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CN2913347Y - Arsenic removal device for drinking water based on novel film material - Google Patents

Arsenic removal device for drinking water based on novel film material Download PDF

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Publication number
CN2913347Y
CN2913347Y CN 200520118599 CN200520118599U CN2913347Y CN 2913347 Y CN2913347 Y CN 2913347Y CN 200520118599 CN200520118599 CN 200520118599 CN 200520118599 U CN200520118599 U CN 200520118599U CN 2913347 Y CN2913347 Y CN 2913347Y
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China
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arsenic
drinking water
membrane module
pressure pump
model
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Expired - Fee Related
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CN 200520118599
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Chinese (zh)
Inventor
桑义敏
徐忠厚
谷庆宝
胡华龙
李发生
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Chinese Research Academy of Environmental Sciences
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Chinese Research Academy of Environmental Sciences
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Abstract

本实用新型涉及一种基于新型膜材料的饮用水除砷装置,其包括:进水管;压力泵,与进水管相连;膜组件,通过管道与压力泵相连,该膜组件为静电纺丝氯化聚氯乙烯膜材料层;流量计及压力表,设置于膜组件与压力泵之间的管道上;以及浓缩液排出管及透过液排出管连接于膜组件。本实用新型在去除饮用水中砷的同时,能进一步去除水中的微量悬浮物、细菌等,无二次污染,使用周期长,效果好,成本低,方便各种场合特别是边远高砷区使用。

Figure 200520118599

The utility model relates to a device for removing arsenic from drinking water based on a novel membrane material, which comprises: a water inlet pipe; a pressure pump connected to the water inlet pipe; The polyvinyl chloride membrane material layer; the flow meter and the pressure gauge are arranged on the pipeline between the membrane module and the pressure pump; and the concentrated liquid discharge pipe and the permeated liquid discharge pipe are connected to the membrane module. While removing arsenic in drinking water, the utility model can further remove trace suspended solids and bacteria in the water without secondary pollution, has long service life, good effect and low cost, and is convenient to be used in various occasions, especially remote areas with high arsenic content .

Figure 200520118599

Description

一种基于新型膜材料的饮用水除砷装置A device for removing arsenic from drinking water based on a new membrane material

技术领域technical field

本实用新型涉及一种饮用水处理装置,具体的说是一种地下水砷污染区饮用水除砷装置。The utility model relates to a drinking water treatment device, in particular to a device for removing arsenic from drinking water in groundwater arsenic polluted areas.

背景技术Background technique

现有饮用水除砷装置,多采用向水中加入化学药剂、无机矿物、活性氧化铝、骨炭等药剂或材料进行化学沉淀、  氧化还原或离子交换吸附除砷,不但除砷效率低,产水率低,耗费材料成本高,而且存在易造成二次污染、材料使用周期短、偏远高砷山区或农村使用不便等不利因素。Existing devices for removing arsenic from drinking water mostly use chemical precipitation, redox or ion exchange adsorption to remove arsenic by adding chemical agents, inorganic minerals, activated alumina, bone char and other agents or materials to the water. Low, high material cost, and there are disadvantages such as easy to cause secondary pollution, short material life cycle, remote high-arsenic mountainous areas or inconvenient use in rural areas.

发明内容Contents of the invention

本实用新型的目的是提供一种基于新型膜材料的新型饮用水除砷装置,以克服上述不利因素,提高除砷效率,降低处理成本。The purpose of this utility model is to provide a new drinking water arsenic removal device based on a new membrane material, so as to overcome the above-mentioned unfavorable factors, improve the efficiency of arsenic removal, and reduce the treatment cost.

本实用新型的目的可以通过以下过程得以实现:本实用新型一种基于新型膜材料的饮用水除砷装置,其包括:进水管;压力泵,与进水管相连;膜组件,通过管道与压力泵相连,该膜组件为静电纺丝氯化聚氯乙烯膜材料层;流量计及压力表,设置于膜组件与压力泵之间的管道上;以及浓缩液排出管及透过液排出管连接于膜组件。The purpose of the utility model can be achieved through the following processes: a device for removing arsenic from drinking water based on a novel membrane material of the utility model, which includes: a water inlet pipe; a pressure pump connected to the water inlet pipe; a membrane module connected to the pressure pump through the pipeline The membrane module is an electrospun chlorinated polyvinyl chloride membrane material layer; the flowmeter and pressure gauge are arranged on the pipeline between the membrane module and the pressure pump; and the concentrated liquid discharge pipe and the permeate discharge pipe are connected to the Membrane components.

本实用新型所采用的膜材料由氯化聚氯乙烯经高压静电纺丝技术制成,由超细纳米纤维组成,纳米纤维上又有微孔,比表面积大,能够吸附、过滤一部分悬浮物。由于该膜材料是荷负电型膜材料,根据Donnan平衡模型机理,借助于排斥同离子的能力,能截留、去除以阴离子存在的砷。The membrane material used in the utility model is made of chlorinated polyvinyl chloride through high-voltage electrospinning technology, and is composed of ultrafine nanofibers with micropores and large specific surface area, which can absorb and filter a part of suspended matter. Since the membrane material is a negatively charged membrane material, according to the mechanism of the Donnan equilibrium model, it can retain and remove arsenic in the form of anions by virtue of the ability to repel the same ions.

本实用新型在去除饮用水中砷的同时,能进一步去除水中的微量悬浮物、细菌等,无二次污染,使用周期长,效果好,成本低,方便各种场合特别边远高砷区使用。While removing arsenic in drinking water, the utility model can further remove trace suspended solids and bacteria in the water without secondary pollution, has long service life, good effect and low cost, and is convenient for use in various occasions, especially remote high-arsenic areas.

附图说明Description of drawings

图1为本实用新型装置示意图。Fig. 1 is the schematic diagram of the utility model device.

1:进水管    2:压力泵1: water inlet pipe 2: pressure pump

3:流量计    4:压力表3: Flow meter 4: Pressure gauge

5:膜组件    6:浓缩液排出管5: Membrane module 6: Concentrate discharge pipe

7:透过液排出管7: Permeate discharge pipe

具体实施方式Detailed ways

下面结合附图对本实用新型的任务完成过程做进一步阐述:含砷原水经进水管1进入压力泵吸水口,然后经压力泵2加压后进入流量计3,经流量计3计量后进入膜组件5。在膜组件5中,由于水中砷多以阴离子形式存在,而静电纺丝纳米纤维带负电,属于荷负电型膜材料,根据donnan平衡原理,砷阴离子被阻止在膜材料的一侧不能通过,而无砷水则透过膜,从而达到分离重金属砷的目的。过滤时,浓缩液经浓缩液排出管6排放或回流,根据工艺运行情况而定,透过膜的无砷水经透过液排出管7排出后供用户使用。其中压力表4反应膜组件的运行压力,根据运行压力的变化,可以调整浓缩液排放量等运行参数。The task completion process of the utility model is further elaborated below in conjunction with the accompanying drawings: the arsenic-containing raw water enters the suction port of the pressure pump through the water inlet pipe 1, then enters the flow meter 3 after being pressurized by the pressure pump 2, and enters the membrane module after being measured by the flow meter 3 5. In membrane module 5, since arsenic in water mostly exists in the form of anions, and electrospun nanofibers are negatively charged, they are negatively charged membrane materials. According to the Donnan balance principle, arsenic anions are prevented from passing through one side of the membrane material, while The arsenic-free water passes through the membrane, so as to achieve the purpose of separating heavy metal arsenic. During filtration, the concentrated liquid is discharged or refluxed through the concentrated liquid discharge pipe 6, and the arsenic-free water permeated through the membrane is discharged through the permeate discharge pipe 7 according to the operation of the process for use by users. Among them, the pressure gauge 4 reflects the operating pressure of the membrane module, and according to the change of the operating pressure, the operating parameters such as the concentrated liquid discharge can be adjusted.

以下借助实施例对本实用新型进一步描述。The utility model is further described below by means of examples.

实施例1Example 1

取地下水(浑浊度,1.4度;总硬度(以CaCO3),510mg.L-1;硫酸盐,123.2mg.L-1;硝酸盐(以N计),60.2mg.L-1),直接添加Na2HAsO4配制成实验水样,砷浓度为5.013mg.L-1,经过静电纺丝氯化聚氯乙烯膜材料过滤后,砷的去除率达到50-70%。Take groundwater (turbidity, 1.4 degrees; total hardness (as CaCO 3 ), 510mg.L -1 ; sulfate, 123.2mg.L -1 ; nitrate (as N), 60.2mg.L -1 ), directly Add Na 2 HAsO 4 to make experimental water sample, the concentration of arsenic is 5.013mg.L -1 , and the removal rate of arsenic reaches 50-70% after being filtered by electrostatic spinning chlorinated polyvinyl chloride membrane material.

实施例2Example 2

取地下水(同实施例1),直接添加Na2HAsO4配制成实验水样,砷浓度为0.10mg.L-1,经过静电纺丝氯化聚氯乙烯膜材料过滤后,出水砷的浓度为0.03mg.L-1,去除率达到70%,砷的浓度低于国家饮用水标准(0.05mg.L-1)。Take ground water (same as Example 1), directly add Na 2 HAsO 4 to make experimental water sample, the concentration of arsenic is 0.10 mg.L -1 , after filtering through electrospun chlorinated polyvinyl chloride membrane material, the concentration of arsenic in the effluent is 0.03mg.L -1 , the removal rate reaches 70%, and the concentration of arsenic is lower than the national drinking water standard (0.05mg.L -1 ).

本实用新型的优点:采用带负电荷纳米纤维膜材料作为过滤材料,无需添加化学药剂,使用简单,砷的去除率高,在去除饮用水中砷的同时,能进一步去除水中的微量悬浮物、细菌等,无二次污染,使用周期长,效果好,成本低,方便各种场合特别是边远高砷区使用。The utility model has the advantages of adopting the negatively charged nanofiber membrane material as the filter material, no need to add chemicals, easy to use, high removal rate of arsenic, while removing arsenic in drinking water, it can further remove trace suspended solids, Bacteria, etc., no secondary pollution, long service life, good effect, low cost, convenient to use in various occasions, especially remote high arsenic areas.

Claims (1)

1、一种基于新型膜材料的饮用水除砷装置,其特征在于其包括:1. A device for removing arsenic from drinking water based on a novel membrane material, characterized in that it comprises: 进水管(1);water inlet pipe (1); 压力泵(2),与进水管相连;The pressure pump (2) is connected with the water inlet pipe; 膜组件(5),通过管道与压力泵(2)相连,该膜组件(5)为静电纺丝氯化聚氯乙烯膜材料层;The membrane module (5) is connected to the pressure pump (2) through a pipeline, and the membrane module (5) is an electrospun chlorinated polyvinyl chloride membrane material layer; 流量计(3)及压力表(4),设置于膜组件(5)与压力泵(2)之间的管道上;以及The flow meter (3) and the pressure gauge (4) are arranged on the pipeline between the membrane module (5) and the pressure pump (2); and 浓缩液排出管(6)及透过液排出管(7)连接于膜组件(5)。The concentrate discharge pipe (6) and the permeate discharge pipe (7) are connected to the membrane module (5).
CN 200520118599 2005-09-23 2005-09-23 Arsenic removal device for drinking water based on novel film material Expired - Fee Related CN2913347Y (en)

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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102405096A (en) * 2009-07-06 2012-04-04 积水化学工业株式会社 Polymer Water Treatment Membrane

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102405096A (en) * 2009-07-06 2012-04-04 积水化学工业株式会社 Polymer Water Treatment Membrane

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