DE19908022A1 - Lagerstabile Wasch- und Reinigungsmittelformkörper - Google Patents

Lagerstabile Wasch- und Reinigungsmittelformkörper

Info

Publication number: DE19908022A1
Authority: DE; Germany
Prior art keywords: detergent tablets; per; bleach; week; molding
Prior art date: 1999-02-25
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Withdrawn

Application number

DE1999108022

Other languages

German (de)

English (en)

Inventor

Thomas Holderbaum

Juergen Haerer

Hans Janke

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Henkel AG and Co KGaA

Original Assignee

Henkel AG and Co KGaA

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1999-02-25

Filing date

1999-02-25

Publication date

2000-08-31

1999-02-25 Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA

1999-02-25 Priority to DE1999108022 priority Critical patent/DE19908022A1/de

2000-02-16 Priority to AU31550/00A priority patent/AU3155000A/en

2000-02-16 Priority to PCT/EP2000/001242 priority patent/WO2000050557A1/fr

2000-02-25 Priority to CA 2300016 priority patent/CA2300016A1/fr

2000-08-31 Publication of DE19908022A1 publication Critical patent/DE19908022A1/de

Status Withdrawn legal-status Critical Current

Links

239000003599 detergent Substances 0.000 title claims description 111
239000007844 bleaching agent Substances 0.000 claims abstract description 84
102000004190 Enzymes Human genes 0.000 claims abstract description 62
108090000790 Enzymes Proteins 0.000 claims abstract description 62
238000005406 washing Methods 0.000 claims abstract description 46
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 36
238000003860 storage Methods 0.000 claims abstract description 30
238000010521 absorption reaction Methods 0.000 claims abstract description 25
238000000465 moulding Methods 0.000 claims description 65
229940088598 enzyme Drugs 0.000 claims description 59
-1 n-nonanoyl Chemical group 0.000 claims description 45
239000000203 mixture Substances 0.000 claims description 38
239000002253 acid Substances 0.000 claims description 35
150000003839 salts Chemical class 0.000 claims description 25
239000004615 ingredient Substances 0.000 claims description 22
239000010457 zeolite Substances 0.000 claims description 21
150000007513 acids Chemical class 0.000 claims description 20
239000012190 activator Substances 0.000 claims description 16
239000002994 raw material Substances 0.000 claims description 16
108091005804 Peptidases Proteins 0.000 claims description 11
239000004365 Protease Substances 0.000 claims description 11
150000004760 silicates Chemical class 0.000 claims description 11
238000004140 cleaning Methods 0.000 claims description 10
229910017052 cobalt Inorganic materials 0.000 claims description 9
239000010941 cobalt Substances 0.000 claims description 9
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 9
108090001060 Lipase Proteins 0.000 claims description 8
102000004882 Lipase Human genes 0.000 claims description 8
239000004367 Lipase Substances 0.000 claims description 8
229920001577 copolymer Polymers 0.000 claims description 8
235000019421 lipase Nutrition 0.000 claims description 8
229910052748 manganese Inorganic materials 0.000 claims description 7
239000011572 manganese Substances 0.000 claims description 7
FRPJTGXMTIIFIT-UHFFFAOYSA-N tetraacetylethylenediamine Chemical compound CC(=O)C(N)(C(C)=O)C(N)(C(C)=O)C(C)=O FRPJTGXMTIIFIT-UHFFFAOYSA-N 0.000 claims description 7
ZGZHWIAQICBGKN-UHFFFAOYSA-N 1-nonanoylpyrrolidine-2,5-dione Chemical compound CCCCCCCCC(=O)N1C(=O)CCC1=O ZGZHWIAQICBGKN-UHFFFAOYSA-N 0.000 claims description 6
108010065511 Amylases Proteins 0.000 claims description 6
102000013142 Amylases Human genes 0.000 claims description 6
235000019418 amylase Nutrition 0.000 claims description 6
235000019832 sodium triphosphate Nutrition 0.000 claims description 6
229910019142 PO4 Inorganic materials 0.000 claims description 5
102000035195 Peptidases Human genes 0.000 claims description 5
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 5
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 5
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239000001301 oxygen Substances 0.000 claims description 5
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UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims description 5
XSVSPKKXQGNHMD-UHFFFAOYSA-N 5-bromo-3-methyl-1,2-thiazole Chemical compound CC=1C=C(Br)SN=1 XSVSPKKXQGNHMD-UHFFFAOYSA-N 0.000 claims description 4
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 4
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PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 4
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150000004649 carbonic acid derivatives Chemical class 0.000 claims description 4
125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 4
239000000460 chlorine Substances 0.000 claims description 4
229910052801 chlorine Inorganic materials 0.000 claims description 4
VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 claims description 4
229940045872 sodium percarbonate Drugs 0.000 claims description 4
YRIZYWQGELRKNT-UHFFFAOYSA-N 1,3,5-trichloro-1,3,5-triazinane-2,4,6-trione Chemical class ClN1C(=O)N(Cl)C(=O)N(Cl)C1=O YRIZYWQGELRKNT-UHFFFAOYSA-N 0.000 claims description 3
JSIAIROWMJGMQZ-UHFFFAOYSA-N 2h-triazol-4-amine Chemical class NC1=CNN=N1 JSIAIROWMJGMQZ-UHFFFAOYSA-N 0.000 claims description 3
OCUCCJIRFHNWBP-IYEMJOQQSA-L Copper gluconate Chemical class [Cu+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O OCUCCJIRFHNWBP-IYEMJOQQSA-L 0.000 claims description 3
125000005263 alkylenediamine group Chemical group 0.000 claims description 3
QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 3
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150000001805 chlorine compounds Chemical class 0.000 claims description 3
150000001868 cobalt Chemical class 0.000 claims description 3
QAHREYKOYSIQPH-UHFFFAOYSA-L cobalt(II) acetate Chemical class [Co+2].CC([O-])=O.CC([O-])=O QAHREYKOYSIQPH-UHFFFAOYSA-L 0.000 claims description 3
229920001519 homopolymer Polymers 0.000 claims description 3
229940099596 manganese sulfate Drugs 0.000 claims description 3
235000007079 manganese sulphate Nutrition 0.000 claims description 3
239000011702 manganese sulphate Substances 0.000 claims description 3
SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 claims description 3
239000012418 sodium perborate tetrahydrate Substances 0.000 claims description 3
IBDSNZLUHYKHQP-UHFFFAOYSA-N sodium;3-oxidodioxaborirane;tetrahydrate Chemical compound O.O.O.O.[Na+].[O-]B1OO1 IBDSNZLUHYKHQP-UHFFFAOYSA-N 0.000 claims description 3
150000003852 triazoles Chemical class 0.000 claims description 3
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 2
150000001860 citric acid derivatives Chemical class 0.000 claims description 2
125000003147 glycosyl group Chemical group 0.000 claims description 2
229910052736 halogen Inorganic materials 0.000 claims description 2
150000002367 halogens Chemical class 0.000 claims description 2
WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical class Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 claims description 2
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 2
PATMLLNMTPIUSY-UHFFFAOYSA-N phenoxysulfonyl 7-methyloctanoate Chemical compound CC(C)CCCCCC(=O)OS(=O)(=O)OC1=CC=CC=C1 PATMLLNMTPIUSY-UHFFFAOYSA-N 0.000 claims description 2
239000003223 protective agent Substances 0.000 claims 1
230000000694 effects Effects 0.000 abstract description 13
239000012459 cleaning agent Substances 0.000 abstract description 8
239000000470 constituent Substances 0.000 abstract description 5
239000003826 tablet Substances 0.000 description 96
239000000126 substance Substances 0.000 description 30
229920002678 cellulose Polymers 0.000 description 28
235000010980 cellulose Nutrition 0.000 description 27
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 24
239000001913 cellulose Substances 0.000 description 20
125000004432 carbon atom Chemical group C* 0.000 description 18
235000014113 dietary fatty acids Nutrition 0.000 description 16
239000000194 fatty acid Substances 0.000 description 16
229930195729 fatty acid Natural products 0.000 description 16
239000003795 chemical substances by application Substances 0.000 description 15
239000010410 layer Substances 0.000 description 15
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 14
150000002191 fatty alcohols Chemical class 0.000 description 14
239000003921 oil Substances 0.000 description 14
235000019198 oils Nutrition 0.000 description 14
229910021536 Zeolite Inorganic materials 0.000 description 13
239000003205 fragrance Substances 0.000 description 13
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 12
150000001875 compounds Chemical class 0.000 description 12
150000001298 alcohols Chemical class 0.000 description 11
239000003945 anionic surfactant Substances 0.000 description 11
239000002736 nonionic surfactant Substances 0.000 description 11
239000000047 product Substances 0.000 description 11
239000011734 sodium Substances 0.000 description 11
150000004665 fatty acids Chemical class 0.000 description 10
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238000000034 method Methods 0.000 description 9
229910052708 sodium Inorganic materials 0.000 description 9
239000004094 surface-active agent Substances 0.000 description 9
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 8
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 8
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 8
125000000217 alkyl group Chemical group 0.000 description 8
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238000002360 preparation method Methods 0.000 description 8
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SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 7
ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 7
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230000003647 oxidation Effects 0.000 description 7
238000007254 oxidation reaction Methods 0.000 description 7
239000002304 perfume Substances 0.000 description 7
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102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 6
ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 6
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238000004851 dishwashing Methods 0.000 description 6
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RUVINXPYWBROJD-UHFFFAOYSA-N para-methoxyphenyl Natural products COC1=CC=C(C=CC)C=C1 RUVINXPYWBROJD-UHFFFAOYSA-N 0.000 description 1
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229920001223 polyethylene glycol Polymers 0.000 description 1
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239000001205 polyphosphate Substances 0.000 description 1
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159000000001 potassium salts Chemical class 0.000 description 1
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WSHYKIAQCMIPTB-UHFFFAOYSA-M potassium;2-oxo-3-(3-oxo-1-phenylbutyl)chromen-4-olate Chemical compound [K+].[O-]C=1C2=CC=CC=C2OC(=O)C=1C(CC(=O)C)C1=CC=CC=C1 WSHYKIAQCMIPTB-UHFFFAOYSA-M 0.000 description 1
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229940079877 pyrogallol Drugs 0.000 description 1
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239000005871 repellent Substances 0.000 description 1
230000002940 repellent Effects 0.000 description 1
239000010670 sage oil Substances 0.000 description 1
239000010671 sandalwood oil Substances 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
235000003441 saturated fatty acids Nutrition 0.000 description 1
150000003333 secondary alcohols Chemical class 0.000 description 1
230000001953 sensory effect Effects 0.000 description 1
229920002545 silicone oil Polymers 0.000 description 1
238000005245 sintering Methods 0.000 description 1
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
239000001509 sodium citrate Substances 0.000 description 1
235000012207 sodium gluconate Nutrition 0.000 description 1
229960001922 sodium perborate Drugs 0.000 description 1
229910000031 sodium sesquicarbonate Inorganic materials 0.000 description 1
235000018341 sodium sesquicarbonate Nutrition 0.000 description 1
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
229910052911 sodium silicate Inorganic materials 0.000 description 1
YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
239000002689 soil Substances 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000008107 starch Substances 0.000 description 1
229940012831 stearyl alcohol Drugs 0.000 description 1
239000000758 substrate Substances 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
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239000012756 surface treatment agent Substances 0.000 description 1
230000008961 swelling Effects 0.000 description 1
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235000020357 syrup Nutrition 0.000 description 1
239000006188 syrup Substances 0.000 description 1
KUCOHFSKRZZVRO-UHFFFAOYSA-N terephthalaldehyde Chemical compound O=CC1=CC=C(C=O)C=C1 KUCOHFSKRZZVRO-UHFFFAOYSA-N 0.000 description 1
150000003505 terpenes Chemical class 0.000 description 1
235000007586 terpenes Nutrition 0.000 description 1
229940116411 terpineol Drugs 0.000 description 1
238000005809 transesterification reaction Methods 0.000 description 1
238000012546 transfer Methods 0.000 description 1
150000003624 transition metals Chemical class 0.000 description 1
229960002622 triacetin Drugs 0.000 description 1
150000003626 triacylglycerols Chemical class 0.000 description 1
150000003918 triazines Chemical class 0.000 description 1
ZKWDCFPLNQTHSH-UHFFFAOYSA-N tribromoisocyanuric acid Chemical compound BrN1C(=O)N(Br)C(=O)N(Br)C1=O ZKWDCFPLNQTHSH-UHFFFAOYSA-N 0.000 description 1
150000005691 triesters Chemical class 0.000 description 1
HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
229940038773 trisodium citrate Drugs 0.000 description 1
WCTAGTRAWPDFQO-UHFFFAOYSA-K trisodium;hydrogen carbonate;carbonate Chemical compound [Na+].[Na+].[Na+].OC([O-])=O.[O-]C([O-])=O WCTAGTRAWPDFQO-UHFFFAOYSA-K 0.000 description 1
239000010679 vetiver oil Substances 0.000 description 1
239000011800 void material Substances 0.000 description 1
230000004584 weight gain Effects 0.000 description 1
235000019786 weight gain Nutrition 0.000 description 1
ZFNVDHOSLNRHNN-UHFFFAOYSA-N xi-3-(4-Isopropylphenyl)-2-methylpropanal Chemical compound O=CC(C)CC1=CC=C(C(C)C)C=C1 ZFNVDHOSLNRHNN-UHFFFAOYSA-N 0.000 description 1
150000003752 zinc compounds Chemical class 0.000 description 1
229910052726 zirconium Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3942—Inorganic per-compounds
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0065—Solid detergents containing builders
- C11D17/0073—Tablets

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Detergent Compositions (AREA)

DE1999108022 1999-02-25 1999-02-25 Lagerstabile Wasch- und Reinigungsmittelformkörper Withdrawn DE19908022A1 (de)

Priority Applications (4)

Application Number	Priority Date	Filing Date	Title
DE1999108022 DE19908022A1 (de)	1999-02-25	1999-02-25	Lagerstabile Wasch- und Reinigungsmittelformkörper
AU31550/00A AU3155000A (en)	1999-02-25	2000-02-16	Washing and cleaning agent shaped bodies which are stable in storage
PCT/EP2000/001242 WO2000050557A1 (fr)	1999-02-25	2000-02-16	Corps moules de produits de lavage et de nettoyage stables au stockage
CA 2300016 CA2300016A1 (fr)	1999-02-25	2000-02-25	Pastille de detergent entreposable

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
DE1999108022 DE19908022A1 (de)	1999-02-25	1999-02-25	Lagerstabile Wasch- und Reinigungsmittelformkörper

Publications (1)

Publication Number	Publication Date
DE19908022A1 true DE19908022A1 (de)	2000-08-31

Family

ID=7898736

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DE1999108022 Withdrawn DE19908022A1 (de)	1999-02-25	1999-02-25	Lagerstabile Wasch- und Reinigungsmittelformkörper

Country Status (4)

Country	Link
AU (1)	AU3155000A (fr)
CA (1)	CA2300016A1 (fr)
DE (1)	DE19908022A1 (fr)
WO (1)	WO2000050557A1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE10053416A1 (de)	2000-10-27	2002-05-08	Bsh Bosch Siemens Hausgeraete	Verfahren zum maschinellen Reinigen von Textilien oder festen Gegenständen

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB8727135D0 (en) *	1987-11-19	1987-12-23	Unilever Plc	Machine dishwashing composition
AU647736B2 (en) *	1989-04-24	1994-03-31	Unilever Plc	Detergent compositions
DE4404279A1 (de) *	1994-02-10	1995-08-17	Henkel Kgaa	Tablette mit Buildersubstanzen
DE19619646A1 (de) *	1996-05-15	1997-11-20	Henkel Kgaa	Stabilisierung von Alkalipercarbonat
FR2781810B1 (fr) *	1998-07-31	2000-09-15	Chimiotechnic	Tablette detergente multicouches pour le lavage du linge et procede de fabrication

1999
- 1999-02-25 DE DE1999108022 patent/DE19908022A1/de not_active Withdrawn
2000
- 2000-02-16 AU AU31550/00A patent/AU3155000A/en not_active Abandoned
- 2000-02-16 WO PCT/EP2000/001242 patent/WO2000050557A1/fr not_active Ceased
- 2000-02-25 CA CA 2300016 patent/CA2300016A1/fr not_active Abandoned

Also Published As

Publication number	Publication date
CA2300016A1 (fr)	2000-08-25
WO2000050557A1 (fr)	2000-08-31
AU3155000A (en)	2000-09-14

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EP1165742B1 (fr)	2006-01-25	Corps moules d'agents de lavage et de nettoyage monophases ou multiphases comportant des activateurs de blanchiment speciaux
EP1123378B1 (fr)	2004-02-11	Corps moules detergents et nettoyants munis d'un systeme granule effervescent exempt d'eau
EP1165741B1 (fr)	2006-05-24	Corps moules d'agents de lavage et de nettoyage avec activateurs de blanchiment speciaux
WO2000014196A1 (fr)	2000-03-16	Pastilles de detergent renfermant des liants
EP1155111B1 (fr)	2005-10-05	Procede de production de corps moules de produits de lavage et de nettoyage de degradation rapide
EP1159392B2 (fr)	2007-12-12	Produits de lavage et de nettoyage moules contenant une association tensioactif/agent de blanchiment/adjuvant de lavage
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DE19908022A1 (de)	2000-08-31	Lagerstabile Wasch- und Reinigungsmittelformkörper
EP1141191B1 (fr)	2005-03-09	Composes phosphates
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DE19907411A1 (de)	2000-08-24	Farbstabile Wasch- und Reinigungsmittelformkörper
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EP1213346A2 (fr)	2002-06-12	Procédé pour la préparer des comprimés detergents collants
WO2000029541A1 (fr)	2000-05-25	Corps moules nettoyants et detergents exempts de parfums
DE19851442A1 (de)	2000-05-11	Wasch- und Reinigungsmittelformkörper mit feinteiligen Lösungsvermittlern
WO2000017305A1 (fr)	2000-03-30	Detergents et nettoyants sous forme de corps moules a constituants de preparation en gros morceaux
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DE19850984A1 (de)	2000-05-11	Formoptimierte Waschmittelformkörper
DE19903289A1 (de)	2000-08-03	Abriebstabile Wasch- und Reinigungsmittelformkörper mit hohem Niotensidanteil
DE19850983A1 (de)	2000-05-11	Wasch- und Reinigungsmittelformkörper mit Entschäumergranulat
WO2000022086A1 (fr)	2000-04-20	Corps moules detergents et nettoyants contenant des activateurs de blanchiment
WO2000015753A1 (fr)	2000-03-23	Corps moules de lavage et de nettoyage contenant de l'alkyle benzene sulfonate
WO2000017306A1 (fr)	2000-03-30	Detergents et nettoyants sous forme de corps moules a constituants de preparation en fins morceaux

Legal Events

Date	Code	Title	Description
2002-12-19	8139	Disposal/non-payment of the annual fee