[go: up one dir, main page]

CO2022008695A2 - Proceso selectivo y catalizadores para la producción de combustibles y destilados renovables de alto peso molecular - Google Patents

Proceso selectivo y catalizadores para la producción de combustibles y destilados renovables de alto peso molecular

Info

Publication number
CO2022008695A2
CO2022008695A2 CONC2022/0008695A CO2022008695A CO2022008695A2 CO 2022008695 A2 CO2022008695 A2 CO 2022008695A2 CO 2022008695 A CO2022008695 A CO 2022008695A CO 2022008695 A2 CO2022008695 A2 CO 2022008695A2
Authority
CO
Colombia
Prior art keywords
molecular weight
high molecular
catalysts
bioqav
kerosene
Prior art date
Application number
CONC2022/0008695A
Other languages
English (en)
Inventor
Jefferson Roberto Gomes
José Luiz Zotin
Almeida Lyra Correa Anilza De
Pacheco Marcelo Edral
Chistone Rodrigo Caetano
Original Assignee
Petroleo Brasileiro Sa Petrobras
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Petroleo Brasileiro Sa Petrobras filed Critical Petroleo Brasileiro Sa Petrobras
Publication of CO2022008695A2 publication Critical patent/CO2022008695A2/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/50—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids in the presence of hydrogen, hydrogen donors or hydrogen generating compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C10G3/45—Catalytic treatment characterised by the catalyst used containing iron group metals or compounds thereof
    • C10G3/46—Catalytic treatment characterised by the catalyst used containing iron group metals or compounds thereof in combination with chromium, molybdenum, tungsten metals or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/30—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/76—Iron group metals or copper
    • B01J29/7615—Zeolite Beta
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/78—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J29/7815—Zeolite Beta
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • C10G47/16—Crystalline alumino-silicate carriers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/20—After treatment, characterised by the effect to be obtained to introduce other elements in the catalyst composition comprising the molecular sieve, but not specially in or on the molecular sieve itself
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/16—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J29/166—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/78—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J29/7884—TON-type, e.g. Theta-1, ISI-1, KZ-2, NU-10 or ZSM-22
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1003—Waste materials
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02—Gasoline
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/04—Diesel oil
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

La presente invención se refiere a un proceso para convertir aceites vegetales, grasas animales, aceites comestibles residuales y ácidos carboxílicos en combustibles líquidos renovables, tales como bionafta, bioQAV y diesel renovable, para su uso en mezcla con combustibles fósiles. El proceso consta de dos etapas: hidrotratamiento e hidrocraqueo. El efluente de la etapa de hidratación contiene aromáticos, olefinas y compuestos resultantes de la polimerización de ésteres y ácidos en su composición. Este hecho se produce debido al uso de catalizadores parcialmente reducidos y sin inyección de agente sulfuro y permite la obtención de un bioQAV con calidad adecuada para su uso en mezcla con querosene fósil. Al mismo tiempo, el proceso genera, además de productos en el rango de destilación de nafta, querosene y diesel, parafinas lineales de alto peso molecular (con hasta 40 átomos de carbono).
CONC2022/0008695A 2019-12-20 2022-06-22 Proceso selectivo y catalizadores para la producción de combustibles y destilados renovables de alto peso molecular CO2022008695A2 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
BR102019027610-0A BR102019027610B1 (pt) 2019-12-20 2019-12-20 Processo seletivo para produção de combustíveis e destilados parafínicos de alto peso molecular renováveis e combustível
PCT/BR2020/050548 WO2021119786A1 (pt) 2019-12-20 2020-12-15 Processo seletivo e catalisadores para produção de combustíveis e destilados de alto peso molecular renováveis

Publications (1)

Publication Number Publication Date
CO2022008695A2 true CO2022008695A2 (es) 2022-06-30

Family

ID=75920482

Family Applications (1)

Application Number Title Priority Date Filing Date
CONC2022/0008695A CO2022008695A2 (es) 2019-12-20 2022-06-22 Proceso selectivo y catalizadores para la producción de combustibles y destilados renovables de alto peso molecular

Country Status (9)

Country Link
US (1) US11939535B2 (es)
EP (1) EP4079826A4 (es)
AR (1) AR120815A1 (es)
BR (1) BR102019027610B1 (es)
CA (1) CA3162442A1 (es)
CL (1) CL2022001695A1 (es)
CO (1) CO2022008695A2 (es)
PE (1) PE20230498A1 (es)
WO (1) WO2021119786A1 (es)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022040766A1 (pt) 2020-08-24 2022-03-03 Petróleo Brasileiro S.A. - Petrobras Catalisadores e processo seletivo para produção de combustíveis de aviação renováveis e biocombustível produzido
KR20230135765A (ko) * 2022-03-17 2023-09-26 에스케이이노베이션 주식회사 폐플라스틱 열분해유로부터 항공 연료를 제조하는 방법 및 제조 장치

Family Cites Families (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2163563A (en) 1935-02-16 1939-06-20 Deutsche Hydrierwerke Ag Method of reclaiming mineral oils
US4032431A (en) 1968-07-25 1977-06-28 Mobil Oil Corporation Shape selective naphtha processing
US3700585A (en) 1969-10-10 1972-10-24 Mobil Oil Corp Dewaxing of oils by shape selective cracking and hydrocracking over zeolites zsm-5 and zsm-8
US3849290A (en) 1972-08-02 1974-11-19 Mobil Oil Corp Upgrading of reformates by catalyst compositions selective for cracking low and high boiling paraffin components
US3894938A (en) 1973-06-15 1975-07-15 Mobil Oil Corp Catalytic dewaxing of gas oils
US3950241A (en) 1974-06-24 1976-04-13 Mobil Oil Corporation Method for upgrading a wide cut naphtha to full range gasoline
US4141859A (en) 1974-09-04 1979-02-27 Mobil Oil Corporation Novel reforming catalysts
US4181598A (en) 1977-07-20 1980-01-01 Mobil Oil Corporation Manufacture of lube base stock oil
US4176050A (en) 1978-12-04 1979-11-27 Mobil Oil Corporation Production of high V.I. lubricating oil stock
US4222855A (en) 1979-03-26 1980-09-16 Mobil Oil Corporation Production of high viscosity index lubricating oil stock
US4229282A (en) 1979-04-27 1980-10-21 Mobil Oil Corporation Catalytic dewaxing of hydrocarbon oils
US4247388A (en) 1979-06-27 1981-01-27 Mobil Oil Corporation Hydrodewaxing catalyst performance
US4419220A (en) 1982-05-18 1983-12-06 Mobil Oil Corporation Catalytic dewaxing process
US4855530A (en) 1982-05-18 1989-08-08 Mobil Oil Corporation Isomerization process
US4518485A (en) 1982-05-18 1985-05-21 Mobil Oil Corporation Hydrotreating/isomerization process to produce low pour point distillate fuels and lubricating oil stocks
US4827076A (en) 1987-07-16 1989-05-02 Union Oil Company Of California Desulfurization and isomerization of N-paraffins
US4913791A (en) 1987-08-28 1990-04-03 Bios Corporation Blot frame and method of handling
US4992605A (en) 1988-02-16 1991-02-12 Craig Wayne K Production of hydrocarbons with a relatively high cetane rating
US4877581A (en) 1988-09-01 1989-10-31 Mobil Oil Corporation Catalyst for dewaxing hydrocarbon feedstock
GB2237815B (en) 1989-11-06 1994-01-05 Univ Singapore Production of synthetic crude petroleum
US5183556A (en) 1991-03-13 1993-02-02 Abb Lummus Crest Inc. Production of diesel fuel by hydrogenation of a diesel feed
IT1256084B (it) 1992-07-31 1995-11-27 Eniricerche Spa Catalizzatore per la idroisomerizzazione di normal-paraffine a catena lunga e procedimento per la sua preparazione
IT1255526B (it) 1992-09-29 1995-11-09 Eniricerche Spa Procedimento per la preparazione di un catalizzatore efficace nella idroisomerizzazione di normal-paraffine
US20080154168A1 (en) 2003-07-17 2008-06-26 Thomas Placido Lutri Surgical bandage for use with tissue adhesives and other medicaments
BRPI0500591A (pt) 2005-02-18 2006-10-03 Petroleo Brasileiro Sa processo para a hidroconversão de óleos vegetais
BRPI0601403B1 (pt) 2006-04-17 2015-11-03 Petroleo Brasileiro Sa processo de obtenção de n-parafinas a partir de óleo vegetal
BRPI0601460B1 (pt) 2006-04-26 2015-11-10 Petroleo Brasileiro Sa processo para hidroconversão de mistura de óleos orgânicos de diferentes origens
US8742183B2 (en) 2007-12-21 2014-06-03 Uop Llc Production of aviation fuel from biorenewable feedstocks
WO2010028717A2 (en) * 2008-09-10 2010-03-18 Haldor Topsøe A/S Hydroconversion process and catalyst
US8314274B2 (en) 2008-12-17 2012-11-20 Uop Llc Controlling cold flow properties of transportation fuels from renewable feedstocks
BRPI0900789B1 (pt) 2009-04-27 2018-02-06 Petroleo Brasileiro S.a. - Petrobrás Processo de hidrotratamento de óleo de biomassa diluído em corrente de refino de petróleo
CO6290087A1 (es) 2009-12-03 2011-06-20 Ecopetrol Sa Proceso para hidrotratar fracciones pesadas de petroleo mezcladas con aceite vegetal
FI125632B (fi) * 2010-05-25 2015-12-31 Upm Kymmene Corp Menetelmä ja laite hiilivetyjen tuottamiseksi
WO2012162403A1 (en) * 2011-05-23 2012-11-29 Virent, Inc. Production of chemicals and fuels from biomass
FR3012467B1 (fr) 2013-10-24 2015-12-18 IFP Energies Nouvelles Procede optimise de conversion de la biomasse pour la fabrication de bases petrochimiques
CA2982067A1 (en) * 2016-10-07 2018-04-07 Ying Zheng Catalytic process for co-processing of lignocellulosic biomass and heavy petroleum fuels

Also Published As

Publication number Publication date
BR102019027610B1 (pt) 2022-03-08
EP4079826A1 (en) 2022-10-26
US11939535B2 (en) 2024-03-26
CL2022001695A1 (es) 2023-01-20
AR120815A1 (es) 2022-03-23
CA3162442A1 (en) 2021-06-24
EP4079826A4 (en) 2024-01-03
BR102019027610A2 (pt) 2021-05-04
US20230047725A1 (en) 2023-02-16
WO2021119786A1 (pt) 2021-06-24
PE20230498A1 (es) 2023-03-24

Similar Documents

Publication Publication Date Title
US10494579B2 (en) Naphthene-containing distillate stream compositions and uses thereof
Lapuerta et al. Key properties and blending strategies of hydrotreated vegetable oil as biofuel for diesel engines
Eller et al. Advanced production process of jet fuel components from technical grade coconut oil with special hydrocracking
US8017819B2 (en) Thermal treatment of triglycerides
BR112022002166A2 (pt) Composição de hidrocarboneto
CO2022008695A2 (es) Proceso selectivo y catalizadores para la producción de combustibles y destilados renovables de alto peso molecular
KR20080078889A (ko) 탄화수소의 제조방법
Belagur et al. Few physical, chemical and fuel related properties of calophyllum inophyllum linn (honne) oil and its blends with diesel fuel for their use in diesel engine
EP2825619B1 (en) Use of a viscosity improver
Lapuerta et al. Blending scenarios for soybean oil derived biofuels with conventional diesel
NL2006731C2 (en) Diesel engine injector fouling improvements with a highly paraffinic diesel.
AR123310A1 (es) Catalizadores y proceso de selección para la producción de combustibles de aviación renovables y biocombustibles producidos
WO2009135307A1 (en) Biofuel or additive and method of manufacture and use
AR093316A1 (es) Proceso para preparar polimeros dispersantes de bajo contenido de azufre
MY171793A (en) Blending fuels
JP6045385B2 (ja) 軽油基材の製造方法及びその基材を配合した軽油組成物
FI130550B (en) Petrol composition with octane synergy
US10889774B2 (en) Lubricity additive for fuel with a low sulphur content
JP6609749B2 (ja) 軽油組成物の製造方法
RU2008142984A (ru) Способ обработки синтетического масла, способ получения углеводородного масла, углеводородное масло для получения водорода, углеводородное масло для добавки, увеличивающей максимальную высоту некоптящего пламени, для керосина и углеводородное масло для базового компонента дизельного топлива
EA201391424A1 (ru) Способ получения керосинового базового материала и керосиновый базовый материал
FI12194U1 (fi) Polttoainekoostumus
RU2581034C1 (ru) Топливная композиция флотского мазута (варианты)
RU2008137857A (ru) Способ получения дизельного топлива
JP6059573B2 (ja) 脱硫した減圧軽油基材の製造方法及びその基材を配合した軽油組成物