DE2123251A1 - Crystallisable borosilicate glass - for coatings on glass or ceramic articles - Google Patents
Crystallisable borosilicate glass - for coatings on glass or ceramic articlesInfo
- Publication number
- DE2123251A1 DE2123251A1 DE19712123251 DE2123251A DE2123251A1 DE 2123251 A1 DE2123251 A1 DE 2123251A1 DE 19712123251 DE19712123251 DE 19712123251 DE 2123251 A DE2123251 A DE 2123251A DE 2123251 A1 DE2123251 A1 DE 2123251A1
- Authority
- DE
- Germany
- Prior art keywords
- glass
- weight
- coatings
- ceramic articles
- crystallisable
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011521 glass Substances 0.000 title claims abstract description 21
- 239000000919 ceramic Substances 0.000 title claims abstract description 5
- 238000000576 coating method Methods 0.000 title claims description 5
- 239000005388 borosilicate glass Substances 0.000 title claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052681 coesite Inorganic materials 0.000 claims abstract description 5
- 229910052906 cristobalite Inorganic materials 0.000 claims abstract description 5
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 5
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 5
- 229910052682 stishovite Inorganic materials 0.000 claims abstract description 5
- 229910052905 tridymite Inorganic materials 0.000 claims abstract description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 5
- FUJCRWPEOMXPAD-UHFFFAOYSA-N Li2O Inorganic materials [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 claims description 4
- XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 claims description 3
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims 2
- 101150024390 CDO1 gene Proteins 0.000 claims 1
- 239000004615 ingredient Substances 0.000 claims 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052593 corundum Inorganic materials 0.000 abstract description 3
- 238000002844 melting Methods 0.000 abstract description 3
- 230000008018 melting Effects 0.000 abstract description 3
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract description 3
- 229910052719 titanium Inorganic materials 0.000 abstract description 2
- 229910052726 zirconium Inorganic materials 0.000 abstract description 2
- 239000000049 pigment Substances 0.000 abstract 1
- 239000003086 colorant Substances 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- PURJGKXXWJKIQR-UHFFFAOYSA-N 4-[(4-hydroxynaphthalen-1-yl)diazenyl]benzenesulfonic acid Chemical compound C12=CC=CC=C2C(O)=CC=C1N=NC1=CC=C(S(O)(=O)=O)C=C1 PURJGKXXWJKIQR-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 1
- 229910000413 arsenic oxide Inorganic materials 0.000 description 1
- 229960002594 arsenic trioxide Drugs 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- OIQPTROHQCGFEF-UHFFFAOYSA-L chembl1371409 Chemical compound [Na+].[Na+].OC1=CC=C2C=C(S([O-])(=O)=O)C=CC2=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 OIQPTROHQCGFEF-UHFFFAOYSA-L 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- KTTMEOWBIWLMSE-UHFFFAOYSA-N diarsenic trioxide Chemical compound O1[As](O2)O[As]3O[As]1O[As]2O3 KTTMEOWBIWLMSE-UHFFFAOYSA-N 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910001947 lithium oxide Inorganic materials 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000011022 opal Substances 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
- C03C3/091—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium
- C03C3/093—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium containing zinc or zirconium
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
- C03C10/0036—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition containing SiO2, Al2O3 and a divalent metal oxide as main constituents
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/062—Glass compositions containing silica with less than 40% silica by weight
- C03C3/064—Glass compositions containing silica with less than 40% silica by weight containing boron
- C03C3/066—Glass compositions containing silica with less than 40% silica by weight containing boron containing zinc
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/04—Frit compositions, i.e. in a powdered or comminuted form containing zinc
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Glass Compositions (AREA)
Abstract
Description
Kristallisierbares Glas zur Herstelluncr von Überzügen auf Glas und Keramik Gegenstand der Erfindung ist ein kristallisierbares Glas zur Herstellung von ijberzüqen auf Glas und Keramik auf der Basis eines Boroqilikatqlases. Crystallizable glass for the production of coatings on glass and Ceramics The invention relates to a crystallizable glass for production of coatings on glass and ceramics on the basis of a boro-silicate glass.
7.ur Herstellung von Überzügen aus Glas auf keramischem Material oder auch Gläsern verwendet man häufig Glasuren, die Blei enthalten. Es wird von Fachleuten behauptet, dan die Herstellung von bleifreien Glasuren für diese ecke unmöqlich sei, da die in diesem Falle zur Erreichung einer niedrigen Schmelztemperatur erforderllche ene an Alkalioxid eine Anwendung auf üblicher Unterlage nicht ohne das Risiko des Reißens der Glasur crestattet. Es ist bereits vorgeschlagen worden (OS 1 942 879), Borosilikatgläser für diese Zwecke zu verwenden, die Lithiumoxid, Arsenoxid, Zirkonoxid, Titanoxid und Zinnoxid enthalten. jedoch hahen auch diese Glasuren nicht die in iedem Falle gewünschten Eigenschaften, da diese in vielen Richtuncren den aeforderten Ansprü@chen entsprechen müssen.7. for the production of coatings made of glass on ceramic material or Glazes containing lead are also often used on glasses. It is made by professionals claims that the production of lead-free glazes for this corner is impossible because in this case it is necessary to achieve a low melting temperature ene of alkali oxide, an application on a normal surface is not possible without the risk of The glaze cracks. It has already been suggested (OS 1 942 879), To use borosilicate glasses for these purposes, the lithium oxide, arsenic oxide, zirconium oxide, Contain titanium oxide and tin oxide. however, these glazes also do not have the in In each case the desired properties, as these are required in many directives Must meet requirements.
Es wurde nun gefunden, daß sich Gläser mit folgender Zusammensetzung besonders vorteilhaft anwenden lassen: 19 - 62 Gew.% SiO2 10 - 43 Gew.% B2O3 5 - 23 Gew.% Al2O3 2 - 15 Gew.% ZnO 2 - 15 Gew.% CdO 1 - 6 Gew.% Li2O Die erfindungsgemäßen Schmelzfarben besitzen in folgender Hinsicht besonders aute Eigenschaften: 1. Sie schmelzen zwischen 700 und 900°C im normalen Brennz@klus oder im Schockbrand völlig glatt.It has now been found that glasses with the following composition can be used particularly advantageously: 19 - 62% by weight SiO2 10 - 43% by weight B2O3 5 - 23% by weight Al2O3 2-15% by weight ZnO 2-15% by weight CdO 1-6% by weight Li2O Melt colors have special properties in the following respects: 1. They melt completely between 700 and 900 ° C in a normal firing cycle or in shock firing smooth.
2. Ihr linearer WAK bei 0 - 300°C liegt zwischen 25x10-7 und 45x10-7. Sie sind besonders geeignet auf Unterlagen mit gerinqer Wärmedehnung, z.B. auf solchen von 20x10-7 bis 50x10-7.2. Your linear CTE at 0 - 300 ° C is between 25x10-7 and 45x10-7. They are particularly suitable on substrates with low thermal expansion, e.g. on such from 20x10-7 to 50x10-7.
3. Sie sind z.B. geeignet für feuerfestes Glas, Opalglas, Porzellan und ähnliche Unterlaven.3. They are e.g. suitable for fireproof glass, opal glass, porcelain and similar sublaves.
4. Das Glas ist bleifrei.4. The glass is lead-free.
5. Das Glas ist resistent gegen Spülmittel.5. The glass is resistant to washing-up liquid.
6. Es besitzt eine te mechanische Resistenz, insbesondere in Bezug auf Kratzfestigkeit.6. It has a te mechanical resistance, especially in relation to on scratch resistance.
Zur Verbesserung der genannten Eigenschaften und auch der Schmelzbarkeit können die gerannten Gläsernoch weitere Zusätze enthalten: 0,1 - 3 Gew.% Na2O o,l - 5 Gew.% K20 @,1 - 8 Gew.% Mgo o,l - 6 Gew.% CaO o,l - 14 Gew.% BaO o,l - lo Gew.% SrO o,l - 2 Gew.% TiO2 o,l - 6 Gew.% ZrOS o,l - 13 Gew.% SnO2 einzeln oder zu mehreren.To improve the properties mentioned and also the meltability The tumbled glasses may contain other additives: 0.1 - 3 wt.% Na2O o, l - 5 wt.% K20 @, 1 - 8 wt.% Mgo o, l - 6 wt.% CaO o, l - 14 wt.% BaO o, l - lo wt.% SrO o, l - 2 wt.% TiO2 o, l - 6 wt.% ZrOS o, l - 13 wt.% SnO2 individually or in groups.
@urch den Titan- und Zirkon-Zusatz wird beispielsweise die chemische Resistenz erhöht, durch den Zusatz von Alkali- und @@dalkalioxid wird die Schmelzbarkeit verbessert.@The addition of titanium and zirconium, for example, makes the chemical Resistance increases, the addition of alkali and @@ dalkali oxide increases the meltability improved.
Cute Pes@stenz wurde beispielsweise mit folgender Formel gefunden: 34,25 Gew.% SiO2 29,30 Gew.% B2O3 13,56 Gew.% Al2O3 8,33 Gew.% BaO 6,97 Gew.% CdO 3,31 Gew.% ZnO 2,41 Gew.% MaO 1,86 Gew.% Li2O Die auf diese Weise hergestellten Gläser entwickeln intensiv übliche anorganische Pigmente, wie z.B.For example, Cute Pes @ stenz was found using the following formula: 34.25 % By weight SiO2 29.30% by weight B2O3 13.56% by weight Al2O3 8.33% by weight BaO 6.97% by weight CdO 3.31 % By weight ZnO 2.41% by weight MaO 1.86% by weight Li2O The glasses produced in this way intensively develop common inorganic pigments, e.g.
Rot, Orange S/Se/Cd Gelb S/Cd Braun Cr/Fe/Zn Schwarz Cr/Cu Blau Al/Co Blau, Blaugrün Cr/Co Grün Cr Rosa Au Weiß Ti/Sn etc. Red, Orange S / Se / Cd Yellow S / Cd Brown Cr / Fe / Zn Black Cr / Cu Blue Al / Co Blue, Teal Cr / Co Green Cr Pink Au White Ti / Sn etc.
Die Gläser werden hergestel]t durch Mischung der Rohstoffe und anschließendes Schmelzen, worauf sie auf die übliche Feinheit unter Zusatz der genannten Piqmente feingemahlen werden.The glasses are made by mixing the raw materials and then Melting, whereupon they are reduced to the usual fineness with the addition of the Piqmente mentioned be finely ground.
Die so erhaltenen Zusammensetzungen eignen sich zu allen üblichen Dekorationsverfahren: Spritzen, Siebdruck, Steindruck, indirekter Druck, Pinselauftrag etc..The compositions thus obtained are suitable for all common ones Decoration methods: spraying, screen printing, stone printing, indirect printing, brush application Etc..
Die SchmelzFarben sind resistent, stark glänzend und haben geringe Wärmedehung, so daß sie sich für alle Unterlagen mit geringer Wärmedehnung eignen.The enamel colors are resistant, have a strong gloss and are poor Thermal expansion, so that they are suitable for all documents with low thermal expansion.
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19712123251 DE2123251A1 (en) | 1971-05-11 | 1971-05-11 | Crystallisable borosilicate glass - for coatings on glass or ceramic articles |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19712123251 DE2123251A1 (en) | 1971-05-11 | 1971-05-11 | Crystallisable borosilicate glass - for coatings on glass or ceramic articles |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2123251A1 true DE2123251A1 (en) | 1972-11-30 |
Family
ID=5807509
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19712123251 Pending DE2123251A1 (en) | 1971-05-11 | 1971-05-11 | Crystallisable borosilicate glass - for coatings on glass or ceramic articles |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE2123251A1 (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2456076A1 (en) * | 1978-07-21 | 1980-12-05 | Ferro Corp | CADMIUM GLASS HAVING LOW SOLUBILITY OF CADMIUM OXIDE |
| EP0709347A1 (en) * | 1994-10-27 | 1996-05-01 | Corning Incorporated | Lithium aluminoborate glass-ceramics |
| RU2306275C1 (en) * | 2006-05-15 | 2007-09-20 | Юлия Алексеевна Щепочкина | Glaze |
| RU2306276C1 (en) * | 2006-04-05 | 2007-09-20 | Юлия Алексеевна Щепочкина | Ceramic glaze |
| RU2309911C1 (en) * | 2006-05-15 | 2007-11-10 | Юлия Алексеевна Щепочкина | Glaze |
| RU2323176C1 (en) * | 2006-09-05 | 2008-04-27 | Юлия Алексеевна Щепочкина | Glaze |
| RU2380328C1 (en) * | 2008-10-14 | 2010-01-27 | Юлия Алексеевна Щепочкина | Ceramic pigment |
| RU2611638C1 (en) * | 2016-02-09 | 2017-02-28 | Юлия Алексеевна Щепочкина | Ceramic pigment |
-
1971
- 1971-05-11 DE DE19712123251 patent/DE2123251A1/en active Pending
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2456076A1 (en) * | 1978-07-21 | 1980-12-05 | Ferro Corp | CADMIUM GLASS HAVING LOW SOLUBILITY OF CADMIUM OXIDE |
| EP0709347A1 (en) * | 1994-10-27 | 1996-05-01 | Corning Incorporated | Lithium aluminoborate glass-ceramics |
| RU2306276C1 (en) * | 2006-04-05 | 2007-09-20 | Юлия Алексеевна Щепочкина | Ceramic glaze |
| RU2306275C1 (en) * | 2006-05-15 | 2007-09-20 | Юлия Алексеевна Щепочкина | Glaze |
| RU2309911C1 (en) * | 2006-05-15 | 2007-11-10 | Юлия Алексеевна Щепочкина | Glaze |
| RU2323176C1 (en) * | 2006-09-05 | 2008-04-27 | Юлия Алексеевна Щепочкина | Glaze |
| RU2380328C1 (en) * | 2008-10-14 | 2010-01-27 | Юлия Алексеевна Щепочкина | Ceramic pigment |
| RU2611638C1 (en) * | 2016-02-09 | 2017-02-28 | Юлия Алексеевна Щепочкина | Ceramic pigment |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OHJ | Non-payment of the annual fee |