DE1542769A1 - Akaricide with ovicidal and larvicidal effects - Google Patents
Akaricide with ovicidal and larvicidal effectsInfo
- Publication number
- DE1542769A1 DE1542769A1 DE19641542769 DE1542769A DE1542769A1 DE 1542769 A1 DE1542769 A1 DE 1542769A1 DE 19641542769 DE19641542769 DE 19641542769 DE 1542769 A DE1542769 A DE 1542769A DE 1542769 A1 DE1542769 A1 DE 1542769A1
- Authority
- DE
- Germany
- Prior art keywords
- nitro
- triazole
- ovicidal
- akaricide
- eggs
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000000974 larvacidal effect Effects 0.000 title claims description 4
- 231100000194 ovacidal Toxicity 0.000 title claims description 4
- 230000003151 ovacidal effect Effects 0.000 title claims description 4
- -1 2- (3,4-dichlorophenyl) -4-nitro-1,2,3-triazole Chemical compound 0.000 claims description 5
- OIWKJKODXXCJSK-UHFFFAOYSA-N 2-(4-fluorophenyl)-4-nitrotriazole Chemical compound [O-][N+](=O)C1=NN(N=C1)C1=CC=C(F)C=C1 OIWKJKODXXCJSK-UHFFFAOYSA-N 0.000 claims description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims description 2
- 239000000460 chlorine Substances 0.000 claims description 2
- 229910052801 chlorine Inorganic materials 0.000 claims description 2
- 229910052731 fluorine Inorganic materials 0.000 claims description 2
- 239000011737 fluorine Substances 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 2
- 235000013601 eggs Nutrition 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 7
- 241001454295 Tetranychidae Species 0.000 description 6
- 239000004480 active ingredient Substances 0.000 description 6
- 241000118205 Ovicides Species 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 244000046052 Phaseolus vulgaris Species 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000007900 aqueous suspension Substances 0.000 description 2
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- SVGYHIKXGFTUAG-UHFFFAOYSA-N 1-benzyl-2-(2-benzyl-4,4-dichlorocyclohexa-1,5-dien-1-yl)sulfanyl-5,5-dichlorocyclohexa-1,3-diene Chemical compound C=1C=CC=CC=1CC=1CC(Cl)(Cl)C=CC=1SC=1C=CC(Cl)(Cl)CC=1CC1=CC=CC=C1 SVGYHIKXGFTUAG-UHFFFAOYSA-N 0.000 description 1
- 125000004189 3,4-dichlorophenyl group Chemical group [H]C1=C([H])C(Cl)=C(Cl)C([H])=C1* 0.000 description 1
- 125000004179 3-chlorophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C(Cl)=C1[H] 0.000 description 1
- 125000001255 4-fluorophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C([H])=C1F 0.000 description 1
- YRWAJOUPZPIBAQ-UHFFFAOYSA-N 4-nitro-2-phenyltriazole Chemical compound N1=C([N+](=O)[O-])C=NN1C1=CC=CC=C1 YRWAJOUPZPIBAQ-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 241000239290 Araneae Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 244000141359 Malus pumila Species 0.000 description 1
- 235000011430 Malus pumila Nutrition 0.000 description 1
- 235000015103 Malus silvestris Nutrition 0.000 description 1
- 241000219833 Phaseolus Species 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 241001454294 Tetranychus Species 0.000 description 1
- 241001454293 Tetranychus urticae Species 0.000 description 1
- 240000006677 Vicia faba Species 0.000 description 1
- 235000010749 Vicia faba Nutrition 0.000 description 1
- 235000002096 Vicia faba var. equina Nutrition 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 230000000895 acaricidal effect Effects 0.000 description 1
- 239000000642 acaricide Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 244000013123 dwarf bean Species 0.000 description 1
- 235000005489 dwarf bean Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical class CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- IZWPGJFSBABFGL-GMFCBQQYSA-M sodium;2-[methyl-[(z)-octadec-9-enoyl]amino]ethanesulfonate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC(=O)N(C)CCS([O-])(=O)=O IZWPGJFSBABFGL-GMFCBQQYSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000004563 wettable powder Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
Akaricide mit ovicider und larvicider Wirkung Gegenstand der vorliegenden Erfindung sind Akaricide mit ovieider und larvicider Wirkung, die gekennzeichnet sind durch.ihren Gehalt an 2-Aryl-4-nitro-1,2,3-triazolen der Formel worin R1 und R2 jeweils Wasserstoff, Fluor, Chlor oder CF3 bedeuten. Akaricides with ovicidal and larvicidal action The present invention relates to acaricides with ovicidal and larvicidal action, which are characterized by their content of 2-aryl-4-nitro-1,2,3-triazoles of the formula wherein R1 and R2 each represent hydrogen, fluorine, chlorine or CF3 .
Diese Mittel töten vor allem Eier und Larven der in immer stärkerem Maße als Schädlinge auftretenden Spinnmilben (Tetranychus urticae), insbesondere der gegen bisher handelsübliche Ovicide resistenten Stämme.These agents mainly kill eggs and larvae in increasing numbers Measures occurring as pests spider mites (Tetranychus urticae), in particular the strains resistant to hitherto commercially available ovicides.
Die Wirkstoffe der obigen Mittel sind nach dem Verfahren der DAS 1 168 437 erhältlich. Sie können in üblichen Mischungen mit Lösungsmitteln, Emulgatoren, Haftmitteln oder Inertmaterialien als Lösungen, Dispersionen, Emulsionen oder Stäubepulver verwendet werden. Folgende Beispiele erläutern die Verwendung'der beanspruchen Ovizide: B e i s p i e 1 1 Bohnenpflanzen (phaseolus), die mit 1 - 5 Tage alten Eiern von Spinnmilben (Tetranychus urtioae) besetzt sind, werden mit einer 0,05 %igen wäßrigen Suspension eines sogenannten Spritzpulvers (wettable powder), bestehend aus 25 % 2-(4-Chlorphenyl)-4-nitro-1,2,3-triazol als Wirkstoff 64 % einer Mischung aus etwa 85 % Si02 + Kaolin als Adsorptions- und Mahlhilfsmittel 10 y& Zellpechpulver (trockene Sulfitzelluloseablauge) als Haft- und Dispergiermittel 1 % Natrium-oleyl-methyltaurid als Netzmittel gespritzt; sämtliche Eier sterben ab. Verzögert sich die Spritzung derart, daß bereits Larven geschlüpft sind, so werden auch diese getc'--t.The active ingredients of the above agents are according to the procedure of DAS 1 168 437 available. They can be mixed with solvents, emulsifiers, Adhesives or inert materials as solutions, dispersions, emulsions or dust powders be used. The following examples explain the use of the claim ovicides: B e i s p i e 1 1 bean plants (phaseolus), which with 1 - 5 day old eggs of spider mites (Tetranychus urtioae) are occupied with a 0.05% aqueous suspension of a so-called wettable powder, consisting of 25% 2- (4-chlorophenyl) -4-nitro-1,2,3-triazole as an active ingredient 64% of a Mixture of about 85% Si02 + kaolin as adsorption and grinding aid 10 y & Cell pitch powder (dry sulphite cellulose waste liquor) as an adhesive and dispersant 1% sodium oleyl methyl tauride sprayed as a wetting agent; all eggs die away. If the spraying is delayed so that larvae have already hatched, so will also getc'-t.
B e i. s p i e 1 2 Apfelbäumchen, die mit 1 - 5 Tage alten Eiern von Spinnmilben besetzt sind, werden mit einer 0,075 %igen wäßrigen Verdünnung eines Emulsionskonzentrates gespritzt, das aus 15 % 2-(4-Fluorphenyl)-4-nitro-1.2.3-triazol als Wirkstoff 75 % Cyclohexanon als Lösungsmittel 10 % oxäthyliertem Nonylphenol als Netzmittel besteht; sämtliche Eier sowie geschlüpfte Larven werden abgetötet. B o i s p i e 1 3 Auf Ackerbohnen (Vicia faba) abgelegte Spinnmilbeneier unterschiedlichen Entwicklungsalters werden abgetötet, indem man die Pflanzen mit einem verstä,ubbaren Präparat, bestehend aus 10 9b 2-Phenyl-4-nitro-1,2,3-triazol als Wirkstoff 90 % Talkum als Inertmittel in einer Aufwandmenge von 20 kg/ha behandelt. Vorgleichsbeispi(, Bohnenpflanzen, die a) mit 1 - 5 Tage alten Eiern normal reagierender Spinnmilben (Tetranychue urticae) b) mit 1 - 5 Tage alten Eiern gegen chlorierte Kohlen- wasserstoffe resistenter Spinnmilben besetzt sind, werden mit wäßrigen Suspensionen sogenannter Spritzpulver gespritzt, die 1) als Wirksubstanz 2-(subst.-Phenyl)-4-nitro-1,2,3-triazole nachfolgender liste bzw. 2) als Vergleichsmittel p-Chlorbenzyl-p-ohlorphenylsulfid, unter der Trivialbezeichnung Chlorbenside im Handel befindlich, enthalten. Bei der mikroskopischen Auszählung 8 Tage nach der Spritzung zeigt es sich, daß die beanspruchten Wirkstoffe und das Vergleichsmittel bei dem normal reagierenden Spinnmilbenstamm-etwa gleichgut wirksam sind. At. Spie 1 2 apple trees, which are occupied with 1 - 5-day-old eggs of spider mites, are sprayed with a 0.075% aqueous dilution of an emulsion concentrate made from 15% 2- (4-fluorophenyl) -4-nitro-1.2.3- triazole as active ingredient 75% cyclohexanone as solvent 10% oxethylated nonylphenol as wetting agent; all eggs and hatched larvae are killed. B o ispie 1 3 on field beans (Vicia faba) stored spider mites eggs different developmental ages are killed by treating the plants with an increases one ubbaren preparation consisting of 10 9b 2-phenyl-4-nitro-1,2,3-triazole as an active ingredient 90% talc treated as an inert agent at an application rate of 20 kg / ha . Previous examples (, bean plants that a) are populated with 1 - 5 day old eggs of normally reacting spider mites (Tetranychue urticae) b) with 1 - 5 day old eggs of spider mites resistant to chlorinated hydrocarbons are sprayed with aqueous suspensions of so-called wettable powders, which 1) as active substance 2- (substituted-phenyl) -4-nitro-1,2,3-triazoles in the following list or 2) as comparison agent p-chlorobenzyl-p-chlorophenyl sulfide, Commercially available under the common name of chlorinated surfactants . A microscopic count 8 days after the spraying shows that the claimed active ingredients and the comparison agent are about equally effective in the normally reacting spider mite strain.
Dagegen bestehen beachtliche Unterschiede bei obigem gegen
chlorierte gohlenwasserstoffe resistenten Stamm.
Hier sind die
2-Aryl-4-nitro-1,2,3-triazole sehr gut
wirksam, während das Vergleichsmittel
versagt.
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEF0043380 | 1964-07-09 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1542769A1 true DE1542769A1 (en) | 1969-07-03 |
Family
ID=7099526
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19641542769 Pending DE1542769A1 (en) | 1964-07-09 | 1964-07-09 | Akaricide with ovicidal and larvicidal effects |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE1542769A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0350237A3 (en) * | 1988-07-08 | 1990-08-29 | Schering Agrochemicals Limited | Triazole insecticides |
| EP0400842A1 (en) * | 1989-05-18 | 1990-12-05 | Schering Agrochemicals Limited | Triazole pesticides |
-
1964
- 1964-07-09 DE DE19641542769 patent/DE1542769A1/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0350237A3 (en) * | 1988-07-08 | 1990-08-29 | Schering Agrochemicals Limited | Triazole insecticides |
| AU611576B2 (en) * | 1988-07-08 | 1991-06-13 | Schering Agrochemicals Limited | Triazole insecticides |
| US5064844A (en) * | 1988-07-08 | 1991-11-12 | Schering Agrochemicals Limited | 1,2,3-triazole insecticides |
| EP0400842A1 (en) * | 1989-05-18 | 1990-12-05 | Schering Agrochemicals Limited | Triazole pesticides |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE3034905C2 (en) | ||
| DE1209799B (en) | Seed dressing against fusariosis | |
| DE2858350C2 (en) | ||
| DE2514402A1 (en) | INSECTICIDAL AGENTS | |
| DE1803728A1 (en) | Pest repellants | |
| DE2709886A1 (en) | 2-IMINOTHIAZOLINE COMPOUNDS AND THEIR 4,5-DIHYDRODE DERIVATIVES, METHOD OF MANUFACTURING AND USE IN PEST CONTROLS | |
| DD149890A5 (en) | MOLD PREPARATION AND METHOD | |
| DE1542769A1 (en) | Akaricide with ovicidal and larvicidal effects | |
| DE1089210B (en) | Herbicides | |
| DE1767924A1 (en) | 1-phenyl-4,4-dialkyl-thiosemicarbazide | |
| DE2131401B2 (en) | Herbicidal mixture based on benzothiadiazinone dioxide | |
| DE1131461B (en) | Combating plant diseases caused by fungi | |
| DE1204878B (en) | Acaricidal agents | |
| WO1982003390A1 (en) | Erivatives of phenoxy-phenyle-isothio-urea,intermediary products based on phenoxy-phenyle-thio-urea,preparation thereof and their utilization against insects | |
| DE2253027A1 (en) | FUNGICIDALS | |
| DE1210620B (en) | Fungitoxic agents | |
| EP0077300B1 (en) | Triorganotinhydantoin compounds, process for their preparation, and their use as biocides | |
| DE1181978B (en) | Means for combating arthropods, molluscs and fish | |
| DE2349970A1 (en) | N-BENZOYL-N- (3-CHLORO-4-FLUOROPHENYL) -2AMINO-PROPIONIC ACID ESTERS AND THEIR USE AS HERBICIDES | |
| DE2242785A1 (en) | 1-ALKYLSULFONYL-2-TRIFLUOROMETHYLBENZIMIDAZOLE, METHOD FOR MANUFACTURING AND USING IT AS AN EECTOPARASITE AGENT | |
| DE2553270A1 (en) | EECTOPARASITICIDE AGENT CONTAINING DIPHENYLCARBODIIMIDE | |
| DE1542889A1 (en) | Means for combating weeds | |
| DE1161078B (en) | Preparations for combating insects, spiders and mites, their eggs and fungi | |
| DE2512940C2 (en) | N-Benzoyl-N-halophenyl-2-aminopropionic acid ester, process for their preparation and their use | |
| DE3200196A1 (en) | OXADIAZINDIONE, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE FOR CONTROLLING INSECTS AND SPIDERS |