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DE1282594B - Sizing agents - Google Patents

Sizing agents

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Publication number
DE1282594B
DE1282594B DE1962R0032994 DER0032994A DE1282594B DE 1282594 B DE1282594 B DE 1282594B DE 1962R0032994 DE1962R0032994 DE 1962R0032994 DE R0032994 A DER0032994 A DE R0032994A DE 1282594 B DE1282594 B DE 1282594B
Authority
DE
Germany
Prior art keywords
polyvinyl
mixture
size
acetate
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DE1962R0032994
Other languages
German (de)
Inventor
Richard Frederick Jame Ingleby
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Revertex Ltd
Original Assignee
Revertex Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB23085/61A external-priority patent/GB932894A/en
Application filed by Revertex Ltd filed Critical Revertex Ltd
Publication of DE1282594B publication Critical patent/DE1282594B/en
Pending legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/35—Heterocyclic compounds
    • D06M13/352—Heterocyclic compounds having five-membered heterocyclic rings
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144—Alcohols; Metal alcoholates
    • D06M13/148—Polyalcohols, e.g. glycerol or glucose
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/418—Cyclic amides, e.g. lactams; Amides of oxalic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D06M15/11—Starch or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
    • D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32—Polyesters

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Description

BUNDESREPUBLIK DEUTSCHLAND DEUTSCHES 007WW PATENTAMT Int. CL: FEDERAL REPUBLIC OF GERMANY GERMAN 007WW PATENTAMT Int. CL:

D 06mD 06m

AUSLEGESCHRIFTEDITORIAL

Deutsche Kl.: 8 k-1/01German class: 8 k-1/01

Nummer: 1282594Number: 1282594

Aktenzeichen: P 12 82 594.4-43 (R 32994)File number: P 12 82 594.4-43 (R 32994)

Anmeldetag: 23. Juni 1962 Filing date: June 23, 1962

Auslegetag: 14. November 1968Opening day: November 14, 1968

Die Erfindung betrifft ein Schlichtemittel für hydrophobe Textilgarne, insbesondere Polyestergarne, die verwebt oder verwirkt werden sollen. Gegenstand der Hauptpatentanmeldung R 27411IV c/8 k (deutsche Auslegeschrift 1 262 208) ist ein Schlichtemittel für hydrophobe Textilgewebe, insbesondere Polyestergarne, das eine wäßrige Lösung einer Mischung einer hydroxylierten Polyvinylverbindung und einer carboxylgruppenhaltigen Polyvinylverbindung enthält, die durch Mischpolymerisation mindestens einer äthylenisch ungesättigten Carbonsäure mit Vinylacetat oder einer Mischung von äthylenisch ungesättigten Verbindungen, die einen größeren Anteil an Vinylacetat enthalten, hergestellt worden ist, wobei die hydroxylierte Polyvinylverbindung 15 bis 50 Gewichtsprozent der Trockenbestandteile der Mischung ausmacht und 35 bis 50 Hydroxylgruppen auf je 100 Kohlenstoffatome in der Polyvinylkette enthält und die carboxylgruppenhaltige Polyvinylverbindung 50 bis 85 Gewichtsprozent der Trockenbestandteile der Mischung darstellt und zwischen 4 und 25 Carboxylgruppen auf je 100 Kohlenstoffatome in der Polyvinylkette enthält und der pH-Wert der Lösung zwischen 5 und 11, vorzugsweise zwischen 6 und 8 liegt.The invention relates to a sizing agent for hydrophobic textile yarns, in particular polyester yarns, the to be woven or forfeited. Subject of the main patent application R 27411IV c / 8 k (German Auslegeschrift 1 262 208) is a sizing agent for hydrophobic textile fabrics, especially polyester yarns, that is an aqueous solution of a mixture of a hydroxylated polyvinyl compound and a carboxyl group-containing one Contains polyvinyl compound which is ethylenically through copolymerization at least one unsaturated carboxylic acid with vinyl acetate or a mixture of ethylenically unsaturated compounds, which contain a larger proportion of vinyl acetate, has been prepared, the hydroxylated Polyvinyl compound constitutes 15 to 50 percent by weight of the dry ingredients of the mixture and 35 contains up to 50 hydroxyl groups for every 100 carbon atoms in the polyvinyl chain and the ones containing carboxyl groups Polyvinyl compound represents from 50 to 85 percent by weight of the dry ingredients of the mixture and contains between 4 and 25 carboxyl groups for every 100 carbon atoms in the polyvinyl chain and the The pH of the solution is between 5 and 11, preferably between 6 and 8.

In weiterer Ausbildung dieser Erfindung wurde nunmehr festgestellt, daß die Eigenschaften der Schlichten noch erheblich verbessert werden können, wenn ihnen Äthylenharnstoff (2-Imidazolidinon) in Mengen von 1 bis 25%; vorzugsweise von 1 bis 15%? bezogen auf das Gewicht der Gesamtfeststoffe, die vor der Zugabe eines Schmelzmittels in der Schlichte enthalten sind, zugesetzt wird.In a further development of this invention it has now been found that the properties of the sizes can still be improved considerably if they give them ethylene urea (2-imidazolidinone) in amounts of 1 to 25%; preferably from 1 to 15%? based on the weight of total solids prior to addition a flux contained in the size is added.

Durch den erfindungsgemäßen Zusatz von Äthylenharnstoff zu den Schlichten wird dem Garn während des Webens erhöhter Schutz verliehen, da hierdurch der auf das Garn aufgebrachte Schlichtefilm in erhöhtem Maße geschlossen gehalten, die Adhäsion der Schlichte an den Fasern verstärkt, der Schlichtefilm geschmeidiger gemacht und die gegenseitige Verträglichkeit der verschiedenen Bestandteile der Schlichte verbessert wird. Diese Verbesserung der Adhäsion, Flexibilität und Verträglichkeit wird ohne starke Zunahme der Weichheit der Schlichte oder der Neigung getrockneter Filme auf dem Garn, unter Druck miteinander zu verkleben, erzielt. Hierdurch ergibt sich eine hohe Webleistung, die sich aus der geringen Zahl von Fadenbrüchen während des Webens ergibt. Auch Fehler durch Verkleben der Kettgarne auf dem Baum werden auf ein Mindestmaß herabgedrückt. By adding ethylene urea to the sizes according to the invention, the yarn is during the weaving given increased protection, since this gives the size film applied to the yarn in increased Dimensions kept closed, the adhesion of the size to the fibers reinforced, the size film made more pliable and the mutual compatibility of the various components of the size is improved. This improvement in adhesion, flexibility and tolerability will be without a large increase the softness of the size or the tendency of dried films on the yarn to be under pressure with one another to glue, achieved. This results in a high weaving performance, which results from the small number of thread breaks during weaving. Also errors due to sticking of the warp yarns the tree are pushed down to a minimum.

In den folgenden Beispielen beziehen sich Mengenangaben auf das Gewicht.In the following examples, quantities are based on weight.

SchlichtemittelSizing agents

Zusatz zur Anmeldung: R 27411IV c/8 k-Auslegeschrift 1 262 208Addition to registration: R 27411IV c / 8 k-Auslegeschrift 1 262 208

Anmelder:Applicant:

Revertex Limited, LondonRevertex Limited, London

Vertreter:Representative:

Dr. Eggert, 5000 Köln 1, DeichmannhausDr. Eggert, 5000 Cologne 1, Deichmannhaus

Als Erfinder benannt:Named as inventor:

Richard Frederick James Ingleby, Harlow, EssexRichard Frederick James Ingleby, Harlow, Essex

(Großbritannien)(Great Britain)

Beanspruchte Priorität:Claimed priority:

Großbritannien vom 26. Juni 1961 (23 085)Great Britain June 26, 1961 (23 085)

Beispiel 1example 1

Eine Schlichte wird aus folgenden Bestandteilen hergestellt: A size is made from the following components:

Wäßrige Lösung einer Mischung einer Teile
hydroxylierten Polyvinylverbindung
mit einer carboxylgruppenhaltigen
Polyvinylverbindung nach Patentanmeldung R 27411IV c/8 k (deutsche
Auslegeschrift 1 262 208) (Beispiel) .. 100Aqueous solution of a mixture of one parts
hydroxylated polyvinyl compound
with a carboxyl group-containing
Polyvinyl compound according to patent application R 27411IV c / 8 k (German
Interpretation document 1 262 208) (example) .. 100

Wasser 240Water 240

3normale Natriumhydroxydlösung .... 103normal sodium hydroxide solution .... 10

Äthylenharnstoff ... 1,8Ethylene urea ... 1.8

Stabilisierte Wachs-Öl-Dispersion 20Stabilized wax-oil dispersion 20

Zu dem Schlichtemittel nach der Hauptpatentanmeldung werden die anderen Bestandteile in der angegebenen Reihenfolge langsam zugegeben. Durch die Zugabe des Natriumhydroxyds wird eine Lösung gebildet. Nach der Zugabe des Äthylenharnstoffs und der Schmelzemulsion ist die Schlichte fertig zum Gebrauch. Sie hat einen pH-Wert von 7,8 bis 8,5, eine Viskosität von etwa 20 cSt bei 2O0C und einen Feststoffgehalt von etwa 10%·The other constituents are slowly added to the sizing agent according to the main patent application in the order given. A solution is formed by adding the sodium hydroxide. After adding the ethylene urea and the melt emulsion, the size is ready for use. It has a pH of 7.8 to 8.5, a viscosity of about 20 cSt at 2O 0 C and a solids content of about 10%

Ein aus endlosen Polyäthylenterephthalat-Kettfäden (100 den, 866 Drehungen pro Meter) hergestellter schmaler Streifen wird in einer Trommeltrockenschlichtmaschine in üblicher Weise geschlichtet,One made from endless polyethylene terephthalate warp threads (100 denier, 866 twists per meter) is made in a drum dry sizing machine arbitrated in the usual way,

809 637/1260809 637/1260

Claims (1)

3 4 wobei durch das Garn etwa 3,5 % Schlichte, gerechnet tigen Polyvinylverbindung enthält, die durch als Trockenmassen, aufgenommen werden. Das Ma- Mischpolymerisation mindestens einer äthylenisch terial kann dann ohne Schwierigkeit zu einer Linon- ungesättigten Carbonsäure mit Vinylacetat oder bindung verwebt werden. einer Mischung von äthylenisch ungesättigten Ver- 5 bindungen, die einen größeren Anteil an Vinyl- Beispiel2 acetat enthalten, hergestellt worden ist, wobei die _..__„ „ „ , . . . hydroxylierte Polyvinylverbindung 15 bis 50 Ge- c S^ fUr Endlosgarn Cellulosetnacetat geeignete wichtsprozent der Trockenbestandteile der Mi- Schhchte wird aus folgenden Bestandteilen hergestellt: schung ausmacht und 35 bis 50 Hydroxylgruppen Teilhydrolysierter Polyvinylalkohol, in TeUe io auf je 100 Kohlenstoffatome in der Polyvinylkette dem etwa 88 °/0 der Acetatgruppen, die enthält und die carboxylgruppenhaltig Polyvinyl- ursprünglich im Polyvinylacetat vor- verbindung 50 bis 85 Gewichtsprozent der Trocken- handen waren aus dem der Polyvinyl- -.. bestandteile der Mischung darstellt und zwischen alkohol erhalten wurde, durch Hy- 4 und 25 Carboxylgruppen auf je 100 Kohlenstoff- droxylgruppen ersetzt worden sind, 1S atome in der Polyvinylkette enthält und der und der als 4%ige wäßrige Lösung pH-Wert der Lösung zwischen 5 und 11, vorzugs- eine Viskosität von etwa 2OcSt bei weise zwischen 6 und 8, liegt, nach Patentanmeldung 2O0C hat 4 R 27411 IV c/8 k(deutscheAuslegeschriftl262208), Saccharose .". ...*. 2 gekennzeichnet durch einen Äthylen-Äthylenharnstoff .................... 2 20 harnstoffgehalt von 1 bis 25 °/0, vorzugsweise 1 bis \\rasser 92 15 %, bezogen auf das Gewicht der Gesamtf est- stoffe, die vor der Zugabe eines Schmelzmittels Das zu schlichtende Garn kann in üblicher Weise in der Schlichte enthalten sind, am Spindelstock der Schlichtemaschine geschmälzt 2. Schlichtemittel nach Anspruch 1, dadurch werden. 25 gekennzeichnet, daß die Schlichte zusätzlich Sac- Patentansprüche: charose enthält.3 4 where the yarn contains about 3.5% size, calculated term polyvinyl compound, which is absorbed by the dry matter. The copolymerization of at least one ethylenic material can then be woven into a linonosaturated carboxylic acid with vinyl acetate or bond without difficulty. a mixture of ethylenically unsaturated compounds which contain a larger proportion of vinyl acetate has been prepared, where the _..__ "" ",. . . Hydroxylated polyvinyl compound 15 to 50 percent by weight of the dry constituents of the mixture, suitable for continuous yarn cellulose acetate, is made from the following components: chemical and 35 to 50 hydroxyl groups partially hydrolysed polyvinyl alcohol, in parts per 100 carbon atoms in the polyvinyl chain the approximately 88 % Of the acetate groups which contain and the polyvinyl originally in the polyvinyl acetate precompound containing carboxyl groups were 50 to 85 percent by weight of the dry hands from which the polyvinyl constituents of the mixture and were obtained between alcohol, by Hy- 4 and 25 carboxyl groups have been replaced for every 100 carbon hydroxyl groups, contains 1S atoms in the polyvinyl chain and the and the as a 4% aqueous solution pH value of the solution between 5 and 11, preferably a viscosity of about 20 cSt at between 6 and 8, is, according to patent application 2O0C has 4 R 27411 IV c / 8 k (deutsche Auslegeschriftl262208), Sac charose. ". ... *. 2 characterized by an ethylene-ethylene urea .................... 2 20 urea content of 1 to 25%, preferably 1 to \\ rasser 92 15%, based on The weight of the total solids, which before the addition of a melting agent. The yarn to be sized can be contained in the size in the usual way, melted on the headstock of the sizing machine. 2. Sizing agent according to claim 1, thereby. 25 characterized in that the size also contains Sac patent claims: charose. 1. Schlichtemittel für hydrophobe Textilgewebe, In Betracht gezogene Druckschriften:1. Sizing agents for hydrophobic textile fabrics, publications considered: insbesondere Polyestergarne, das eine wäßrige Deutsche Patentschriften Nr. 681818, 701071, Lösung einer Mischung einer hydroxylierten Poly- 30 932420;in particular polyester yarns, which is an aqueous German patent specification No. 681818, 701071, Solution of a mixture of a hydroxylated poly-30 932420; vinylverbindung und einer carboxylgruppenhal- britische Patentschrift Nr. 744 093.vinyl compound and a carboxyl group-containing British Patent No. 744 093. 809 637/1260 11.68 © Bundesdruckelei Berlin809 637/1260 11.68 © Bundesdruckelei Berlin
DE1962R0032994 1961-06-26 1962-06-23 Sizing agents Pending DE1282594B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB23085/61A GB932894A (en) 1966-10-10 1961-06-26 Improvements in or relating to compositions for sizing textile yarns

Publications (1)

Publication Number Publication Date
DE1282594B true DE1282594B (en) 1968-11-14

Family

ID=40677704

Family Applications (1)

Application Number Title Priority Date Filing Date
DE1962R0032994 Pending DE1282594B (en) 1961-06-26 1962-06-23 Sizing agents

Country Status (1)

Country Link
DE (1) DE1282594B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008098138A1 (en) 2007-02-07 2008-08-14 The Government Of The United States Of America As Represented By The Secretary Of The Department Of Health And Human Services Synthetic macrocyclic compounds for treating cancer

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE681818C (en) * 1933-08-26 1939-10-02 I G Farbenindustrie Akt Ges Additive for starch finishes
DE701071C (en) * 1934-01-27 1941-01-08 I G Farbenindustrie Akt Ges ose fibers or fiber mixtures containing them
DE932420C (en) * 1948-01-27 1955-09-01 Ditisheim & Cie Fabriques Vulc Anchor steering wheel drive for the alarm hammer in alarm wristwatches
GB744093A (en) * 1952-08-11 1956-02-01 Union Carbide & Carbon Corp Method of sizing cellulosic sheet materials

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE681818C (en) * 1933-08-26 1939-10-02 I G Farbenindustrie Akt Ges Additive for starch finishes
DE701071C (en) * 1934-01-27 1941-01-08 I G Farbenindustrie Akt Ges ose fibers or fiber mixtures containing them
DE932420C (en) * 1948-01-27 1955-09-01 Ditisheim & Cie Fabriques Vulc Anchor steering wheel drive for the alarm hammer in alarm wristwatches
GB744093A (en) * 1952-08-11 1956-02-01 Union Carbide & Carbon Corp Method of sizing cellulosic sheet materials

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008098138A1 (en) 2007-02-07 2008-08-14 The Government Of The United States Of America As Represented By The Secretary Of The Department Of Health And Human Services Synthetic macrocyclic compounds for treating cancer

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