CO2022006642A1 - Dry process to recycle rechargeable lithium ion, lithium polymer and nickel metal hydride batteries and directly recover cobalt, nickel, lithium, manganese, base metals and electrolyte - Google Patents
Dry process to recycle rechargeable lithium ion, lithium polymer and nickel metal hydride batteries and directly recover cobalt, nickel, lithium, manganese, base metals and electrolyteInfo
- Publication number
- CO2022006642A1 CO2022006642A1 CONC2022/0006642A CO2022006642A CO2022006642A1 CO 2022006642 A1 CO2022006642 A1 CO 2022006642A1 CO 2022006642 A CO2022006642 A CO 2022006642A CO 2022006642 A1 CO2022006642 A1 CO 2022006642A1
- Authority
- CO
- Colombia
- Prior art keywords
- lithium
- nickel
- manganese
- cobalt
- metal hydride
- Prior art date
Links
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title abstract 10
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title abstract 6
- 229910052744 lithium Inorganic materials 0.000 title abstract 6
- 229910052759 nickel Inorganic materials 0.000 title abstract 6
- 239000010941 cobalt Substances 0.000 title abstract 4
- 229910017052 cobalt Inorganic materials 0.000 title abstract 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 title abstract 4
- 229920000642 polymer Polymers 0.000 title abstract 3
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 title abstract 2
- 239000010953 base metal Substances 0.000 title abstract 2
- 238000001035 drying Methods 0.000 title abstract 2
- 229910001416 lithium ion Inorganic materials 0.000 title abstract 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 title abstract 2
- 229910052987 metal hydride Inorganic materials 0.000 title abstract 2
- -1 nickel metal hydride Chemical class 0.000 title abstract 2
- 239000003792 electrolyte Substances 0.000 title 1
- 239000000463 material Substances 0.000 abstract 5
- 238000000034 method Methods 0.000 abstract 4
- 239000011244 liquid electrolyte Substances 0.000 abstract 2
- 239000002243 precursor Substances 0.000 abstract 2
- 238000011084 recovery Methods 0.000 abstract 2
- 101100114697 Danio rerio cpeb1 gene Proteins 0.000 abstract 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052748 manganese Inorganic materials 0.000 abstract 1
- 239000011572 manganese Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 238000004064 recycling Methods 0.000 abstract 1
- 239000002699 waste material Substances 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03B—SEPARATING SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS
- B03B9/00—General arrangement of separating plant, e.g. flow sheets
- B03B9/06—General arrangement of separating plant, e.g. flow sheets specially adapted for refuse
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
- B29B17/02—Separating plastics from other materials
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/02—Obtaining nickel or cobalt by dry processes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B26/00—Obtaining alkali, alkaline earth metals or magnesium
- C22B26/10—Obtaining alkali metals
- C22B26/12—Obtaining lithium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B47/00—Obtaining manganese
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/54—Reclaiming serviceable parts of waste accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/52—Reclaiming serviceable parts of waste cells or batteries, e.g. recycling
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Sustainable Development (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Secondary Cells (AREA)
Abstract
La presente invención se relaciona con un proceso en seco para el reciclaje de baterías recargables de litio ion, litio polímero y níquel metal hidruro y para la recuperación directa de cobalto, litio, níquel, manganeso, metales base y electrolito líquido, en donde dicho proceso permite reciclar las baterías recargables de forma segura a través de procesos mecánicos y fisicoquímicos que no producen ni vertimientos ni emisiones contaminantes, además de permitir la recuperación de tres corrientes de materiales (material precursor con alto contenido de cobalto, litio, níquel y manganeso), material zorba (mezcla de metales y polímeros laminares) y electrolito líquido. Una de las principales ventajas de la presente invención se basa en el hecho que con el presente proceso es posible recuperar materiales precursores con alto contenido de elementos clasificados como estratégicos y en peligro de desabastecimiento como el cobalto, el litio y el níquel cuyas proporciones dependen del tipo de batería ingresada. Además, los materiales son recuperados se comercializan para ser utilizados nuevamente en la industria de fabricación de baterías, cerrando el ciclo de vida de estas con un proceso sostenible y circular.The present invention relates to a dry process for the recycling of rechargeable lithium ion, lithium polymer and nickel metal hydride batteries and for the direct recovery of cobalt, lithium, nickel, manganese, base metals and liquid electrolyte, where said process allows rechargeable batteries to be recycled safely through mechanical and physicochemical processes that do not produce waste or polluting emissions, in addition to allowing the recovery of three material streams (precursor material with high content of cobalt, lithium, nickel and manganese), zorba material (mixture of metals and lamellar polymers) and liquid electrolyte. One of the main advantages of the present invention is based on the fact that with the present process it is possible to recover precursor materials with a high content of elements classified as strategic and in danger of shortage such as cobalt, lithium and nickel, whose proportions depend on the type of battery entered. In addition, the recovered materials are marketed to be used again in the battery manufacturing industry, closing their life cycle with a sustainable and circular process.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CONC2022/0006642A CO2022006642A1 (en) | 2022-05-19 | 2022-05-19 | Dry process to recycle rechargeable lithium ion, lithium polymer and nickel metal hydride batteries and directly recover cobalt, nickel, lithium, manganese, base metals and electrolyte |
| PCT/IB2023/054800 WO2023223144A1 (en) | 2022-05-19 | 2023-05-09 | Dry process for recycling lithium-ion rechargeable batteries, lithium-polymer rechargeable batteries and nickel-metal hydride rechargeable batteries and directly recovering cobalt, nickel, lithium, manganese, base metals and electrolyte |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CONC2022/0006642A CO2022006642A1 (en) | 2022-05-19 | 2022-05-19 | Dry process to recycle rechargeable lithium ion, lithium polymer and nickel metal hydride batteries and directly recover cobalt, nickel, lithium, manganese, base metals and electrolyte |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CO2022006642A1 true CO2022006642A1 (en) | 2023-11-20 |
Family
ID=88757730
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CONC2022/0006642A CO2022006642A1 (en) | 2022-05-19 | 2022-05-19 | Dry process to recycle rechargeable lithium ion, lithium polymer and nickel metal hydride batteries and directly recover cobalt, nickel, lithium, manganese, base metals and electrolyte |
Country Status (2)
| Country | Link |
|---|---|
| CO (1) | CO2022006642A1 (en) |
| WO (1) | WO2023223144A1 (en) |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104183855B (en) * | 2013-05-28 | 2017-03-08 | 深圳市泰力废旧电池回收技术有限公司 | A kind of waste battery recovery system and recovery method thereof |
| DE102016120046A1 (en) * | 2016-10-20 | 2018-04-26 | Duesenfeld Gmbh | Recycling process for treating used batteries, especially rechargeable batteries and battery processing equipment |
| CN108011146B (en) * | 2017-11-17 | 2021-04-23 | 四川长虹电器股份有限公司 | Recycling method of waste lithium battery |
| CN208315672U (en) * | 2018-05-16 | 2019-01-01 | 金宇芳 | A kind of recycling and processing device of scrap dry battery |
| CN114497789A (en) * | 2021-11-19 | 2022-05-13 | 陆越自动化科技(上海)有限公司 | Economical ternary lithium battery disassembling and recycling system and method |
-
2022
- 2022-05-19 CO CONC2022/0006642A patent/CO2022006642A1/en unknown
-
2023
- 2023-05-09 WO PCT/IB2023/054800 patent/WO2023223144A1/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| WO2023223144A1 (en) | 2023-11-23 |
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