DE2752320A1 - COSMETIC PREPARATION - Google Patents
COSMETIC PREPARATIONInfo
- Publication number
- DE2752320A1 DE2752320A1 DE19772752320 DE2752320A DE2752320A1 DE 2752320 A1 DE2752320 A1 DE 2752320A1 DE 19772752320 DE19772752320 DE 19772752320 DE 2752320 A DE2752320 A DE 2752320A DE 2752320 A1 DE2752320 A1 DE 2752320A1
- Authority
- DE
- Germany
- Prior art keywords
- cosmetic preparation
- preparation according
- cellulose
- colored
- aryl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000002360 preparation method Methods 0.000 title claims description 31
- 239000002537 cosmetic Substances 0.000 title claims description 29
- 239000001913 cellulose Substances 0.000 claims description 31
- 229920002678 cellulose Polymers 0.000 claims description 31
- 239000000843 powder Substances 0.000 claims description 14
- 239000000126 substance Substances 0.000 claims description 14
- 239000002453 shampoo Substances 0.000 claims description 13
- 150000003839 salts Chemical class 0.000 claims description 12
- 125000003118 aryl group Chemical group 0.000 claims description 11
- 125000000217 alkyl group Chemical group 0.000 claims description 10
- 230000002421 anti-septic effect Effects 0.000 claims description 9
- 238000004040 coloring Methods 0.000 claims description 8
- 229910052751 metal Inorganic materials 0.000 claims description 8
- 239000002184 metal Substances 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 7
- 239000002304 perfume Substances 0.000 claims description 7
- 229910052736 halogen Inorganic materials 0.000 claims description 6
- 150000002367 halogens Chemical class 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 5
- 239000003638 chemical reducing agent Substances 0.000 claims description 5
- 239000012286 potassium permanganate Substances 0.000 claims description 5
- 239000000758 substrate Substances 0.000 claims description 5
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 4
- 239000004480 active ingredient Substances 0.000 claims description 4
- 150000004982 aromatic amines Chemical class 0.000 claims description 4
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 4
- 229910052794 bromium Inorganic materials 0.000 claims description 4
- 229910052801 chlorine Inorganic materials 0.000 claims description 4
- 239000000460 chlorine Substances 0.000 claims description 4
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 claims description 4
- 230000003647 oxidation Effects 0.000 claims description 4
- 238000007254 oxidation reaction Methods 0.000 claims description 4
- 239000000049 pigment Substances 0.000 claims description 4
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims description 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 3
- 230000000844 anti-bacterial effect Effects 0.000 claims description 3
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 3
- 239000003153 chemical reaction reagent Substances 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 229910052731 fluorine Inorganic materials 0.000 claims description 3
- 239000011737 fluorine Substances 0.000 claims description 3
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims description 3
- 229910044991 metal oxide Inorganic materials 0.000 claims description 3
- 150000004706 metal oxides Chemical class 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 claims description 2
- 150000007530 organic bases Chemical class 0.000 claims description 2
- 238000000034 method Methods 0.000 claims 6
- 150000003856 quaternary ammonium compounds Chemical class 0.000 claims 2
- 239000002904 solvent Substances 0.000 claims 2
- 229940064004 antiseptic throat preparations Drugs 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 239000000725 suspension Substances 0.000 claims 1
- 235000010980 cellulose Nutrition 0.000 description 24
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 10
- 229940078916 carbamide peroxide Drugs 0.000 description 6
- AQLJVWUFPCUVLO-UHFFFAOYSA-N urea hydrogen peroxide Chemical compound OO.NC(N)=O AQLJVWUFPCUVLO-UHFFFAOYSA-N 0.000 description 6
- 229920002472 Starch Polymers 0.000 description 5
- 235000019698 starch Nutrition 0.000 description 5
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 4
- 239000003463 adsorbent Substances 0.000 description 4
- 239000003899 bactericide agent Substances 0.000 description 4
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 4
- 239000000975 dye Substances 0.000 description 4
- -1 m-toluenediamine sulfate Chemical compound 0.000 description 4
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 4
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- YBJHBAHKTGYVGT-ZKWXMUAHSA-N (+)-Biotin Chemical compound N1C(=O)N[C@@H]2[C@H](CCCCC(=O)O)SC[C@@H]21 YBJHBAHKTGYVGT-ZKWXMUAHSA-N 0.000 description 2
- KZTWOUOZKZQDMN-UHFFFAOYSA-N 2,5-diaminotoluene sulfate Chemical compound OS(O)(=O)=O.CC1=CC(N)=CC=C1N KZTWOUOZKZQDMN-UHFFFAOYSA-N 0.000 description 2
- VLZVIIYRNMWPSN-UHFFFAOYSA-N 2-Amino-4-nitrophenol Chemical compound NC1=CC([N+]([O-])=O)=CC=C1O VLZVIIYRNMWPSN-UHFFFAOYSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- HVHNMNGARPCGGD-UHFFFAOYSA-N 2-nitro-p-phenylenediamine Chemical compound NC1=CC=C(N)C([N+]([O-])=O)=C1 HVHNMNGARPCGGD-UHFFFAOYSA-N 0.000 description 2
- OOZQLPDAELLDNY-UHFFFAOYSA-N 4-n-(4-aminophenyl)benzene-1,4-diamine;sulfuric acid Chemical compound OS(O)(=O)=O.C1=CC(N)=CC=C1NC1=CC=C(N)C=C1 OOZQLPDAELLDNY-UHFFFAOYSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- ORILYTVJVMAKLC-UHFFFAOYSA-N adamantane Chemical compound C1C(C2)CC3CC1CC2C3 ORILYTVJVMAKLC-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000003380 propellant Substances 0.000 description 2
- 229940079877 pyrogallol Drugs 0.000 description 2
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- LDXYDHGRKFMULJ-UHFFFAOYSA-N (3-azaniumylphenyl)azanium;sulfate Chemical compound OS(O)(=O)=O.NC1=CC=CC(N)=C1 LDXYDHGRKFMULJ-UHFFFAOYSA-N 0.000 description 1
- 229940075147 2,5-diaminotoluene sulfate Drugs 0.000 description 1
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 description 1
- IIXKYPNYBBSSER-UHFFFAOYSA-N 2-methylbenzene-1,3-diamine;sulfuric acid Chemical compound OS(O)(=O)=O.CC1=C(N)C=CC=C1N IIXKYPNYBBSSER-UHFFFAOYSA-N 0.000 description 1
- ZJSSDJCFSASGNQ-UHFFFAOYSA-N 4-(hydroxymethyl)pyridine-2-carbonitrile Chemical compound OCC1=CC=NC(C#N)=C1 ZJSSDJCFSASGNQ-UHFFFAOYSA-N 0.000 description 1
- HDGMAACKJSBLMW-UHFFFAOYSA-N 4-amino-2-methylphenol Chemical compound CC1=CC(N)=CC=C1O HDGMAACKJSBLMW-UHFFFAOYSA-N 0.000 description 1
- RAUWPNXIALNKQM-UHFFFAOYSA-N 4-nitro-1,2-phenylenediamine Chemical compound NC1=CC=C([N+]([O-])=O)C=C1N RAUWPNXIALNKQM-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- 229920002261 Corn starch Polymers 0.000 description 1
- SNPLKNRPJHDVJA-ZETCQYMHSA-N D-panthenol Chemical class OCC(C)(C)[C@@H](O)C(=O)NCCCO SNPLKNRPJHDVJA-ZETCQYMHSA-N 0.000 description 1
- ZAKOWWREFLAJOT-UHFFFAOYSA-N DL-alpha-tocopherylacetate Chemical compound CC(=O)OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C ZAKOWWREFLAJOT-UHFFFAOYSA-N 0.000 description 1
- 229920000168 Microcrystalline cellulose Polymers 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 239000005662 Paraffin oil Substances 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- BRCUNOJKRUQJGR-UHFFFAOYSA-N [Cl-].C(C1CO1)[NH2+]C(C1=CC=CC=C1)C1=CC=CC=C1 Chemical compound [Cl-].C(C1CO1)[NH2+]C(C1=CC=CC=C1)C1=CC=CC=C1 BRCUNOJKRUQJGR-UHFFFAOYSA-N 0.000 description 1
- 230000000274 adsorptive effect Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 229960002685 biotin Drugs 0.000 description 1
- 235000020958 biotin Nutrition 0.000 description 1
- 239000011616 biotin Substances 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000008119 colloidal silica Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- ITQRVMZJBMZUBB-UHFFFAOYSA-M dimethyl(diphenyl)azanium;chloride Chemical compound [Cl-].C=1C=CC=CC=1[N+](C)(C)C1=CC=CC=C1 ITQRVMZJBMZUBB-UHFFFAOYSA-M 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- PASCYLAFGHJSHW-UHFFFAOYSA-N ethyl 2-[(4-methoxyphenyl)methyl]-3-(methylamino)propanoate Chemical compound CCOC(=O)C(CNC)CC1=CC=C(OC)C=C1 PASCYLAFGHJSHW-UHFFFAOYSA-N 0.000 description 1
- 239000004744 fabric Chemical class 0.000 description 1
- 210000004907 gland Anatomy 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000012676 herbal extract Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical class Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 1
- 235000013980 iron oxide Nutrition 0.000 description 1
- 159000000014 iron salts Chemical class 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical class [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 150000002696 manganese Chemical class 0.000 description 1
- PPNAOCWZXJOHFK-UHFFFAOYSA-N manganese(2+);oxygen(2-) Chemical class [O-2].[Mn+2] PPNAOCWZXJOHFK-UHFFFAOYSA-N 0.000 description 1
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 description 1
- 229910000357 manganese(II) sulfate Inorganic materials 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- OGGXBSGFTTXROS-UHFFFAOYSA-M methyl(triphenyl)azanium;chloride Chemical compound [Cl-].C=1C=CC=CC=1[N+](C=1C=CC=CC=1)(C)C1=CC=CC=C1 OGGXBSGFTTXROS-UHFFFAOYSA-M 0.000 description 1
- 235000019813 microcrystalline cellulose Nutrition 0.000 description 1
- 239000008108 microcrystalline cellulose Substances 0.000 description 1
- 229940016286 microcrystalline cellulose Drugs 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 239000012875 nonionic emulsifier Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 210000004761 scalp Anatomy 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 235000010356 sorbitol Nutrition 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical class [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0216—Solid or semisolid forms
- A61K8/022—Powders; Compacted Powders
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/43—Pigments; Dyes
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
Description
Patenr-inwälleSponsorship walls
n. Dr-Fr. ·:: Lcdsrcr 275232Q n . Dr-Fr. · :: Lcdsrcr 275232Q
3000 iviun -hen SO ^ 3000 iviun -hen SO ^
RAN 6400/12RAN 6400/12
Die vorliegende Erfindung betrifft ein gefärbtes, pulverförmiges kosmetisches Präparat, welches insbesondere als Trockenshampoo geeignet ist.The present invention relates to a colored, powdery cosmetic preparation, which in particular as Dry shampoo is suitable.
Die auf dem Markt erhältlichen Trockenshampoos sind Pulvermischungen, die aus verschiedenen Komponenten bestehen, wie Weizen-, Reis- und Maisstärken, Kaolin, Talcum, Metallstearaten und Carbonaten sowie kolloider Kieselsäure, Kieselgur usw. Diese Komponenten werden in entsprechenden Mischtrommeln vermengt und quantitativ variiert.The dry shampoos available on the market are powder mixtures that consist of different components, such as wheat, rice and corn starches, kaolin, talc, metal stearates and carbonates as well as colloidal silica, kieselguhr etc. These components are mixed in appropriate mixing drums and varied quantitatively.
Ihre Wirkung beruht auf einer Saugfähigkeit gegenüber Fettstoffen der Talgdrüsen, die sich aufgrund ihres Spreitvermögens über die Oberfläche der Haut und der Haare verteilen, wobei verschiedene Komponenten, z.B. die Stärken, mit Fettstoffen zur Hauptsache konglomerieren. Rückstände dieser Trockenshampoos verbleiben immer teilweise auf Kopfhaut und Haaren.Their effect is based on their ability to absorb fatty substances in the sebum glands, which are due to their ability to spread Spread over the surface of the skin and hair, using various components, e.g. the starches, with fatty substances mainly conglomerate. Residues from these dry shampoos always remain partially on the scalp and hair.
809822/0791809822/0791
Da die verwendeten Komponenten meist weiss sind, bleiben diese Rückstände deutlich sichtbar, insbesondere auf dunkelblonden bis schwarzen Haaren. Diese Rückstände lassen sich - bedingt durch die Struktur der Haare - nie vollständig ausbürsten. Solche Rückstände stören aber den angestrebten kosmetischen Effekt und wirken unästhetisch.Since the components used are mostly white, these residues remain clearly visible, especially on dark blond ones to black hair. Due to the structure of the hair, these residues can never be brushed out completely. Such residues, however, interfere with the desired cosmetic effect and have an unaesthetic effect.
Es ist deshalb auch nicht verwunderlich, dass bereits versucht wurde, gefärbte Trockenshampoos herzustellen, wobei gefärbte Stärke als Farbstoffträger und Adsorptionsmittel verwendet wurde. Da Stärken - wie bereits erwähnt - mit Fett zusammenballen anstatt dieses nur zu adsorbieren, haben Stärke enthaltende Trockenshampoos den Nachteil, dass es nötig ist, noch zusätzlich Stoffe mit hohem Adsorptionsvermögen, wie z.B. Silikagel, beizugeben. Ausserdem sind Stärken Nährböden für Bakterien sobald sie mit verunreinigten Fetten oder Luftfeuchtigkeit gesättigt sind.It is therefore not surprising that attempts have already been made to produce colored dry shampoos, with colored Starch was used as a dye carrier and adsorbent. Because starches - as already mentioned - with fat instead of just adsorbing it, dry shampoos containing starch have the disadvantage that it is necessary to substances with a high adsorptive capacity, such as silica gel, must also be added. In addition, starches are breeding grounds for Bacteria as soon as they are contaminated with fats or humidity are saturated.
Erfindungsgemäss wurde nun ein kosmetisches Präparat geschaffen, welches die obigen Nachteile nicht aufweist.According to the invention, a cosmetic preparation has now been created which does not have the above disadvantages.
Genauer gesagt betrifft die vorliegende Erfindung ein kosmetisches Präparat, welches gefärbte pulverförmige Cellulose als Adsorptionsmittel enthält.More specifically, the present invention relates to a cosmetic preparation containing colored powdery cellulose contains as an adsorbent.
Ganz besonders bevorzugt ist Cellulose mit einer Teilchengrösse zwischen 5 und 40 Mm, vorzugsweise zwischen 10 und 30 μΐη.Cellulose with a particle size between 5 and 40 μm, preferably between 10 and 30 μm, is very particularly preferred.
Das erfindungsgemässe pulverförmige kosmetische Präparat kann hergestellt werden, indem man das Adsorptionsmittel anfärbt und anschliessend trocknet und gegebenenfalls auf einer beliebigen Stufe Wirk- und/oder Hilfsstoffe zusetzt.The powdery cosmetic preparation according to the invention can be prepared by staining the adsorbent and then drying and optionally on a any level of active ingredients and / or auxiliaries added.
Geeignete Stoffe zur Färbung der Cellulose sind solche, welche weder wasser- noch lösungsmittel-löslich sind. Das Verhältnis vom farbgebenden Stoff zur Cellulose liegt je nach der gewünschten Färbung zwischen 0,1 und 8 Gewichtsprozente bezogenSuitable substances for coloring cellulose are those which are neither water nor solvent-soluble. The relationship from the coloring substance to the cellulose is between 0.1 and 8 percent by weight, depending on the desired color
809822/0791809822/0791
auf das Gewicht an Cellulose.on the weight of cellulose.
In diesem Zusammenhang eignen sich als farbgebende Mittel Metallverbindungen, insbesondere Metalloxyde. Besonders geeignete Metalloxyde sind Eisenoxyde und Manganoxyde. In diesem Fall wird ein geeignetes Metallsalz in einem organischen Lösungsmittel wie Alkohol oder Aceton gelöst und der Cellulose zugesetzt. Nach einigen Stunden werden die Metallsalze mit einem geeigneten Reagenz, wie z.B. einem Reduktions- oder einem Oxydationsmittel, in wasserunlösliche, gefärbte Pigmente, vorzugsweise Oxyde oder Mischungen von Oxyden, übergeführt. Das auf diese Weise gefärbte Substrat wird anschliessend getrocknet.In this context, metal compounds, in particular metal oxides, are suitable as coloring agents. Particularly suitable Metal oxides are iron oxides and manganese oxides. In this case, a suitable metal salt is used in an organic Solvents such as alcohol or acetone dissolved and added to the cellulose. After a few hours the metal salts will be with a suitable reagent, such as a reducing or oxidizing agent, into water-insoluble, colored pigments, preferably Oxides or mixtures of oxides. The substrate colored in this way is then dried.
Besonders geeignete Metallsalze sind Eisensalze wie z.B. Eisen-chloride und Eisen-sulfate, Mangansalze wie Kaliumpermanganat und Mangan(II)-sulfat.Particularly suitable metal salts are iron salts such as iron chlorides and iron sulfates, manganese salts such as potassium permanganate and manganese (II) sulfate.
Geeignete Reagenzien zum Ueberführen der Metallsalze in wasserunlösliche Pigmente sind Sauerstoff, Wasserstoffperoxyd, Carbamidperoxyd, Methanol und Aethanol.Suitable reagents for converting the metal salts into water-insoluble pigments are oxygen, hydrogen peroxide, Carbamide peroxide, methanol and ethanol.
Weiter eignen sich als farbgebende Stoffe Oxydationsfarbstoffe. In diesem Fall wird ein Gemisch von farbstoffbildenden Säureadditionssalzen von aromatischen Aminen, Reduktionsmitteln und Stoffen zur Steuerung der gewünschten Nuance, hergestellt. Anschliessend werden die Säureadditionssalze von aromatischen Aminen mit organischen Basen wie Triäthanolamin oder Monoäthanolamin in die entsprechenden freien Basen überführt, die entstandene Mischung in Gegenwart eines geeigneten Netzmittels in Alkohol gelöst und Cellulose zugesetzt. Nach einigen Stunden wird durch Oxydation mit einem üblichen Oxydationsmittel, wie z.B. Wasserstoffperoxyd, Carbamidperoxyd oder Sauerstoff, der Farbstoff auf dem Substrat gebildet und das auf diese Weise gefärbte Substrat getrocknet.Oxidation dyes are also suitable as coloring substances. In this case, a mixture of dye-forming acid addition salts of aromatic amines, reducing agents and fabrics to control the desired shade. Then the acid addition salts are aromatic Amines with organic bases such as triethanolamine or monoethanolamine converted into the corresponding free bases, the resulting mixture in the presence of a suitable wetting agent in Dissolved alcohol and added cellulose. After a few hours, oxidation with a common oxidizing agent such as e.g. hydrogen peroxide, carbamide peroxide or oxygen, the dye formed on the substrate and the one colored in this way Substrate dried.
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Besonders geeignete Säureadditionssalze von aromatischen Aminen sind z.B. p-Toluylendiaminsulfat, 4,4'-Diaminodiphenylaminsulfat, 2,5-Diaminoanisolsulfat, m-Phenylendiaminsulfat und asymmetrisches m-Toluylendiaminsulfat.Particularly suitable acid addition salts of aromatic amines are, for example, p-tolylenediamine sulfate, 4,4'-diaminodiphenylamine sulfate, 2,5-diaminoanisole sulfate, m-phenylenediamine sulfate and asymmetric m-toluenediamine sulfate.
Als Reduktionsmittel kann Natriumsulfit eingesetzt werden. Als weitere Reduktionsmittel werden Dioxybenzole, d.h. Brenzcatechin, Resorcin und/oder Hydrochinon und/oder Trioxybenzole wie Pyrogallol besonders bevorzugt, v/eil sie gleichzeitig zur Steuerung der Nuance beitragen.Sodium sulfite can be used as a reducing agent. Dioxybenzenes, i.e. pyrocatechol, resorcinol and / or hydroquinone and / or trioxybenzenes, are used as further reducing agents like pyrogallol particularly preferred, v / eil they simultaneously contribute to the control of the nuance.
Als weitere Substanzen zur Steuerung der Nuance können nitrierte oder aminierte aromatische Kohlenwasserstoffe wie p-Amino-o-kresol, 4-Nitro-o-phenylendiamin, 2-Nitro-p-phenylendiamin und 4-Nitro-2-aminophenol eingesetzt werden.Nitrated or aminated aromatic hydrocarbons such as p-amino-o-cresol, 4-nitro-o-phenylenediamine, 2-nitro-p-phenylenediamine and 4-nitro-2-aminophenol can be used.
Das gefärbte pulverförmige kosmetische Präparat kann zusätzlich noch Wirkstoffe wie z.B. bakterizide Mittel und/oder Substanzen wie Biotin, Panthenol-derivate und/oder Kräuterextrakte enthalten. Mit Vorteil beträgt die Menge an bakteriziden Mitteln im erfindungsgemässen Präparat 0,01 bis 5 Gewichtsprozente bezogen auf Cellulose. Bei Verwendung des erfindungsgemässen Präparats als Trockenshampoo beträgt die Menge an bakteriziden Mitteln vorzugsweise 0,01 bis 0,1 Gewichtsprozente bezogen auf Cellulose, während bei Verwendung als antiseptisches Puder die Menge an bakteriziden Mitteln bezogen auf Cellulose vorzugsweise zwischen 2 und 5 Gewichtsprozenten liegt.The colored powdery cosmetic preparation can also contain active ingredients such as bactericidal agents and / or Contain substances such as biotin, panthenol derivatives and / or herbal extracts. The amount of bactericidal is advantageous Agents in the preparation according to the invention 0.01 to 5 percent by weight based on cellulose. When the preparation according to the invention is used as a dry shampoo, the amount is bactericidal agents preferably 0.01 to 0.1 percent by weight based on cellulose, while when used as an antiseptic Powder, the amount of bactericidal agents based on cellulose is preferably between 2 and 5 percent by weight.
So kann z.B. gefärbte Cellulose mit der Wirkstofflösung eines quaternären Ammoniumsalzes oder 1-(3-Chlorallyl)-3,5,7-triaza-1-azonia adamantan (Dowicil), einzeln oder zusammen durchtränkt und anschliessend unter Bewegung schonend getrocknet werden. Als quaternäre Ammoniumsalze eignen sich beispielsweise Verbindungen der folgenden Struktur:For example, colored cellulose can be mixed with the active ingredient solution a quaternary ammonium salt or 1- (3-chloroallyl) -3,5,7-triaza-1-azonia adamantan (Dowicil), individually or together soaked and then gently dried while moving. Examples of suitable quaternary ammonium salts are Connections of the following structure:
809822/0791809822/0791
•Ν• Ν
Halogenhalogen
worin R, Methyl, R„ Alkyl oder Aryl, R3 Alkyl oder Aryl, R. Alkyl, Aryl, Aralkyl oder Glycidyl und Halogen Fluor, Chlor, Brom oder Jod bedeuten.in which R, methyl, R "is alkyl or aryl, R 3 is alkyl or aryl, R. is alkyl, aryl, aralkyl or glycidyl and halogen is fluorine, chlorine, bromine or iodine.
Der Ausdruck "Alkyl" umfasst geradkettige oder verzweigte Kohlenwasserstoffe mit bis zu 20 Kohlenstoffatomen. Der Ausdruck "Aryl" bedeutet ein aromatisches Ringsystem mit 6 bis 12 Kohlenstoffatomen, vorzugsweise Phenyl. Der Ausdruck "Halogen" umfasst Fluor, Chlor, Brom und Jod, vorzugsweise Chlor oder Brom.The term "alkyl" embraces straight or branched chain hydrocarbons having up to 20 carbon atoms. The expression "Aryl" means an aromatic ring system with 6 to 12 carbon atoms, preferably phenyl. The term "halogen" includes fluorine, chlorine, bromine and iodine, preferably chlorine or bromine.
Ganz besonders geeignet sind folgende Verbindungen:The following compounds are particularly suitable:
Methyltriphenylammoniumchlorid bzw. bromid Dimethyldiphenylammoniumchlorid bzw. bromid Trimethylphenylammoniumchlorid bzw. bromid Glycidyldiphenylmethylammoniumchlorid Distearyldimethylammoniumchlorid.Methyltriphenylammonium chloride or bromide, dimethyldiphenylammonium chloride or bromide Trimethylphenylammonium chloride or glycidyldiphenylmethylammonium chloride bromide Distearyl dimethyl ammonium chloride.
Das erfindungsgemässe pulverförmige kosmetische Mittel kann auch noch Hilfsstoffe wie Parfüms, Pflanzenextrakte, Vitamine und Vitaminderivate und zusätzliche übliche kosmetische Pudergrundlagen enthalten.The powdery cosmetic agent according to the invention can also contain auxiliary substances such as perfumes, plant extracts, vitamins and contain vitamin derivatives and additional conventional cosmetic powder bases.
Mit Vorteil beträgt die Menge an Parfüm im erfindungsgemässen Präparat 0,01 bis 0,3 Gewichtsprozente.The amount of perfume in the invention is advantageously Preparation 0.01 to 0.3 percent by weight.
Obwohl das erfindungsgemässe Präparat sich ganz besondersAlthough the preparation according to the invention is very special
als Trockenshampoo eignet kann es auch für andere Zwecke wieAs a dry shampoo, it can also be used for other purposes such as
809822/0791809822/0791
z.B. als Grundlage für Make-up oder als gefärbtes antiseptisches Puder verwendet werden.e.g. used as a basis for make-up or as a colored antiseptic powder.
Das erfindungsgemässe kosmetische Präparat kann je nach Zweck auf verschiedene Weise verabreicht werden, z.B. als Pulver, Puder, Spray, Paste oder Creme. Im Fall eines Trockenshampoos wird ein Puder oder eine Sprayform bevorzugt.The cosmetic preparation of the present invention can be administered in various ways depending on the purpose, e.g., as Powder, powder, spray, paste or cream. In the case of a dry shampoo a powder or spray form is preferred.
Ein Trockenshampoo enthält mit Vorteil ausschliesslich gefärbte Cellulose als Adsorptionsmittel und (abgesehen von allfälligem Treibgas) nur geringe Mengen an Zusätzen. Die Menge dieser Zusätze (meistens Parfüm und ein bakterizides Mittel) übersteigt in der Regel nicht 0,5 Gewichtsprozente.A dry shampoo advantageously contains only colored cellulose as an adsorbent and (apart from any propellant gas) only small amounts of additives. The amount these additives (mostly perfume and a bactericidal agent) usually do not exceed 0.5 percent by weight.
Die Menge an gefärbter Cellulose in einem Make-up oder in einem antiseptischen Puder kann beliebig variiert werden, liegt jedoch mit Vorteil zwischen 5 bis 99,5% bezogen auf das Gesamtgewicht des Präparates.The amount of colored cellulose in a make-up or in an antiseptic powder can be varied as desired but with advantage between 5 to 99.5% based on the total weight of the preparation.
Die Erfindung wird anhand der folgenden Beispiele erläutert. The invention is illustrated by the following examples.
809822/0791809822/0791
275232Q ΑΛ 275232Q ΑΛ
In einen SuIfierkolben, versehen mit Rührwerk, Rückflusskühler, Thermometer und Tropftrichter werdenIn a suIfing flask equipped with a stirrer, reflux condenser, Thermometer and dropping funnel will be
1,2 g 2,5-Diaminotoluolsulfat, 0,4 g Pyrogallol,1.2 g 2,5-diaminotoluene sulfate, 0.4 g pyrogallol,
0,4 g Brenzcatechin, 0,4 g Resorcin,0.4 g catechol, 0.4 g resorcinol,
0,4 g Hydrochinon,0.4 g hydroquinone,
0,2 g 4-Nitro-2-aminophenol, 0,6 g 2-Nitro-p-phenylendiamin, 2,0 g 2,6-Diaminotoluolsulfat, 2,0 g 4,4'-Diaminodiphenylaminsulfat und 4,0 g wasserfreies Na3SO3 0.2 g of 4-nitro-2-aminophenol, 0.6 g of 2-nitro-p-phenylenediamine, 2.0 g of 2,6-diaminotoluene sulfate, 2.0 g of 4,4'-diaminodiphenylamine sulfate and 4.0 g of anhydrous Na 3 SO 3
gegeben.given.
Dieser Mischung werdenThis mix will be
9,0 g Aethanol 94% und 10,0 g Monoäthanolamin9.0 g of 94% ethanol and 10.0 g of monoethanolamine
zugesetzt, und das Gemisch eine halbe Stunde gerührt. Nach ungefähr 30 Minuten werden 3OO ml Aceton zugegeben. Anschliessend werden der erhaltenen Lösung 100 g Cellulose (bis 30 μΐη) zugesetzt. Man lässt unter ständigem Rühren bei gleichbleibender Temperatur während 3-4 Stunden auf die Cellulose adsorbieren. added, and the mixture stirred for half an hour. After about 30 minutes, 300 ml of acetone are added. Afterward 100 g of cellulose (up to 30 μΐη) are added to the resulting solution added. It is allowed to adsorb onto the cellulose for 3-4 hours at constant temperature while stirring continuously.
Anschliessend wird mit 20 ml H2O2 30%igThen, with 20 ml of H 2 O 2, 30% strength
unter langsamen Zutropfen oxydiert. Man lässt weitere 12-14 Stunden unter ständigem Rühren reagieren bis zur vollständigen Oxydation des Farbstoffes.oxidized with slow dropping. It is allowed to react for a further 12-14 hours with constant stirring until it is complete Oxidation of the dye.
809822/0791809822/0791
Ueber der Nutsche wird mit Aceton gewaschen bis die Mutterlauge farblos ist und worauf man bei 7O°C trocknet.It is washed with acetone over the suction filter until the mother liquor is colorless and then dried at 70.degree.
Man erhält eine homogene dunkelbraune Färbung des Substrates, wobei das aufgebaute Pigment wasser- und ölresistent ist.A homogeneous dark brown coloration of the substrate is obtained, the pigment built up being water- and oil-resistant is.
In einem SuIfierkolben mit Thermometer, Rückflusskühler und Rührwerk werden 100 g reine mikrokristalline Cellulose (bis 30 Mm) und 4 g pulverisiertes Kaliumpermanganat während 24 Stunden bei Raumtemperatur unter ständigem Rühren in 500 ml Aceton suspendiert. Anschliessend werden dann 4 ml einer 10%igen Lösung von Carbamidperoxyd in Aceton langsam zugetropft und es wird während 2 Stunden bei Raumtemperatur weitergerührt. Das erhaltene Produkt wird über die Nutsche filtriert. Nach Trocknen bei 80°C in einem Trockenschrank erhält man eine homogen gefärbte mittelbraune Cellulose.In a suIfing flask with thermometer, reflux condenser and agitator, 100 g of pure microcrystalline cellulose (up to 30 µm) and 4 g of powdered potassium permanganate are used for 24 hours suspended in 500 ml of acetone at room temperature with constant stirring. Then 4 ml of a 10% Solution of carbamide peroxide in acetone is slowly added dropwise and stirring is continued for 2 hours at room temperature. That The product obtained is filtered through a suction filter. After drying at 80 ° C. in a drying cabinet, a homogeneously colored medium brown cellulose.
Beispiel 2 wird wiederholt mit H-O- anstatt Carbamidperoxyd. Man erhält ebenfalls eine homogen gefärbte mittelbraune Cellulose.Example 2 is repeated with H-O instead of carbamide peroxide. A homogeneously colored, medium brown cellulose is also obtained.
Beispiel 2 wird wiederholt mit 50 ml CH3OH anstatt 4 ml einer 10%igen Lösung von Carbamidperoxyd. Man erhält ebenfalls eine homogen gefärbte mittelbraune Cellulose.Example 2 is repeated with 50 ml of CH 3 OH instead of 4 ml of a 10% solution of carbamide peroxide. A homogeneously colored, medium brown cellulose is also obtained.
Beispiel 2 wird wiederholt mit 50 ml C-H-OH anstatt 4 ml einer lo%igen Lösung von Carbamidperoxyd. Man erhält ebenfalls eine homogen gefärbte mittelbraune Cellulose.Example 2 is repeated with 50 ml of C-H-OH instead of 4 ml a lo% solution of carbamide peroxide. A homogeneously colored, medium brown cellulose is also obtained.
809822/0791809822/0791
4343
Beispiel 2 wird wiederholt mit 2 g Kaliumpermanganat anstatt 4 g Kaliumpermanganat. Man erhält eine homogene blonde (hellbraune) Cellulose.Example 2 is repeated with 2 g of potassium permanganate instead of 4 g of potassium permanganate. A homogeneous blonde is obtained (light brown) cellulose.
Eine in Analogie zu Beispiel 2 gefärbte Cellulose wird mit einer Lösung von 1-(3-Chlorallyl)-3,5,7-triaza-l-azoniaadamantan-chlorid (Dowicil) bis zur Sättigung durchtränkt. Anschliessend wird bei 4O°C unter Bewegung getrocknet.Cellulose colored analogously to Example 2 is treated with a solution of 1- (3-chloroallyl) -3,5,7-triaza-1-azoniaadamantane chloride (Dowicil) soaked to saturation. It is then dried at 40 ° C. with agitation.
Man erhält auf diese Weise ein gefärbtes, mit einer bakteriziden Verbindung (Dowicil) versehenes Trockenshampoo in Puderform.In this way, a colored dry shampoo provided with a bactericidal compound (Dowicil) is obtained Powder form.
Beispiel 8 Gefärbtes Trockenshampoo in Sprayform: Example 8 Colored dry shampoo in spray form:
Gefärbte Cellulose (gemäss Beispiel 2) 10 gColored cellulose (according to Example 2) 10 g
Treibgas 90 gPropellant gas 90 g
Parfüm 0,05 g quaternäres Glycidyltrimethyl-Perfume 0.05 g quaternary glycidyl trimethyl
ammoniumchlorid 0,01 gammonium chloride 0.01 g
Beispiel 9 Beispiel eines gefärbten antiseptischen PudersExample 9 Example of a colored antiseptic powder
Eine in Analogie zu Beispiel 2 gefärbte Cellulose wird mit einer 3%igen Lösung von Glycidyldiphenylmethylammoniumchlorid bis zur Sättigung durchtränkt. Anschliessend wird bei 4o°C unter Bewegung schonend getrocknet.Cellulose colored in analogy to Example 2 is mixed with a 3% strength solution of glycidyldiphenylmethylammonium chloride soaked to saturation. It is then gently dried at 40 ° C. with movement.
809822/0791809822/0791
Man erhält auf diese Weise ein gefärbtes antiseptisches Puder, welches optisch nicht erkennbar ist in Bezug auf die üblichen ungefärbten weissen antiseptischen Puder.In this way, a colored antiseptic powder is obtained which is not visually recognizable in relation to the usual uncolored white antiseptic powder.
Beispiele 10-12 Make-up Cremes können folgendermassen hergestellt werden: Examples 10-12 make-up creams can be prepared as follows:
Cetylstearylalkohol nichtionogener Emulgator Aethylenglykolstearat
Paraffinöl
Mg-Stearat
Gefärbte Cellulose dl-a-Tocopherol-Acetat
destilliertes Wasser Sorbit Sirup (Glycerin) Parfüm und Konservierungsmittel
q.s,Cetyl stearyl alcohol nonionic emulsifier ethylene glycol stearate paraffin oil
Mg stearate
Colored cellulose dl-a-tocopherol acetate distilled water sorbitol syrup (glycerin) perfume and preservative qs,
1010
1111
100,0100.0
100,0100.0
100,0100.0
809822/0791809822/0791
Claims (24)
gekennzeichnet, dass es eine quaternäre Ammoniumverbindung
der Formel11. Cosmetic preparation according to claim 10, characterized
characterized as being a quaternary ammonium compound
the formula
R3 Alkyl oder Aryl und R4 Alkyl, Aryl,
Aralkyl oder Glycidyl bedeuten,
enthält.where R, methyl, R 2 alkyl or aryl,
R 3 is alkyl or aryl and R 4 is alkyl, aryl,
Mean aralkyl or glycidyl,
contains.
1-11, dadurch gekennzeichnet, dass es als Trockenshampoo
formuliert ist.12. Cosmetic preparation according to one of the claims
1-11, characterized in that it is used as a dry shampoo
is formulated.
Puder formuliert ist.characterized in that it is used as a colored antiseptic
Powder is formulated.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH1499876 | 1976-11-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2752320A1 true DE2752320A1 (en) | 1978-06-01 |
Family
ID=4405493
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19772752320 Withdrawn DE2752320A1 (en) | 1976-11-29 | 1977-11-23 | COSMETIC PREPARATION |
Country Status (11)
| Country | Link |
|---|---|
| JP (1) | JPS5369839A (en) |
| AR (1) | AR217657A1 (en) |
| AT (1) | AT362881B (en) |
| BE (1) | BE861261A (en) |
| BR (1) | BR7707945A (en) |
| DE (1) | DE2752320A1 (en) |
| ES (1) | ES464542A1 (en) |
| FR (1) | FR2371917A1 (en) |
| GB (1) | GB1581377A (en) |
| IT (1) | IT1143699B (en) |
| SE (1) | SE7713458L (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2771634A1 (en) * | 1997-12-02 | 1999-06-04 | Jean Pierre Benoit | HAIR AND / OR BODY HYGIENE PRODUCT FOR MEN AND ANIMALS AND METHOD FOR THE PRODUCTION THEREOF |
| WO2015059169A1 (en) * | 2013-10-22 | 2015-04-30 | Unilever Plc | Composition |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59184115A (en) * | 1983-04-01 | 1984-10-19 | Shiseido Co Ltd | Hair cosmetic |
| JPS63190815A (en) * | 1987-02-04 | 1988-08-08 | Hoou Kk | Powdery hair dye composition |
| LU86946A1 (en) * | 1987-07-17 | 1989-03-08 | Oreal | ULTRAFINE POWDER COMPRISING MELANIC PIGMENTS, ITS PREPARATION METHOD AND ITS USE IN COSMETICS |
| LU87429A1 (en) * | 1989-01-17 | 1990-07-24 | Oreal | POLYMER PARTICLE PRODUCT COMPRISING MELANIC PIGMENTS, PREPARATION METHOD AND USE THEREOF, PARTICULARLY IN COSMETICS |
| US20140193500A1 (en) * | 2011-04-18 | 2014-07-10 | Phillip Loraine Cotrell | Dry shampoo comprising urea-formaldehyde |
| WO2015059170A1 (en) * | 2013-10-22 | 2015-04-30 | Unilever Plc | Composition |
| WO2018075604A1 (en) | 2016-10-18 | 2018-04-26 | Sterilex LLC | Ambient moisture-activated surface treatment powder |
| DE102016225660A1 (en) * | 2016-12-20 | 2018-06-21 | Henkel Ag & Co. Kgaa | Preparations and methods for hair cleansing |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE830996C (en) * | 1945-09-17 | 1952-02-21 | Otto Wenz | Use of wood flour as a powder base |
| FR967081A (en) * | 1948-05-31 | 1950-10-25 | Laboratoires B M G Soc D | Product and process for coloring cosmetic or other products |
| FR1322144A (en) * | 1960-10-27 | 1963-03-29 | American Viscose Corp | Cosmetic preparations containing aggregates of cellulose crystallites |
| FR1332049A (en) * | 1962-05-29 | 1963-07-12 | Inst Delcourt | Hair product or shampoo |
| DE1617850C3 (en) * | 1967-12-08 | 1974-08-01 | Hans Schwarzkopf Gmbh, 2000 Hamburg | Preparations for degreasing and cleaning living hair |
| CH522717A (en) * | 1969-02-07 | 1972-06-30 | Hoffmann La Roche | Dye preparation |
| CH603159A5 (en) * | 1974-08-20 | 1978-08-15 | Hoffmann La Roche |
-
1977
- 1977-09-30 IT IT28179/77A patent/IT1143699B/en active
- 1977-10-27 AR AR269753A patent/AR217657A1/en active
- 1977-11-23 DE DE19772752320 patent/DE2752320A1/en not_active Withdrawn
- 1977-11-24 FR FR7735355A patent/FR2371917A1/en not_active Withdrawn
- 1977-11-25 JP JP14083977A patent/JPS5369839A/en active Pending
- 1977-11-28 AT AT0850377A patent/AT362881B/en active
- 1977-11-28 SE SE7713458A patent/SE7713458L/en unknown
- 1977-11-28 GB GB49359/77A patent/GB1581377A/en not_active Expired
- 1977-11-28 ES ES464542A patent/ES464542A1/en not_active Expired
- 1977-11-28 BE BE182972A patent/BE861261A/en unknown
- 1977-11-29 BR BR7707945A patent/BR7707945A/en unknown
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2771634A1 (en) * | 1997-12-02 | 1999-06-04 | Jean Pierre Benoit | HAIR AND / OR BODY HYGIENE PRODUCT FOR MEN AND ANIMALS AND METHOD FOR THE PRODUCTION THEREOF |
| WO1999027899A1 (en) * | 1997-12-02 | 1999-06-10 | Benoit Jean Pierre | Hair and/or body hygienic product for human beings and animals |
| US6451297B1 (en) | 1997-12-02 | 2002-09-17 | Jean-Pierre Benoit | Hair and/or body care product for human beings and animals |
| WO2015059169A1 (en) * | 2013-10-22 | 2015-04-30 | Unilever Plc | Composition |
| CN105705203A (en) * | 2013-10-22 | 2016-06-22 | 荷兰联合利华有限公司 | Composition |
| US9889075B2 (en) | 2013-10-22 | 2018-02-13 | Conopco, Inc. | Dry shampoo composition |
Also Published As
| Publication number | Publication date |
|---|---|
| BR7707945A (en) | 1978-08-08 |
| IT1143699B (en) | 1986-10-22 |
| FR2371917A1 (en) | 1978-06-23 |
| BE861261A (en) | 1978-05-29 |
| SE7713458L (en) | 1978-05-30 |
| AT362881B (en) | 1981-06-25 |
| AR217657A1 (en) | 1980-04-15 |
| ES464542A1 (en) | 1978-09-01 |
| GB1581377A (en) | 1980-12-10 |
| ATA850377A (en) | 1980-11-15 |
| JPS5369839A (en) | 1978-06-21 |
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