DE19847808A1 - Lotion for styling hair or restoring body of dry hair - Google Patents

Abstract

Lotion or non-aerosol spray lotion, in combination with a suitable mechanical spray, contains dimethylpolysiloxane/methyl-3-mercaptopropylsiloxane/isobutyl methacrylate copolymer(s); alcohol-soluble cationic polymer(s); cosmetically compatible 1-4 carbon alcohol; nonionic surfactant(s); nonionic, film-forming polymer for fixing hair; and water, the amount being adjusted to give a clear solution. Lotion or non-aerosol spray lotion, in combination with a suitable mechanical spray, contains (a) 0.01-15 wt.% dimethylpolysiloxane/methyl-3-mercaptopropylsiloxane/isobutyl methacrylate copolymer(s); (b) 0.01-10 wt.% alcohol-soluble cationic polymer(s) with a charge density of 0.1-10 milliequivalents/g; (c) >= 80 wt.% cosmetically compatible 1-4 carbon alcohol; (d) 0.01-15 wt.% nonionic surfactant(s) with a hydrophilic lipophilic balance (HLB) value of 5-20; (e) 0.01-15 wt.% nonionic, film-forming polymer for fixing hair; and (f) 0-7.5 wt.% water, the amount being adjusted to give a clear solution.

Description

The invention relates to a hair treatment agent containing at least one non-ionic, water-insoluble vinyl / silicone copolymer with a Basic structure made of polymeric siloxane units and Side chains made of polymer vinyl units as well as with a content of at least one cationic polymer in an aqueous or aqueous-alcoholic solvent.

Hair treatment products that give the hair more volume and Hold on are known. The more common for these purposes wise used cosmetic polymers show in aqueous or alcoholic solutions good strengthening properties after application more or less well deform and strengthen the hair and the hair can also give more volume. Often stops this effect does not last long and already at Combing the hair gives the desired volume effect partially lost again. Especially with fine hair the hairstyle falls within a few hours partly together again, d. H. the volume effect lasts not for a whole day from morning to night.

Hair treatment agents are known from WO 95/03776 containing certain vinyl / silicone  Copolymers which, depending on the nature of the contained therein Vinyl or acrylate monomers and depending on the type of Composition of the hair fixative or hair have conditioning properties. The well-known However, funds are not yet completely satisfied posed. For example, when using Vinyl / silicone copolymers on pre-damaged, especially on hair that has been oxidatively damaged inadequate combability, especially to one inadequate combability or the habit beautiful styling effect is only of relatively short duration.

It was therefore the task of a hair treatment agent to provide the benefits of a typical styling agent, in particular characterized by a long-lasting volume effect, good combability even with damaged hair guaranteed without straining the hair. Furthermore the components of the agent should be used be compatible with each other, d. H. the means should be as homogeneous and clear as possible and an unintended one Precipitation of recipe components should be avoided will.

It has now been found that the object is achieved by a hair treatment composition containing

• (A) at least one non-ionic, water-insoluble Vinyl / silicone graft copolymers with a  Basic structure made of polymeric siloxane units and Side chains made of polymer vinyl units,
• (B) at least one cationic polymer,
• (C) at least 80, preferably at least 90, weight percent of a cosmetically acceptable alcohol with 1 up to 4 carbon atoms, especially ethanol or Isopropanol and
• (D) from 0 to 7.5, preferably from 0 to 4, weight percent water,

the quantitative ratios of components (A) to (D) are set so that a clear solution results.

The vinyl / silicone copolymer is in the invention Agents preferably in an amount of 0.01 to 15, particularly preferably from 0.1 to 5 percent by weight and the cationic polymer in an amount of 0.01 to 10, particularly preferably from 0.1 to 5 percent by weight included, if both polymers in the average in completely dissolved form.

The water content is dependent on the Solubility of the cationic polymer chosen. All right alcohol-soluble cationic polymers, in particular those with a low cationic charge density from, for example, 0.1 to 3 meq / g, or with a high one The proportion of alcohol-soluble monomers can be in the agent be essentially free of water or if the cationic polymer in the form of an aqueous solution  is available, no additional water added will. If poorly soluble in pure alcohol cationic polymers, especially those with a high charge density of, for example, greater than 3 to 10 meq / g can improve the solubility up to 7.5 percent by weight, preferably up to 4 percent by weight Water are added, the amount of added Water depending on the charge density or Alcohol solubility of the cationic polymer and of Amount of silicone copolymer is chosen so that both the silicone copolymer as well as the cationic polymer stay in solution.

Suitable vinyl / silicone copolymers are, for example, those of the general formula (I)

R1R2R3Si- (O-SiR4R5-) _n O-SiR6R7R8 (I),

the radicals R1 to R8 being the same or different can and independently of one another for an alkyl, Aryl, alkylaryl, alkoxy, alkylamino, fluoroalkyl, Represent hydrogen, hydroxy or a ZSA group, Z for a divalent connecting group, S for sulfur and A for one made up of nonionic monomers Vinyl polymer segment stands and n is a number larger or 5 means with the proviso that at least one the residues R1 to R8 represent a ZSA group. Suitable are non-ionic monomers of vinyl polymer segment A. preferably selected from low polar esters of Acrylic acid or the methacrylic acid with alcohols short  to medium chain length that the polymer in make it substantially water-insoluble. Suitable alcohols are, for example, ethanol, 1-propanol, 2-propanol, 1-butanol, 1,1-dimethylethanol, 2-methyl-1-propanol, 1-pentanol, 2-pentanol, 3-pentanol, 2-methyl-1-butanol, 3-methyl-1-butanol, 2-hexanol, 3-methyl-1-pentanol, 3-methyl-1-pentanol, cyclohexanol, 2-ethyl-1-butanol, 3-heptanol, benzyl alcohol, 2-octanol, 6-methyl-1-heptanol, 2-ethyl-1-hexanol, 3,5-dimethyl-1-hexanol, 3,5,5-tri methyl-1-hexanol, 1-decanol, 1-dodecanol and similar. The alcohols preferably contain 1 to 18, particularly preferably 1 to 12 or 2 to 4 Carbon atoms. Small amounts of copolymerizable Monomers such as styrene, vinyl ester, vinyl chloride, Vinylidene chloride, acrylonitrile, methacrylonitrile, Acryloxypropyltrimethoxysilane, methacryloxypropyltri methoxysilane, other acryloyl monomers and structural similar monomers can be used. Examples particularly preferred monomers include isooctyl meth acrylate, isononyl methacrylate, 2-ethylhexyl methacrylate, Lauryl methacrylate, i-pentyl methacrylate, n-butyl meth acrylate, i-butyl methacrylate, methyl methacrylate, ethyl methacrylate, t-butyl methacrylate, tridecyl methacrylate, Stearyl methacrylate and structurally similar monomers and mixtures of the monomers defined above. High polar, nonionic monomers can turn into a small Be copolymerized in the vinyl polymer segment A, if the polymer defined according to feature (A) in  remains essentially water-insoluble. Examples high polar, non-ionic monomers do not include ionogenic acrylates or methacrylates with at least one highly polarizable group such as a hydroxyl, one Alkoxy, an amino group (primary, secondary or tertiary) or an alkenyl heterocycle, vinyl pyrrolidone or monomers with an ethylene oxide or Propylene oxide side chain. The vinyl / silicone copolymer is however, preferably free of groups which by Copolymerization of highly polar, non-ionic Monomers come into the vinyl polymer segment A.

The vinyl polymer segment A of the vinyl / silicone copolymer is preferably free of anionic, cationic or amphoteric groups which are obtained by polymerizing anionic, cationic or amphoteric monomers come from. Use the manufacture of the invention baren vinyl / silicone copolymers is in WO 93/23009 and described in WO 95/03776. Particularly preferred as polymers for the hair treatment according to the invention middle are dimethylsiloxane / methyl-3-mercaptopropyl siloxane / tsobutyl methacrylate copolymers (Polysilicone-6).

A suitable product is for example under the Description Silicone Plus Polymer® VS 70 from the company 3M, USA distributed.

For the cationic polymers of component (B) it is preferably hair-fixing or  hair conditioning polymers. Such are suitable Polymers that have sufficient alcohol solubility possess in in the agent according to the invention completely dissolved form. The cationic Charge density is preferably 1 to 7 meq / g. Suitable polymers of component (B) contain preferably quaternary amine groups. The cationic Polymers can be homo- or copolymers, the quaternary nitrogen groups either in the polymer chain or preferably as a substituent on one or several of the monomers are contained. The ammonium group-containing monomers can not cationic monomers can be copolymerized. Suitable cationic monomers are unsaturated, radical polymerizable compounds which have at least one wear cationic group, especially ammonium substituted vinyl monomers such as trialkyl methacryloxyalkylammonium, trialkylacryloxyalkyl ammonium, dialkyldiallylammonium and quaternary vinyl ammonium monomers with cyclic, cationic stick groups containing substances such as pyridinium, imidazolium or quaternary pyrrolidones, e.g. B. Alkyl vinyl imidazo lium, alkyl vinyl pyridinium, or alkyl vinyl pyrrolidone Salts. The alkyl groups of these monomers are preferred wise lower alkyl groups such as C1 to C7 alkyl groups, particularly preferred C1 to C3 alkyl groups.  

The monomers containing ammonium groups can with be copolymerized non-cationic monomers. Suitable comonomers are, for example, acrylamide, Methacrylamide, alkyl and dialkyl acrylamide, alkyl and Dialkyl methacrylamide, alkyl acrylate, alkyl methacrylate, Vinyl caprolactone, vinyl caprolactam, vinyl pyrrolidone, Vinyl esters, e.g. B. vinyl acetate, vinyl alcohol, propylene glycol or ethylene glycol, the alkyl groups of these monomers preferably C1 to C7 alkyl groups, C1 to C3 alkyl groups are particularly preferred.

Suitable polymers with quaternary amine groups are for example those in the CTFA Cosmetic Ingredient Dictionary under the designation Polyquaternium described polymers such as methylvinylimidazolium chloride / vinyl pyrrolidone copolymer (Polyquaternium-16) or quaternized vinyl pyrrolidone / dimethylamino ethyl methacrylate copolymer (Polyquaternium-11) as well quaternary silicone polymers or oligomers such as for example silicone polymers with quaternary End groups (Quaternium-80).

Of the cationic polymers used in the invention appropriate means may be included, for example Vinyl pyrrolidone / dimethylaminoethyl methacrylate metho sulfate copolymer sold under the trade names Gafquat® 755 N and Gafquat® 734 from Gaf Co., USA is sold and of which the Gafquat® 734  is particularly preferred. More cationic Polymers are, for example, from BASF, Germany under the trade name LUVIQUAT® MM 550 distributed copolymer of polyvinylpyrrolidone and Imidazolimine methochloride, manufactured by Calgon / USA sold under the trade name Merquat® Plus 3300 Terpolymer of dimethyldiallylammonium chloride, sodium acrylate and acrylamide, which is available from ISP / USA Terpolymer sold under the trade name Gaffix® VC 713 from vinyl pyrrolidone, dimethylaminoethyl methacrylate and Vinylcaprolactam, which is manufactured by Gaf under the Trade names Gafquat® HS 100 vinyl pyrroli don / methacrylamidopropyltrimethylammonium chloride Copolymer and that from the company GOLDSCHMIDT / Germany marketed under the trade name Abil® Quat 3272 diquaternary polydimethylsiloxane.

In a preferred embodiment, this contains agents according to the invention additionally at least one nonionic surfactant. The nonionic surfactant is preferably in an amount of 0.01 to 15, especially preferably contain from 0.05 to 5 percent by weight.

Ethoxylated surfactants are preferred, the Number of ethylene oxide units between 1 and 1000, preferably between 1 to 300, particularly preferred is between 1 and 15. Fatty alcohol is preferred ethoxylates, fatty amine ethoxylates, fatty acid alkanolamide  ethoxylates and fatty acid ester ethoxylates each with 1 up to 15 ethylene oxide units. Examples of suitable ones Fatty alcohol ethoxylates are ethoxylated lauryl, Tetradecyl, cetyl, oleyl or stearyl alcohol, the can be used alone or in a mixture, and Fatty alcohols of ethoxylated lanolin or ethoxylated lanolin. The ethoxylated fatty alcohols, too under the type designation Dehydol® from Henkel or under the type name Brij® from ICI Surfactants are distributed for the invention appropriate hair treatment agents.

Among the fatty acid ester ethoxylates are above all To name diglyceride ethoxylates like that from the ICI Surfactants under the trade name Arlatone® G distributed, ethoxylated with 25 ethylene oxide units Castor oil with the INCI name PEG-25 Hydrogenated Castor Oil, which is sold by BASF under the trade name Cremophor® El distributed, with 35 ethylene oxide units ethoxy castor oil with the INCI name PEG-35 Castor Oil, that from BASF under the trade name Cremophor® RH 410 sold with 40 ethylene oxide units ethoxy gated, hydrogenated castor oil with the INCI name PEG-40 Hydrogenated Castor Oil, and that from Witco Surfactants sold under the name Rewoderm® LI To name raw materials.  

Furthermore, they can be used as non-ionic surfactants known ethoxylated fatty acid sugar esters, in particular the ethoxylated sorbitan fatty acid ester, but also non-ethoxylated surfactants, such as the fatty acid sugar esters manufactured by ICI Surfactants under the Trade names Tween® and Arlacel® are sold as well the alkyl polyglycosides manufactured by the Henkel company the trade name Plantaren® or Plantacare® or from from Seppic under the trade name Oramix® are sold for the cosmetic according to the invention Preparation can be used.

Generally it can be said that non-ionic surfactants for the hair treatment composition according to the invention suitable are preferred if they have an HLB value of maximum 20 have from 5 to 18. Is particularly preferred a mixture of two surfactants, one surfactant one mean HLB value of about 8 to 11 and the other Surfactant has a higher HLB value of approx. 14 to 17 having. A mixture of, for example, is suitable Tetraethoxy lauryl ether (HLB 9.5) and Polysorbate-40 (HLB 15.6).

In a further preferred embodiment contains the agent according to the invention additionally 0.01 to 15% by weight, preferably 0.5 to 10% by weight percent of at least one synthetic or natural, non-ionic, basic, anionic or amphoteric  film-forming, hair-fixing polymer, of which nonionic polymers are particularly preferred. Suitable polymers are those that have an adequate Have alcohol solubility to use in the Invention appropriate means in completely dissolved form to be present.

Under hair-fixing polymers according to the invention understood such polymers that when used in 0.01 up to 5% aqueous, alcoholic or aqueous alcoholic solution are able on the hair deposit a polymer film and in this way the To fix hair.

If the polymers contain acid groups, they can partially or entirely with a suitable base such. B. Aminomethylpropanol are neutralized. Contain the Polymeric basic groups, some of them or entirely with a suitable acid such as e.g. B. ants acid, pyrrolidone carboxylic acid, lactic acid etc. be neutralized.

Suitable synthetic, nonionic film-forming, hair setting polymers are homo- or copolymers that built up from at least one of the following monomers are: vinyl pyrrolidone, vinyl caprolactam, vinyl esters such as e.g. B. vinyl acetate, vinyl alcohol, acrylamide, methacrylic amide, alkyl and dialkyl acrylamide, alkyl and dialkyl  methacrylamide, alkyl acrylate, alkyl methacrylate, propy lenglycol or ethylene glycol, the alkyl groups of these monomers preferably C1 to C7 alkyl groups, C1 to C3 alkyl groups are particularly preferred.

Are suitable for. B. homopolymers of vinyl caprolactam, of vinyl pyrrolidone or N-vinyl formamide. Further suitable synthetic film-forming, non-ionic, hair setting polymers are e.g. B. copolymers Vinyl pyrrolidone and vinyl acetate, terpolymers Vinyl pyrrolidone, vinyl acetate and vinyl propionate, Polyacrylamides, for example, under the trade names Akypomine® P 191 from CHEM-Y, Emmerich, or Sepigel® 305 from Seppic to be expelled; Polyvinyl alcohols, for example under the trade names Elvanol® from Du Pont or Vinol® 523/540 sold by Air Products as well as polyethylene glycol / polypropylene glycol co polymers, for example, under the trade designations Ucon® from Union Carbide. Polyvinyl caprolactam is particularly preferred.

Suitable natural film-forming polymers with are hair-setting effects, for example Cellulose derivatives, e.g. B. hydroxypropyl cellulose with a Molecular weight of 30,000 to 50,000 g / mol, which for example under the trade name Nisso Sl® is distributed by the company Lehmann & Voss, Hamburg.  

Another natural polymer is shellac. Shellac can be in neutralized form and unneutralized.

Suitable synthetic film-forming, anionic polymers are z. B. cross-linked or uncross-linked vinyl acetate / crotonic acid copolymers, for example in Form a 60% solution in isopropanol / water under the trade name ARISTOFLEX® from the company HOECHST / Germany or from the company BASF sold under the trade name LUVTSET® CA-66 will. Other suitable anionic polymers are for Example terpolymers of acrylic acid, alkyl acrylate and N-alkyl acrylamide, especially acrylic acid / ethyl acrylic lat / N-t-butylacrylamide terpolymers or terpolymers Vinyl acetate, crotonate and vinyl alkanoate, in particular Vinyl acetate / crotonate / vinyl neodecanoate copolymers.

Suitable amphoteric polymers are for example Copolymers formed from alkyl acrylamide, in particular Octylacrylamide, alkylaminoalkyl methacrylate, in particular t-butylaminoethyl methacrylate and two or more Monomers consisting of acrylic acid, methacrylic acid or their esters, such as those available under the trade named Resyn 28-4910 or Amphomer LV-71 from the company NATIONAL STARCH, USA are available.  

In a further preferred embodiment contains the agent according to the invention additionally at least one low-viscosity, liquid silicone compound such as B. linear or cyclic polydimethylsiloxanes (INCI-Be drawing: Dimethicone and Cyclomethicone). These Silicone compounds can be used in an amount of 0.01 to 15, preferably from 0.1 to 5 percent by weight be. Cyclic polydimethylsiloxanes are preferred four, five or six Si atoms.

The agent according to the invention is preferably in a essential non-aqueous, alcoholic medium assembled. The water content of the agent is included maximum 7.5, preferably less than 5 percent by weight. As additional co-solvents can be organic solutions medium or a mixture of solvents with a Boiling point below 400 ° C in an amount from 0.1 to 15 weight percent preferably from 1 to 10 weight percent be included. Suitable co-solvents are e.g. B. Glycerin, propylene glycol, unbranched or branched Hydrocarbons such as pentane, hexane or isopentane, cyclic hydrocarbons such as cyclopentane or Cyclohexane and cyclic or linear silicone oils.

The agent according to the invention can also be used for Hair treatment agent usual additional ingredients contain, for example wetting agents or emulsifiers the classes of anionic or amphoteric upper  surface-active surfactants, such as fatty alcohol sulfates, alkyl benzenesulfonates, alkyltrimethylammonium salts, alkyl betaine, in an amount of 0.1 to 15 percent by weight; Humectants; Perfume oils in an amount of 0.1 to 0.5 percent by weight; Opacifiers, such as Ethylene glycol distearate, in an amount of about 0.2 to 5.0 percent by weight; Pearlescent agents, such as a mixture of fatty acid monoalkylolamide and ethylene glycol distearate, in an amount of about 1.0 to 10 Weight percent; bactericidal and fungicidal active ingredients such as 2,4,4-trichloro-2-hydroxydiphenyl ether or methyl chloroisothiazole ion, in an amount of 0.01 up to 1.0 percent by weight; Thickeners, such as for example coconut fatty acid diethanolamide, in one Amount from about 0.2 to 3.0 percent by weight, buffer substances, such as sodium citrate or Sodium phosphate, in an amount of 0.1 to 1.0 percent by weight; Stains, such as Fluorescein sodium salt, in an amount of about 0.1 up to 1.0 percent by weight; Care substances, such as Plant and herbal extracts, protein and silk hydrolysates, lanolin derivatives, in an amount of 0.1 up to 5 percent by weight; physiologically acceptable Silicone derivatives, such as silicone oil, silicone polymers and siloxanes; Sunscreen, antioxidant dantien, radical scavengers, antidandruff agents, in an amount of about 0.01 to 2 percent by weight; substantive hair dyes, hair dyes that  be developed oxidatively, oxidizing agents, Reducing agents, fatty alcohols, brighteners, vitamins, Plasticizers, combability improvers, lipid replenishing agents Agents and defoamers.

The agent according to the invention can be in various Application forms are used, for example as a lotion, as a spray, in particular as a non-aerosol, which by means of a pump or as a pump and spray for Commitment comes. Also an insert in the form of one usual thickener thickened lotion or a gel is possible.

The agent according to the invention is in the form of a lotion before, it is packed in a portion bottle and can be applied directly to the hair from this. To achieve a volume effect directly from Hairline on, packaging can be done with a nozzle be equipped, by means of which an application directly is possible on the hairline.

A particularly preferred form of application is Non-aerosol spray lotion. Here is the means according to the invention with the aid of a suitable mechanically operated spraying device. Mechanical sprayers include such Understand devices that the spraying a Liquid without using a blowing agent  enable. As a suitable mechanical spray device can, for example, a spray pump or one with a Spray valve provided elastic container in which the cosmetic agents according to the invention under pressure is filled, whereby the elastic container expands and from which the agent due to the contraction of the elastic container when the spray valve is opened continuously released, can be used.

In a particularly preferred embodiment, the agent according to the invention is present as a lotion or as a non-aerosol spray lotion in combination with a suitable mechanical device for spraying

• (A) 0.01 to 15 percent by weight of at least one Dimethylpolysiloxane / methyl-3-mercaptopropyl siloxane / isobutyl methacrylate copolymer,
• (B) 0.01 to 10 percent by weight of at least one alcohol-soluble cationic polymer with a Charge density from 0.1 to 10 meq / g,
• (C) at least 80, preferably at least 90, weight percent of a cosmetically acceptable alcohol with 1 up to 4 carbon atoms, especially ethanol or Isopropanol,
• (D) from 0 to 7.5, preferably from 0 to 4, weight percent water,
• (E) 0.01 to 15, preferably 0.05 to 5 percent by weight at least one nonionic surfactant with one HLB value between 5 and 20 and  
• (F) 0.01 to 15 percent by weight of at least one non-ionic, film-forming, hair-fixing Polymers,

the quantitative ratios of components (A) to (D) are set so that a clear solution results.

The cosmetic agent according to the invention is applied by using it to achieve the Volume effect sufficient amount moist, towel-dried hair is applied. Subsequently can the hairstyle be shaped in the usual way or can put the hair in and dry at the end be blow-dried. But it is also possible to Refreshing the volume effect directly on the agent apply dry hair.

The following examples are intended to illustrate the subject of Explain the invention in more detail.

Examples example 1 Non-aerosol spray lotion

1.4 g Silicone Plus Polymer® VS70 (3M Co.) ¹⁾

0.5 g Luviskol® Plus (BASF) ²⁾

0.5 g Luviquat® FC 550 ³⁾

0.5 g tetraethoxy lauryl ether
0.5 g polysorbate 40
96.6 g of ethanol
100.0 g

¹⁾ 25% solution of dimethylpolysiloxane / methyl-3-mercaptopropylsiloxane / isobutyl methacrylate copolymer (Polysilicone-6) in cyclomethicone
²⁾ 40% solution of polyvinyl caprolactam in ethanol
³⁾ 40% solution of methyl vinyl imidazolium chloride / vinyl pyrrolidone copolymer (polyquaternium-16) in water

The lotion is made using a commercially available Spray pump directly on dry or damp hair sprayed.  

Example 2 Volume lotion

0.8 g Silicone Plus Polymer® VS70 (3M Co.) ¹⁾

0.3 g Luviskol® Plus (BASF) ²⁾

0.25 g Luviquat® FC 370 (BASF) ³⁾

0.25 g tetraethoxy lauryl ether
0.1 g perfume
2.0 g water
ad 100 g ethanol

¹⁾ 25% solution of dimethylpolysiloxane / methyl-3-- mercaptopropylsiloxane / isobutyl methacrylate copolymer (Polysilicone-6) in cyclomethicone
²⁾ 40% solution of polyvinyl caprolactam in ethanol
³⁾ 40% solution of methyl vinyl imidazolium chloride / vinyl pyrrolidone copolymer (polyquaternium-16) in water

The lotion is in a commercial portion pack packed for liquid fixatives, out of which the lotion is applied to dry or damp hair.  

Example 3 Neck volume lotion

2.0 g Silicone Plus Polymer® VS70 (3M Co.) ¹⁾

0.5 g Luviskol® Plus (BASF) ²⁾

0.4 g Gafquat® 734 (ISP) ³⁾

0.5 g tetraethoxy lauryl ether
0.1 g perfume
1.0 g water
ad 100 g ethanol

¹⁾ 25% solution of dimethylpolysiloxane / methyl-3-mercaptopropylsiloxane / isobutyl methacrylate copolymer (Polysilicone-6) in cyclomethicone
²⁾ 40% solution of polyvinyl caprolactam in ethanol
³⁾ 50% solution of vinyl pyrrolidone / dimethylamino ethyl methacrylate methosulfate copolymer (polyquaternium-11) in ethanol

The lotion comes with an application bottle with Nozzle in dry hair is applied to the hairline and the hairline is then blow-dried.

Claims (5)

1. Composition in the form of a lotion or a non-aerosol spray lotion in combination with a suitable mechanical device for spraying containing

• (A) 0.01 to 15 percent by weight of at least one dimethylpolysiloxane / methyl-3-mercaptopropyl siloxane / isobutyl methacrylate copolymer,
• (B) 0.01 to 10 percent by weight of at least one alcohol-soluble cationic polymer with a charge density of 0.1 to 10 meq / g,
• (C) at least 80 percent by weight of a cosmetically acceptable alcohol with 1 to 4 carbon atoms,
• (D) from 0 to 7.5 weight percent water,
• (E) 0.01 to 15 percent by weight of at least one nonionic surfactant with an HLB value between 5 and 20 and
• (F) 0.01 to 15 percent by weight of at least one nonionic, film-forming, hair-fixing polymer,
  the quantitative ratios of components (A) to
• (D) are set so that a clear solution results.

2. Composition according to claim 1, characterized in that Component (B) a hair setting or a is hair conditioning polymer. 3. Composition according to one of claims 1 to 2, characterized characterized in that component (C) in at least 90 Weight percent is present. 4. Agent according to one of claims 1 to 3, characterized characterized in that it is 0 to 4 weight percent water contains. 5. Agent according to one of claims 1 to 4, characterized characterized in that it contains component (E) in an amount contains from 0.05 to 5 percent by weight.