DE1492322A1 - Use of UV-absorbing substances as additives for cosmetics - Google Patents
Use of UV-absorbing substances as additives for cosmeticsInfo
- Publication number
- DE1492322A1 DE1492322A1 DE19641492322 DE1492322A DE1492322A1 DE 1492322 A1 DE1492322 A1 DE 1492322A1 DE 19641492322 DE19641492322 DE 19641492322 DE 1492322 A DE1492322 A DE 1492322A DE 1492322 A1 DE1492322 A1 DE 1492322A1
- Authority
- DE
- Germany
- Prior art keywords
- cosmetics
- substances
- additives
- skin
- absorbing substances
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000126 substance Substances 0.000 title claims description 15
- 239000002537 cosmetic Substances 0.000 title claims description 12
- 239000000654 additive Substances 0.000 title claims description 3
- 206010040914 Skin reaction Diseases 0.000 claims description 7
- 231100000430 skin reaction Toxicity 0.000 claims description 7
- 230000035483 skin reaction Effects 0.000 claims description 7
- 238000010521 absorption reaction Methods 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- -1 dentonite Substances 0.000 description 3
- 239000003504 photosensitizing agent Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 235000019499 Citrus oil Nutrition 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 206010020751 Hypersensitivity Diseases 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 208000026935 allergic disease Diseases 0.000 description 2
- 150000001545 azulenes Chemical class 0.000 description 2
- 239000010500 citrus oil Substances 0.000 description 2
- 230000002165 photosensitisation Effects 0.000 description 2
- 239000011269 tar Substances 0.000 description 2
- 244000061520 Angelica archangelica Species 0.000 description 1
- 101150038108 Art7 gene Proteins 0.000 description 1
- 206010008570 Chloasma Diseases 0.000 description 1
- 241000207199 Citrus Species 0.000 description 1
- 235000001287 Guettarda speciosa Nutrition 0.000 description 1
- 208000003351 Melanosis Diseases 0.000 description 1
- 206010037867 Rash macular Diseases 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 206010042496 Sunburn Diseases 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 208000038016 acute inflammation Diseases 0.000 description 1
- 230000006022 acute inflammation Effects 0.000 description 1
- 230000007815 allergy Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 235000020971 citrus fruits Nutrition 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000008406 cosmetic ingredient Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 235000019441 ethanol Nutrition 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000009610 hypersensitivity Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000031700 light absorption Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 208000017983 photosensitivity disease Diseases 0.000 description 1
- 231100000434 photosensitization Toxicity 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- ZXWJOCNGCUPEMH-UHFFFAOYSA-N propan-2-yl 3-(4-propan-2-ylphenyl)prop-2-enoate Chemical compound CC(C)OC(=O)C=CC1=CC=C(C(C)C)C=C1 ZXWJOCNGCUPEMH-UHFFFAOYSA-N 0.000 description 1
- 239000011814 protection agent Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
- A61K8/445—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof aromatic, i.e. the carboxylic acid directly linked to the aromatic ring
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4973—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom
- A61K8/498—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom having 6-membered rings or their condensed derivatives, e.g. coumarin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/43—Pigments; Dyes
- A61K2800/434—Luminescent, Fluorescent; Optical brighteners; Photosensitizers
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Description
Der überwiegende Teil der unerwünschten Hautrealctionen auf Kosmetika und ähnliche Präparate beruht auf einer individuellen (Jberempfindlichkeit (Allergie). Daneben sind jedoch auch Hautreaktionen bekannt, die dann auftreten können, wenn in den Präparaten Substanzen mit Lichtabsorptionsrr.axima oberhalb 300 nm enthalten sind und das Präparat in aufgetragenem Zustand auf der Haut der Einwirkung von Sonnenstrahlen oder ähnlichen Lichtquellen ausgesetzt ist. Unter diesen Voraussetzungen kann es auf dem V/ege einer Photosensibillsierung (photodynamische Reaktion) zu Ilautreaktionen kommen, die sich als akute Entzündung und/oder Überpigrnentie- rung zu erkennen geben. Derartige Hautreaktionen sind bei- The predominant part of the undesirable skin reactions to cosmetics and similar preparations is based on an individual (hypersensitivity (allergy). In addition, however, skin reactions are known which can occur if the preparations contain substances with light absorption maxima above 300 nm and the preparation is exposed to in-applied state on the skin exposure to sun rays or similar light sources. Under these conditions it may be on the V / ege a Photosensibillsierung (photodynamic reaction) occur Ilautreaktionen which tion as an acute inflammation and / or Überpigrnentie- make known Such skin reactions are both
909883/1571909883/1571
■ KfeiOMN . PMMmUmI* Mta*Mtm74■ KfeiOMN. PMMmUmI * Mta * Mtm74
cpielsv/eise unter der Bezeichnung M3erloque-Derrr.atitio" bekannt, können aber auch eine fleckige Verfärbung des Gesichtes (Chloasma) zur Folge haben.cpielsv / eise known as M 3erloque-Derrr.atitio ", but can also result in blotchy discoloration of the face (chloasma).
Obwohl diese Hautreaktionen relativ selten sind, lassen sie sich doch, cofern sie einmal aufgetreten sind, nur sehr schwierig wieder beseitigen, so daß nach Höflichkeiten gesucht v/erden muß, derartige Hautreaktionen ::u vermeiden.Although these skin reactions are relatively rare, once they have occurred they can be very difficult difficult to get rid of, so looked for courtesies must avoid such skin reactions.
2s wurde nun gefunden, daß durch Verwendung von Substanzen, die kurzwelliges Ultraviolett etwa in dem Bereich zwischen 300 und 450 nr. zu absorbieren vermögen, als Zusätze zu photosensibilisierende Bestandteile enthaltenden Kosmetika in Mengen von weniger als 10 c/?, bezogen auf die Kosmetika, unerwünschte Hautreaktionen vermieden v/erden können.2s it has now been found that by using substances which have short-wave ultraviolet in the range between 300 and 450 nr. able to absorb, as additives to cosmetics containing photosensitizing constituents in amounts of less than 10 c /?, based on the cosmetics, undesired skin reactions can be avoided.
Von photosensibilisierenden Substanzen, die in Kosmetika, wie beispielsweise Parfüms, Kölnisch V/ässer, Toilettewässer, Lippenstiften oder Hautpflegemitteln, enthalten sein können, seien Citrusöle, Azulene, Teere oder Sosine erwähnt.Of photosensitizing substances used in cosmetics, such as perfumes, cologne, toilet waters, Lipsticks or skin care products, citrus oils, azulenes, tars or sosines may be mentioned.
Ss sind bereits Kosmetika bekannt, denen Stoffe beigemischt sind, die das Eindringen bestimmter Lichtbereiche in die Haut einschränken bzw. ganz verhindern (DAS 1 021 541, DDR-Patentschrift 32 279, Karl Rothemann, Das große Rezeptbuch der Haut- und Körperpflegemittel, 1902, 3. 64^ sowie Sagarin, Cosmetics Science and Technology, 1957, S. 205).Ss cosmetics are already known to which substances are mixed that the penetration of certain areas of light into the Restrict skin or prevent it entirely (DAS 1 021 541, GDR patent specification 32 279, Karl Rothemann, Das Großes recipe book der skin and body care products, 1902, 3. 64 ^ as well as Sagarin, Cosmetics Science and Technology, 1957, p. 205).
909883/1571909883/1571
Bisher erfolgte der Zusatz üV-absorbierender J ifes tanzen :'.u Kosr.:etika nur deshalb, um entweder den Kosmetika eine gegen Jonr.enbrand schützende V/irkunß zu verleihen oder urr. eire Zersetzung von in ihnen enthaltenen Substanzen zu verhindern, ileiner der angegebenen Literaturstellcn ist der Hinweis darauf zu entnehmen, daß es möglich ist, durch Zvfatz uY-absorbierender Substanzen zu photosensibilisiererxle Bestandteile enthaltenden Kosmetika unerwünschte H onen zu vermeiden.So far, the addition of UV-absorbing J ifes has been added : '. u Kosr.:etika only to either the cosmetics a to give protective measures against fire or urr. prevent the decomposition of substances contained in them, one of the cited references is the Indication to infer that it is possible to photosensitizerxle by adding uY-absorbing substances Cosmetics containing ingredients to avoid undesirable honing.
Als errindungs£eraäß verwendbare Substanzen, die kurzv/ Ultraviolett zu absorbieren vermögen, kommen Verbindungen in Frage, die folgende Voraussetzungen erfüllen:Substances that can be used as rindings, which are briefly Able to absorb ultraviolet, compounds come in Question that meet the following requirements:
1. Sie müssen weitgehend lichtbeständig sein,1. They must be largely lightfast,
2. sie müssen eine gute Hautverträgliehkeit besitzen,2. they must be well tolerated by the skin,
3. sie sollen möglichst wenig in die Kaut eindringen,3. They should penetrate the chew as little as possible,
4. sie sollen zur Vermeidung unerwünschter Umsetzungen mit anderen Bestandteilen der Kosmetika chemisch ir.ö™-lichst indifferent sein, und4. They are intended to avoid undesired conversions chemically ir.ö ™ with other components of cosmetics be indifferent, and
5. sie müssen die Fähigkeit besitzen, Licht zu absorbieren, zu reflektieren oder zu zerstreuen, insbesondere in der. Bereich zwischen 300 und ^50 nm.5. they must have the ability to absorb light, to reflect or disperse, especially in the. Range between 300 and ^ 50 nm.
Aufgrund der vorstehend genannten Kriterien kommen Substanzen, die zum Schutz der menschlichen Haut vor Sonnenbrand verwendet werden (Sonnen- oder Lichtschutzmittel) sowie solche Substanzen oder Gemische in Betracht, die aufgrund ihrer BeschaffenheitOn the basis of the criteria mentioned above, substances are which are used to protect human skin from sunburn (sun or light protection agents) as well as substances or mixtures that are due to their nature
909883/1571909883/1571
in der Lage sind, Licht zu absorbieren, zu reflektieren oder zu streuen, beispielsweise Talkum, Dentonit, Zinkoxyd, Stärke, Titandioxyd oder dergleichen. Unter den löslichen, lichtabsorbierenden .Substanzen richtet sich die Auswahl in erster Linie nach den optischen Eigenschaften des photosensicilisierenden Kosmetikumbestandteils, da die beste Wirkung dann erzielt wird, wenn die lichtfilternde Substanz den gleichen oder einen wenig längerwelligen Lichtbereich maximal absorbiert, wie der Photosensibilisator.are able to absorb, reflect or light to sprinkle, for example talc, dentonite, zinc oxide, starch, titanium dioxide or the like. Among the soluble, light-absorbing The selection of substances depends primarily on the optical properties of the photosensicilizing agent Cosmetic ingredient, as the best effect then achieved becomes when the light-filtering substance is the same or one A little longer-wave light range is maximally absorbed, like the photosensitizer.
Beispielsweise wird die Photosensibilisierungsreaktion durch die Purocumarine.der Citrus- oder Angelikaöle (maximale Absorption zwischen 300 und 315 nm) am besten durch Substanzen verhindert, deren Absorptionsmaximum zwischen 3OO und 3^0 nm liegt. Entsprechend zeigen bei Teeren oder Azulenen Substanzen mit Absorptionsmaxima zwischen 350 und 450 nm die günstigste Wirkung.For example, the photosensitization reaction is caused by the purocoumarins of the citrus or angelica oils (maximum absorption between 300 and 315 nm) best by substances prevents their absorption maximum between 3OO and 3 ^ 0 nm lies. Correspondingly, in the case of tars or azulenes, substances with absorption maxima between 350 and 450 nm show the most favorable Effect.
Die folgenden Beispiele erläutern die Erfindung.The following examples illustrate the invention.
2 g p-Aminobenzoesäure-monoglycerinester und 0,5 ^ p-Isopropylzimtsäure-isopropylester werden mit 30,0 g $2 g of p-aminobenzoic acid monoglycerol ester and 0.5 ^ p-isopropylcinnamic acid isopropyl ester are with 30.0 g $
CO ·· y.CO ·· y.
o Äthylalkohol gemischt und zu 67,5 G Citrusöl-haltigem o Ethyl alcohol mixed and added to 67.5 g of citrus oil
co Toilettenwasser gegeben.co given toilet water.
w w Beispiel 2Example 2
-» 5,0 ζ P-Methylenaminobenzoesäure-polyglykolester und 5,0 g Trimethoxy-dihydroxybenzophenon werden mit 990,0 g Kölnischwasser vermischt.- "5.0 ζ P Methylenaminobenzoesäure-polyglycol and 5.0 g of trimethoxy-dihydroxybenzophenone are mixed with 990.0 g colognes.
Dei dor Herstellung der Kölnischwaooer-otifto werden in die warme Grundmasse 0,5 % Umbelliferonessissäure und 2 £ 3entonit eingearbeitet.During the production of the Kölnischwaooer otifto, 0.5 % umbelliferonessis acid and 2 £ 3entonite are incorporated into the warm base mass.
909883/1571909883/1571
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DED0044629 | 1964-06-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1492322A1 true DE1492322A1 (en) | 1970-01-15 |
Family
ID=7048445
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19641492322 Pending DE1492322A1 (en) | 1964-06-08 | 1964-06-08 | Use of UV-absorbing substances as additives for cosmetics |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE1492322A1 (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4136165A (en) * | 1976-04-23 | 1979-01-23 | Henkel Kommanditgesellschaft Auf Aktien | Cosmetic preparations with alkoxybenzoic acid esters as inflammation inhibitors and method |
| FR2409751A1 (en) * | 1977-11-29 | 1979-06-22 | Thorel Jean Noel | Sun tan compsn. giving rapid bronzing - contg. 5-methoxy psoralen, lanolin, and UV filter cpd. |
| FR2539623A1 (en) * | 1983-01-26 | 1984-07-27 | Oreal | COSMETIC COMPOSITIONS CONTAINING NATURAL ESSENCES AND DERIVATIVES OF BENZYLIDENE CAMPHOR |
| FR2539625A1 (en) * | 1983-01-26 | 1984-07-27 | Oreal | ALCOHOLIC OR HYDRO-ALCOHOLIC COMPOSITIONS CONTAINING NATURAL SPECIES AND DERIVATIVES OF BENZYLIDENE CAMPHOR |
| EP0257928A3 (en) * | 1986-08-22 | 1988-05-18 | Kays Kaidbey | Suntanning composition |
| EP0376821A1 (en) * | 1988-12-30 | 1990-07-04 | L'oreal | Compositions for inducing and stimulating hair growth and/or stop their fall based on pyrimidine derivatives and UV filters |
| WO2001093823A1 (en) * | 2000-06-02 | 2001-12-13 | Quest International B.V. | Improvements in or relating to perfumes |
-
1964
- 1964-06-08 DE DE19641492322 patent/DE1492322A1/en active Pending
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4136165A (en) * | 1976-04-23 | 1979-01-23 | Henkel Kommanditgesellschaft Auf Aktien | Cosmetic preparations with alkoxybenzoic acid esters as inflammation inhibitors and method |
| FR2409751A1 (en) * | 1977-11-29 | 1979-06-22 | Thorel Jean Noel | Sun tan compsn. giving rapid bronzing - contg. 5-methoxy psoralen, lanolin, and UV filter cpd. |
| FR2539623A1 (en) * | 1983-01-26 | 1984-07-27 | Oreal | COSMETIC COMPOSITIONS CONTAINING NATURAL ESSENCES AND DERIVATIVES OF BENZYLIDENE CAMPHOR |
| FR2539625A1 (en) * | 1983-01-26 | 1984-07-27 | Oreal | ALCOHOLIC OR HYDRO-ALCOHOLIC COMPOSITIONS CONTAINING NATURAL SPECIES AND DERIVATIVES OF BENZYLIDENE CAMPHOR |
| US4731200A (en) * | 1983-01-26 | 1988-03-15 | L'oreal | Alcoholic or aqueous-alcoholic compositions containing natural essences and benzylidene-camphor derivatives |
| US4950478A (en) * | 1983-01-26 | 1990-08-21 | L'oreal | Cosmetic compositions containing natural essences and benzylidenecamphor derivatives |
| EP0257928A3 (en) * | 1986-08-22 | 1988-05-18 | Kays Kaidbey | Suntanning composition |
| EP0376821A1 (en) * | 1988-12-30 | 1990-07-04 | L'oreal | Compositions for inducing and stimulating hair growth and/or stop their fall based on pyrimidine derivatives and UV filters |
| FR2641184A1 (en) * | 1988-12-30 | 1990-07-06 | Oreal | COMPOSITION FOR INDUCING AND STIMULATING HAIR GROWTH AND / OR BRAKING THEIR FALL BASED ON PYRIMIDINE DERIVATIVES AND SOLAR FILTERS |
| WO2001093823A1 (en) * | 2000-06-02 | 2001-12-13 | Quest International B.V. | Improvements in or relating to perfumes |
| US7129204B2 (en) | 2000-06-02 | 2006-10-31 | Quest International Services B.V. | Perfumes |
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