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DE1839947U - CERAMIC PANEL TO BE STICKED ON AS A COVERING STREETS, SQUARES ETC., AND FOR WALLS. - Google Patents

CERAMIC PANEL TO BE STICKED ON AS A COVERING STREETS, SQUARES ETC., AND FOR WALLS.

Info

Publication number
DE1839947U
DE1839947U DEP15668U DEP0015668U DE1839947U DE 1839947 U DE1839947 U DE 1839947U DE P15668 U DEP15668 U DE P15668U DE P0015668 U DEP0015668 U DE P0015668U DE 1839947 U DE1839947 U DE 1839947U
Authority
DE
Germany
Prior art keywords
mixtures
streets
covering
walls
sticked
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEP15668U
Other languages
German (de)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dr Plate GmbH
Original Assignee
Dr Plate GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dr Plate GmbH filed Critical Dr Plate GmbH
Priority to DEP15668U priority Critical patent/DE1839947U/en
Publication of DE1839947U publication Critical patent/DE1839947U/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/46Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
    • C04B41/48Macromolecular compounds
    • C04B41/488Other macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
    • C04B41/4884Polyurethanes; Polyisocyanates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/24Macromolecular compounds
    • C04B24/26Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B24/2641Polyacrylates; Polymethacrylates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/24Macromolecular compounds
    • C04B24/28Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B24/282Polyurethanes; Polyisocyanates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/10Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/14Polyepoxides
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/10Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/16Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/46Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
    • C04B41/48Macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/46Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
    • C04B41/48Macromolecular compounds
    • C04B41/4826Polyesters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Road Paving Structures (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Description

Keramikplatte zum Aufkleben als Belag für Straßen, Plätze usw. sowie für Wände. Zur Markierung von Fahrbahnrändern und Fußgängerüberwegen auf Straßen wurden bisher meist Anstriche verwendet, die aber bei starkem Gebrauch sehr schnell abgenutzt waren. Deshalb versuchte man helle Platten in die Fahrbahn einzubetten. Die Schwierigkeit besteht jedoch in der richtigen Befestigung von Platten auf Straßen. w C> Bisher wurden Keramikplatten in Llörtel verlegt, der so stark aufgetragen wurde, daß alle Unebenheiten der Platten und des Untergrundes damit ausgeglichen wurden. Mit den herkömmlichen Befestigungsmitteln wird nicht die notwendige Druck-und Scherfestigkeit erreicht. Durch den Einfluß von Wasser und Temperaturunterschieden lösen sich die Keramikplatten ab.Ceramic plate to be glued on as a covering for streets, squares etc. as well as for walls. For marking the edges of the lane and pedestrian crossings on roads paints were mostly used up to now, but with heavy use Wore out very quickly. Therefore one tried light panels in to embed the roadway. The difficulty, however, is that correct fastening of panels on roads. w C> So far, ceramic tiles were laid in Llörtel, which was applied so heavily that all unevenness of the tiles and the sub-floor were evened out. The necessary compressive and shear strength is not achieved with the conventional fastening means. The ceramic plates peel off due to the influence of water and temperature differences.

Insbesondere konnte auf stark befahrenen Straßen eine dauerhafte Befestigung nicht erreicht werden. Aushärtende Komponentenkleber haben sich zum Kleben von Metall und Holz als geeignet erwiesen, sie konnten aber zum Aufkleben von Keramikplatten nicht verwendet werden, weil ein geeignetes Klebeverfahren fehlte. Um Keramikplatten mit einem Kunststoffkleber gut haftend zu verbinden, müssen die Flächen auf denen der'Kleber aufgetragen wird, mäßig rauh und eben sein. Die Platten dürfen also keinesfalls wellig oder narbig sein, als Untergrund kann nicht Schotter, Kies oder Splitt Verwendung finden, es muß vielmehr ein Fundament von bester Oberflächenbeschaffenheit vorhanden sein. Zweckmäßig werden daher Fundamentblöcke vorgefertigt und mit Keramikplatten beklebt. Überraschenderweise ergibt sich unter Anwendung von Kunstharzklebern bei gut vorbereiteten Oberflächen, trockener und staubfreier Verklebung ein außergewöhnlich gutes Haften der Keramikplatten. Die angeklebten Platten zeigen kein Splittern, trotz hoher Druckbean- C> spruchung, kein Ablösen infolge Wärmespannungen, kein Ausfrieren nach Wasseraufnahme und Temperaturunterschieden. Der Kunststoffkleber stellt eine elastische Verbindung dar, die allen Beanspruchungen gut widersteht.In particular, permanent paving could not be achieved on roads with heavy traffic. Hardening component adhesives have proven to be suitable for bonding metal and wood, but they could not be used for bonding ceramic plates because a suitable bonding process was lacking. In order to bond ceramic plates with a plastic adhesive, the surfaces on which the adhesive is applied must be moderately rough and flat. The slabs must not be wavy or pitted, gravel, gravel or chippings cannot be used as the subsurface, rather a foundation with the best surface quality must be available. For this reason, foundation blocks are expediently prefabricated and covered with ceramic plates. Surprisingly, the use of synthetic resin adhesives with well-prepared surfaces, dry and dust-free bonding results in an extraordinarily good adhesion of the ceramic plates. The glued panels show no splintering, despite the high pressure C> stress, no peeling due to thermal stress, no freezing out after water absorption and temperature differences. The plastic adhesive represents an elastic connection that withstands all stresses well.

Die zur Verwendung gelangenden Stoffe sind Zwei-oder Mehrkomponentenkleber, beispielsweise : 1.) hydroxylgruppenhaltige Polyester und Di-oder Triisocynate, 2.) ungesättigte Polyester, Monostyrol und organische Peroxyde (wie Benzoylperoxyd) als Katalysator, 3.) Reaktionsprodukte aus epichlorhydrin und Bis. Phenolen mit Aminverbindungen z. B. Phenol-Formaldehyd. The substances used are two- or multi-component adhesives, for example: 1.) hydroxyl-containing polyesters and di- or tri-isocyanates, 2.) unsaturated polyester, monostyrene and organic peroxides (such as benzoyl peroxide) as a catalyst, 3.) reaction products from epichlorohydrin and bis. Phenols with Amine compounds e.g. B. phenol-formaldehyde.

Den Klebern kann ein Füllstoff aus Steinmehl oder ähnlichem zugesetzt werden. Ein geeigneter Katalysator verursacht das Abbinden in 20-60 Minuten bei normaler Temperatur. Durch Aufwärmen kann die Erstarrungzeit noch herabgesetzt werden. Ein außerordentlicher Vorteil gegenüber allen bisher bekannten Verfahren ist der schnelle Arbeitsablauf bei der Plattenverlegung mit Kunstharz. Während eine Zementmischung mindestens 2 Tage zum Abbinden braucht, kann der Kunststoffbelag bereits nach 2 Stunden befahren werden.A filler made of stone dust or the like can be added to the adhesives will. A suitable catalyst causes setting in 20-60 minutes normal temperature. The setting time can be reduced by warming up. An extraordinary advantage over all previously known methods is that fast workflow when laying panels with synthetic resin. While a cement mix needs at least 2 days to set, the synthetic flooring can already be used after 2 Hours.

Die Abbildung zeigt einen Straßenbelag, bei welchem Platten (1) auf einen Betonsockel (2) aufgeklebt sind. Der Betonsockel ist vorgefertigt, gut geglättet, er wird nach dem Beleben als Fertigteil auf Kies oder Schotter verlegt. Die Fugen der Platten werden nach dem Aufkleben und Verlegen mit Zementbrühe, Asphalt oder Kunstharz ausgegossen. tD CD 1.Beispiel Kleberherstellung : 3,6 Gewichtsteile eines hydroxylgruppenhaltigen Polyesters, her- gestellt aus 3 Mol Adipinsäure, 1 Mol Hexantriol, 3 Mol Butylenglykol 3,6 Gewichtsteile eines hydroxylgruppenhaltigen Polyesters, hergestellt aus 7, 5 Mol Adipinsäure, 1 Mol Hexantriol 1, 5 Mol Butylenglykol, gelöst in 1,8 Teilen Aethylacetat werden vermischt mit 5, 2 Teilen eines Triisocyanat, gelöst in 3,8 Teilen Aethylacetat.The figure shows a road surface in which plates (1) are glued to a concrete base (2). The concrete base is prefabricated, well smoothed, it is laid as a prefabricated part on gravel or crushed stone after revitalization. The joints of the panels are after gluing and Laying with cement mixture, asphalt or synthetic resin poured out. tD CD 1st example Glue production: 3.6 parts by weight of a polyester containing hydroxyl groups, made from 3 moles of adipic acid, 1 mole of hexanetriol, 3 moles of butylene glycol 3.6 parts by weight of a polyester containing hydroxyl groups from 7.5 moles of adipic acid, 1 mole of hexanetriol, 1.5 moles of butylene glycol dissolved in 1.8 parts of ethyl acetate are mixed with 5.2 parts of a triisocyanate dissolved in 3.8 parts of ethyl acetate.

12 Teile Quarzsand werden zugesetzt. 12 parts of quartz sand are added.

Der Kleber wird auf die Bauteile aufgetragen und der Aushärtung überlassen.The adhesive is applied to the components and left to harden.

2. Beispiel Kleberherstellung : 10 Gewichtsteile eines ungesättigten Polyesters mit der Viskosität von ca. 2.000 cP 2,5 Gewichtsteile eines ungesättigten Polyesters mit der Viscosität 3. 000 cP in Gegenwart von etwas Monostyrol werden unter Zugabe von 1 Teil Benzoylperoxyd vermischt und 60 Teile Quarzsand zugesetzt.2nd example adhesive production: 10 parts by weight of an unsaturated one Polyester with a viscosity of about 2,000 cP 2.5 parts by weight of an unsaturated Polyester with a viscosity of 3,000 cP in the presence of some monostyrene mixed with the addition of 1 part of benzoyl peroxide and added 60 parts of quartz sand.

Der Kleber wird auf die Bauteile aufgetragen und der Aushärtung überlassen.The adhesive is applied to the components and left to harden.

Claims (2)

Schutzansprüche 1. Keramikplatte zum Aufkleben als Belag für Straßen, Plätze usw. sowie für Wände, dadurch gekennzeichnet, daß die Klebeflächen der Bauteile ir mäßig rauh und sehr eben sind, und daß als Kunststoffkleber solche Mischungen verwendet werden, die durch Polymerisation härten, wie :
- Mischungen aus hydroxylgruppenhaltigen Polyestern und Di-oder Triisocyanate Mischungen aus ungesättigten Polyestern und Vinylverbindungen (wie Monostyrol) und organischen Peroxyden (wie Benzoylperoxyd) als Reaktionsauslöser Mischungen eines Reaktionsproduktes aus Epichlorhydrin mit Bis-Phenolen, z. B. Diphenylolpropan einerseits und Aminverbindungen, wie beispielsweise solche aus Harnstoff-Formaldehyd oder Melamin-Formaldehyd andererseits.
Protection claims 1. Ceramic plate for gluing as a covering for streets, squares, etc. and for walls, characterized in that the adhesive surfaces of the components ir moderately rough and very even, and that plastic adhesives are such Mixtures are used that cure by polymerization, such as:
- Mixtures of hydroxyl-containing polyesters and di- or triisocyanates Mixtures of unsaturated polyesters and vinyl compounds (such as monostyrene) and organic peroxides (such as benzoyl peroxide) as a reaction trigger Mixtures of a reaction product of epichlorohydrin with bis-phenols, e.g. B. Diphenylolpropane on the one hand and amine compounds such as those from urea-formaldehyde or melamine-formaldehyde on the other hand.
2. Keramikplatte nach Anspruch 1, dadurch gekennzeichnet, daß die in trockenem Zustand geklebten Keramikplatten nach dem Abbinden mit Zementbrühe, Asphalt oder Kunstharz ausgefugt werden.2. Ceramic plate according to claim 1, characterized in that the Ceramic plates glued in the dry state after setting with cement broth, Asphalt or synthetic resin.
DEP15668U 1959-10-17 1959-10-17 CERAMIC PANEL TO BE STICKED ON AS A COVERING STREETS, SQUARES ETC., AND FOR WALLS. Expired DE1839947U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEP15668U DE1839947U (en) 1959-10-17 1959-10-17 CERAMIC PANEL TO BE STICKED ON AS A COVERING STREETS, SQUARES ETC., AND FOR WALLS.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEP15668U DE1839947U (en) 1959-10-17 1959-10-17 CERAMIC PANEL TO BE STICKED ON AS A COVERING STREETS, SQUARES ETC., AND FOR WALLS.

Publications (1)

Publication Number Publication Date
DE1839947U true DE1839947U (en) 1961-10-26

Family

ID=33009112

Family Applications (1)

Application Number Title Priority Date Filing Date
DEP15668U Expired DE1839947U (en) 1959-10-17 1959-10-17 CERAMIC PANEL TO BE STICKED ON AS A COVERING STREETS, SQUARES ETC., AND FOR WALLS.

Country Status (1)

Country Link
DE (1) DE1839947U (en)

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