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DE1015359B - Method for preventing surface stress cracks in objects made of thermoplastics, in particular polystyrene housings of vehicle batteries - Google Patents

Method for preventing surface stress cracks in objects made of thermoplastics, in particular polystyrene housings of vehicle batteries

Info

Publication number
DE1015359B
DE1015359B DEB20675A DEB0020675A DE1015359B DE 1015359 B DE1015359 B DE 1015359B DE B20675 A DEB20675 A DE B20675A DE B0020675 A DEB0020675 A DE B0020675A DE 1015359 B DE1015359 B DE 1015359B
Authority
DE
Germany
Prior art keywords
housings
thermoplastics
plastic
vehicle batteries
objects made
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DEB20675A
Other languages
German (de)
Inventor
Alfred Felber
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Robert Bosch GmbH
Original Assignee
Robert Bosch GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Robert Bosch GmbH filed Critical Robert Bosch GmbH
Priority to DEB20675A priority Critical patent/DE1015359B/en
Publication of DE1015359B publication Critical patent/DE1015359B/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04Coating
    • C08J7/0427Coating with only one layer of a composition containing a polymer binder
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2325/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2325/02Homopolymers or copolymers of hydrocarbons
    • C08J2325/04Homopolymers or copolymers of styrene
    • C08J2325/06Polystyrene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Sealing Battery Cases Or Jackets (AREA)
  • Connection Of Batteries Or Terminals (AREA)

Description

Verfahren zum Verhüten oberflächlicher Spannungsrisse bei Gegenständen aus thermoplastischen Kunststoffen, insbesondere Polystyrolgehäusen von Fahrzeugb atterien Die Erfindung betrifft ein Verfahren zum Verhüten oberflächlicher Spannungsrisse bei Gegenständen aus thermoplastischen Kunststoffen, insbesondere Polystyrolgehäusen von Fahrzeugbatterien.Method for preventing superficial stress cracks in objects made of thermoplastics, in particular polystyrene housings from Fahrzeugb atteries The invention relates to a method for preventing superficial stress cracks for objects made of thermoplastics, especially polystyrene housings of vehicle batteries.

Bei einigen vorzugsweise säurefesten Kunststoffsorten, z. B. Ocrylharzen und Polystyrol, treten neben den mit den bekannten Kunststoffeigenschaften gegebenen Vorteilen, z. B. geringes Gewicht, leichte Spritz- oder Formarbeit, und gegebenenfalls Säurebeständigkeit auch Nachteile auf, die darin bestehen, daß manche Kunststoffe insbesondere gegen Biegungsspannungen sehr empfindlich sind und entweder unmittelbar oder mehr oder weniger lange Zeit nach dem Auftreten äußerer oder innerer Spannungen reißen. Es ist Aufgabe der Erfindung, derartige Kunststoffe in einfacher Weise gegen die Gefahr des Entstehens von Spannungsrissen weitgehend zu schützen. With some preferably acid-resistant types of plastic, e.g. B. Acrylic resins and polystyrene, occur in addition to those given with the known plastic properties Advantages, e.g. B. light weight, light injection molding or molding, and optionally Acid resistance also has disadvantages, which consist in the fact that some plastics are particularly sensitive to bending stresses and are either immediate or more or less long time after the appearance of external or internal tensions tear. It is the object of the invention to counteract such plastics in a simple manner to largely protect the risk of stress cracking.

Erfindungsgemäß wird dieses Ziel dadurch erreicht, daß der zu schützende Kunststoffgegenstand teilweise oder allseitig mit einem dem Kunststoff des Gegenstandes zumindest chemisch verwandten, jedoch weicheren Kunststoff durch Auftragen einer Lösung des Kunststoffs in einem leicht flüchtigen Lösungsmittel überzogen wird. According to the invention this goal is achieved in that the to be protected Plastic object partially or on all sides with one of the plastic of the object at least chemically related, but softer plastic by applying a Solution of the plastic in a volatile solvent is coated.

Der Schutzüberzug wird zweckmäßig durch Überfluten der zu überziehenden Kunststoffteile mit dem gelösten Stoff, durch Tauchen dieser Teile in den gelösten Stoff oder durch Aufspritzen des gelösten Stoffs auf die zu überziehenden Zonen des Kunststoffteiles hergestellt. In den Fällen, wo der Schutzüberzug auf Polystyrolteile, z. B. Polystyrolgehäuse von Fahrzeugbatterien, aufgetragen werden soll, hat sich als Überzugsstoff ein gegenüber dem Gehäusematerial weicheres Polystyrol bewährt, welches zweckmäßig in Xylol gelöst und in dieser Lösung möglichst auf alle Teile des Batteriegehäuses gespritzt wird. The protective coating is expediently by flooding the to be coated Plastic parts with the solute, by immersing these parts in the solute Fabric or by spraying the solute onto the areas to be coated of the plastic part. In cases where the protective coating is on polystyrene parts, z. B. Polystyrene housing of vehicle batteries to be applied, has A polystyrene, which is softer than the housing material, has proven its worth as a covering material, which is expediently dissolved in xylene and in this solution as far as possible on all parts the battery housing is sprayed.

Erfindungsgemäß behandelte Kunststoffteile sind praktisch unempfindlich gegen das Auftreten von mechanischen Spannungen. Es können z. B. Polystyrolbehälter oder Polystyrolteile im Rahmen ihrer normalen Werkstoffestigkeit auch Zug- und Biegeheanspruchungen ausgesetzt werden, welche beispielsweise durch ihren Inhalt oder durch äußere Beanspruchungen hervorgerufen werden. Besonders bewährt hat sich das Verfahren bei Polystyrolgehäusen von Fahrzeugbatterien, die mit dem Schutzüberzug praktisch unempfindlich gegen mechanische Spannungen sind, die z. B. durch Passungstoleranzen, etwa beim Einbau von Elektrodenplatten, oder beim Aufsetzen des Gehäusedeckels auf den Batteriekasten oder durch äußere Spannungen, z. B. bei der Halterung der Batterie oder bei Erschütterungen des Fahrzeugs, auftreten können. Da der Schutzüberzug aus praktisch dem gleichen Kunststoff wie der zu schützende Teil besteht, wird er zweckmäßig unauffällig und in derselben Farbe wie der Grundstoff, z. B. auch farblos, aufgetragen. Die Auftragung kann auch so erfolgen, daß eine vorher glatte Oberfläche des Kunststoffteiles nach Aufbringen des Schutzüberzuges mehr oder weniger aufgerauht ist. Schließlich hat sich besonders bei gegen Kraftstoffbenetzung empfindlichem Polystyrol gezeigt, daß der Überzug auch kraftstoffbeständig ist, so daß sich die nachträgliche Aufbringung von kraftstoffempfindlichen Lack auf einen erfindungsgemäß behandelten kraftstoffempfindlichen Polystyrolteil erübrigt. Plastic parts treated according to the invention are practically insensitive against the occurrence of mechanical stresses. It can e.g. B. polystyrene container or polystyrene parts within the scope of their normal material strength also tensile and bending loads which are exposed, for example, by their content or by external stresses be evoked. The process has proven particularly useful for polystyrene housings of vehicle batteries, which with the protective coating are practically insensitive to mechanical Are tensions z. B. through fit tolerances, for example when installing electrode plates, or when placing the housing cover on the battery box or through external Tensions, e.g. B. when holding the battery or when the vehicle is shaken, may occur. Because the protective cover is made from practically the same plastic as the part to be protected exists, it is expediently inconspicuous and in the same Color like the base material, e.g. B. also colorless, applied. The application can also done so that a previously smooth surface of the plastic part after application the protective coating is more or less roughened. Finally got special shown in polystyrene sensitive to fuel wetting that the coating is also fuel-resistant, so that the subsequent application of fuel-sensitive Paint on a fuel-sensitive polystyrene part treated according to the invention unnecessary.

Claims (1)

PATENTANSPRUCH: Verfahren zum Verhüten oberflächlicher Spannungsrisse bei Gegenständen aus thermoplastischen Kunststoffen, insbesondere Polystyrolgehäusen von Fahrzeugbatterien, dadurch gekennzeichnet, daß der Gegenstand teilweise oder allseitig mit einem dem Kunststoff des Gegenstandes zumindest chemisch verwandten, jedoch weicheren Kunststoff durch Auftragen einer Lösung des Kunststoffs in einem leicht flüchtigen Lösungsmittel überzogen wird. ~~~~~~~ In Betracht gezogene Druckschriften: Deutsche Patentschriften Nr. 549886, 676 179, 767 292; deutsche Patentanmeldung B 1588 IVb/39b; schweizerische Patentschrift Nr. 155 552; USA.-Patentschrift Nr. 2 578 665; deutsches Gebrauchsmuster Nr. 1 627 645. PATENT CLAIM: Method for preventing superficial stress cracks for objects made of thermoplastics, especially polystyrene housings of vehicle batteries, characterized in that the object is partially or on all sides with a material that is at least chemically related to the plastic of the object, however softer plastic by applying a solution of the plastic in one volatile solvent is coated. ~~~~~~~ Publications considered: German Patent Nos. 549886, 676 179, 767 292; German patent application B 1588 IVb / 39b; Swiss Patent No. 155 552; U.S. Patent No. 2,578,665; German utility model No. 1 627 645.
DEB20675A 1952-06-04 1952-06-04 Method for preventing surface stress cracks in objects made of thermoplastics, in particular polystyrene housings of vehicle batteries Pending DE1015359B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEB20675A DE1015359B (en) 1952-06-04 1952-06-04 Method for preventing surface stress cracks in objects made of thermoplastics, in particular polystyrene housings of vehicle batteries

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEB20675A DE1015359B (en) 1952-06-04 1952-06-04 Method for preventing surface stress cracks in objects made of thermoplastics, in particular polystyrene housings of vehicle batteries

Publications (1)

Publication Number Publication Date
DE1015359B true DE1015359B (en) 1957-09-05

Family

ID=6960403

Family Applications (1)

Application Number Title Priority Date Filing Date
DEB20675A Pending DE1015359B (en) 1952-06-04 1952-06-04 Method for preventing surface stress cracks in objects made of thermoplastics, in particular polystyrene housings of vehicle batteries

Country Status (1)

Country Link
DE (1) DE1015359B (en)

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE549886C (en) * 1929-07-13 1932-05-02 Rheinisch Westfaelische Spreng Process for the surface refinement of moldings made from hardened phenol-formaldehyde condensation products
CH155552A (en) * 1931-09-26 1932-06-30 Chem Ind Basel Process for the production of firmly adhering coatings.
DE676179C (en) * 1933-08-31 1939-05-27 Gerhard E Koken Dr Process for covering metal foils with synthetic resin-containing nitrocellulose lacquers
DE1627645U (en) * 1951-07-16 1951-08-30 Peter Josef Moll ELECTRIC COLLECTOR WITH CONTROL WINDOW.
US2578665A (en) * 1947-02-21 1951-12-18 Nash Kelvinator Corp Coated plastic products
DE767292C (en) * 1940-02-03 1952-04-15 Aluminiumwerk Tscheulin G M B Process for the production of coatings from heat-hardenable lacquers

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE549886C (en) * 1929-07-13 1932-05-02 Rheinisch Westfaelische Spreng Process for the surface refinement of moldings made from hardened phenol-formaldehyde condensation products
CH155552A (en) * 1931-09-26 1932-06-30 Chem Ind Basel Process for the production of firmly adhering coatings.
DE676179C (en) * 1933-08-31 1939-05-27 Gerhard E Koken Dr Process for covering metal foils with synthetic resin-containing nitrocellulose lacquers
DE767292C (en) * 1940-02-03 1952-04-15 Aluminiumwerk Tscheulin G M B Process for the production of coatings from heat-hardenable lacquers
US2578665A (en) * 1947-02-21 1951-12-18 Nash Kelvinator Corp Coated plastic products
DE1627645U (en) * 1951-07-16 1951-08-30 Peter Josef Moll ELECTRIC COLLECTOR WITH CONTROL WINDOW.

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