DE1011349B - A glaze-forming coating for ceramic objects by firing and a method for applying foils to ceramic objects - Google Patents
A glaze-forming coating for ceramic objects by firing and a method for applying foils to ceramic objectsInfo
- Publication number
- DE1011349B DE1011349B DEA21621A DEA0021621A DE1011349B DE 1011349 B DE1011349 B DE 1011349B DE A21621 A DEA21621 A DE A21621A DE A0021621 A DEA0021621 A DE A0021621A DE 1011349 B DE1011349 B DE 1011349B
- Authority
- DE
- Germany
- Prior art keywords
- glaze
- ceramic
- objects
- foils
- film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000919 ceramic Substances 0.000 title claims description 14
- 239000011888 foil Substances 0.000 title claims description 13
- 238000000034 method Methods 0.000 title claims description 8
- 239000011248 coating agent Substances 0.000 title claims description 4
- 238000000576 coating method Methods 0.000 title claims description 4
- 238000010304 firing Methods 0.000 title claims description 4
- 239000011230 binding agent Substances 0.000 claims description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- 239000004014 plasticizer Substances 0.000 claims description 6
- 229910010293 ceramic material Inorganic materials 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 229920003002 synthetic resin Polymers 0.000 claims description 4
- 239000000057 synthetic resin Substances 0.000 claims description 4
- 229920001169 thermoplastic Polymers 0.000 claims description 4
- 239000004416 thermosoftening plastic Substances 0.000 claims description 4
- 235000011187 glycerol Nutrition 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 238000003825 pressing Methods 0.000 claims description 3
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 claims description 2
- 229920002678 cellulose Polymers 0.000 claims description 2
- 239000001913 cellulose Substances 0.000 claims description 2
- 239000011247 coating layer Substances 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 230000000694 effects Effects 0.000 claims description 2
- 239000003292 glue Substances 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 239000000976 ink Substances 0.000 claims description 2
- 239000000853 adhesive Substances 0.000 claims 1
- 230000001070 adhesive effect Effects 0.000 claims 1
- 239000000306 component Substances 0.000 claims 1
- 238000004049 embossing Methods 0.000 claims 1
- 239000010410 layer Substances 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000010422 painting Methods 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- 229920000609 methyl cellulose Polymers 0.000 description 2
- 235000010981 methylcellulose Nutrition 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 238000007650 screen-printing Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 108010010803 Gelatin Proteins 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 235000010980 cellulose Nutrition 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/4505—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements characterised by the method of application
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Description
Durch Brennen eine Glasur bildender Überzug für keramische Gegenstände und Verfahren zum Aufbringen von Folien auf keramische Gegenstände Die Herstellung einer Glasurschicht auf keramischen Körpern, die bei Temperaturen von etwa 800 bis 1200° eingebrannt werden soll, wurde bisher in folgender Weise bewirkt: Die Glasurrohstoffe oder auch die Fritten wurden auf nassem Wege gemahlen, und die zu glasierenden Gegenstände, z. B. Wandplatten., durchlaufen entweder einen Flüssigkeitsfilm, werden in die wäßrige Glasuremulsion getaucht oder werden mittels Spritzpistole gespritzt, oder man trocknet die gemahlene Glasur und bepudert die zu glasierenden Teile.A glaze-forming coating for ceramic objects by firing and methods of applying foils to ceramic articles. Manufacture a layer of glaze on ceramic bodies, which is at temperatures of about 800 to 1200 ° is to be baked, was previously effected in the following way: The glaze raw materials or the fries were ground wet, and the objects to be glazed, z. B. wall panels., Either pass through a liquid film, are in the aqueous Glaze emulsion is dipped or sprayed with a spray gun, or you dry it the ground glaze and powder the parts to be glazed.
Die zu glasierenden keramischen Gegenstände sind meist vorgebrannt und porös. Beim Glasieren wird die Flüssigkeit vom Scherben aufgesogen, und nach relativ kurzer Zeit, je nach Glasurauflage, sind die glasierten Gegenstände so trocken, daß sie für weitere Manipulationen mit den Händen angefaßt werden können.The ceramic objects to be glazed are mostly pre-fired and porous. During glazing, the liquid is absorbed by the broken glass, and afterwards relatively short time, depending on the glaze layer, the glazed objects are so dry that that they can be touched with the hands for further manipulation.
Handelt es sich dagegen beim Glasieren um gesinterte Gegenstände, wie Fußbodenplatten oder wetterfeste Wandplatten, so wird das Glasurwasser nicht aufgesogen, sondern die Glasurschicht liegt als dickflüssige Masse auf der Platte und muß nun langsam antrocknen. Dabei müssen die Platten waagerecht liegen, um das Ablaufen der Glasurschicht zu vermeiden, und können erst nach längerer Zeit - je nach Glasurart mitunter erst nach Tagen - weiterverarbeitet werden.If, on the other hand, glazing is a sintered object, like floor panels or weatherproof wall panels, the glaze water will not soaked up, but the glaze layer lies as a viscous mass on the plate and must now slowly dry up. The panels must be horizontal in order to Avoid running off of the glaze layer, and can take a long time - depending Depending on the type of glaze, sometimes only after days - can be further processed.
Beim Glasieren von ungebrannten keramischen Körpern, wie Wandplatten, ergibt sich die Schwierigkeit, daß zwar die Platte das Glasurwasser aufsaugt, doch zu quellen anfängt und dadurch stark an Festigkeit einbüßt, was die weitere Verarbeitung stark erschwert.When glazing unfired ceramic bodies such as wall panels, the difficulty arises that although the plate soaks up the glaze water, it does begins to swell and consequently loses a lot of its strength, which makes further processing very difficult.
Sollen die glasierten Gegenstände auch dekoriert werden, so geschieht das auf folgende Weise: Erstens durch Unterglasurmalerei oder Siebdruck auf den gebrannten Scherben, der dann anschließend transparent glasiert wird; zweitens durch Aufglasurmalerei, Siebschablonendruck oder Abziehbilder auf die glasierten und gebrannten Platten., was einen weiteren Brand erfordert; oder drittens Malen auf die glasierte, jedoch noch nicht gebrannte Platte. Abziehbilder scheiden bei dieser Art der Dekorierung praktisch aus, desgleichen erfordert der Siebschablonendruck besondere Hilfsmittel.If the glazed objects are also to be decorated, this is what happens this in the following way: First, by underglaze painting or screen printing on the fired shards, which are then glazed transparently; second by Overglaze painting, screen stencil printing or decals on the glazed and fired Plates., Which requires another fire; or thirdly, painting on the glazed, but not yet burned plate. Decals differ with this type of decoration practical, and screen stencil printing also requires special aids.
Bekannt sind Verfahren zum Überziehen von Gegenständen mit einer Schicht von Glasur oder Email, wobei diese Schicht vor Aufbringung gepreßt wird. Der Preßling muß dabei der Form der zu überziehenden Oberfläche angepaßt sein. Nach der Her- ; stellung des Preßlings wird dieser auf die betreffende Oberfläche aufgelegt und das Ganze erhitzt, so daß eine feste Verbindung des flachen Preßlings mit der Barunterliegenden Oberfläche entsteht. Man hat dabei auch vorgeschlagen, lediglich das die Glasur bildende Pulver zu einem Körper zu pressen, der der Form der zu überziehenden Oberfläche entspricht. Anschließend wird dann der so gepreßte Körper auf die Oberfläche aufgebracht und erhitzt.Methods are known for coating objects with a layer of glaze or enamel, this layer being pressed before application. The compact must be adapted to the shape of the surface to be coated. After the her- ; position of the compact this is placed on the surface in question and the whole is heated, so that a firm connection of the flat pressed part with the bar below Surface is created. It has also been suggested that only the glaze be used to press the forming powder into a body that corresponds to the shape of the surface to be coated is equivalent to. The body pressed in this way is then applied to the surface and heated.
Die Erfindung stellt sich die Aufgabe, eine völlig neue Art des Glasierens und Dekorierens von keramischen Gegenständen zu schaffen, bei der die obengenannten Nachteile nicht vorhanden sind.The invention sets itself the task of a completely new type of glazing and decorating ceramic objects in which the above There are no disadvantages.
Die Erfindung besteht darin, daß die lediglich aus gemahlenen Glasurbestandteilen bzw. pulverförmigen keramischen Stoffen oder deren Mischungen und einem Bindemittel bestehende, ungepreßte Überzugsschicht durch Zusatz eines Weichmachers als biegsame Folie ausgebildet ist, die erst nach Auflegen auf den zu überziehenden Gegenstand mit diesem bei 600 bis 1200° C gebrannt wird.The invention consists in that the only ground glaze components or powdery ceramic materials or mixtures thereof and a binder existing, uncompressed coating layer by adding a plasticizer as a flexible one Foil is formed, which only after it has been placed on the object to be coated is fired with this at 600 to 1200 ° C.
Die Erfindung besteht ferner darin, daß als Bindemittel für die überwiegend aus gemahlenen Glasurbestandteilen (Roh- oder Fritteglasur) bestehende Folie Kunstharze, thermoplastische Massen, Zelluloseleim od. dgl. verwendet sind und daß die ungepreßte Masse als Weichmacher Glyzerin, Trikresylphosphat u. ä. enthält.The invention also consists in that as a binder for the predominantly Foil consisting of ground glaze components (raw or fritted glaze) synthetic resins, Thermoplastic masses, cellulose glue or the like. Are used and that the uncompressed The mass contains glycerine, tricresyl phosphate and the like as a plasticizer.
Weitere Erfindungsmerkmale bestehen in den besonderen Ausbildungen der Folie zur Erzielung verschiedener Glasureffekte.Further features of the invention consist in the special training the film to achieve various glaze effects.
Erfindungsgemäß besteht die Folie aus gemahlenen Glasurbestandteilen, Roh- oder Fritteglasuren oder pulverförmigen keramischen Stoffen bzw. aus Mischungen von Glasurbestandteilen und pulverisierten keramischen Stoffen. Das Gemenge wird mittels geeigneter Binde- bzw. Verdickungsmittel, z. B. Methylzellulosen, thermoplastischen .Massen u. a., und Weichmachungsmitteln in geringen Zusätzen,- 5 bis 20%, verdickt und mittels geeigneter Maschinen zu einer biegsamen Folie nach Art von Kunstharzfolien aufgearbeitet. - - -Diese geschmeidige, jedoch in sich feste Glasurfolie kann nun entweder in entsprechende Stücke geschnitten auf die zu- glasierenden Teile gelegt und normal im Ofen je nach Art der-Glasurkomponenten bei 600 bis 1200° gebrannt werden. Hierbei fällt besonders bei glasierten Gegenständen der Zeitverlust" durch das Auftrocknen der dicken Glasurschicht fort.According to the invention, the film consists of ground glaze components, Raw or frit glazes or powdered ceramic materials or mixtures of glaze components and powdered ceramic materials. The mix becomes by means of suitable binders or thickeners, e.g. B. methyl celluloses, thermoplastic .Masses, among other things, and plasticizers in small additions, - 5 to 20%, thickened and by means of suitable machines into a flexible film in the manner of synthetic resin films worked up. - - -This smooth, but inherently firm glaze film can now either cut into appropriate pieces and placed on the parts to be glazed and normally fired in the oven at 600 to 1200 °, depending on the type of glaze components will. In this case, the loss of time "falls through particularly with glazed objects the drying of the thick layer of glaze continues.
Die Folie kann auch beim Pressen der keramischen Körper, z. B. kleinen Mosaiksteinchen, die beim Glasieren erhebliche- Arbeit und Kosten verursachen, entweder unter oder besser über die zu verpressende Masse gelegt werden, wobei beim Pressen durch den Oberstempel gleich die entsprechend großen Stücke aus der Folie herausgestanzt und auf die rohen Körper aufgepreßt werden. Die Körper können dann sofort im Glattofen gebrannt werden: Andererseits läßt sich die Folie auch einfach in entsprechend großen Stücken auf die gepreßten, jedoch ungebrannten Gegenstände auflegen, um im Einbrandverfahren gebrannt zu werden. Bei Verwendung von thermoplastischen Massen als Verdickungsmittel läßt sich die Folie auch durch kurze Wärmebehandlung auf die zu glasierenden Gegenstände »aufschweißen«.The film can also be used when pressing the ceramic body, e.g. B. small Tesserae that cause considerable labor and expense when glazing, either be placed under or better over the mass to be pressed, whereby when pressing the correspondingly large pieces are punched out of the foil by the upper punch and pressed onto the raw body. The bodies can then immediately be put in the smooth oven be fired: On the other hand, the film can also be easily cut into appropriately large sizes Place pieces on the pressed, but unfired objects in order to use the burn-in process to be burned. When using thermoplastic compounds as thickeners the film can also be applied to the objects to be glazed by brief heat treatment "Weld on".
Ferner läßt sich die Folie mittels Siebdruckverfahrens vorher bedrucken und gestattet auf oben beschriebene Weise sogar die Herstellung von dekorierten Platten im Einbrandverfahren.Furthermore, the film can be pre-printed by means of a screen printing process and even allows the production of decorated ones in the manner described above Panels in one-firing process.
Endlich kann die Glasurfolie nach Art der Herstellung von Abziehbildern mit keramischen Farben maschinell bedruckt werden und gibt so die Möglichkeit, die schwierigen Motive mit Halbtönen unter Umgehung von Abziehbildern auf Gegenstände aufzutragen.Finally, the glaze film can be made in the manner of decals can be machine-printed with ceramic inks and thus gives the possibility of the difficult motifs with halftones, bypassing decals on objects to apply.
Als Glasurkoniponente kann jede gewünschte, bisher in der normalen Produktion benutzte Majolika-, Weiß-, Elfenbein- und Craquele-; betupfte oder bestreute, glänzende oder matte Glasur verwendet werden.Any desired glaze component can be used as a glaze component, previously in the normal Production used majolica, white, ivory and craquelure; dabbed or sprinkled, glossy or matte glaze can be used.
Als: -Verdickungsmittel können je nach Verwendungsart alle möglichen wasserlöslichen Methylzellulosen, Gelatinearten oder bei wasserunlöslichen Filmen in organischen Lösungsmitteln gelöste Kunstharze dienen, die ohne Rückstand verbrennen. Als Weichmacher kann Glyzerin genommen werden.As: -Thickeners can be all possible depending on the type of use water-soluble methyl celluloses, types of gelatin or in the case of water-insoluble films Synthetic resins dissolved in organic solvents that burn without residue are used. Glycerine can be used as a plasticizer.
Claims (7)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEA21621A DE1011349B (en) | 1954-11-25 | 1954-11-25 | A glaze-forming coating for ceramic objects by firing and a method for applying foils to ceramic objects |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEA21621A DE1011349B (en) | 1954-11-25 | 1954-11-25 | A glaze-forming coating for ceramic objects by firing and a method for applying foils to ceramic objects |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1011349B true DE1011349B (en) | 1957-06-27 |
Family
ID=6924980
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEA21621A Pending DE1011349B (en) | 1954-11-25 | 1954-11-25 | A glaze-forming coating for ceramic objects by firing and a method for applying foils to ceramic objects |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE1011349B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2364206A1 (en) * | 1972-12-27 | 1974-07-11 | Toppan Printing Co Ltd | Process for making ceramic from particulate sheet material using cationic wood pulp |
| DE19951483A1 (en) * | 1998-11-07 | 2000-07-27 | Stephan Chung | Flat glass is patterned with ice crystals and pigment by transfer from accommodation plate chambers through a pattern plate onto an adhesive coated glass sheet |
| DE10232858B4 (en) * | 2001-08-22 | 2006-04-06 | AEG Hausgeräte GmbH | Method for producing an at least partially enamelled component and use of this component |
| ITUA20162488A1 (en) * | 2016-04-11 | 2017-10-11 | Paola Lenti S R L | PROCEDURE FOR OBTAINING A STRATIFIED COMPOSITE AND RELATIVE LASER |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AT166245B (en) * | ||||
| CH256194A (en) * | 1943-12-31 | 1948-08-15 | Philips Nv | Process for coating objects with a glaze. |
-
1954
- 1954-11-25 DE DEA21621A patent/DE1011349B/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AT166245B (en) * | ||||
| CH256194A (en) * | 1943-12-31 | 1948-08-15 | Philips Nv | Process for coating objects with a glaze. |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2364206A1 (en) * | 1972-12-27 | 1974-07-11 | Toppan Printing Co Ltd | Process for making ceramic from particulate sheet material using cationic wood pulp |
| DE19951483A1 (en) * | 1998-11-07 | 2000-07-27 | Stephan Chung | Flat glass is patterned with ice crystals and pigment by transfer from accommodation plate chambers through a pattern plate onto an adhesive coated glass sheet |
| DE19951483C2 (en) * | 1998-11-07 | 2002-03-21 | Stephan Chung | Process for applying multicolored patterns from glass granules (crystal ice) to glass plates |
| DE10232858B4 (en) * | 2001-08-22 | 2006-04-06 | AEG Hausgeräte GmbH | Method for producing an at least partially enamelled component and use of this component |
| ITUA20162488A1 (en) * | 2016-04-11 | 2017-10-11 | Paola Lenti S R L | PROCEDURE FOR OBTAINING A STRATIFIED COMPOSITE AND RELATIVE LASER |
| EP3231783A1 (en) * | 2016-04-11 | 2017-10-18 | Paola Lenti S.r.l. | Process for obtaining a multilayer plate of composite material and composite multilayer plate obtained therefrom |
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