DE1146897B - Process for removing copper from iron melts containing carbon, silicon, phosphorus and manganese by washing out with lead - Google Patents
Process for removing copper from iron melts containing carbon, silicon, phosphorus and manganese by washing out with leadInfo
- Publication number
- DE1146897B DE1146897B DESCH18216A DESC018216A DE1146897B DE 1146897 B DE1146897 B DE 1146897B DE SCH18216 A DESCH18216 A DE SCH18216A DE SC018216 A DESC018216 A DE SC018216A DE 1146897 B DE1146897 B DE 1146897B
- Authority
- DE
- Germany
- Prior art keywords
- lead
- washing
- copper
- manganese
- silicon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims description 26
- 238000005406 washing Methods 0.000 title claims description 17
- 229910052742 iron Inorganic materials 0.000 title claims description 13
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims description 12
- 229910052802 copper Inorganic materials 0.000 title claims description 12
- 239000010949 copper Substances 0.000 title claims description 12
- 238000000034 method Methods 0.000 title claims description 9
- 239000000155 melt Substances 0.000 title claims description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims description 5
- 229910052799 carbon Inorganic materials 0.000 title claims description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title claims description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 title claims description 4
- 229910052698 phosphorus Inorganic materials 0.000 title claims description 4
- 239000011574 phosphorus Substances 0.000 title claims description 4
- 229910052710 silicon Inorganic materials 0.000 title claims description 4
- 239000010703 silicon Substances 0.000 title claims description 4
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 title claims description 3
- 229910052748 manganese Inorganic materials 0.000 title claims description 3
- 239000011572 manganese Substances 0.000 title claims description 3
- 239000004575 stone Substances 0.000 claims description 8
- 239000007789 gas Substances 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 3
- 230000008929 regeneration Effects 0.000 claims description 2
- 238000011069 regeneration method Methods 0.000 claims description 2
- 239000000376 reactant Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229910000805 Pig iron Inorganic materials 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- BWFPGXWASODCHM-UHFFFAOYSA-N copper monosulfide Chemical compound [Cu]=S BWFPGXWASODCHM-UHFFFAOYSA-N 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- DALUDRGQOYMVLD-UHFFFAOYSA-N iron manganese Chemical compound [Mn].[Fe] DALUDRGQOYMVLD-UHFFFAOYSA-N 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C1/00—Refining of pig-iron; Cast iron
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
Description
Verfahren zum Entkupfern von Kohlenstoff, Silizium, Phosphor und Mangan enthaltenden Eisenschmelzen durch Auswaschen mit Blei Bekanntlich ist Kupfer im Eisen im allgemeinen ein unerwünschter Begleiter. Es verschlechtert schon bei geringen Gehalten dessen Warmverformbarkeit und Schweißbarkeit und beeinträchtigt seine Oberfläche. Da viele Erze, wie z. B. Spateisenstein, Kupfer, wenn auch nur in geringen Mengen, enthalten und insbesondere der Schrott in praktisch nicht kontrollierbarer Weise durch Kupfer verunreinigt ist, hat die Beseitigung der Kupferschwierigkeiten von jeher ein besonderes Problem dargestellt. Es ist zwar bekannt, daß sich Kupfer .aus Roheisen- und Stahlschmelzen durch flüssiges Blei sowie durch Silber oder Wismut auswaschen l'äßt und im Eisen enthaltener Kohlenstoff ein gutes Durchmischen der Reaktionsteilnehmer den Waschprozeß begünstigt. In die Praxis haben sich solche Waschverfahren jedoch nicht einführen können, offenbar weil die Art und Weise, wie man große Eisenmengen mit dem preiswertesten Waschmittel, nämlich dem Blei, auf wirtschaftliche Weise entkupfern kann, noch nicht gefunden war.Process for removing copper from carbon, silicon, phosphorus and manganese containing iron melts by washing out with lead. It is known that copper is in the Iron is generally an undesirable companion. It worsens even at low levels Maintained its hot formability and weldability and adversely affects its surface. Since many ores, such as B. Spateisenstein, copper, even if only in small quantities, contain and in particular the scrap in a practically uncontrollable manner is contaminated by copper, eliminating the copper has difficulties of always presented a special problem. It is known that copper is Pig iron and steel smelting using liquid lead as well as silver or bismuth wash out and the carbon contained in the iron ensures thorough mixing of the Reactants favored the washing process. In practice such However, washing methods can not introduce, apparently because of the way how you can use the cheapest detergent, namely lead, on large amounts of iron can decopper in an economical way has not yet been found.
Mit diesem Problem befaßt sich die Erfindung. Sie löst es durch ein Verfahren zum Entkupfern von Kohlenstoff, Silizium, Phosphor und Mangan enthaltenden Eisenschmelzen durch Auswaschen mit flüssigem Blei, gemäß dem das Waschblei mittels inerter oder reduzierend wirkender Gase durch Düsen oder feuerfeste Filtersteine in gleichmäßiger Verteilung auf die Oberfläche der zu reinigenden Eisenschmelze aufgebracht oder in die Schmelze eingesprüht, unter Verwendung eines Siphons od. dgl. am Boden des Waschgefäßes laufend .abgezogen und nach einer in bekannter Weise durchgeführten Regenerierung wieder in den Waschprozeß zurückgebracht wird.This is the problem addressed by the invention. She redeems it through Process for removing copper from carbon, silicon, phosphorus and manganese Iron melting by washing out with liquid lead, according to which the washing lead means inert or reducing gases through nozzles or refractory filter stones evenly distributed over the surface of the molten iron to be cleaned applied or sprayed into the melt, using a siphon or. Like. At the bottom of the washing vessel .abzuged and according to a known manner carried out regeneration is brought back into the washing process.
Das Regenerierendes kupferhaltigen Bleies erfolgt am einfachsten durch Einrühren von Schwefel in das Bleibad, wobei das Kupfer in Kupfersulfür übergeführt wird, das, da es an die Oberfläche des Bades steigt, von diesem abgehoben werden kann.The easiest way to regenerate copper-containing lead is through Stirring sulfur into the lead bath, the copper being converted into copper sulphur that, as it rises to the surface of the bath, will be lifted from it can.
Durch .die gleichmäßige Verteilung des Waschbleies über die zu reinigende Eisenschmelze bei der vorstehend angegebenen erfindungsgemäßen Art der Zuführung des Waschbleies zur Eisenschmelze sowie zusätzlich durch ein drehendes Bewegen des Waschbehälters, das bekanntlich eine gute Durchmischung der Reaktionsteilnehmer ergibt, gelingt es, den Waschprozeß mit dem spezifisch schweren Blei auch bei großen Chargen in wirtschaftlicher Weise durchzuführen.Due to the even distribution of the washing lead over the to be cleaned Iron melt with the type of feed according to the invention specified above of the wash lead to the iron melt and additionally by rotating the Washing container, which is known to ensure thorough mixing of the reactants results, it succeeds in the washing process with the specifically heavy lead even with large ones Carry out batches in an economical manner.
Zum Einsprühen des Waschbleies in die zu entkupfernde Eisenschmelze wird ein pfannenartiges, das einzusprühende Waschblei enthaltendes Gefäß verwendet, dessen Boden aus einem porösen Filterstein besteht und der Boden des Gefäßes dabei so ausgebildet ist, daß sich der Filterstein beim Einsprühen des Bleies unter der Oberfläche der zu entkupfernden Schmelze befindet.For spraying the wash lead into the molten iron to be removed from the copper a pan-like vessel containing the washing lead to be sprayed is used, the bottom of which consists of a porous filter stone and the bottom of the vessel is designed so that the filter stone when the lead is sprayed under the Surface of the melt to be copper-removed is located.
Pfannenartige Behälter mit einem porösen Bodenstein sind bekannt. Bei der vorbekannten Arbeitsweise werden Gase durch den porösen Bodenstein hindurch in die im Behälter befindliche Metallschmelze .geblasen.Pan-like containers with a porous floor stone are known. In the previously known mode of operation, gases are passed through the porous soil stone blown into the molten metal in the container.
Das Verfahren der Erfindung benötigt wegen der physikalischen und mechanischen Behandlung der Reaktionsteilnehmer einen nur verhältnismäßig geringen Aufwand an Blei. Das ist von entscheidender Bedeutung, weil nur ein so beschaffener Prozeß in wirtschaftlicher und wärmetechnischer Beziehung betrieblich brauchbar ist.The method of the invention needed because of the physical and mechanical treatment of the reactants is only relatively minor Expenditure of lead. This is vital because only one is made that way The process can be used in an economic and thermo-technical relationship is.
Claims (3)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DESCH18216A DE1146897B (en) | 1955-06-27 | 1955-06-27 | Process for removing copper from iron melts containing carbon, silicon, phosphorus and manganese by washing out with lead |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DESCH18216A DE1146897B (en) | 1955-06-27 | 1955-06-27 | Process for removing copper from iron melts containing carbon, silicon, phosphorus and manganese by washing out with lead |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1146897B true DE1146897B (en) | 1963-04-11 |
Family
ID=7428157
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DESCH18216A Pending DE1146897B (en) | 1955-06-27 | 1955-06-27 | Process for removing copper from iron melts containing carbon, silicon, phosphorus and manganese by washing out with lead |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE1146897B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10016075C1 (en) * | 1998-11-17 | 2002-01-17 | Nippon Steel Corp | Method of removing impurities in ion, involves separating iron and copper phase and copper in iron phase is removed by difference in specific gravity |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR882417A (en) * | 1941-05-29 | 1943-06-02 | Licentia Gmbh | Process for degassing mergers |
| GB684048A (en) * | 1949-06-22 | 1952-12-10 | Mini Of Mines And Technical Su | The gas flushing of liquid masses |
-
1955
- 1955-06-27 DE DESCH18216A patent/DE1146897B/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR882417A (en) * | 1941-05-29 | 1943-06-02 | Licentia Gmbh | Process for degassing mergers |
| GB684048A (en) * | 1949-06-22 | 1952-12-10 | Mini Of Mines And Technical Su | The gas flushing of liquid masses |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10016075C1 (en) * | 1998-11-17 | 2002-01-17 | Nippon Steel Corp | Method of removing impurities in ion, involves separating iron and copper phase and copper in iron phase is removed by difference in specific gravity |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE1146897B (en) | Process for removing copper from iron melts containing carbon, silicon, phosphorus and manganese by washing out with lead | |
| DE1558425C2 (en) | Process for the continuous extraction of copper from molten iron silicate slags | |
| DE2809702C2 (en) | Process for the extraction of metal, in particular copper, from a solution containing metal ions by cementation in a vibrating container | |
| DE4039310C2 (en) | Treatment vessel for treating metal melts | |
| DE1458819C3 (en) | Process and device for the continuous production of steel from Rohelsen | |
| DE648244C (en) | Process for removing impurities from copper other than oxygen | |
| DE1225678C2 (en) | Process for the production of nitrogenous steel refiners | |
| DE579469C (en) | Melting process for metal chips and metal residues in fine distribution | |
| DE1263795B (en) | Process for producing iron and steel directly from ores | |
| DE750334C (en) | Process for the processing of slag resulting from the desulphurisation of hot metal | |
| DE557189C (en) | Process for the production of welding iron or welding steel | |
| DE705365C (en) | Process for galvanizing pipes, sheets, etc. like | |
| DE517495C (en) | Process for the preparation of ammonia and ammonium bisulfate from ammonium sulfate by melting down | |
| DE506351C (en) | Process for the production of titanium-free iron or steel | |
| DE626018C (en) | Process and furnace for the separation of specifically light metals from heavier insoluble impurities | |
| DE865319C (en) | Process for the treatment of cast iron or foundry iron | |
| DE750243C (en) | Process for the dephosphorization of steel strips | |
| DE330987C (en) | Method and device for the treatment of tungsten minerals | |
| DE917186C (en) | Process for cleaning liquid pig iron with soda or masses containing soda | |
| DE1433569A1 (en) | Process for increasing the performance of Siemens-Martin-OEfen | |
| AT230408B (en) | Device for mixing a steadily flowing metal with aggregates | |
| DE871367C (en) | Process for the production of chromium-containing slag for the recovery of chromium | |
| DE687294C (en) | iron | |
| DE3618510A1 (en) | METHOD AND DEVICE FOR CONTINUOUS TREATMENT OF MELT-LIQUID METAL | |
| DE4325595C2 (en) | Process for the treatment of plastic residues containing metallic and organic contaminants |