide emulsion (B). The pH of the ready-to-use product obtained by mixing (A) and (B) is 9.5.
Man trägt 120 g des gebrauchsfertigen Mittels auf mittelbraune, menschliche Haare auf und läßt das Gemisch 20 Minuten bei Raumtemperatur einwirken. Danach wird das Haarfärbegemisch mit Wasser ausgespült und das Haar getrocknet. Das so behandelte Haar ist vom Haaransatz bis zu den Haarspitzen gleichmäßig hellbraun gefärbt. Das erfindungsgemäße Mittel zum oxidativen Färben von Haaren läßt sich sehr leicht auftragen und verteilen; dunkelt während der Einwirkzeit nur geringfügig nach; riecht nur schwach nach Ammoniak und ist gut hautvertäglich. Das Haar besitzt sowohl in nassem als auch im trockenen Zustand einen weichen und glatten Griff.Apply 120 g of the ready-to-use product to medium brown human hair and allow the mixture to work for 20 minutes at room temperature. The hair dye mixture is then rinsed out with water and the hair is dried. The hair treated in this way is evenly colored light brown from the roots to the tips. The product according to the invention for oxidative hair dyeing is very easy to apply and distribute; it only darkens slightly during the exposure time; it only smells faintly of ammonia and is well tolerated by the skin. The hair has a soft and smooth feel both when wet and when dry.
Beispiel 2: OxidationshaarfärbemittelExample 2: Oxidation hair dye
2,8 g 2,5-Diaminotoluolsulfat2.8 g 2,5-diaminotoluene sulfate
1,0 g Resorcin1.0 g resorcinol
0,4 g m-Aminophenol0.4 g m-aminophenol
0,2 g 2-Amino-4-(2'-hydroxyethylamino)-anisolsulfat0.2 g 2-amino-4-(2'-hydroxyethylamino)anisole sulfate
5,0 g Laurylglucosid (Plantaren 1200 der Henkel KGaA/DE)5.0 g lauryl glucoside (Plantaren 1200 from Henkel KGaA/DE)
5,0 g Natriurnlaurylalkohol-diglykolethersulfat, 28 %ige5.0 g sodium lauryl alcohol diglycol ether sulfate, 28%
wäßrige Lösungaqueous solution
0,1 g Valin0.1 g valine
0,3 g Ascorbinsäure0.3 g ascorbic acid
0,1 g Ethylendiamintetraessigsäure0.1 g ethylenediaminetetraacetic acid
0,1 g Keratinhydrolysat0.1 g keratin hydrolysate
12,2 g Ammoniak, 25 %ige wäßrige Lösung12.2 g ammonia, 25% aqueous solution
16,0 g Propylenglykol16.0 g propylene glycol
ad 100,0 g Wasserad 100.0 g water
Komponente (B): Wasserstoffperoxid - Emulsion 10,0 g Cetylstearylalkohol
3,0 g Acrylates/Ceteth-20 Itaconate Coploymer (Structure Component (B): Hydrogen peroxide emulsion 10.0 g Cetylstearyl alcohol
3.0 g Acrylates/Ceteth-20 Itaconate Coploymer (Structure
3001 der National Starch & Chemical Company/USA) 5,0 g Polyoxypropylenoxid(1)polyoxyethylenoxid(9)3001 from National Starch & Chemical Company/USA) 5.0 g polyoxypropylene oxide (1) polyoxyethylene oxide (9)
laurylether (PPG-1-PEG-9 Lauryl Ether) 4,0 g Natriumlaurylalkohol-diglykolethersulfat, 28 %igelauryl ether (PPG-1-PEG-9 lauryl ether) 4.0 g sodium lauryl alcohol diglycol ether sulfate, 28%
wäßrige Lösung
20,0 g Wasserstoffperoxid, 35 %ige wäßrige Lösungaqueous solution
20.0 g hydrogen peroxide, 35 % aqueous solution
0,3 g Parfüm
ad 100,0 g Wasser0.3 g perfume
ad 100.0 g water
Man vermischt vor dem Gebrauch 40 g der flüssigen Farbträgermasse mit g der Wasserstoffperoxid-Emulsion. Der pH-Wert des erhaltenen gebrauchsfertigen Mittels beträgt 10.Before use, mix 40 g of the liquid color carrier mass with 10 g of the hydrogen peroxide emulsion. The pH value of the resulting ready-to-use product is 10.
Man trägt 120 g des gebrauchsfertigen Mittels auf graues, menschliches Haar auf und läßt das Gemisch 20 Minuten bei Raumtemperatur einwirken. Anschließend wird das Haarfärbegemisch mit Wasser ausgespült und das Haar getrocknet. Das erfindungsgemäße Mittel zum oxidativen Färben von Haaren riecht nur schwach nach Ammoniak; läßt sich sehr leicht auftragen und verteilen;dunkelt nach dem Zumischen desApply 120 g of the ready-to-use product to grey human hair and allow the mixture to work for 20 minutes at room temperature. The hair dye mixture is then rinsed out with water and the hair is dried. The product according to the invention for oxidative hair dyeing has only a faint smell of ammonia; is very easy to apply and distribute; darkens after the
Oxidationsmittels kaum nach und ist gut hautverträglich. Das so behandelte Haar hat einen gleichmäßigen, dunkelbraunen Ton angenommen und weist einen glatten, angenehmen Griff auf.The color hardly changes in color due to the oxidizing agent and is well tolerated by the skin. The hair treated in this way has taken on a uniform, dark brown tone and is smooth and pleasant to the touch.
Die in der vorliegenden Anmeldungen enthaltenen Viskositätsangaben beziehen sich auf mit einem Rotationsviskosimeter bei 25 0C ermittelte Viskositätswerte (beispielsweise einem Rotationsviskosimeter der Firma Haake, Typ ROTOVISCO 12 unter Verwendung der Meßeinrichtung MV (DIN 53018) [Meßkörper: R= 20,04 mm; L= 60 mm; Meßbecher: R3= 21 mm; Ra/Rj= 1,05; Spaltweite= 0,96 mm; Systemfaktoren: f= 65,7 Pa/Ncm und M= 2,34 min/s]The viscosity data contained in the present application refer to viscosity values determined with a rotational viscometer at 25 0 C (for example a rotational viscometer from Haake, type ROTOVISCO 12 using the measuring device MV (DIN 53018) [measuring body: R = 20.04 mm; L = 60 mm; measuring cup: R 3 = 21 mm; R a /Rj = 1.05; gap width = 0.96 mm; system factors: f = 65.7 Pa/Ncm and M = 2.34 min/s]
Alle in der vorliegenden Anmeldung angegebenen Prozentzahlen stellen, soweit nicht anders angegeben, Gewichtsprozente darAll percentages given in this application are by weight unless otherwise stated
Claims (14)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE29923520U DE29923520U1 (en) | 1999-05-12 | 1999-05-12 | Oxidation hair dye |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE29923520U DE29923520U1 (en) | 1999-05-12 | 1999-05-12 | Oxidation hair dye |
| DE1999121962 DE19921962C2 (en) | 1999-05-12 | 1999-05-12 | Means and methods for the oxidative dyeing of hair |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE29923520U1 true DE29923520U1 (en) | 2000-10-05 |
Family
ID=26053331
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE29923520U Expired - Lifetime DE29923520U1 (en) | 1999-05-12 | 1999-05-12 | Oxidation hair dye |
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| Country | Link |
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| DE (1) | DE29923520U1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2013039887A3 (en) * | 2011-09-12 | 2014-03-20 | The Procter & Gamble Company | Method for colouring hair |
-
1999
- 1999-05-12 DE DE29923520U patent/DE29923520U1/en not_active Expired - Lifetime
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2013039887A3 (en) * | 2011-09-12 | 2014-03-20 | The Procter & Gamble Company | Method for colouring hair |
| EP2898877A1 (en) * | 2011-09-12 | 2015-07-29 | The Procter and Gamble Company | Method for colouring hair |
| US10625101B2 (en) | 2011-09-12 | 2020-04-21 | Noxell Corporation | Method for colouring hair |
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