DE10310906A1 - Synergistic active agent combination, useful as insecticide, acaricide and/or fungicide, comprises N,N'-disubstituted phthalamide derivative and other active agent(s), e.g. strobilurins or triazoles - Google Patents

Abstract

New synergistic active agent combination comprises: (1) (A) N 2>-(1,1-dimethyl-2-(methylsulfonyl)-ethyl)-3-iodo-N 1>-(2-methyl-4-(1,2,2,2-tetrafluoro-1-(trifluoromethyl)-ethyl)-phenyl)-phthalamide (I); (2) (B) other active agent(s) selected from e.g. strobilurins, triazoles, sulfenamides, valinamides, carboxamides, dithiocarbamates, acylalanines, anilino-pyrimidines, benzimidazoles and carbamates. New synergistic active agent combination comprise: (A) the phthalamide derivative (I); and (B) at least one active agent selected from: (1) strobilurins of formula (II); (2) triazoles of formula (III); (3) the sulfenamides dichlofluanid or tolylfluanid; (4) the valinamides iprovalincarb or N 1>-(2-(4-((3-(4-chlorophenyl)-2-propynyl)-oxy)-3-methoxyphenyl)-ethyl)-N 2>-(methylsulfonyl)-D-valinamide; (5) carboxamides of formula X-CONH-Y-Z (V); (6) the dithiocarbamates mancozeb, maneb, metiram, propineb, thiram, zineb and/or ziram; (7) acylalanines of formula (VI) (in which the asterisked C-atom has R- or preferably S-configuration); (8) 2-anilino-4-methyl-6-(methyl, cyclopropyl or 1-propynyl)-pyrimidines; (9) benzimidazoles of formula (VIII); (10) carbamates of formula R 1 9>-O-CO-NH-R 2> 0> (IX); (11) the dicarboximides captafol, captan, folpet, iprodione, procymidone or vinclozolin; (12) the guanidines dodine, guazatine, iminoctadine triacetate or iminoctadine tris-(albesil); (13) the imidazoles cyazofamid, prochloraz or triazoxide; (14) 2-(R 2> 1>)-6-(R 2> 2>)-4-(R 2> 3>)-morpholines; (15) pyrroles of formula (XI); (16) the phosphonates fosetyl-Al or phosphonic acid; (17) phenylethanamides of formula (XII); and/or (18) the fungicides acibenzolar-S-methyl, chlorothalonil, cymoxanil, edifenphos. famoxadone, fluazinam, copper oxychloride, copper hydroxide, oxadixyl or spiroxamine. [Image] A : -C(=A 2>-OMe)-CO-A 1>-Me, (5,6-dihydro-1,4,2-dioxazin-3-yl)-(methoxyimino)-methyl, 3-methoxy-1-methyl-5-oxo-4,5-dihydro-1,2,4-triazol-4-yl or -N(OMe)-COOMe; A 1>NH or O; A 2>N or CH; L : -O-(5-(R 1>)-pyrimidin-4,6-diyl)-, -CH 2ON=C(Me)-, -CH=N-O-CH(Me)-, -CH 2O- or -O- (all bonded to the phenyl ring at the left-hand terminal); R 1>H or F; R : phenyl, phenoxy or pyridinyl (all optionally substituted (os) by 1 or 2 of Cl, CN, Me or CF 3); or 1-(4-chlorophenyl)-pyrazol-3-yl or 1,2-propanedione-bis-(O-methyl oxime)-1-yl; Q : H or SH; m : 0 or 1; R 2>H, F, Cl, Ph or 4-chlorophenoxy; R 3>H or Cl; A 3>direct bond, CH 2, CH 2CH 2 or O; or CH 2CHR 6> or CH=CR 6> (both bonded to the phenyl ring at the left-hand terminal), in which case R 5> + R 6> together form CH 2CH 2CH(CHMe 2) or CH 2CH 2C(Me) 2; A 4>C or Si; R 4>H, OH or CN; R 5>1-cyclopropylethyl, 1-chlorocyclopropyl, 1-4C alkyl, 1-6C hydroxyalkyl, (1-4C) alkylcarbonyl, (1-2C) haloalkoxy-(1-2C) alkyl, trimethylsilyl-(1-2C) alkyl, monofluorophenyl or Ph; or R 4> + R 5>OCH 2CHR 7>O, OCH 2CHR 7>CH 2 or OCHR 8>; R 7>H, 1-4C alkyl or Br; R 8>2-chlorophenyl; X : 2-chloro-3-pyridinyl; 1-methyl-pyrazol-4-yl, substituted by Me or CF 3 in the 3-position and os by H or Cl in the 5-position; 4-ethyl-2-ethylamino-1,3-thiazol-5-yl; 1-methyl-cyclohexyl; 2,2-dichloro-1-ethyl-3-methyl-cyclopropyl; 2-fluoro-2-propyl; or phenyl substituted by 1-3 of Cl and/or Me; Y : direct bond, 1-6C alkanediyl (os by Cl, CN or =O) or thiophenediyl; Z : H, 2-(R 1> 0>)-3-(R 1> 1>)-4-(R 1> 2>)-phenyl or 3-(R 1> 0>)-4-(R 1> 1>)-5-(R 1> 2>)-pyridin-2-yl; R 1> 0>H, Cl or phenyl (os by 1 or 2 of Cl and/or di-(1-3C) alkylaminocarbonyl; R 1> 1>H or Cl; R 1> 2>H, Cl, OH, Me or CF 3; or R 1> 0> + R 1> 1>CHMeCH 2CMe 2 or CHMeOCMe 2 (both bonded in the R 1> 0> position at the left-hand terminal); R 1> 3>Ph, furyl or OMe; R 1> 5>, R 1> 6>H; or together form OCF 2O; R 1> 7>H, (1-4C) alkylaminocarbonyl or 3,5-dimethyl-isoxazol-4-ylsulfonyl; R 1> 8>Cl, NHCOOMe, chlorophenyl, furyl or thiazolyl; R 1> 9>n-propyl or isopropyl; R 2> 0>di-(1-2C) alkylamino-(2-4C) alkyl or diethoxyphenyl; R 2> 1>, R 2> 2>H or Me; R 2> 3>1-14C (preferably 12-14C) alkyl, 5-12C (preferably 10-12C) cycloalkyl or phenyl-(1-4C) alkyl (os in the ring by halo or 1-4C alkyl); or acryloyl substituted by chlorophenyl and dimethoxyphenyl; R 2> 4>Cl or CN; R 2> 5>Cl or NO 2; R 2> 6>Cl; or R 2> 5> + R 2> 6>OCF 2O; R 2> 7>phenyl (os by F, Cl, Br, Me or Et), 2-naphthyl, 1,2,3,4-tetrahydronaphthyl or indanyl. ACTIVITY : Insecticide; Acaricide; Fungicide; Bactericide; Nematocide; Antifouling. In tests for protection of vines against Plasmopara viticola, the degree of effectiveness was 8% for (I) at 5 g/ha, 0% for propineb (B') at 100 g/ha and 75% for a combination of (I) at 5 g/ha and (B') at 100 g/ha. MECHANISM OF ACTION : None given.

Description

The present invention relates to new combinations of active ingredients made from a known phthalamide on the one hand and known fungicidal active ingredients on the other hand exist and very good for fighting of unwanted animal pests such as insects or acarids and unwanted phytopathogenic fungi are suitable.

It is already known that N ² - [1,1-dimethyl-2- (methylsulfonyl) ethyl] -3-iodo-N ¹ - {2-methyl-4- [1,2,2,2-tetrafluoro-1 - (Trifluoromethyl) ethyl] phenyl} phthalamide (CAS Reg.No .: 272451-65-7) has insecticidal properties (cf. EP-A 1 006107 ). The effectiveness of this substance is good, but leaves something to be desired at low application rates in some cases.

Furthermore, it is already known that numerous triazole derivatives, aniline derivatives, dicarboximides and other heterocycles can be used to combat fungi (cf. EP-A 0 040 345 . DE-A 22 01 063 . DE-A 23 24 010 , Pesticide Manual, 9th. Edition (1991), pages 249 and 827, EP-A 0 382 375 and EP-A 0 515 901 ). However, the effect of these substances is not always sufficient at low application rates.

Furthermore, it is already known that 1- (3,5-dimethyl-isoxazole-4-sulfonyl) -2-chloro-6,6-difluoro- [1,3] -dioxolo- [4,5f] benzimidazole has fungicidal properties (cf. WO 97/06171).

Finally, it is also known that substituted halopyrimidines have fungicidal properties (cf. DE-A1-196 46 407 . EP-B-712 396 ).

und mindestens einen Wirkstoff, der aus den folgenden Gruppen (1) bis (18) ausgewählt ist: Gruppe (1) Strobilurine der allgemeinen Formel (II)

in welcher
A für eine der Gruppen

steht,
A¹ für NH oder O steht,
A² für N oder CH steht,
L für eine der Gruppen

steht, wobei die Bindung, die mit einem Stern (*) markiert ist an den Phenylring gebunden ist,
R¹ für Wasserstoff oder Fluor steht,
R für jeweils gegebenenfalls einfach oder zweifach, gleich oder verschieden durch Chlor, Cyano, Methyl oder Trifluormethyl substituiertes Phenyl, Phenoxy oder Pyridinyl, oder für 1-(4-Chlorphenyl)-pyrazol-3-yl oder für 1,2-Propandion-bis(O-methyloxim)-1-yl steht; Gruppe (2) Triazole der allgemeinen Formel (III)

in welcher
entweder
Q für Wasserstoff oder SH steht,
m für 0 oder 1 steht,
R² für Wasserstoff, Fluor, Chlor, Phenyl oder 4-Chlor-phenoxy steht,
R³ für Wasserstoff oder Chlor steht,
A³ für eine direkte Bindung, -CH₂-, -(CH₂)₂- oder -O- steht,
A³ außerdem für *-CH₂-CHR⁶- oder *-CH=CR⁶- steht, wobei die mit * markierte Bindung mit dem Phenylring verknüpft ist, und R⁵ und R⁶ dann zusammen für -CH₂-CH₂-CH[CH(CH₃)₂]- oder -CH₂-CH₂-C(CH₃)₂- stehen,
A⁴ für C oder Si (Silizium) steht,
R⁴ für Wasserstoff, Hydroxy oder Cyano steht,
R⁵ für 1-Cyclopropylethyl, 1-Chlorcyclopropyl, C₁-C₄-Alkyl, C₁-C₆-Hydroxyalkyl, C₁-C₄-Alkylcarbonyl, C₁-C₂-Halogenalkoxy-C₁-C₂-alkyl, Trimethylsilyl-C₁-C₂-a1kyl, Monofluorphenyl, oder Phenyl steht,
R⁴ und R⁵ außerdem zusammen für -O-CH₂-CH(R⁷)-O-, -O-CH₂-CH(R⁷)-CH₂-, oder -O-CH(R⁸)- stehen,
R⁷ für Wasserstoff, C₁-C₄-Alkyl oder Brom steht,
R⁸ für 2-Chlorphenyl steht; Gruppe (3) Sulfenamide der allgemeinen Formel (IV)

in welcher
R⁹ für Wasserstoff oder Methyl steht;We have now found new active compound combinations with very good insecticidal, acaricidal and fungicidal properties, comprising the phthalamide of the formula (I)

and at least one active ingredient which is selected from the following groups (1) to (18): group (1) strobilurins of the general formula (II)

in which
A for one of the groups

stands,
A ^{1 represents} NH or O,
A ^{2 represents} N or CH,
L for one of the groups

where the bond marked with an asterisk (*) is attached to the phenyl ring,
R ^{1 represents} hydrogen or fluorine,
R for phenyl, phenoxy or pyridinyl substituted by chlorine, cyano, methyl or trifluoromethyl, each mono- or disubstituted, identically or differently, or for 1- (4-chlorophenyl) pyrazol-3-yl or for 1,2-propanedione-bis (O-methyloxime) -1-yl; Group (2) triazoles of the general formula (III)

in which
either
Q represents hydrogen or SH,
m represents 0 or 1,
R ^{2 represents} hydrogen, fluorine, chlorine, phenyl or 4-chlorophenoxy,
R ^{3 represents} hydrogen or chlorine,
A ^{3 represents} a direct bond, -CH ₂ -, - (CH ₂ ) ₂ - or -O-,
A ³ also stands for * -CH ₂ -CHR ⁶ - or * -CH = CR ⁶ -, the bond marked with * being linked to the phenyl ring, and R ⁵ and R ⁶ then together for -CH ₂ -CH ₂ - CH [CH (CH ₃ ) ₂ ] - or -CH ₂ -CH ₂ -C (CH ₃ ) ₂ -,
A ^{4 stands} for C or Si (silicon),
R ^{4 represents} hydrogen, hydroxy or cyano,
R ⁵ for 1-cyclopropylethyl, 1-chlorocyclopropyl, C ₁ -C ₄ alkyl, C ₁ -C ₆ hydroxyalkyl, C ₁ -C ₄ alkylcarbonyl, C ₁ -C ₂ haloalkoxy-C ₁ -C ₂ alkyl , Trimethylsilyl-C ₁ -C ₂ -alkyl, monofluorophenyl or phenyl,
R ⁴ and R ⁵ together also represent -O-CH ₂ -CH (R ⁷ ) -O-, -O-CH ₂ -CH (R ⁷ ) -CH ₂ -, or -O-CH (R ⁸ ) - .
R ^{7 represents} hydrogen, C ₁ -C ₄ alkyl or bromine,
R ^{8 represents} 2-chlorophenyl; Group (3) sulfenamides of the general formula (IV)

in which
R ^{9 represents} hydrogen or methyl;

Group (4) valinamides selected out

• (4-1) Iprovalicarb
• (4-2) N ¹ - [2- (4 - {[3- (4-chlorophenyl) -2-propynyl] oxy} -3-methoxyphenyl) ethyl] -N ² - (methylsulfonyl) -D-valinamide; Group (5) carboxamides of the general formula (V)
  
  in which
• X for 2-chloro-3-pyridinyl, for 1-Methylpyrazol-4-yl, which is in the 3-position by methyl or trifluoromethyl and is substituted in the 5-position by hydrogen or chlorine, for 4-ethyl-2-ethylamino-1,3-thiazol-5-yl, for 1-methylcyclohexyl, for 2,2-dichloro-1-ethyl-3-methyl-cyclopropyl, for 2-fluoro-2-propyl, or for phenyl which is single to triple, the same or different Chlorine or methyl is substituted,
• Y represents a direct bond, optionally substituted by chlorine, cyano or oxo-substituted C ₁ -C ₆ alkanediyl or thiophene diyl,
• Z for hydrogen or the group
  
  stands,
• A ^{5 represents} CH or N,
• R ^{10 represents} hydrogen, chlorine, by phenyl which is optionally mono- or disubstituted, identically or differently, by chlorine or di (C ₁ -C ₃ -alkyl) aminocarbonyl,
• R ^{11 represents} hydrogen or chlorine,
• R ^{12 represents} hydrogen, chlorine, hydroxy, methyl or trifluoromethyl,
• R ¹⁰ and R ¹¹ also together represent * -CH (CH ₃ ) -CH ₂ -C (CH ₃ ) ₂ - or * -CH (CH ₃ ) -OC (CH ₃ ) ₂ -, the bond marked with * is linked to R ¹⁰ ;

Group (6) dithiocarbamates selected out

• (6-1) Mancozeb
• (6-2) Maneb
• (6-3) Metiram
• (6-4) Propineb
• (6-5) Thiram
• (6-6) Zineb
• (6-7) Ziram group (7) acylalanines of the general formula (VI)
  
  in which
• * a carbon atom in the R or S configuration, preferred in the S configuration, features,
• R ^{13 represents} phenyl, furyl or methoxy; Group (8): anilino-pyrimidines of the general formula (VII)
  
• in which
• R ^{14 represents} methyl, cyclopropyl or 1-propynyl; Group (9): Benzimidazoles of the general formula (VIII)
  
  in which
• R ¹⁵ and R ¹⁶ each represent hydrogen or together represent -O-CF ₂ -O-,
• R ^{17 represents} hydrogen, C ₁ -C ₄ -alkylaminocarbonyl or 3,5-dimethylisoxazol-4-ylsulfonyl,
• R ^{18 represents} chlorine, methoxycarbonylamino, chlorophenyl, furyl or thiazolyl; Group (10): carbamates of the general formula (IX)
  
  in which
• R ^{19 represents} n- or isopropyl,
• R ^{20 represents} di (C ₁ -C ₂ alkyl) amino-C ₂ -C ₄ alkyl or diethoxyphenyl;

Group (11): dicarboximides selected out

• (11-1) Captafol
• (11-2) Captan
• (11-3) Folpet
• (11-4) Iprodione
• (11-5) procymidones
• (11-6) vinclozolin

Group (12): guanidines selected out

• (12-1) Dodine
• (12-2) Guazatine
• (12-3) Iminoctadine triacetate
• (12-4) Iminoctadine tris (albesilate)

Group (13): Imidazole selected out

• (13-1) Cyazofamide
• (13-2) Prochloraz
• (13-3) triazoxides

Group (14): morpholines of the general formula (X)

• in which
• R ²¹ and R ²² independently of one another represent hydrogen or methyl,
• R ²³ for C ₁ -C ₁₄ alkyl (preferably C ₁₂ -C ₁₄ alkyl), C ₅ -C ₁₂ cycloalkyl (preferably C ₁₀ -C ₁₂ cycloalkyl), phenyl-C ₁ -C ₄ alkyl, which may be substituted in the phenyl part by halogen or C ₁ -C ₄ -alkyl, or stands for acrylyl which is substituted by chlorophenyl and dimethoxyphenyl; Group (15): pyrroles of the general formula (XI)
  
  in which
• R ^{24 represents} chlorine or cyano,
• R ^{25 represents} chlorine or nitro,
• R ^{26 represents} chlorine
• R ²⁵ and R ²⁶ also together represent -O-CF ₂ -O-;

Group (16): phosphonates selected out

• (16-1) Fosetyl-A1
• (16-2) phosphonic acid; Group (17): phenylethanamides of the general formula (XII)
  
  in which
• R ^{27 represents} phenyl which is unsubstituted or substituted by fluorine, chlorine, bromine, methyl or ethyl, 2-naphthyl, 1,2,3,4-tetrahydronaphthyl or indanyl;

Group (18): fungicides selected out

• (18-1) Acibenzolar-S-methyl
• (18-2) chlorothalonil
• (18-3) cymoxanil
• (18-4) Edifenphos
• (18-5) Famoxadone
• (18-6) fluazinam
• (18-7) copper oxychloride
• (18-8) copper hydroxide
• (18-9) oxadixyl
• (18-10) Spiroxamines

Surprisingly is the fungicidal activity of the active compound combinations according to the invention significantly higher than the sum of the effects of the individual active ingredients. So it is an unforeseeable, real synergistic effect before and not just a supplement.

Surprisingly is the insecticidal and acaricidal activity of the active compound combinations according to the invention also much higher than the sum of the effects of the individual active ingredients. So it is an unforeseeable, real synergistic effect before and not just a supplement.

Formula (II) includes the following preferred mixing partners of group (1):

• (1-1) Azoxystrobin (known from EP-A 0 382 375 ) of the formula
  
• (1-2) Fluoxastrobin (known from DE-A 196 02 095 ) of the formula
  
• (1-3) the connection (known from DE-A 196 46 407 . EP-B 0 712 396 ) of the formula
  
• (1-4) trifloxystrobin (known from EP-A 0 460 575 ) of the formula
  
• (1-5) the connection (known from EP-A 0 569 384 ) of the formula
  
• (1-6) the connection (known from EP-A 0 596 254 ) of the formula
  
• (1-7) Orysastrobin (known from DE-A 195 39 324 ) of the formula
  
• (1-8) the compound (known from WO 98/23155) of the formula
  
• (1-9) Kresoxim-methyl (known from EP-A 0 253 213 ) of the formula
  
• (1-10) dimoxystrobin (known from EP-A 0 398 692 ) of the formula
  
• (1-11) Picoxystrobin (known from EP-A 0 278 595 ) of the formula
  
• (1-12) pyraclostrobin (known from DE-A 44 23 612 ) of the formula
  
• (1-13) metominostrobin (known from EP-A 0 398 692 ) of the formula
  

Formula (III) includes the following preferred mixing partners of group (2):

• (2-1) Azaconazole (known from DE-A 25 51 560 ) of the formula
  
• (2-2) etacazazole (known from DE-A 25 51 560 ) of the formula
  
• (2-3) Propiconazole (known from DE-A 25 51 560 ) of the formula
  
• (2-4) difenoconazole (known from EP-A 0 112 284 ) of the formula
  
• (2-5) Bromuconazole (known from EP-A 0 258 161 ) of the formula
  
• (2-6) Cyproconazole (known from DE-A 34 06 993 ) of the formula
  
• (2-7) Hexaconazole (known from DE-A 30 42 303 ) of the formula
  
• (2-8) Penconazole (known from DE-A 27 35 872 ) of the formula
  
• (2-9) Myclobutanil (known from EP-A 0 145 294 ) of the formula
  
• (2-10) tetraconazole (known from EP-A 0 234 242 ) of the formula
  
• (2-11) Flutriafol (known from EP-A 0 015 756 ) of the formula
  
• (2-12) Epoxiconazole (known from EP-A 0 196 038 ) of the formula
  
• (2-13) Flusilazole (known from EP-A 0 068 813 ) of the formula
  
• (2-14) Simeconazole (known from EP-A 0 537 957 ) of the formula
  
• (2-15) prothioconazole (known from DE-A 195 28 046 ) of the formula
  
• (2-16) Fenbuconazole (known from DE-A 37 21 786 ) of the formula
  
• (2-17) Tebuconazole (known from EP-A 0 040 345 ) of the formula
  
• (2-18) Ipconazole (known from EP-A 0 329 397 ) of the formula
  
• (2-19) metconazole (known from EP-A 0 329 397 ) of the formula
  
• (2-20) Triticonazole (known from EP-A 0 378 953 ) of the formula
  
• (2-21) Bitertanol (known from DE-A 23 24 010 ) of the formula
  
• (2-22) triadimenol (known from DE-A 23 24 010 ) of the formula
  
• (2-23) Triadi phone (known from DE-A 22 01 063 ) of the formula
  

Formula (IV) includes the following preferred mixing partners of group (3):

• (3-1) dichlofluanide (known from DE-A 11 93 498 ) of the formula
  
• (3-2) Tolylfluanid (known from DE-A 11 93 498 ) of the formula
  

Preferred mix partner of Group (4) is

• (4-2) Iprovalicarb (known from DE-A 40 26 966 ) of the formula
  

Formula (V) includes the following preferred ones Mixing partner of group (5):

• (5-1) the connection (known from EP-A 0 256 503 ) of the formula
  
• (5-2) Boscalid (known from DE-A 195 31 813 ) of the formula
  
• (5-3) Furametpyr (known from EP-A 0 315 502 ) of the formula
  
• (5-4) the connection (known from EP-A 0 737 682 ) of the formula
  
• (5-5) Ethaboxam (known from EP-A 0 639 574 ) of the formula
  
• (5-6) fenhexamide (known from EP-A 0 339 418 ) of the formula
  
• (5-7) Carpropamide (known from EP-A 0 341 475 ) of the formula
  
• (5-8) the connection (known from EP-A 0 600 629 ) of the formula
  
• (5-9) Picobenzamide (known from WO 99/42447) of the formula
  
• (5-10) Zoxamide (known from EP-A 0 604 019 ) of the formula
  

Preferred mixing partners in the group (6) are

• (6-1) Mancozeb (known from DE-A 12 34 704 ) with the IUPAC name Manganese ethylenebis (dithiocarbamate) (polymenc) complex with zinc salt
• (6-2) Maneb (known from US 2,504,404 ) of the formula
  
• (6-3) Metiram (known from DE-A 10 76 434 ) with the IUPAC name Zinc ammoniate ethylenebis (dithiocarbamate) - poly (ethylenethiuram disulfide)
• (6-4) Propineb (known from GB 935 981 ) of the formula
  
• (6-5) Thiram (known from US 1,972,961 ) of the formula
  
• (6-6) Zineb (known from DE-A 10 81 446 ) of the formula
  
• (6-7) Ziram (known from US 2,588,428 ) of the formula
  

Formula (VI) includes the following preferred mixing partners of group (7):

• (7-1) Benalaxyl (known from DE-A 29 03 612 ) of the formula
  
• (7-2) Furalaxyl (known from DE-A 25 13 732 ) of the formula
  
• (7-3) Metalaxyl (known from DE-A 25 15 091 ) of the formula
  
• (7-4) Metalaxyl-M (known from WO 96/01559) of the formula
  

Formula (VII) includes the following preferred mixing partners of group (8):

• (8-1) Cyprodinil (known from EP-A 0 310 550 ) of the formula
  
• (8-2) Mepanipyrim (known from EP-A 0 270 111 ) of the formula
  
• (8-3) Pyrimethanil (known from DD 151 404 ) of the formula
  

Formula (VIII) includes the following preferred mixing partners of group (9):

• (9-1) the compound (known from WO 97/06171) of the formula
  
• (9-2) Benomyl (known from US 3,631,176 ) of the formula
  
• (9-3) Carbendazim (known from US 3,010,968 ) of the formula
  
• (9-4) Chlorfenazoles of the formula
  
• (9-5) Fuberidazole (known from DE-A 12 09 799 ) of the formula
  
• (9-6) Thiabendazole (known from US 3,206,468 ) of the formula
  

Formula (IX) includes the following preferred mixing partners of group (10):

• (10-1) Diethofencarb (known from EP-A 0 078 663 ) of the formula
  
• (10-2) Propamocarb (known from US 3,513,241 ) of the formula
  
• (10-3) Propamocarb hydrochloride (known from US 3,513,241 ) of the formula
  

Preferred mixing partners in the group (11) are

• (11-1) Captafol (known from US 3,178,447 ) of the formula
  
• (11-2) Captan (known from US 2,553,770 ) of the formula
  
• (11-3) Folpet (known from US 2,553,770 ) of the formula
  
• (11-4) Iprodione (known from DE-A 21 49 923 ) of the formula
  
• (11-5) procymidones (known from DE-A 20 12 656 ) of the formula
  
• (11-6) vinclozolin (known from DE-A 22 07 576 ) of the formula
  

Preferred mixing partners in the group (12) are

• (12-1) Dodine (known from GB 11 03 989 ) of the formula
  
• (12-2) Guazatine (known from GB 11 14 155 )
• (12-3) Iminoctadine triacetate (known from EP-A 0 155 509 ) of the formula
  

Preferred mix partner of Group (13) is

• (13-1) Cyazofamide (known from EP-A 0 298 196 ) of the formula
  

Formula (X) includes the following preferred ones Mixing partner of the group (14):

• (14-1) Aldimorph (known from DD 140 041 ) of the formula
  
• (14-2) Tridemorph (known from GB 988 630 ) of the formula
  
• (14-3) Dodemorph (known from DE-A 25 432 79 ) of the formula
  
• (14-4) Fenpropimorph (known from DE-A 26 56 747 ) of the formula
  
• (14-5) Dimethomorph (known from EP-A 0 219 756 ) of the formula
  

Formula (XI) includes the following preferred mixing partners of group (15):

• (15-1) Fenpiclonil (known from EP-A 0 236 272 ) of the formula
  
• (15-2) Fludioxonil (known from EP-A 0 206 999 ) of the formula
  
• (15-3) pyrrole nitrine (known from JP 65-25876 ) of the formula
  

Preferred mixing partners in the group (16) are

• (16-1) Fosetyl-Al (known from DE-A 24 56 627 ) of the formula
  
• (16-2) Phosphonic acid (known chemical) of the formula
  

Formula (XII) includes the following preferred mixing partners of group (17), which from WO 96/23793 are known and can each be present as E or Z isomers. links of the formula (XII) therefore as a mixture of different isomers or in the form of a only isomers are present. Compounds of the formula are preferred (XII) in the form of their E isomer:

• (17-1) the compound of formula
  
• (17-2) the compound of formula
  
• (17-3) the compound of formula
  
• (17-4) the compound of the formula
  
• (17-5) the compound of formula
  
• (17-6) the compound of formula
  

Preferred mixing partners in the group (18) are

• (18-1) Acibenzolar-S-methyl (known from EP-A 0 313 512 ) of the formula
  
• (18-2) Chlorothalonil (known from US 3,290,353 ) of the formula
  
• (18-3) Cymoxanil (known from DE-A 23 12 956 ) of the formula
  
• (18-4) Edifenphos (known from DE-A 14 93 736 ) of the formula
  
• (18-5) Famoxadone (known from EP-A 0 393 911 ) of the formula
  
• (18-6) fluazinam (known from EP-A 0 031 257 ) of the formula
  
• (18-9) oxadixyl (known from DE-A 30 30 026 ) of the formula
  
• (18-10) Spiroxamine (known from DE-A 37 35 555 ) of the formula
  

The compound (2-15) prothioconazole can be in the "mercapto" form and in the tautomeric "thiono" form. For the sake of simplicity, only the "Mercapto" shape is shown.

(1R,3S)-2,2-Dichlor-N-[(1R)-1-(4-chlorphenyl)ethyl]-1-ethyl-3-methylcyclopropancarboxamid der Formel

The compound (5-7) carpropamide has three asymmetric substituted carbon atoms. (5-7) can therefore be present as a mixture of different isomers or in the form of a single component. The compounds (1S, 3R) -2,2-dichloro-N - [(1R) -1- (4-chlorophenyl) ethyl] -1-ethyl-3-methylcyclopropanecarboxamide of the formula are particularly preferred

(1R, 3S) -2,2-dichloro-N - [(1R) -1- (4-chlorophenyl) ethyl] -1-ethyl-3-methylcyclopropanecarboxamide of the formula

The following are the mixing partners Active ingredients particularly preferred:

• (1-1) Azoxystrobin
• (1-2) fluoxastrobin
• (1-3) the compound (2E) -2- (2 - {[6- (3-chloro-2-methylphenoxy) -5-fluoro-4-pyrimidinyl] oxy} phenyl) -2- (methoxyimino) -N -methylethanamid
• (1-4) trifloxystrobin
• (1-5) the compound (2E) -2- (methoxyimino) -N-methyl-2- (2 - {[({(1E) -1- [3- (trifluoromethyl) phenyl] ethylidene} amino) oxy] methyl} phenyl) ethanamide
• (1-6) the compound (2E) -2- (methoxyimino) -N-methyl-2- {2 - [(E) - ({1- [3- (trifluoromethyl) phenyl] ethoxy} imino) methyl) phenyl } ethanamide
• (1-8) the compound 5-methoxy-2-methyl-4- (2 - {[({(1E) -1- [3- (trifluoromethyl) phenyl] ethylidene} amino) oxy] methyl} phenyl) -2 , 4-dihydro-3H-1,2,4-triazol-3-one
• (1-11) Picoxystrobin
• (2-3) Propiconazole
• (2-4) difenoconazole
• (2-6) Cyproconazole
• (2-7) hexaconazoles
• (2-8) Penconazole
• (2-9) myclobutanil
• (2-10) tetraconazoles
• (2-13) Flusilazole
• (2-15) prothioconazole
• (2-16) fenbuconazole
• (2-17) Tebuconazole
• (2-21) Bitertanol
• (2-22) triadimenol
• (2-23) Triadi phone
• (3-1) dichlofluanide
• (3-2) Tolylfluanid
• (4-2) Iprovalicarb
• (5-2) Boscalid
• (5-5) ethaboxam
• (5-6) fenhexamide
• (5-7) carpropamide
• (5-8) the compound 2-chloro-4 - [(2-fluoro-2-methylpropanoyl) amino] -N, N-dimethylbenzamide
• (5-9) Picobenzamide
• (5-10) Zoxamides
• (6-1) Mancozeb
• (6-2) Maneb
• (6-4) Propineb
• (6-5) Thiram
• (6-6) Zineb
• (7-1) Benalaxyl
• (7-2) Furalaxyl
• (7-3) metalaxyl
• (8-1) Cyprodinil
• (8-2) Mepanipyrim
• (8-3) pyrimethanil
• (9-1) the compound 6-chloro-5 - [(3,5-dimethyl-4-isoxazolyl) methyl] -2,2-difluoro-5H- [1,3] dioxolo [4,5-f] benzimidazole
• (10-1) Diethofencarb
• (10-2) Propamocarb
• (11-2) Captan
• (11-3) Folpet
• (11-4) Iprodione
• (11-5) procymidones
• (12-1) Dodine
• (12-2) Guazatine
• (12-3) Iminoctadine triacetate
• (13-1) Cyazofamide
• (14-5) Dimethomorph
• (15-2) Fludioxonil
• (16-1) Fosetyl-Al
• (16-2) Phosphonic acid
• (18-1) Acibenzolar-S-methyl
• (18-2) chlorothalonil
• (18-3) cymoxanil
• (18-5) Famoxadone
• (18-6) fluazinam
• (18-9) oxadixyl
• (18-10) Spiroxamines

The following are the mixing partners Active ingredients very particularly preferred:

• (1-2) fluoxastrobin
• (1-4) trifloxystrobin
• (2-17) Tebuconazole
• (2-21) Bitertanol
• (3-1) dichlofluanide
• (3-2) Tolylfluanid
• (4-2) Iprovalicarb
• (5-6) fenhexamide
• (5-9) Picobenzamide
• (6-4) Propineb

The active ingredient combinations according to the invention contain at least one in addition to an active ingredient of the formula (I) Active ingredient from the compounds of groups (1) to (18). You can go beyond that also contain other fungicidally active admixture components.

If the active ingredients in the active ingredient combinations according to the invention in certain weight ratios the synergistic effect is particularly evident. However, can the weight ratios of the active substances in the active substance combinations in a relatively large range can be varied. In general, the combinations according to the invention contain Active ingredients of formula (I) and a mixing partner from one of the groups 1 to 18 in the mixing ratios given as examples in the table below.

The mixing ratios are based on weight ratios. The ratio is to be understood as an active ingredient of formula (I): mixing partner

The mixing ratio is like this in any case to choose, that a synergistic mixture is obtained. The mixing ratios between the compound of formula (I) and a compound one of the groups (1) to (18) can also be used between the individual Connections in a group vary.

The active ingredient combinations according to the invention have very good fungicidal properties and can be used to control phytopathogenic fungi, such as Plasmodiophoromycetes, Oomycetes, Chytridiomycetes, Use Zygomycetes, Ascomycetes, Basidiomycetes, Deuteromycetes etc.

The active ingredient combinations according to the invention are particularly suitable for controlling Phytophthora infestans, Plasmopara viticola and Botrytis cinerea.

Some pathogens of fungal and bacterial diseases that fall under the generic names listed above may be mentioned as examples, but not by way of limitation:
Xanthomonas species, such as, for example, Xanthomonas campestris pv. Oryzae; Pseudomonas species, such as, for example, Pseudomonas syringae pv. Lachrymans; Erwinia species, such as, for example, Erwinia amylovora; Pythium species, such as, for example, Pythium ultimum; Phytophthora species, such as, for example, Phytophthora infestans; Pseudoperonospora species, such as, for example, Pseudoperonospora humuli or Pseudoperonospora cubensis; Plasmopara species, such as, for example, Plasmopara viticola; Bremia species, such as, for example, Bremia lactucae; Peronospora species, such as, for example, Peronospora pisi or P. brassicae; Erysiphe species, such as, for example, Erysiphe graminis; Sphaerotheca species, such as, for example, Sphaerotheca fuliginea; Podosphaera species, such as, for example, Podosphaera leucotricha; Venturia species, such as, for example, Venturia inaequalis; Pyrenophora species, such as, for example, Pyrenophora teres or P. graminea (conidial form: Drechslera, Syn: Helminthosporium); Cochliobolus species, such as, for example, Cochliobolus sativus (conidial form: Drechslera, Syn: Helminthosporium); Uromyces species, such as, for example, Uromyces appendiculatus; Puccinia species, such as, for example, Puccinia recondita; Sclerotinia species, such as, for example, Sclerotinia sclerotiorum; Tilletia species, such as, for example, Tilletia caries; Ustilago species, such as, for example, Ustilago nuda or Ustilago avenae; Pellicularia species, such as, for example, Pellicularia sasakii; Pyricularia species, such as, for example, Pyricularia oryzae; Fusarium species, such as, for example, Fusarium culmorum; Botrytis species, such as, for example, Botrytis cinerea; Sepia species, such as, for example, Septoria nodorum; Leptosphaeria species, such as, for example, Leptosphaeria nodorum; Cercospora species, such as, for example, Cercospora canescens; Alternaria species, such as, for example, Alternaria brassicae; Pseudocercosporella species, such as, for example, Pseudocercosporella herpotrichoides.

The active compound combinations according to the invention are furthermore suitable for controlling animal pests, preferably arthropods and nematodes, in particular insects and arachnids, which occur in agriculture, animal health in forests, in the protection of stored products and materials and in the hygiene sector. They are effective against normally sensitive and resistant species as well as against all or individual stages of development. The pests mentioned above include:
From the order of the Isopoda, for example Oniscus asellus, Armadillidium vulgare, Porcellio scaber.
From the order of the Diplopoda, for example, Blaniulus guttulatus.
From the order of the Chilopoda, for example, Geophilus carpophagus and Scutigera spp.
From the order of the Symphyla, for example, Scutigerella immaculata.
From the order of the Thysanura, for example Lepisma saccharina.
From the order of the Collembola, for example Onychiurus armatus.
From the order of the Orthoptera, for example Acheta domesticus, Gryllotalpa spp., Locusta migratoria migratorioides, Melanoplus spp., Schistocerca gregaria.
From the order of the Blattaria, for example Blatta orientalis, Periplaneta americana, Leucophaea maderae, Blattella germanica.
From the order of the Dermaptera, for example, Forficula auricularia.
From the order of the Isoptera, for example Reticulitermes spp.
From the order of the Phthiraptera, for example Pediculus humanus corporis, Haematopinus spp., Linognathus spp., Trichodectes spp., Damalinia spp.
From the order of the Thysanoptera, for example Hercinothrips femoralis, Thrips tabaci, Thrips palmi, Frankliniella accidentalis.
From the order of the Heteroptera, for example Eurygaster spp., Dysdercus intermedius, Piesma quadrata, Cimex lectularius, Rhodnius prolixus, Triatoma spp.
From the order of the Homoptera, for example Aleurodes brassicae, Bemisia tabaci, Trialeurodes vaporariorum, Aphis gossypii, Brevicoryne brassicae, Cryptomyzus ribis, Aphis fabae, Aphis pomi, Eriosoma lanigerum, Hyalopterus arundinis, Phylloxera vastatrix, Pemphigususpp. Phorodon humuli, Rhopalosiphum padi, Empoasca spp., Euscelis bilobatus, Nephotettix cincticeps, Lecanium corni, Saissetia oleae, Laodelphax striatellus, Nilaparvata lugens, Aonidiella aurantii, Aspidiotus hederae, Pseudocylcus s.
From the order of the Lepidoptera, for example, Pectinophora gossypiella, Bupalus piniarius, Cheimatobia brumata, Lithocolletis blancardella, Hyponomeuta padella, Plutella xylostella, Malacosoma neustria, Euproctis chrysorrhoea, Lymantria spp., Agristella sppber, Bucculisella syll ., Earias insulana, Heliothis spp., Mamestra brassicae, Panolis flammea, Spodoptera spp., Trichoplusia ni, Carpocapsa pomonella, Pieris spp., Chilo spp., Pyrausta nubilalis, Ephestia kuehniella, Galleria mellonella, Tineolaeaellellaella, Tineolaeaellellaella, Tineolaeaellaella , Cacoecia podana, Capua reticulana, Choristoneura fumiferana, Clysia ambiguella, Homona magnanima, Tortrix viridana, Cnaphalocerus spp., Oulema oryzae.
From the order of the Coleoptera, for example, Anobium punctatum, Rhizopertha dominica, Bruchidius obtectus, Acanthoscelides obtectus, Hylotrupes bajulus, Agelastica alni, Leptinotarsa decemlineata, Phaedon cochleariae, Diabrotica spp., Psylliodes chrysoisusamasppas, Atomic spp. , Sitophilus spp., Otiorrhynchus sulcatus, Cosmopolites sordidus, Ceuthonhynchus assimilis, Hypera postica, Dermestes spp., Trogoderma spp., Anthrenus spp., Attagenus spp., Lyctus spp., Meligethes aeneus, Ptinus holpp., Ptinus holpp., Ptinus holpp. Tribolium spp., Tenebrio molitor, Agriotes spp., Conoderus spp., Melolontha melolontha, Amphimallon solstitialis, Costelytra zealandica, Lissorhoptrus oryzophilus.
From the order of the Hymenoptera, for example Diprion spp., Hoplocampa spp., Lasius spp., Monomorium pharaonis, Vespa spp.
From the order of the Diptera, for example Aedes spp., Anopheles spp., Culex spp., Drosophila melanogaster, Musca spp., Fannia spp., Calliphora erythrocephala, Lucilia spp., Chrysomyia spp., Cuterebra spp., Gastrophilus spp., Hyppobosca ., Stomoxys spp., Oestrus spp., Hypoderma spp., Tabanus spp., Tannia spp., Bibio hortulanus, Oscinella frit, Phorbia spp., Pegomyia hyoscyami, Ceratitis capitata, Dacus oleae, Tipula paludosa, Hylemyomy spp., ,
From the order of the Siphonaptera, for example Xenopsylla cheopis, Ceratophyllus spp.
From the class of the Arachnida, for example Scorpio maurus, Latrodectus mactans, Acarus siro, Argas spp., Ornithodoros spp., Dermanyssus gallinae, Eriophyes ribis, Phyllocoptruta oleivora, Boophilus spp., Rhipicephalus spp., Amblyomma spp., ., Psoroptes spp., Chorioptes spp., Sarcoptes spp., Tarsonemus spp., Bryobia praetiosa, Panonychus spp., Tetranychus spp., Hemitarsonemus spp., Brevipalpus spp.

To the plant parasitic nematodes belong e.g. Pratylenchus spp., Radopholus similis, Ditylenchus dipsaci, Tylenchulus semipenetrans, Heterodera spp., Globodera spp., Meloidogyne spp., Aphelenchoides spp., Longidorus spp., Xiphinema spp., Trichodorus spp., Bursaphelenchus spp.

The good plant tolerance of the active ingredient combinations in the to combat plant diseases necessary concentrations allows treatment from above ground Parts of plants, of seedlings, and of the soil. The active ingredient combinations according to the invention can for leaf application or as a mordant.

The active ingredient combinations according to the invention are also suitable for increasing the crop yield. They are also less toxic and are well tolerated by plants.

According to the invention, all plants and parts of plants be treated. Plants include all plants and Plant populations understood how desired and undesirable wild plants or Cultivated plants (including Naturally crops). Crop plants can be plants that are caused by conventional breeding and optimization methods or through biotechnological and genetic engineering Methods or combinations of these methods can be obtained, including the transgenic Plants and including of those that can be estimated by plant variety rights or non-estimable plant varieties. Under plant parts, all above-ground and underground Parts and organs of plants, such as sprout, leaf, flower and root are understood, examples being leaves, needles, stems, stems, flowers, fruiting bodies, fruits and Seeds as well as roots, tubers and rhizomes are listed. To the plant parts heard also crops and vegetative and generative propagation material, for example cuttings, tubers, rhizomes, cuttings and seeds.

The treatment of the plants according to the invention and parts of plants with the active ingredients are carried out directly or through Impact on their environment, living space or storage space according to the usual Treatment methods, e.g. by dipping, spraying, evaporating, atomizing, Scattering, spreading and propagating material, in particular in the case of seeds, still by single or multi-layer coating.

As already mentioned above, according to the invention all plants can and their parts are treated. In a preferred embodiment become wild or by conventional organic breeding methods, plant species obtained such as crossing or protoplast fusion and Plant varieties and their parts treated. In another preferred embodiment are transgenic plants and plant varieties that are caused by genetic engineering Methods if necessary in combination with conventional methods were obtained (Genetically Modified Organisms) and their parts treated. The term “parts” or “parts of plants "or" plant parts "was explained above.

Plants are particularly preferred according to the invention the commercially available in each case or plant varieties in use.

Depending on the plant species or plant varieties, their location and growth conditions (soils, climate, growing season, Nutrition) can by the treatment according to the invention also super-additives ("Synergistic") effects occur. For example, reduced application rates and / or extensions of the Spectrum of activity and / or an enhancement of the effect of those which can be used according to the invention Substances and agents, better plant growth, increased tolerance across from high or low temperatures, increased drought tolerance or against water or soil salt content, increased flowering performance, easier harvesting, Acceleration of maturity, higher Crop yields, higher quality and / or higher Nutritional value of Crops, higher Shelf life and / or workability of the harvested products is possible, which is beyond what is actually to be expected Effects go beyond.

The preferred transgenic plants or plant cultivars to be treated according to the invention include all plants which have received genetic material through the genetic engineering modification, which gives these plants particularly advantageous valuable properties (“traits”). Examples of such properties are better plant growth, Increased tolerance to high or low temperatures, increased tolerance to drought or to water or soil salt content, increased flowering performance, easier harvesting, acceleration of ripening, higher harvest yields, higher quality and / or higher nutritional value of the harvested products, higher storability and / or workability of the Further and particularly highlighted examples of such properties are an increased defense of the plants against animal and microbial pests, such as against insects, mites, phytopathogenic fungi, bacteria and / or viruses as well as an increased tolerance of the plants to certain herbicidal active ingredients. Examples of transgenic plants are the important crop plants, such as cereals (wheat, rice), corn, soybeans, potatoes, cotton, rapeseed and fruit plants (with the fruits apples, pears, citrus fruits and grapes), with corn, soybeans, potatoes and cotton and rapeseed are highlighted. The properties (“traits”) which are particularly emphasized are the plants' increased defense against insects by toxins arising in the plants, in particular those which are caused by the genetic material from Bacillus thuringiensis (for example by the genes CryIA (a), CryIA (b), CryIA (c), CryIIA, CryIIIA, CryIIIB2, Cry9c, Cry2Ab, Cry3Bb and CryIF as well as their combinations) are produced in the plants (hereinafter “Bt plants”). The increased tolerance is also particularly emphasized as properties (“traits”) of the plants against certain herbicidal active compounds, for example imidazolinones, sulfonylureas, glyphosates or phosphinotricin (for example “PAT” gene). The genes which impart the desired properties (“traits”) can also occur in combinations with one another in the transgenic plants. Examples of "Bt plants" are corn varieties, cotton varieties, soy varieties and potato varieties which are marketed under the trade names YIELD GARD ^® (e.g. corn, cotton, soy), KnockOut ^® (e.g. corn), StarLink ^® (e.g. corn), Bollgard ^® ( Cotton), Nucotn ^® (cotton) and NewLeaf ^® (potato). Examples of herbicide-tolerant plants are corn varieties, cotton varieties and soy varieties which are sold under the trade names Roundup Ready ^® (tolerance to glyphosate, eg corn, cotton, soybeans), Liberty Link ^® (tolerance to phosphinotricin, eg rapeseed), IMI ^® (tolerance to imidazolinones) and STS ^® (tolerance to sulfonylureas, eg maize). Herbicide-resistant plants (conventionally bred to herbicide tolerance) are also the plants under the name Clearfield ^{® sold} varieties (eg maize) mentioned, of course, these statements also apply to future developed or future Pf lance varieties with these or future-developed genetic traits.

The active ingredient combinations according to the invention can dependent on of their respective physical and / or chemical properties in the usual Formulations are transferred like solutions, emulsions, Suspensions, powders, dusts, foams, Pastes, soluble Powders, granules, aerosols, suspension emulsion concentrates, impregnated with active ingredients Natural and synthetic substances as well as very fine encapsulation in polymers Fabrics and in enveloping masses for seeds, as well as ULV cold and warm fog formulations.

These formulations are known in the art Manufactured in such a way, e.g. by mixing the active ingredients or Active ingredient combinations with extenders, i.e. liquid solvents, pressurized liquefied Gases and / or solid carriers, if necessary, using surface-active agents, that is to say emulsifiers and / or dispersing agents and / or foaming agents.

In case of using water as an extender e.g. also organic solvents as auxiliary solvent be used. As a liquid solvent essentially come into question: aromatics, such as xylene, toluene or Alkylnaphthalenes, chlorinated aromatics or chlorinated aliphatic Hydrocarbons, such as chlorobenzenes, chlorethylenes or methylene chloride, aliphatic hydrocarbons, such as cyclohexane or paraffins, e.g. Petroleum fractions, mineral and vegetable oils, Alcohols, such as butanol or glycol, and their ethers and esters, ketones, such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents such as dimethylformamide and dimethyl sulfoxide, and water.

With liquefied gaseous extenders or carriers are such liquids meant which are gaseous at normal temperature and pressure, e.g. Aerosol propellants such as butane, propane, nitrogen and carbon dioxide.

Solid carriers are possible: e.g. Ammonium salts and natural Rock flours, such as kaolins, clays, talc, chalk, quartz, attapulgite, Montmorillonite or diatomaceous earth and synthetic rock powder, like finely divided silica, Alumina and silicates. Solid carriers for granules are: e.g. broken and fractionated natural rocks such as calcite, Marble, pumice, sepiolite, dolomite and synthetic granules inorganic and organic flours and granules from organic Material like sawdust, Coconut shells, corn cobs and tobacco stems. As an emulsifier and / or foam generator Funds are possible: e.g. non-ionic and anionic emulsifiers, such as polyoxyethylene fatty acid esters, Polyoxyethylene fatty alcohol ethers, e.g. alkylaryl, Alkyl sulfonates, alkyl sulfates, aryl sulfonates and protein hydrolyzates. Possible dispersants are: e.g. Lignin liquors and methyl cellulose.

It can be in the formulations Adhesives such as carboxymethyl cellulose, natural and synthetic powdery, grained or latex-shaped Polymers are used, such as gum arabic, polyvinyl alcohol, Polyvinyl acetate, as well as natural Phospholipids such as cephalins and lecithins, and synthetic phospholipids. Further Can additive mineral and vegetable oils his.

Dyes such as inorganic Pigments, e.g. Iron oxide, titanium oxide, ferrocyan blue and organic Dyes such as alizarin, azo and metal phthalocyanine dyes and trace nutrients, such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc be used.

The active ingredient content from the commercially available Formulations of prepared application forms can be used in a wide range vary. The active ingredient concentration of the application forms for controlling animal pests such as insects and acarids, can range from 0.0000001 to 95% by weight of active ingredient, preferably between 0.0001 and 1% by weight. The application happens in a customary adapted to the application forms Wise.

The formulations to combat unwanted phytopathogenic mushrooms generally contain between 0.1 and 95% by weight of active ingredients, preferably between 0.5 and 90%.

The active compound combinations according to the invention, as such, in the form of their formulations or the use forms prepared therefrom, such as ready-to-use solutions, emulsifiable concentrates, Emulsions, suspensions, wettable powders, soluble powders, dusts and granules can be used. They are used in the customary manner, for example by watering, spraying, atomizing, scattering, dusting, foaming, brushing, brushing, dry pickling, wet pickling, wet pickling, slurry pickling, incrusting, etc.

The active ingredient combinations according to the invention can in commercially available Formulations as well as those prepared from these formulations Application forms in a mixture with other active ingredients, such as insecticides, Attractants, sterilants, bactericides, acaricides, nematicides, Fungicides, growth regulators or herbicides are present.

When using the active ingredient combinations according to the invention can the application rates depending on the type of application within a larger range can be varied. In the treatment of parts of plants are the Application rates of active ingredient combination generally between 0.1 and 10,000 g / ha, preferably between 10 and 1,000 g / ha. In the Seed treatment is the application rate of the active ingredient combination generally between 0.001 and 50 g per kilogram of seed, preferably between 0.01 and 10 g per kilogram of seed. During treatment In general, the application rates of the active ingredient combination are in the soil between 0.1 and 10,000 g / ha, preferably between 1 and 5,000 g / ha.

It was also found that the active ingredient combinations according to the invention a high insecticidal activity against insects, the technical Destroy materials.

The following insects may be mentioned by way of example and preferably, but without limitation:
Beetles such as Hylotrupes bajulus, Chlorophorus pilosis, Anobium punctatum, Xestobium rufovillosum, Ptilinus pecticornis, Dendrobium pertinex, Ernobius mollis, Priobium carpini, Lyctus brunneus, Lyctus africanus, Lyctus planicolles, Lyctus pubisxis, Lyctus pubisoleis, Lyctus pubisoleis, Lyctus pubxis syllable, Lyctus pubxis, Tryptodendron spec. Apate monachus, Bostrychus capucins, Heterobostrychus brunneus, Sinoxylon spec. Dinoderus minutus.
Hymenoptera such as Sirex juvencus, Urocerus gigas, Urocerus gigas taignus, Urocerus augur.
Termites such as Kalotermes flavicollis, Cryptotermes brevis, Heterotermes indicola, Reticulitermes flavipes, Reticulitermes santonensis, Reticulitermes lucifugus, Mastotermes darwiniensis, Zootermopsis nevadensis, Coptotermes formosanus.
Bristle tails such as Lepisma saccharina.

Among technical materials are to understand non-living materials in the present context, such as preferably plastics, adhesives, glues, papers and cartons, Leather, wood, wood processing products and paints.

Acts very particularly preferably the material to be protected against insect infestation is wood and Timber products.

Wood and wood processing products that can be protected by the agent according to the invention or mixtures containing it are to be understood as examples:
Lumber, wooden beams, railway sleepers, bridge parts, jetties, wooden vehicles, boxes, pallets, containers, telephone poles, wooden cladding, wooden windows and doors, plywood, chipboard, carpentry or wooden products that are generally used in house construction or joinery.

The active substance combinations can be used as such, in the form of concentrates or general formulations such as Powders, granules, solutions, Suspensions, emulsions or pastes can be used.

The formulations mentioned can be found in in a manner known per se, e.g. by mixing the active ingredients with at least one solvent or diluent, Emulsifier, dispersant and / or binder or fixative, water repellent, optionally desiccants and UV stabilizers and if appropriate Dyes and pigments and other processing aids.

The protection of wood and wood-based materials Insecticidal agents or concentrates used contain the active ingredient according to the invention in a concentration of 0.0001 to 95% by weight, in particular 0.001 up to 60% by weight.

The amount of funds used or concentrates depends on the type and occurrence of the insects and depending on the medium. The optimum amount of use can be determined in each case by test series become. In general, however, it is sufficient from 0.0001 to 20% by weight preferably 0.001 to 10 wt .-%, of the active ingredient, based on the to be protected Material.

As a solvent and / or diluent serves an organic chemical solvent or solvent mixture and / or an oily or oily difficult to flee organic chemical solvent or Solvent mixture and / or a polar organic chemical solvent or solvent mixture and / or water and optionally an emulsifier and / or wetting agent.

As an organic chemical solvent are preferably oily or oily solvent with an evaporation number above 35 and a flash point above 30 ° C, preferably above 45 ° C, used. As such volatile, water-insoluble, oily and oily solvent corresponding mineral oils or their aromatic fractions or mineral oil-containing solvent mixtures, preferably White spirit, petroleum and / or alkylbenzene used.

Mineral oils with a Boiling range from 170 to 220 ° C, White spirit with a boiling range of 170 to 220 ° C, spindle oil with a Boiling range from 250 to 350 ° C, Petroleum or aromatics with a boiling range of 160 to 280 ° C, turpentine oil and the like. for use.

In a preferred embodiment become fluid aliphatic hydrocarbons with a boiling range of 180 to 210 ° C or high-boiling mixtures of aromatic and aliphatic hydrocarbons with a boiling range of 180 to 220 ° C and / or locker oil and / or Monochloronaphthalene, preferably α-monochloronaphthalene, is used.

The organic volatile oily or oily solvent with an evaporation number above 35 and a flash point above 30 ° C, preferably above 45 ° C, can partially by easily or moderately volatile organic chemical solvents be replaced with the proviso that the solvent mixture also an evaporation number over 35 and a flash point above 30 ° C, preferably above 45 ° C and that the mixture in this solvent mixture soluble or is emulsifiable.

According to a preferred embodiment becomes part of the organic chemical solvent or solvent mixture or an aliphatic polar organic chemical solvent or solvent mixture replaced. Preferably hydroxyl and / or ester and / or Aliphatic organic chemical solvents containing ether groups such as glycol ether, ester or the like for use.

As an organic chemical binder within the scope of the present invention are those known per se water-dilutable and / or in the organic chemical solvents used soluble or dispersible or emulsifiable synthetic resins and / or binding drying oils, in particular Binder consisting of or containing an acrylate resin, a vinyl resin, e.g. Polyvinyl acetate, polyester resin, polycondensation or polyaddition resin, Polyurethane resin, alkyd resin or modified alkyd resin, phenolic resin, Hydrocarbon resin such as inden-coumarone resin, silicone resin, drying vegetable and / or drying oils and / or physically drying binders based on a natural and / or Resin used.

The synthetic resin used as a binder can be used in the form of an emulsion, dispersion or solution. As Binder can also bitumen or bituminous Substances up to 10% by weight can be used. In addition, can well-known dyes, pigments, water-repellent agents, odor correctors and inhibitors or corrosion protection agents and the like become.

Is preferred according to the invention as an organic chemical Binder at least one alkyd resin or modified alkyd resin and / or a drying vegetable oil in the medium or in the concentrate contain. Are preferred according to the invention Alkyd resins with an oil content of more than 45% by weight, preferably 50 to 68% by weight.

The binder mentioned can be whole or partially by a fixative (mixture) or a plasticizer (mixture) be replaced. These additions are supposed to evaporate the active ingredients and prevent crystallization or precipitation. They preferably replace 0.01 to 30% of the binder (based on 100% of the binder used).

The plasticizers come from the chemical Classes of phthalic acid esters such as dibutyl, dioctyl or benzyl butyl phthalate, phosphoric acid esters such as tributyl phosphate, adipic acid esters such as di- (2-ethylhexyl) adipate, stearates such as butyl stearate or amyl stearate, Oleates such as butyl oleate, glycerol ether or higher molecular weight glycol ether, Glycerol ester and p-toluenesulfonic acid ester.

Fixing agents are chemically based on polyvinyl alkyl ethers such as Polyvinyl methyl ether or ketones such as benzophenone, ethylene benzophenone.

As a solvent or diluent water is also particularly suitable, if appropriate in a mixture with one or more of the above-mentioned organic chemical solution or Diluents, Emulsifiers and dispersants.

A particularly effective wood protection is through large-scale impregnation, e.g. Vacuum, double vacuum or pressure process.

At the same time, the active compound combinations according to the invention to protect objects, especially hulls, screens, from fouling Networks, structures, quay systems and signal systems, which are or brackish water come into contact.

Fouling by sessile oligochaetes, like lime tube worms as well by mussels and species of the group Ledamorpha (barnacles), like different types of Lepas and Scalpellum, or by species of the group Balanomorpha (barnacles), such as balanus or pollicipes species, elevated the frictional resistance of ships and consequently leads to increased energy consumption and above through frequent dry dock stays to a significant increase in operating costs.

In addition to fouling by algae, for example Ectocarpus sp. and Ceramium sp., comes especially to the vegetation by sessile Entomostraken groups, which are called Cirripedia (Rankenflußkrebse) summarized become of particular importance.

It has now surprisingly been found that the active ingredient combinations according to the invention have excellent antifouling effect.

By using the active ingredient combinations according to the invention can rely on the use of heavy metals such as in bis (trialkyltin) sulfides, Tri-n-butyltin laurate, tri-n-butyltin chloride, Copper (I) oxide, triethyltin chloride, tri-n-butyl (2-phenyl-4-chlorophenoxy) tin, Tributyltin oxide, molybdenum disulfide, Antimony oxide, polymeric butyl titanate, phenyl (bispyridine) bismuth chloride, Tri-n-butyltin fluoride, manganese ethylene bisthiocarbamate, zinc dimethyldithiocarbamate, Zinc ethylene bisthiocarbamate, zinc and copper salts of 2-pyridinthiol-1-oxide, bisdimethyldithiocarbamoyl zinc ethylene bisthiocarbamate, Zinc oxide, copper (I) ethylene bisdithiocarbamate, copper thiocyanate, Copper naphthenate and tributyltin halides can be dispensed with or the concentration of these compounds can be significantly reduced.

The ready-to-use antifouling paints can optionally other active ingredients, preferably algicides, fungicides, Contain herbicides, molluscicides or other antifouling agents.

Suitable combination partners for the antifouling agents according to the invention are preferably:
Algicides such as 2-tert-butylamino-4-cyclopropylamino-6-methylthio-1,3,5-triazine, dichlorophen, diuron, endothal, fentin acetate, isoproturon, methabenzthiazuron, oxyfluorfen, quinoclamine and terbutryn;
Fungicides such as benzo [b] thiophenecarboxylic acid cyclohexylamide-S, S-dioxide, dichlofluanid, fluorfolpet, 3-iodo-2-propynylbutylcarbamate, tolylfluanid and azoles such as azaconazole, cyproconazole, epoxyconazole, hexaconazole, metconazole, propylazole, propanol
Molluscicides such as fentin acetate, metaldehyde, methiocarb, niclosamide, thiodicarb and trimethacarb;
or conventional antifouling agents such as 4,5-dichloro-2-octyl-4-isothiazolin-3-one, diiodomethylparatrylsulfone, 2- (N, N-dimethylthiocarbamoylthio) -5-nitrothiazyl, potassium, copper, sodium and zinc salts of 2-pyridinthiol-1-oxide, pyridine triphenylborane, tetrabutyldistannoxane, 2,3,5,6-tetrachloro-4- (methylsulfonyl) pyridine, 2,4,5,6-tetrachloroisophthalonitrile, tetramethylthiuram disulfide and 2,4,6 -Trichlorphenylmaleinimid.

The antifouling agents used contain the active ingredient combinations according to the invention in a concentration of 0.001 to 50 wt .-%, in particular of 0.01 to 20% by weight.

The antifouling agents according to the invention contain furthermore the usual Components such as in Ungerer, Chem. Ind. 1985, 37, 730-732 and Williams, Antifouling Marine Coatings, Noyes, Park Ridge, 1973.

Antifouling paints included in addition to the algicides, fungicides, molluscicides and insecticides according to the invention Active substances, in particular binders.

Examples of recognized binders are Polyvinyl chloride in a solvent system, chlorinated rubber in a solvent system, Acrylic resins in a solvent system especially in an aqueous system, Vinyl chloride / vinyl acetate copolymer systems in the form of aqueous dispersions or in the form of organic solvent systems, Butadiene / styrene / acrylonitrile rubbers, drying oils, such as Linseed oil, Resin esters or modified hard resins in combination with tar or Bitumen, asphalt and epoxy compounds, small amounts of chlorinated rubber, chlorinated polypropylene and vinyl resins.

May contain paint also inorganic pigments, organic pigments or dyes, which are preferably insoluble in sea water. Paints can also be used Materials, such as rosin, contain controlled release of the active ingredients. The paintings can also Plasticizers, modifiers influencing the rheological properties as well as other conventional ones Components included. They can also be used in self-polishing antifouling systems compounds of the invention or the above-mentioned mixtures can be incorporated.

The active substance combinations are also suitable for controlling animal pests, in particular insects, arachnids and mites, which live in closed rooms, such as, for example, apartments, factory halls, offices, vehicle cabins and the like. occurrence. They can be used to control these pests in household insecticide products. They are effective against sensitive and resistant species and against all stages of development. These pests include:
From the order of the Scorpionidea, for example Buthus occitanus.
From the order of the Acarina, for example Argas persicus, Argas reflexus, Bryobia ssp., Dermanyssus gallinae, Glyciphagus domesticus, Ornithodorus moubat, Rhipicephalus sanguineus, Trombicula alfreddugesi, Neutrombicula autumnalis, Dermatophagoides pteronissimus forina.
From the order of the Araneae, for example Aviculariidae, Araneidae.
From the order of the Opiliones, for example Pseudoscorpiones chelifer, Pseudoscorpiones cheiridium, Opiliones phalangium.
From the order of the Isopoda, for example Oniscus asellus, Porcellio scaber.
From the order of the Diplopoda, for example, Blaniulus guttulatus, Polydesmus spp.
From the order of the Chilopoda, for example Geophilus spp.
From the order of the Zygentoma, for example Ctenolepisma spp., Lepisma saccharina, Lepismodes inquilinus.
From the order of the Blattaria, for example Blatta orientalies, Blattella germanica, Blattella asahinai, Leucophaea maderae, Panchlora spp., Parcoblatta spp., Periplaneta austra lasiae, Periplaneta americana, Periplaneta brunnea, Periplaneta fuliginosa, Supella longipalpa.
From the order of the Saltatoria, for example Acheta domesticus.
From the order of the Dermaptera, for example, Forficula auricularia.
From the order of the Isoptera, for example Kalotermes spp., Reticulitermes spp.
From the order of Psocoptera, for example Lepinatus spp., Liposcelis spp.
From the order of the Coleptera, for example Anthrenus spp., Attagenus spp., Dermestes spp., Latheticus oryzae, Necrobia spp., Ptinus spp., Rhizopertha dominica, Sitophilus granarius, Sitophilus oryzae, Sitophilus zeamais, Stegobium paniceum.
From the order of the Diptera, for example Aedes aegypti, Aedes albopictus, Aedes taeniorhynchus, Anopheles spp., Calliphora erythrocephala, Chrysozona pluvialis, Culex quinquefasciatus, Culex pipiens, Culex tarsalis, Drosophila domppis, Phanncaotpp , Simulium spp., Stomoxys calcitrans, Tipula paludosa.
From the order of the Lepidoptera, for example Achroia grisella, Galleria mellonella, Plodia interpunctella, Tinea cloacella, Tinea pellionella, Tineola bisselliella.
From the order of the Siphonaptera, for example Ctenocephalides canis, Ctenocephalides felis, Pulex imtans, Tunga penetrans, Xenopsylla cheopis.
From the order of the Hymenoptera, for example Camponotus herculeanus, Lasius fuliginosus, Lasius niger, Lasius umbratus, Monomorium pharaonis, Paravespula spp., Tetramorium caespitum.
From the order of the anoplura, for example Pediculus humanus capitis, Pediculus humanus corporis, Phthirus pubis.
From the order of the Heteroptera, for example Cimex hemipterus, Cimex lectularius, Rhodinus prolixus, Triatoma infestans.

The application takes place in aerosols, unpressurized sprays, e.g. Pump and atomizer sprays, Automatic fog machines, foggers, foams, Gels, vaporizer products with vaporizer plates made of cellulose or plastic, Liquid evaporators, Gel and membrane evaporators, propeller-driven evaporators, energy-free or passive evaporation systems, Moth papers, moth bags and moth gels, as granules or dusts, in lures or Bait stations.

The good insecticidal and acaricidal Effect of the active ingredient combinations according to the invention can be seen from the following examples. While the individual active ingredients weaknesses in insecticidal activity have, the combinations show an effect that over a simple summation of effects goes beyond.

There is a synergistic effect with insecticides and acaricides always before if the fungicidal Effect of the drug combinations is greater than the sum of the effects of the individually applied active ingredients.

The expected insecticidal / acaricidal activity for a given combination of two active compounds can be calculated according to SR Colby ("Calculating Synergistic and Antagonistic Responses of Herbicide Combinations", Weeds 1967, 15, 24-22) as follows:
If
X means the degree of destruction, expressed in% of the untreated control, when the active ingredient A is used in an application rate of m ppm,
Y means the degree of destruction, expressed in% of the untreated control, when the active compound B is used in an application rate of n ppm and
E means the degree of destruction, expressed in% of the untreated control, when active ingredients A and B are used in application rates of m and n ppm,
then

Is the actual insecticide / acaricide Abtötungsgad larger than calculated, the combination is superadditive in its killing, i.e. it is a synergistic effect. In this case, the one actually observed must be observed kill rate to be taller than that from the above Formula calculated value for the expected efficiency (E).

The good fungicidal activity of the active compound combinations according to the invention can be seen from the following examples. While the individual active ingredients weaknesses in fungicidal activity have, the combinations show an effect that over a simple summation of effects goes beyond.

There is a synergistic effect with fungicides always before, if the fungicidal effect of the active ingredient combinations is bigger than the sum of the effects of the individually applied active ingredients.

The expected fungicidal activity for a given combination of two active compounds can be calculated according to SR Colby ("Calculating Synergistic and Antagonistic Responses of Herbicide Combinations", Weeds 1967, 15, 20-22) as follows:
If
X means the efficiency when using the active ingredient A in an application rate of mg / ha,
Y means the efficiency when using the active ingredient B in an application rate of ng / ha and
E means the efficiency when using active ingredients A and B in application rates of m and ng / ha,
then

The efficiency in% determined. It means 0% an efficiency that of control corresponds while an efficiency of 100% means that no infection is observed becomes.

The actual fungicidal activity is greater than calculated, the effect of the combination is super-additive, i.e. there is a synergistic effect. In this case the actually observed efficiency may be greater than that from the above Formula calculated value for the expected efficiency (E).

The invention is illustrated by the following Illustrated examples. However, the invention is not based on the Examples limited.

Example A

Plutella test, sensitive strain Solvent: 7 parts by weight of dimethylformamide emulsifier: 2 parts by weight of alkylaryl polyglycol ether

For the preparation of a suitable active ingredient preparation 1 part by weight of active ingredient is mixed with the stated amounts solvent and emulsifier and diluted the concentrate with water containing emulsifier to the desired concentration.

Cabbage leaves (Brassica oleracea) by diving into the active ingredient preparation of the desired concentration treated and with caterpillars caterpillars (Plutella xylostella, more sensitive Stem) occupied as long as the leaves are still damp.

After the desired period of time, the kill in % certainly. 100% means that all caterpillars have been killed; 0% means that no caterpillars have been killed. The determined kill rates are calculated using the Colby formula (see page 52 above).

In this test, the following showed Active ingredient combination according to the present Registration compares a synergistically enhanced effectiveness for the individual active ingredients used:

Table A plant-damaging insect Plutella test, sensitive strain

Example B

Phaedon larvae test Solvent: 7 parts by weight of dimethylformamide emulsifier: 2 parts by weight of alkylaryl polyglycol ether

For the preparation of a suitable active ingredient preparation 1 part by weight of active ingredient is mixed with the stated amounts solvent and emulsifier and diluted the concentrate with water containing emulsifier to the desired concentration.

Cabbage leaves (Brassica oleracea) by diving into the active ingredient preparation of the desired concentration treated and with larvae of horseradish leaf beetle (Phaedon cochleariae) occupied as long as the leaves are still damp.

After the desired period of time, the kill in % certainly. 100% means that all beetle larvae have been killed; 0% means that no beetle larvae killed were. The determined killing values one uses the Colby formula (see page 52 above).

In this test, the following showed Active ingredient combination according to the present Registration compares a synergistically enhanced effectiveness for the individual active ingredients used:

Table B plant-damaging insect Phaedon larva test

Example C

Heliothis armigera test Solvent: 7 parts by weight of dimethylformamide emulsifier: 2 parts by weight of alkylaryl polyglycol ether

For the preparation of a suitable active ingredient preparation 1 part by weight of active ingredient is mixed with the stated amounts solvent and emulsifier and diluted the concentrate with water containing emulsifier to the desired concentration.

Soybean shoots (Glycine max) are through Dipping into the drug preparation of the desired concentration is treated and set with Heliothis armigera caterpillars while the leaves are still are damp.

After the desired period of time, the kill in % certainly. 100% means that all caterpillars have been killed; 0% means that no caterpillars have been killed. The determined kill rates are calculated using the Colby formula (see page 52 above).

In this test, the following showed Active ingredient combination according to the present Registration compares a synergistically enhanced effectiveness for the individual active ingredients used:

Table C plant-damaging insect Heliothis armigera test

Example D

Plutella test, resistant strain Solvent: 7 parts by weight of dimethylformamide emulsifier: 2 parts by weight of alkylaryl polyglycol ether

For the preparation of a suitable active ingredient preparation 1 part by weight of active ingredient is mixed with the stated amounts solvent and emulsifier and diluted the concentrate with water containing emulsifier to the desired concentration.

Cabbage leaves (Brassica oleracea) by diving into the active ingredient preparation of the desired concentration treated and caterpillar caterpillars (Plutella xylostella, more resistant Stem) occupied as long as the leaves are still damp.

After the desired period of time, the kill in % certainly. 100% means that all caterpillars have been killed; 0% means that no caterpillars have been killed. The determined kill rates are calculated using the Colby formula (see page 52 above).

In this test, the following showed Active ingredient combination according to the present Registration compares a synergistically enhanced effectiveness for the individual active ingredients used:

Table D plant-damaging insect Plutella test, resistant strain

Example E

Phytophthora test (tomato) / protective Solvent: 49 parts by weight of acetone emulsifier: 1 part by weight of alkylaryl polyglycol ether

For the preparation of a suitable active ingredient preparation 1 part by weight of active ingredient is mixed with the stated amounts solvent and emulsifier and diluted the concentrate with water to the desired concentration.

For testing for protective effectiveness are young plants with the active ingredient preparation in the specified Spray rate applied. After the spray coating has dried on, the plants are washed with an aqueous Spore suspension of Phytophthora infestans inoculated. The plants are then in an incubation cabin at approx. 20 ° C and 100 % relative humidity set up.

3 days after the inoculation the evaluation. 0% means an efficiency that the one corresponds to the control while an efficiency of 100% means that no infection is observed.

The table below shows clearly shows that the found effect of the active ingredient combination according to the invention is bigger than the calculated one, i.e. there is a synergistic effect.

Table E Phytophthora test (tomato) / protective

Example F

Plasmopara test (vine) / protective Solvent: 49 parts by weight of acetone emulsifier: 1 part by weight of alkyl aryl polyglycol ether

For the preparation of a suitable active ingredient preparation 1 part by weight of active ingredient is mixed with the stated amounts solvent and emulsifier and diluted the concentrate with water to the desired concentration.

For testing for protective effectiveness are young plants with the active ingredient preparation in the specified Spray rate applied. After the spray coating has dried on, the plants are washed with an aqueous Spore suspension of Plasmopara viticola is inoculated and remains then 1 day in an incubation cabin at approx. 20 ° C and 100% relative humidity. Subsequently the plants are grown for 4 days in a greenhouse at approx. 21 ° C and approx. 90% humidity set up. The plants are then moistened and Put in an incubation cabin for 1 day.

6 days after the inoculation the evaluation. 0% means an efficiency that the one corresponds to the control while an efficiency of 100% means that no infection is observed.

The table below shows clearly shows that the found effect of the active ingredient combination according to the invention is bigger than the calculated one, i.e. there is a synergistic effect.

Table F Plasmopara test (vine) / protective

Example G

Botrytis test (bean) / protective Solvent: 49 parts by weight of acetone emulsifier: 1 part by weight of alkylaryl polyglycol ether

For the preparation of a suitable active ingredient preparation 1 part by weight of active ingredient is mixed with the stated amounts solvent and emulsifier and diluted the concentrate with water to the desired concentration.

For testing for protective effectiveness are young plants with the active ingredient preparation in the specified Spray rate applied. After the spray coating has dried on, 2 small ones are placed on each sheet pieces of agar overgrown with botrytis cinerea. The inoculated Plants are grown in a darkened chamber at approx. 20 ° C and 100 % relative humidity set up.

2 days after the inoculation the size of the infection spots on the leaves evaluated. 0% means an efficiency that the one corresponds to the control while an efficiency of 100% means that no infection is observed becomes.

The table below shows clearly shows that the found effect of the active ingredient combination according to the invention is bigger than the calculated one, i.e. there is a synergistic effect.

Table G Botrytis test (bean) / protective

Claims (4)

Synergistic active ingredient combinations containing the phthalamide of the formula (I)

and at least one active ingredient which is selected from the following groups (1) to (18): group (1) strobilurins of the general formula (II)

in which A for one of the groups

A ^{1 is} NH or O, A ^{2 is} N or CH, L is one of the groups

stands, wherein the bond, which is marked with an asterisk (*) is bound to the phenyl ring, R ^{1 stands} for hydrogen or fluorine, R stands for phenyl, optionally substituted once or twice, identically or differently by chlorine, cyano, methyl or trifluoromethyl , Phenoxy or pyridinyl, or for 1- (4-chlorophenyl) pyrazol-3-yl or for 1,2-propanedione-bis (O-methyloxime) -1-yl; Group (2) triazoles of the general formula (III)

in which either Q is hydrogen or SH, m is 0 or 1, R ^{2 is} hydrogen, fluorine, chlorine, phenyl or 4-chlorophenoxy, R ^{3 is} hydrogen or chlorine, A ^{3 is} a direct bond, -CH ₂ -, - (CH ₂ ) ₂ - or -O-, A ³ also stands for * -CH ₂ -CHR ⁶ - or * -CH = CR ⁶ -, the bond marked with * being linked to the phenyl ring and R ⁵ and R ⁶ together then represent -CH ₂ -CH ₂ -CH [CH (CH ₃ ) ₂ ] - or -CH ₂ -CH ₂ -C (CH ₃ ) ₂ -, A ^{4 represents} C or Si (silicon), R ^{4 is} hydrogen, hydroxy or cyano, R ^{5 is} 1-cyclopropylethyl, 1-chlorocyclopropyl, C ₁ -C ₄ alkyl, C ₁ -C ₆ hydroxyalkyl, C ₁ -C ₄ alkylcarbonyl , C ₁ -C ₂ haloalkoxy-C ₁ -C ₂ alkyl, trimethylsilyl-C ₁ -C ₂ alkyl, monofluorophenyl, or phenyl, R ⁴ and R ⁵ together also represent -O-CH ₂ -CH (R ⁷ ) -O-, -O-CH ₂ -CH (R ⁷ ) -CH ₂ -, or -O-CH (R ⁸ ) -, R ^{7 represents} hydrogen, C ₁ -C ₄ alkyl or bromine, R ^{8 represents} 2-chlorophenyl; Group (3) sulfenamides of the general formula (IV)

in which R ^{9 represents} hydrogen or methyl; Group (4) valinamides selected from (4-1) iprovalicarb (4-2) N ¹ - [2- (4 - {[3- (4-chlorophenyl) -2-propynyl] oxy} -3-methoxyphenyl) ethyl ] -N ² - (methylsulfonyl) -D-valinamide; Group (5) carboxamides of the general formula (V)

in which X represents 2-chloro-3-pyridinyl, 1-methylpyrazol-4-yl, which is substituted in the 3-position by methyl or trifluoromethyl and in the 5-position by hydrogen or chlorine, for 4-ethyl-2-ethylamino -1,3-thiazol-5-yl, for 1-methyl-cyclohexyl, for 2,2-dichloro-1-ethyl-3-methylcyclopropyl, for 2-fluoro-2-propyl, or for phenyl, which is a simple is substituted three to three times, identically or differently by chlorine or methyl, Y represents a direct bond, C ₁ -C ₆ -alkanediyl or thiophene diyl optionally substituted by chloro, cyano or oxo, Z represents hydrogen or the group

A ^{5 is} CH or N, R ^{10 is} hydrogen, chlorine, by phenyl which is optionally mono- or disubstituted, identically or differently, by chlorine or di (C ₁ -C ₃ -alkyl) aminocarbonyl, R ^{11 is} hydrogen or chlorine R ^{12 represents} hydrogen, chlorine, hydroxy, methyl or trifluoromethyl, R ¹⁰ and R ¹¹ also together represent * -CH (CH ₃ ) -CH ₂ -C (CH ₃ ) ₂ - or * -CH (CH ₃ ) -OC (CH ₃ ) ₂ -, where the bond marked with * is linked to R ¹⁰ ; Group (6) dithiocarbamates selected from (6-1) Mancozeb (6-2) Maneb (6-3) Metiram (6-4) Propineb (6-5) Thiram (6-6) Zineb (6-7) Ziram Group (7) acylalanines of the general formula (VI)

in which * denotes a carbon atom in the R or S configuration, preferably in the S configuration, R ^{13 represents} phenyl, furyl or methoxy; Group (8): anilino-pyrimidines of the general formula (VII)

in which R ^{14 represents} methyl, cyclopropyl or 1-propynyl; Group (9): Benzimidazoles of the general formula (VIII)

in which R ¹⁵ and R ¹⁶ each represent hydrogen or together represent -O-CF ₂ -O-, R ^{17 represents} hydrogen, C ₁ -C ₄ alkylaminocarbonyl or 3,5-dimethylisoxazol-4-ylsulfonyl, R ¹⁸ represents chlorine, methoxycarbonylamino, chlorophenyl, furyl or thiazolyl; Group (10): carbamates of the general formula (IX)

in which R ^{19 represents} n- or iso-propyl, R ^{20 represents} di (C ₁ -C ₂ alkyl) amino-C ₂ -C ₄ alkyl or diethoxyphenyl; Group (11): Dicarboximides selected from (11-1) Captafol (11-2) Captan (11-3) Folpet (11-4) Iprodione (11-5) Procymidone (11-6) Vinclozolin Group (12): Guanidines selected from (12-1) dodine (12-2) guazatine (12-3) iminoctadine triacetate (12-4) iminoctadine tris (albesil) group (13): imidazole selected from (13-1) cyazofamide (13-2) Prochloraz (13-3) triazoxide group (14): morpholines of the general formula (X)

in which R ²¹ and R ²² independently of one another are hydrogen or methyl, R ^{23 is} C ₁ -C ₁₄ alkyl (preferably C ₁₂ -C ₁₄ alkyl), C ₅ -C ₁₂ cycloalkyl (preferably C ₁₀ -C ₁₂ -Cycloalkyl), phenyl-C ₁ -C ₄ -alkyl, which may be substituted in the phenyl part by halogen or C ₁ -C ₄ -alkyl, or acrylyl, which is substituted by chlorophenyl and dimethoxyphenyl; Group (15): pyrroles of the general formula (XI)

in which R ^{24 stands} for chlorine or cyano, R ^{25 stands} for chlorine or nitro, R ²⁶ stands for chlorine, R ²⁵ and R ²⁶ also together represent -O-CF ₂ -O-; Group (16): phosphonates selected from (16-1) fosetyl-Al (16-2) phosphonic acid; Group (17): phenylethanamides of the general formula (XII)

in which R ^{27 represents} unsubstituted or substituted by fluorine, chlorine, bromine, methyl or ethyl, phenyl, 2-naphthyl, 1,2,3,4-tetrahydronaphthyl or indanyl; Group (18): fungicides selected from (18-1) acibenzolar-S-methyl (18-2) chlorothalonil (18-3) cymoxanil (18-4) edifenphos (18-5) famoxadone (18-6) fluazinam (18 -7) Copper oxychloride (18-8) copper hydroxide (18-9) oxadixyl (18-10) spiroxamine Use of active substance combinations according to claim 1 to combat of unwanted animal pests like insects, unwanted Acarid as well as unwanted phytopathogenic mushrooms. Combat procedures of unwanted animal pests like insects, unwanted acarids as well as unwanted phytopathogenic mushrooms, characterized in that one drug combinations according to claim 1 on the unwanted animal pests like insects, unwanted Acarid as well as unwanted phytopathogenic fungi and / or their habitat. Process for making insecticidal, acaricidal and / or fungicidal agents, characterized in that active ingredient combinations according to claim 1 mixed with extenders and / or surfactants.