CO4790171A1 - NEW INDENONAFTOPIRANOS CONDENSED HETEROCICLICOS PHOTOCROMICOS - Google Patents
NEW INDENONAFTOPIRANOS CONDENSED HETEROCICLICOS PHOTOCROMICOSInfo
- Publication number
- CO4790171A1 CO4790171A1 CO97033497A CO97033497A CO4790171A1 CO 4790171 A1 CO4790171 A1 CO 4790171A1 CO 97033497 A CO97033497 A CO 97033497A CO 97033497 A CO97033497 A CO 97033497A CO 4790171 A1 CO4790171 A1 CO 4790171A1
- Authority
- CO
- Colombia
- Prior art keywords
- substituted
- mono
- alkyl
- hydrogen
- unsubstituted
- Prior art date
Links
- -1 indenonaphthopyran compound Chemical class 0.000 abstract 11
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 abstract 5
- 229910052739 hydrogen Inorganic materials 0.000 abstract 5
- 239000001257 hydrogen Substances 0.000 abstract 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 5
- 125000001624 naphthyl group Chemical group 0.000 abstract 4
- 125000004191 (C1-C6) alkoxy group Chemical group 0.000 abstract 2
- IANQTJSKSUMEQM-UHFFFAOYSA-N 1-benzofuran Chemical compound C1=CC=C2OC=CC2=C1 IANQTJSKSUMEQM-UHFFFAOYSA-N 0.000 abstract 2
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 abstract 2
- 125000000623 heterocyclic group Chemical class 0.000 abstract 2
- 125000003884 phenylalkyl group Chemical group 0.000 abstract 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 2
- 125000006274 (C1-C3)alkoxy group Chemical group 0.000 abstract 1
- 125000002490 anilino group Chemical group [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 abstract 1
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 1
- 125000001153 fluoro group Chemical group F* 0.000 abstract 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- UEOGLANRPZAEAC-UHFFFAOYSA-N indeno-naphthopyran Chemical compound O1C=CC=C2C3=C4C=C(C=CC=C5)C5=C4C=CC3=CC=C21 UEOGLANRPZAEAC-UHFFFAOYSA-N 0.000 abstract 1
- PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Natural products CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 abstract 1
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Natural products C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 abstract 1
- 125000004573 morpholin-4-yl group Chemical group N1(CCOCC1)* 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 125000000587 piperidin-1-yl group Chemical group [H]C1([H])N(*)C([H])([H])C([H])([H])C([H])([H])C1([H])[H] 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/20—Filters
- G02B5/22—Absorbing filters
- G02B5/23—Photochromic filters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K9/00—Tenebrescent materials, i.e. materials for which the range of wavelengths for energy absorption is changed as a result of excitation by some form of energy
- C09K9/02—Organic tenebrescent materials
Landscapes
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
Un compuesto de indenonaftopirano representado porlas siguientes fórmulas gráficas:donde,a) A es un anillo heterocíclico sin sustituir, mono- sustituido o di-sustituido seleccionado queconsiste en benzotieno, benzofurano e indol, estando las posiciones 2, 3 ó 3, 2 de dicho anilloheterocíclico condensadas con el aldo g, h, y, n, o ó p del indenonaftopirano. Entre los ejemplosde sustituyentes del anillo heterocíclico descrito se incluyen alquilo de C1 -C6 , cicloalquilo de C5 -C7 , alcoxi de C1 -C6 , bromo-, cloro- o fluoro-.(b) R1 es hidrógeno, hidroxi, bromo-, fluoro- o cloro- y R2 es el grupo -CH(V)2 , donde V es -CNo -COOR5 , y cada R5 es hidrógeno, alquilo de C1 -C6 , fenilalquilo (C1 -C3 ), fenilalquilo (C1 -C3 ) monoalquil (C1 -C6 )-sustituido, fenilalquilo (C1 -C3 ) monoalcoxi (C1 -C6 )-sustituido o los grupos arilo sin sustituir, mono- o di- sustituidos fenilo o naftilo, o R2 es el grupo -CH(R6 ) Y, donde R6 es hidrógeno, alquilo de C1 -C6 o los grupos arilo sin sustituir, mono- o di- sustituidos fenilo o naptilo, e Y es -COOR5 , -COR7 , o -CH2 OR11 , donde R7 es fenilo o naftilo, e Y es -COOR5 , -COR7 , o -CH2 OR11 , donde R7 es hidrógeno, alquilo de C1 -C6 , los grupos arilo sin sustituir, mono- o di- sustituidos fenilo o naftilo, amino, monoalquil (C1 -C6 ) amino, dialquil (C1 -C6 ) amino, fenilamino, fenilamino mono- o di- alquil (C1 -C6 ) -sustituido, fenilamino mono- o di- alcoxi (C1 -C6 ) -sustituido, difenilamino, difenilamino mono- o di- alquil (C1 -C6 ) -sustituido, difenilamino mono- o di- alcoxi (C1 -C6 )- sustituido, morfolino o piperidino; R11 es hidrógeno, -COR5 , alquilode C1 -C6 , alcoxi (C1 -C3 ) alquilo (C1 -C6 ) - sustituido, o los grupos arilo sin sustituir, mono- o di-sustituidos fenilo o naftilo, siendo todos los sustituyentes de dicho grupo arilo alquilo de C1 -C6 o alcoxi de C1 -C6 ; o(c) R1 y R2 forman juntos el grupo =C(V)2 o =C(R6 )W, donde W es -COOR5 o -COR7 ,(d) R3 y R4 son cada uno alquilo de C1 -C6 ,...An indenonaphthopyran compound represented by the following graphical formulas: where, a) A is a selected unsubstituted, mono-substituted or di-substituted heterocyclic ring consisting of benzothiene, benzofuran and indole, positions 2, 3 or 3, 2 of said heterocyclic ring condensed with the aldo g, h, y, n, o or p of the indenonaphthopyran. Examples of the described heterocyclic ring substituents include C1-C6 alkyl, C5-C7 cycloalkyl, C1-C6 alkoxy, bromo-, chloro- or fluoro-. (B) R1 is hydrogen, hydroxy, bromo-, fluoro - or chloro- and R2 is the group -CH (V) 2, where V is -CNo -COOR5, and each R5 is hydrogen, C1-C6 alkyl, phenylalkyl (C1-C3), phenylalkyl (C1-C3) monoalkyl (C1-C6) -substituted, phenyl (C1-C3) alkyl monoalkoxy (C1-C6) -substituted or unsubstituted, mono- or di-substituted phenyl or naphthyl groups, or R2 is the group -CH (R6) Y , where R6 is hydrogen, C1-C6 alkyl or unsubstituted, mono- or di-substituted phenyl or naptyl groups, and Y is -COOR5, -COR7, or -CH2 OR11, where R7 is phenyl or naphthyl, and Y is -COOR5, -COR7, or -CH2 OR11, where R7 is hydrogen, C1-C6 alkyl, unsubstituted, mono- or di-substituted phenyl or naphthyl groups, amino, (C1-C6) monoalkyl amino, dialkyl (C1-C6) amino, phenylamino, phenylamino mono- or di - (C 1 -C 6) -alkyl-substituted, phenylamino mono- or di-C 1 -C 6) -substituted, diphenylamino, diphenylamino mono- or di-C 1 -C 6) -substituted, diphenylamino mono- or di-alkoxy ( C1-C6) - substituted, morpholino or piperidino; R11 is hydrogen, -COR5, C1-C6 alkylode, (C1-C3) alkoxy (C1-C6) -substituted alkyl, or unsubstituted, mono- or di-substituted phenyl or naphthyl groups, all substituents of said aryl group C1-C6 alkyl or C1-C6 alkoxy; or (c) R1 and R2 together form the group = C (V) 2 o = C (R6) W, where W is -COOR5 or -COR7, (d) R3 and R4 are each C1-C6 alkyl,. ..
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US66694296A | 1996-06-17 | 1996-06-17 | |
| US08/783,343 US5698141A (en) | 1996-06-17 | 1997-01-16 | Photochromic heterocyclic fused indenonaphthopyrans |
| US08/819,969 US5723072A (en) | 1996-06-17 | 1997-03-18 | Photochromic heterocyclic fused indenonaphthopyrans |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CO4790171A1 true CO4790171A1 (en) | 1999-05-31 |
Family
ID=24676161
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CO97033497A CO4790171A1 (en) | 1996-06-17 | 1997-06-17 | NEW INDENONAFTOPIRANOS CONDENSED HETEROCICLICOS PHOTOCROMICOS |
Country Status (2)
| Country | Link |
|---|---|
| CO (1) | CO4790171A1 (en) |
| ZA (1) | ZA975175B (en) |
-
1997
- 1997-06-11 ZA ZA975175A patent/ZA975175B/en unknown
- 1997-06-17 CO CO97033497A patent/CO4790171A1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ZA975175B (en) | 1998-12-11 |
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