CO4560388A1 - RECOVERY OF NICKEL AND COBALT FROM LATERITE MINES - Google Patents
RECOVERY OF NICKEL AND COBALT FROM LATERITE MINESInfo
- Publication number
- CO4560388A1 CO4560388A1 CO95061791A CO95061791A CO4560388A1 CO 4560388 A1 CO4560388 A1 CO 4560388A1 CO 95061791 A CO95061791 A CO 95061791A CO 95061791 A CO95061791 A CO 95061791A CO 4560388 A1 CO4560388 A1 CO 4560388A1
- Authority
- CO
- Colombia
- Prior art keywords
- nickel
- cobalt
- solution
- range
- recovery
- Prior art date
Links
- 229910017052 cobalt Inorganic materials 0.000 title abstract 4
- 239000010941 cobalt Substances 0.000 title abstract 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 title abstract 4
- 238000011084 recovery Methods 0.000 title abstract 2
- 229910001710 laterite Inorganic materials 0.000 title 1
- 239000011504 laterite Substances 0.000 title 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 12
- 229910052759 nickel Inorganic materials 0.000 abstract 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 4
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 abstract 1
- 101000936911 Chionoecetes opilio Sarcoplasmic/endoplasmic reticulum calcium ATPase Proteins 0.000 abstract 1
- QXZUUHYBWMWJHK-UHFFFAOYSA-N [Co].[Ni] Chemical compound [Co].[Ni] QXZUUHYBWMWJHK-UHFFFAOYSA-N 0.000 abstract 1
- 238000010521 absorption reaction Methods 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 238000005868 electrolysis reaction Methods 0.000 abstract 1
- 238000005342 ion exchange Methods 0.000 abstract 1
- 239000003456 ion exchange resin Substances 0.000 abstract 1
- 229920003303 ion-exchange polymer Polymers 0.000 abstract 1
- 150000002500 ions Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 abstract 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/04—Obtaining nickel or cobalt by wet processes
- C22B23/0476—Separation of nickel from cobalt
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Electrolytic Production Of Metals (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
UN PROCESO PARA RECUPERAR DE MANERA SELECTIVA NI- QUEL POR MEDIO DE ABSORCION DE INTERCAMBIO DE ION A PARTIRDE UNA SOLUCION DE ALIMENTACION DE ACIDO SULFURICO CON Ni/Co QUE CONTIENE NIQUEL EN EL RAN- GO DE 0,5 A 40 g/l Y COBALTO EN EL RANGO ENTRE 0.01 Y 2 g/l COMO SULFATOS QUE COMPRENDEN, PONER EN CONTACTO DICHA SOLUCION ACIDA A UN pH QUE ESTA EN EL RANGO ENTRE 0.3 A 6 CON UNA CAMA DE RE- SINA DE INTERCAMBIO DE ION PROTONAZADA EN LA CUAL LOS PROTONES DE LA MISMA SON INTERCAMBIABLE CON IO NES DE NIQUEL EN DICHA SOLUCION DURANTE EL INTERCA MBIO DE ION, EXTRACTAR DE UNA MANERA SELECTIVA DICHO NIQUEL EN PREFERENCIA AL COBALTO DESDE DICHA SOLUCION CON UN pH DE MENOS QUE CERCA DE 2, FORMANDO UN REFINADO QUE CONTIENE DICHO COBALTO, Y LUEGO REMOVER EL NIQUEL ABSORBIDO DESDE DICHA RE SINA CON ACIDO SULFURICO PARA FORMAR UNA SOLUCION DE SULFATO DE NIQUEL CARACTERIZADO POR UNA PROPOR- CION DE NIQUEL A COBALTO DE SERCA DE 50.1 ADECUADA PARA LA RECUPERACION DE NIQUEL SUBSTANCIALMENTE PU RO POR MEDIO DE ELECTROLISIS. VER FIGURA 1.A PROCESS TO SELECTIVELY RECOVER NICKEL BY MEANS OF ION EXCHANGE ABSORPTION FROM A Ni / Co SULFURIC ACID FEEDING SOLUTION CONTAINING NICKEL IN THE RANGE OF 0.5 TO 40 g / l AND COBALT IN THE RANGE BETWEEN 0.01 AND 2 g / l AS SULPHATES THAT UNDERSTAND, TO CONTACT SUCH ACID SOLUTION AT A pH THAT IS IN THE RANGE BETWEEN 0.3 TO 6 WITH A PROTONED ION EXCHANGE RESIN BED IN WHICH THE PROTONS THEY ARE INTERCHANGEABLE WITH IO NES OF NICKEL IN SUCH SOLUTION DURING THE EXCHANGE OF ION, TO EXTRACT IN A SELECTIVE WAY NICHEL IN PREFERENCE TO COBALT FROM SUCH A SOLUTION WITH A pH OF LESS THAN 2, FORMING A REFINED THAN WITH COBALT, AND THEN REMOVE THE NICKEL ABSORBED FROM SUCH KINGDOM WITH SULFURIC ACID TO FORM A NICKEL SULPHATE SOLUTION CHARACTERIZED BY A PROPORTION OF 50.1 SERCA NICKEL COBALT BY THE RECOVERY OF SUBSTANTIAL NICKEL. OR OF ELECTROLYSIS. SEE FIGURE 1.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US36489294A | 1994-12-27 | 1994-12-27 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CO4560388A1 true CO4560388A1 (en) | 1998-02-10 |
Family
ID=23436550
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CO95061791A CO4560388A1 (en) | 1994-12-27 | 1995-12-27 | RECOVERY OF NICKEL AND COBALT FROM LATERITE MINES |
Country Status (6)
| Country | Link |
|---|---|
| AU (1) | AU699127B2 (en) |
| BR (1) | BR9510115A (en) |
| CO (1) | CO4560388A1 (en) |
| CU (1) | CU22611A3 (en) |
| OA (1) | OA10492A (en) |
| WO (1) | WO1996020291A1 (en) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AUPO837197A0 (en) * | 1997-08-01 | 1997-08-28 | Centaur Mining & Exploration Limited | Selective precipitation of nickel and cobalt |
| US20010001650A1 (en) * | 1999-03-09 | 2001-05-24 | William P.C. Duyvesteyn | Recovery of nickel and cobalt from ore |
| US6350420B1 (en) * | 1999-10-15 | 2002-02-26 | Bhp Minerals International, Inc. | Resin-in-pulp method for recovery of nickel and cobalt |
| US6261527B1 (en) * | 1999-11-03 | 2001-07-17 | Bhp Minerals International Inc. | Atmospheric leach process for the recovery of nickel and cobalt from limonite and saprolite ores |
| EP1841891A4 (en) * | 2004-12-30 | 2008-06-25 | Bhp Billiton Ssm Tech Pty Ltd | Extraction of nickel and cobalt from a resin eluate stream |
| BRPI0604853B1 (en) * | 2006-10-27 | 2016-03-08 | Vale Do Rio Doce Co | Method for the production of metallic cobalt from nickel solvent extraction refining |
| AU2008251010B2 (en) * | 2007-05-14 | 2012-07-12 | Cerro Matoso Sa | Nickel recovery from a high ferrous content laterite ore |
| US20090056502A1 (en) * | 2007-08-29 | 2009-03-05 | Vale Inco Limited | Hydrometallurgical process for recovery of nickel and cobalt |
| BRPI0909875A2 (en) * | 2008-06-13 | 2019-03-06 | Murrin Murrin Operations Pty Ltd | rheological method for hydrometallurgical recovery of base metals from ores and method for improving rheological characteristics of a laterite or other oxide ore |
| US20120204680A1 (en) * | 2011-02-11 | 2012-08-16 | Emc Metals Corporation | System and Method for Recovery of Nickel Values From Nickel-Containing Ores |
| US9068247B2 (en) | 2012-05-01 | 2015-06-30 | Dow Global Technologies Llc | Nickel and cobalt recovery using continuous ion exchange |
| WO2014025568A1 (en) | 2012-08-06 | 2014-02-13 | Dow Global Technologies Llc | Recovery of nickel using integrated continuous ion exchange and electo-winning process |
| US10604414B2 (en) | 2017-06-15 | 2020-03-31 | Energysource Minerals Llc | System and process for recovery of lithium from a geothermal brine |
| US11365128B2 (en) | 2017-06-15 | 2022-06-21 | Energysource Minerals Llc | Process for selective adsorption and recovery of lithium from natural and synthetic brines |
| AU2018363879B2 (en) * | 2017-11-10 | 2024-06-13 | Bhp Billiton Nickel West Pty Ltd | Production of high purity nickel sulfate |
| CN111270070A (en) * | 2018-12-04 | 2020-06-12 | 格林美（江苏）钴业股份有限公司 | Washing method and device for P507 cobalt extraction system |
| JP7607760B2 (en) * | 2020-10-14 | 2024-12-27 | エルジー エナジー ソリューション リミテッド | Method for producing high nickel positive electrode active material |
| US12286686B2 (en) | 2021-02-24 | 2025-04-29 | Sherritt International Corporation | Co-processing of copper sulphide concentrate with nickel laterite ore |
| CN113526576B (en) * | 2021-05-31 | 2022-06-03 | 金川集团股份有限公司 | A kind of preparation method of nickel sulfate solution with high nickel, low acid and low sodium |
| WO2025227101A1 (en) * | 2024-04-25 | 2025-10-30 | Andrew Harley | Fertilizer and production method |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE790141A (en) * | 1971-10-19 | 1973-04-16 | Duisburger Kupferhuette | PROCESS FOR SEPARATING NICKEL AND / OR COBALT FROM MANGANESE |
| US3991159A (en) * | 1975-01-09 | 1976-11-09 | Amax Inc. | High temperature neutralization of laterite leach slurry |
| US3998924A (en) * | 1975-08-04 | 1976-12-21 | The Dow Chemical Company | Recovery of non-ferrous metals from acidic liquors with a chelate exchange resin in presence of iron(III) |
| US4320099A (en) * | 1980-07-28 | 1982-03-16 | Inco Limited | Process for nickel removal from concentrated aqueous cobaltous sulfate solutions |
| JPH0765127B2 (en) * | 1986-03-29 | 1995-07-12 | ミヨシ油脂株式会社 | Cobalt separation and recovery method |
| AU701811B2 (en) * | 1994-10-05 | 1999-02-04 | Billiton Intellectual Property B.V. | Recovery of nickel |
-
1995
- 1995-12-13 BR BR9510115A patent/BR9510115A/en not_active Application Discontinuation
- 1995-12-13 AU AU45153/96A patent/AU699127B2/en not_active Ceased
- 1995-12-13 WO PCT/US1995/016118 patent/WO1996020291A1/en not_active Ceased
- 1995-12-20 CU CU1995138A patent/CU22611A3/en not_active IP Right Cessation
- 1995-12-27 CO CO95061791A patent/CO4560388A1/en unknown
-
1997
- 1997-06-18 OA OA70028A patent/OA10492A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| OA10492A (en) | 2002-04-10 |
| CU22611A3 (en) | 2000-02-10 |
| BR9510115A (en) | 1997-12-30 |
| WO1996020291A1 (en) | 1996-07-04 |
| AU699127B2 (en) | 1998-11-26 |
| AU4515396A (en) | 1996-07-19 |
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