CN203800133U - Winding cell and electrochemical device - Google Patents
Winding cell and electrochemical device Download PDFInfo
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- CN203800133U CN203800133U CN201420127600.XU CN201420127600U CN203800133U CN 203800133 U CN203800133 U CN 203800133U CN 201420127600 U CN201420127600 U CN 201420127600U CN 203800133 U CN203800133 U CN 203800133U
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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Abstract
本实用新型提供了一种卷绕式电芯及电化学装置,包括:具有第一集流体的第一极片;电连接于第一集流体的第一极耳;具有第二集流体的第二极片;电连接于第二集流体的第二极耳;隔离膜。第一极耳设置于第一集流体的位置和第二极耳设置于第二集流体的位置处于卷绕式电芯的卷绕起始处或卷绕式电芯的卷绕收尾处。第一极耳具有与第一集流体接触的第一接触部及露出第一集流体的第一导出部,第二极耳具有与第二集流体接触的第二接触部及露出第二集流体的第二导出部,第一接触部和第二接触部相互错位,以保证卷绕形成电芯后在电芯宽度方向上相互不重叠。
The utility model provides a winding type electric core and an electrochemical device, comprising: a first pole piece with a first current collector; a first tab electrically connected to the first current collector; a second pole piece with a second current collector The dipole piece; the second tab electrically connected to the second current collector; the isolation film. The position where the first tab is disposed on the first current collector and the position where the second tab is disposed on the second current collector is at the beginning of the winding of the wound cell or at the end of the winding of the wound cell. The first tab has a first contact portion in contact with the first current collector and a first lead-out portion that exposes the first current collector, and the second tab has a second contact portion that contacts the second current collector and exposes the second current collector. The second lead-out part, the first contact part and the second contact part are misaligned with each other, so as to ensure that they do not overlap each other in the width direction of the battery core after being wound up to form the battery core.
Description
技术领域technical field
本实用新型涉及储能器件领域,尤其涉及一种卷绕式电芯及电化学装置。The utility model relates to the field of energy storage devices, in particular to a winding electric core and an electrochemical device.
背景技术Background technique
目前,锂离子电池已经成为消费类便携式电子产品的首选甚至是唯一的电源。伴随着手机、笔记本电脑在内的移动通信设备、多媒体设备的快速发展,人们对应用在这些设备上的锂离子二次电池的性能提出了越来越高的要求,特别是锂离子二次电池的能量密度。At present, lithium-ion batteries have become the first choice or even the only power source for consumer portable electronic products. With the rapid development of mobile communication devices and multimedia devices including mobile phones and notebook computers, people have put forward higher and higher requirements for the performance of lithium-ion secondary batteries used in these devices, especially lithium-ion secondary batteries energy density.
由于各种移动设备功能越来越复杂,使用过程中耗电量也越来越高,同时设备体积越来越小,供锂离子电池利用的空间越来越少。这就要求锂离子电池要具有更高的能量密度,在尽可能小的空间内提供最大的能量。As the functions of various mobile devices become more and more complex, the power consumption during use is also getting higher and higher, and at the same time, the size of the devices is getting smaller and smaller, and the space for lithium-ion batteries is getting less and less. This requires lithium-ion batteries to have higher energy density and provide maximum energy in as small a space as possible.
目前传统方形锂离子电池制造工艺都是将条状极耳焊接在电池极片上伸出电芯外部,作为电流在电池内部和外部传输的通道。受制于空间有限,条状极耳宽度较窄,一般为3mm-10mm(根据电池尺寸决定),其宽度相当于电池宽度的十分之一至十五分之一。导致电池内部焊接有极耳的位置比其他没有焊接极耳的位置厚度偏大,使电池沿宽度方向不能保持平整,而是呈轻微波浪起伏状,造成电池内部受力分布不均匀。在使用过程中极片会随着电池的充放电不断膨胀、收缩,进一步加剧受力的不均匀。在应力的作用下,电池发生更严重地波浪型变形,最终失效无法使用。At present, the traditional square lithium-ion battery manufacturing process is to weld the strip-shaped tabs on the battery pole pieces to protrude from the outside of the battery cell, as a channel for current transmission inside and outside the battery. Due to the limited space, the width of the strip tab is narrow, generally 3mm-10mm (depending on the size of the battery), and its width is equivalent to one-tenth to one-fifteenth of the battery width. As a result, the thickness of the position where the tab is welded inside the battery is thicker than the other positions where the tab is not welded, so that the battery cannot be kept flat along the width direction, but is slightly undulating, resulting in uneven force distribution inside the battery. During use, the pole piece will continue to expand and contract with the charging and discharging of the battery, further aggravating the uneven force. Under the action of stress, the battery undergoes more serious wave-shaped deformation, and eventually fails and cannot be used.
实用新型内容Utility model content
鉴于背景技术中存在的问题,本实用新型的目的在于提供一种卷绕式电芯及电化学装置,其能有效抑制电芯变形并提高电芯的性能。In view of the problems existing in the background technology, the purpose of the utility model is to provide a winding battery cell and an electrochemical device, which can effectively suppress the deformation of the battery cell and improve the performance of the battery cell.
为了实现上述目的,在第一方面,本实用新型提供了一种卷绕式电芯,其包括:第一极片,包括第一集流体以及设置在第一集流体的表面上的含有第一活性材料的第一膜片;第一极耳,设置并电连接于第一极片的第一集流体;第二极片,与第一极片极性相反,包括第二集流体以及设置在第二集流体的表面上的含有第二活性材料的第二膜片;第二极耳,设置并电连接于第二极片的第二集流体;以及隔离膜,设置于第一极片和第二极片之间;其中,第一极片、隔离膜和第二极片依序卷绕形成卷绕式电芯;在卷绕式电芯的卷绕起始处和卷绕收尾处,第一极片的第一集流体未设置有第一膜片,第二极片的第二集流体未设置有第二膜片。其中,第一极耳设置于第一极片的第一集流体的位置和第二极耳设置于第二极片的第二集流体的位置处于卷绕式电芯的卷绕起始处或处于卷绕式电芯的卷绕收尾处。第一极耳具有与第一集流体接触的第一接触部及露出第一集流体的第一导出部,第一接触部的长度为卷绕式电芯的长度的2/3~1,第一接触部的宽度为卷绕式电芯的宽度的1/3~1/2。第二极耳具有与第二集流体接触的第二接触部及露出第二集流体的第二导出部,第二接触部的长度为卷绕式电芯的长度的2/3~1,第二接触部的宽度为卷绕式电芯的宽度的1/3~1/2。其中,第一极耳的第一接触部和第二极耳的第二接触部相互错位,以保证在卷绕形成电芯后第一极耳的第一接触部和第二极耳的第二接触部在电芯宽度方向上相互不重叠。In order to achieve the above object, in the first aspect, the utility model provides a winding battery core, which includes: a first pole piece, including a first current collector and a first The first diaphragm of the active material; the first tab, arranged and electrically connected to the first current collector of the first pole piece; the second pole piece, opposite in polarity to the first pole piece, includes a second current collector and is arranged on the The second diaphragm containing the second active material on the surface of the second current collector; the second tab is arranged and electrically connected to the second current collector of the second pole piece; and the isolation film is arranged on the first pole piece and the second pole piece. Between the second pole pieces; wherein, the first pole piece, the separator and the second pole piece are sequentially wound to form a wound battery; at the beginning and end of the winding of the wound battery, The first current collector of the first pole piece is not provided with a first diaphragm, and the second current collector of the second pole piece is not provided with a second diaphragm. Wherein, the position where the first tab is arranged on the first current collector of the first pole piece and the position where the second tab is arranged on the second current collector of the second pole piece is at the beginning of the winding of the wound electric core or At the winding end of the wound cell. The first tab has a first contact portion in contact with the first current collector and a first lead-out portion exposing the first current collector. The length of the first contact portion is 2/3 to 1 of the length of the wound battery core. The width of a contact portion is 1/3˜1/2 of the width of the winding battery core. The second tab has a second contact portion in contact with the second current collector and a second lead-out portion exposing the second current collector. The length of the second contact portion is 2/3 to 1 of the length of the wound battery core. The width of the two contact parts is 1/3-1/2 of the width of the winding battery core. Wherein, the first contact portion of the first tab and the second contact portion of the second tab are misaligned with each other to ensure that the first contact portion of the first tab and the second contact portion of the second tab are wound to form the battery core. The contact parts do not overlap with each other in the width direction of the cell.
为了实现上述目的,在第二方面,本实用新型提供了一种电化学装置,其包括:根据本实用新型第一方面所述的卷绕式电芯;电解液;以及包装袋,封装卷绕式电芯并容纳电解液以使电解液浸润卷绕式电芯的第一极片和第二极片。In order to achieve the above object, in the second aspect, the utility model provides an electrochemical device, which includes: the winding battery cell according to the first aspect of the utility model; the electrolyte; and a packaging bag for packaging and winding The battery cell contains the electrolyte solution so that the electrolyte solution soaks the first pole piece and the second pole piece of the wound battery cell.
本实用新型的有益效果如下:The beneficial effects of the utility model are as follows:
第一极耳和第二极耳分别与第一集流体和第二集流体的接触面积增大,第一接触部和第二接触部的宽度相加接近或者等于卷绕式电芯的宽度,从而电芯在平面上厚度分布更均匀、电芯受力更均匀,由此抑制电芯局部变形;同时由于极耳与极片集流体的接触面积增大,由此整体上增加了电芯的抗变形能力、有效抑制电芯变形;接触面积增加可优化接触电阻,提高电芯高倍率放电的容量保持率,从而提高电芯的性能。The contact areas of the first tab and the second tab with the first current collector and the second current collector respectively increase, and the sum of the widths of the first contact portion and the second contact portion is close to or equal to the width of the wound cell, Therefore, the thickness distribution of the cell on the plane is more uniform, and the force of the cell is more uniform, thereby suppressing the local deformation of the cell; at the same time, due to the increase in the contact area between the tab and the current collector, the overall increase in the cell Anti-deformation ability, effectively inhibit the deformation of the battery cell; the increase of the contact area can optimize the contact resistance, improve the capacity retention rate of the high-rate discharge of the battery cell, thereby improving the performance of the battery cell.
宽度增加的第一极耳和第二极耳相互不重叠,不增加电芯的额外厚度,从而不影响电芯的能量密度。The first lug and the second lug with increased width do not overlap each other, do not increase the extra thickness of the battery core, and thus do not affect the energy density of the battery core.
附图说明Description of drawings
图1为根据本实用新型的卷绕式电芯的第一极片的一实施例的正视图;Fig. 1 is a front view of an embodiment of a first pole piece of a wound battery according to the present invention;
图2为根据本实用新型的卷绕式电芯的第一极片的另一实施例的正视图;Fig. 2 is a front view of another embodiment of the first pole piece of the wound electric core according to the present invention;
图3为根据本实用新型的卷绕式电芯的一实施例的平面示意图;Fig. 3 is a schematic plan view of an embodiment of a winding battery core according to the present invention;
图4为根据本实用新型的卷绕式电芯的正面剖视图;Fig. 4 is a front cross-sectional view of a winding battery core according to the present invention;
图5为根据本实用新型的卷绕式电芯的一实施例的平面示意图;Fig. 5 is a schematic plan view of an embodiment of a winding battery core according to the present invention;
图6为根据本实用新型的卷绕式电芯的一对比例的平面示意图;Fig. 6 is a schematic plan view of a pair of proportions of the winding battery core according to the present invention;
图7为一现有的卷绕式电芯的平面示意图;FIG. 7 is a schematic plan view of an existing winding battery cell;
图8为一现有的卷绕式电芯的平面示意图;Fig. 8 is a schematic plan view of an existing winding battery cell;
图9为一现有的卷绕式电芯的平面示意图。FIG. 9 is a schematic plan view of a conventional wound battery.
其中,附图标记说明如下:Wherein, the reference signs are explained as follows:
1卷绕式电芯14第二极耳1 winding cell 14 second tab
11第一极片 141第二接触部11 first pole piece 141 second contact part
111第一集流体 142第二导出部111 The first collector 142 The second outlet
112第一膜片 15隔离膜112 First diaphragm 15 Isolation film
12第一极耳 S卷绕起始处12 The first tab S winding starting point
121第一接触部 E卷绕收尾处121 The first contact part E winding end
122第一导出部 L长度方向122 first lead-out part L length direction
13第二极片 W宽度方向13 second pole piece W width direction
131第二集流体 T厚度方向131 second current collector T thickness direction
132第二膜片 2包装袋132 second diaphragm 2 bags
具体实施方式Detailed ways
下面参照附图详细说明根据本实用新型第一方面的卷绕式电芯。The winding battery cell according to the first aspect of the present invention will be described in detail below with reference to the accompanying drawings.
在以下实施例的说明中,L为卷绕式电芯1及其各部件的长度方向,W为卷绕式电芯1及其各部件的宽度方向,T为卷绕式电芯1及其各部件的厚度方向。In the description of the following embodiments, L is the length direction of the wound battery 1 and its components, W is the width direction of the wound battery 1 and its components, and T is the wound battery 1 and its components. The thickness direction of each part.
参照图1至图5,根据本实用新型第一方面的的卷绕式电芯1包括:第一极片11,包括第一集流体111以及设置在第一集流体111的表面上的含有第一活性材料的第一膜片112;第一极耳12,设置并电连接于第一极片11的第一集流体111;第二极片13,与第一极片11极性相反,包括第二集流体131以及设置在第二集流体131的表面上的含有第二活性材料的第二膜片132;第二极耳14,设置并电连接于第二极片13的第二集流体131;以及隔离膜15,设置于第一极片11和第二极片13之间;其中,第一极片11、隔离膜15和第二极片13依序卷绕形成卷绕式电芯1;在卷绕式电芯1的卷绕起始处S和卷绕收尾处E,第一极片11的第一集流体111未设置有第一膜片112,第二极片13的第二集流体131未设置有第二膜片132。Referring to FIGS. 1 to 5 , according to the first aspect of the present utility model, the winding cell 1 includes: the first pole piece 11 , including the first current collector 111 and the surface of the first current collector 111 containing the first A first diaphragm 112 of active material; the first tab 12 is arranged and electrically connected to the first current collector 111 of the first pole piece 11; the second pole piece 13 is opposite in polarity to the first pole piece 11, including The second current collector 131 and the second diaphragm 132 containing the second active material disposed on the surface of the second current collector 131; the second tab 14 is disposed and electrically connected to the second current collector of the second pole piece 13 131; and the separator 15, which is arranged between the first pole piece 11 and the second pole piece 13; wherein, the first pole piece 11, the separator 15 and the second pole piece 13 are sequentially wound to form a wound electric core 1; At the winding start S and the winding end E of the winding cell 1, the first current collector 111 of the first pole piece 11 is not provided with the first diaphragm 112, and the first diaphragm 112 of the second pole piece 13 is not provided. The second collector 131 is not provided with the second diaphragm 132 .
其中,第一极耳12设置于第一极片11的第一集流体111的位置和第二极耳14设置于第二极片13的第二集流体131的位置处于卷绕式电芯1的卷绕起始处S或处于卷绕式电芯1的卷绕收尾处E。Wherein, the first tab 12 is arranged at the position of the first current collector 111 of the first pole piece 11 and the second tab 14 is arranged at the position of the second current collector 131 of the second pole piece 13 in the winding cell 1 The starting point S of the winding or the ending point E of the winding cell 1 .
第一极耳12具有与第一集流体111接触的第一接触部121及露出第一集流体111的第一导出部122,第一接触部121的长度为卷绕式电芯1的长度的2/3~1,第一接触部121的宽度为卷绕式电芯1的宽度的1/3~1/2。The first tab 12 has a first contact portion 121 in contact with the first current collector 111 and a first lead-out portion 122 exposing the first current collector 111, and the length of the first contact portion 121 is 1/2 of the length of the wound electric core 1. 2/3˜1, the width of the first contact portion 121 is 1/3˜1/2 of the width of the wound battery 1 .
第二极耳14具有与第二集流体131接触的第二接触部141及露出第二集流体131的第二导出部142,第二接触部141的长度为卷绕式电芯1的长度的2/3~1,第二接触部141的宽度为卷绕式电芯1的宽度的1/3~1/2。The second tab 14 has a second contact portion 141 in contact with the second current collector 131 and a second lead-out portion 142 exposing the second current collector 131, and the length of the second contact portion 141 is 1/2 of the length of the wound electric core 1. 2/3˜1, the width of the second contact portion 141 is 1/3˜1/2 of the width of the wound battery 1 .
其中,第一极耳12的第一接触部121和第二极耳14的第二接触部141相互错位,以保证在卷绕形成电芯后第一极耳12的第一接触部121和第二极耳14的第二接触部141在电芯宽度方向上相互不重叠(参照图4)。Wherein, the first contact portion 121 of the first tab 12 and the second contact portion 141 of the second tab 14 are misaligned with each other, so as to ensure that the first contact portion 121 of the first tab 12 and the second contact portion 141 of the first tab 12 are formed after winding to form an electric core. The second contact portions 141 of the dipole tabs 14 do not overlap with each other in the cell width direction (see FIG. 4 ).
参照图8,传统的卷绕式电芯1使用条状(即矩形)的极耳,极耳的导出部和接触部的宽度和厚度一样,其宽度一般为2~7mm,厚度一般为:0.03~0.15mm。组装成卷绕式电芯1后,卷绕式电芯1有极耳的位置明显的比没有极耳的位置厚,受力不均匀。在充放电过程中由于极片的膨胀会加剧这种不均匀,最终导致卷绕式电芯1变形,变形呈波浪形或者“S”形。Referring to Figure 8, the traditional winding cell 1 uses strip-shaped (i.e. rectangular) tabs. The lead-out part of the tab and the contact part have the same width and thickness. The width is generally 2-7mm, and the thickness is generally: 0.03 ~0.15mm. After being assembled into the wound cell 1, the position of the wound cell 1 with tabs is obviously thicker than the position without tabs, and the force is not uniform. The unevenness will be exacerbated by the expansion of the pole piece during the charging and discharging process, which will eventually lead to the deformation of the wound battery 1 in a wavy or "S" shape.
在根据本实用新型的卷绕式电芯1中,第一极耳12具有与第一集流体111接触的第一接触部121及露出第一集流体111的第一导出部122,第二极耳14具有与第二集流体131接触的第二接触部141及露出第二集流体131的第二导出部142,第一接触部121和第二接触部141的长度分别为卷绕式电芯1的长度的2/3~1,第一接触部121和第二接触部141的宽度分别为卷绕式电芯1的宽度的1/3~1/2。第一极耳12和第二极耳14分别与第一集流体111和第二集流体131的接触面积增大,第一接触部121和第二接触部141的宽度相加接近或者等于卷绕式电芯1的宽度,从而电芯在平面上厚度分布更均匀、电芯受力更均匀,由此减少电芯局部变形;同时由于极耳与极片集流体的接触面积增大,由此整体上增加了电芯的抗变形能力、有效抑制电芯变形;接触面积增加可优化接触电阻,提高电芯高倍率放电的容量保持率,从而提高电芯的性能。In the wound battery core 1 according to the present invention, the first tab 12 has a first contact portion 121 in contact with the first current collector 111 and a first lead-out portion 122 exposing the first current collector 111 , the second pole The ear 14 has a second contact portion 141 in contact with the second current collector 131 and a second lead-out portion 142 exposing the second current collector 131. The lengths of the first contact portion 121 and the second contact portion 141 are respectively 100% of the length of the wound battery cell. 2/3˜1 of the length of 1, and the widths of the first contact portion 121 and the second contact portion 141 are respectively 1/3˜1/2 of the width of the wound battery 1 . The contact areas of the first tab 12 and the second tab 14 with the first current collector 111 and the second current collector 131 respectively increase, and the sum of the widths of the first contact portion 121 and the second contact portion 141 is close to or equal to the winding width. The width of the type battery 1, so that the thickness distribution of the battery on the plane is more uniform, and the force of the battery is more uniform, thereby reducing the local deformation of the battery; at the same time, due to the increased contact area between the tab and the current collector, the On the whole, the anti-deformation ability of the battery is increased, and the deformation of the battery is effectively suppressed; the increase in the contact area can optimize the contact resistance, improve the capacity retention rate of the high-rate discharge of the battery, and thereby improve the performance of the battery.
宽度增加的第一极耳12和第二极耳14相互不重叠,不增加电芯的额外厚度,从而不影响电芯的能量密度。The first lug 12 and the second lug 14 with increased width do not overlap each other, do not increase the extra thickness of the battery core, and thus do not affect the energy density of the battery core.
在根据本实用新型的卷绕式电芯的一实施例中,第一极片11可为负极极片或正极极片,第二极片13相应地可为正极极片或负极极片。In an embodiment of the wound battery cell according to the present invention, the first pole piece 11 can be a negative pole piece or a positive pole piece, and the second pole piece 13 can be a positive pole piece or a negative pole piece accordingly.
在根据本实用新型的卷绕式电芯的一实施例中,第一极耳12可焊接于第一极片11的第一集流体111;第二极耳14可焊接于第二极片13的第二集流体131。In an embodiment of the wound electric core according to the present invention, the first tab 12 can be welded to the first current collector 111 of the first pole piece 11; the second tab 14 can be welded to the second pole piece 13 The second current collector 131.
在根据本实用新型的卷绕式电芯的一实施例中,第一极耳12和第二极耳14的材质可为纯铝带、纯铜带、纯镍带、或为经过表面处理的铝带、铜带、镍带、或为铜合金、镍合金、镀铜、镀镍的金属带。In an embodiment of the wound battery core according to the present invention, the material of the first tab 12 and the second tab 14 can be pure aluminum strip, pure copper strip, pure nickel strip, or surface-treated Aluminum strip, copper strip, nickel strip, or copper alloy, nickel alloy, copper-plated, nickel-plated metal strip.
在根据本实用新型的卷绕式电芯的一实施例中,第一极耳12的第一导出部122和第二极耳14的第二导出部142的宽度可为3mm-10mm,长度可为10mm-18mm。In an embodiment of the wound battery core according to the present invention, the width of the first lead-out portion 122 of the first tab 12 and the second lead-out portion 142 of the second tab 14 may be 3mm-10mm, and the length may be 10mm-18mm.
在根据本实用新型的卷绕式电芯的一实施例中,第一极耳12和第二极耳14的厚度可为0.05mm-0.15mm。In an embodiment of the wound battery cell according to the present invention, the thickness of the first tab 12 and the second tab 14 may be 0.05mm-0.15mm.
在根据本实用新型的卷绕式电芯的一实施例中,第一极耳12的第一接触部121和第一导出部122可构成T形(参照图2)或L形(参照图1);第二极耳14的第二接触部141和第二导出部142可构成T形(参照图4)或L形。但实际中,不限于这两种情况。In an embodiment of the winding battery core according to the present invention, the first contact portion 121 and the first lead-out portion 122 of the first tab 12 can form a T shape (refer to FIG. 2 ) or an L shape (refer to FIG. 1 ); the second contact portion 141 and the second lead-out portion 142 of the second tab 14 may form a T shape (refer to FIG. 4 ) or an L shape. But in practice, it is not limited to these two cases.
在根据本实用新型的卷绕式电芯的一实施例中,第一极耳12的第一接触部121的宽度与第二极耳14的第二接触部141的宽度可相同或不同;第一极耳12的第一接触部121的长度与第二极耳14的第二接触部141的长度可相同或不同。In an embodiment of the wound electric core according to the present invention, the width of the first contact portion 121 of the first tab 12 and the width of the second contact portion 141 of the second tab 14 may be the same or different; The length of the first contact portion 121 of a tab 12 and the length of the second contact portion 141 of the second tab 14 may be the same or different.
接下来说明根据本实用新型第二方面的电化学装置。Next, the electrochemical device according to the second aspect of the present invention will be described.
参照图4,根据本实用新型第二方面的电化学装置包括:根据本实用新型第一方面的卷绕式电芯1;电解液(未示出);以及包装袋2,封装卷绕式电芯1并容纳电解液以使电解液浸润卷绕式电芯1的第一极片11和第二极片13。Referring to Fig. 4, the electrochemical device according to the second aspect of the utility model includes: the wound battery cell 1 according to the first aspect of the utility model; the electrolyte solution (not shown); and the packaging bag 2 for packaging the wound battery cell The core 1 also contains the electrolyte so that the electrolyte wets the first pole piece 11 and the second pole piece 13 of the wound battery cell 1 .
根据本实用新型的电化学装置的一实施例中,所述电化学装置可为电池或电容器。在一实施例中,所述电池可为锂离子电池。In an embodiment of the electrochemical device according to the present invention, the electrochemical device can be a battery or a capacitor. In one embodiment, the battery may be a lithium-ion battery.
最后给出根据本实用新型的电化学装置的实施例、对比例及测试结果,其中,电化学装置以锂离子电池为例,第一极片以负极极片而第二极片以正极极片为例。Finally provide the embodiment, comparative example and test results according to the electrochemical device of the present utility model, wherein, the electrochemical device is an example with lithium ion battery, the first pole piece is negative pole piece and the second pole piece is positive pole piece as an example.
实施例1(参照图3和图4)Example 1 (refer to Figure 3 and Figure 4)
A第一极片11(即负极极片)的制备A preparation of the first pole piece 11 (i.e. negative pole piece)
将石墨(即第一活性材料)、导电碳、粘结剂丁苯橡胶、增稠剂羧甲基纤维素钠(CMC)以质量比95.7:1:3.1:0.2加入去离子水中混合搅拌均匀制成负极活性材料浆料,将负极活性材料浆料涂覆在8μm厚的负极集流体铜箔(即第一集流体111)的正反两个表面上,之后进行辊压、烘干(形成第一膜片112)、裁剪,成为负极极片。Graphite (that is, the first active material), conductive carbon, binder styrene-butadiene rubber, and thickener sodium carboxymethylcellulose (CMC) were added to deionized water at a mass ratio of 95.7:1:3.1:0.2, mixed and stirred evenly to prepare To form a negative electrode active material slurry, the negative electrode active material slurry is coated on the front and back surfaces of an 8 μm thick negative electrode current collector copper foil (that is, the first current collector 111), and then rolled and dried (forming the first current collector 111 ). A diaphragm 112), cut to become the negative pole piece.
B第二极极片13(即正极极片)的制备Preparation of B second pole piece 13 (i.e. positive pole piece)
按照常规锂离子电池的制作方法和工序,将钴酸锂(LiCoO2)(即第二活性材料)、导电碳、粘结剂聚偏氟乙烯(PVDF)以质量比96:2:2加入N-甲基吡咯烷酮(NMP)中混合搅拌均匀制成正极活性材料浆料涂覆在12μm厚的正极集流体铝箔(即第二集流体131)的正反两个表面上,之后进行辊压、烘干(形成第二膜片132)、裁剪,成为正极极片。According to the production method and process of conventional lithium-ion batteries, lithium cobalt oxide (LiCoO 2 ) (ie, the second active material), conductive carbon, and binder polyvinylidene fluoride (PVDF) were added to N at a mass ratio of 96:2:2. -Mixed and stirred in methylpyrrolidone (NMP) to make positive active material slurry and coated on the positive and negative surfaces of the 12 μm thick positive current collector aluminum foil (that is, the second current collector 131 ), and then rolled and baked dry (forming the second diaphragm 132 ), cut, and become the positive electrode sheet.
C隔离膜15的准备C Isolation Film 15 Preparation
采用16μm的聚丙烯(PP)隔离膜。A 16μm polypropylene (PP) isolation film is used.
D卷绕式电芯1的制备Preparation of D winding cell 1
采用卷绕式工艺制备,其中第一极耳12为铜、第二极耳14为铝,第一极耳12与第一集流体111焊接,第二极耳14与第二集流体131焊接,将第一极片11、第二极极片13和隔离膜15卷绕成裸电芯,第一极耳12的第一接触部121和第二极耳14的第二接触部141的宽度为25mm、长度为45mm,第一导出部122和第二导出部142的宽度为6mm、长度为15mm、厚度均为0.08mm,两部分构成倒T形。卷绕式电芯1的宽度约为53.5mm、长度为46.5mm。第一接触部121和第二接触部141的宽度分别为卷绕式电芯1的宽度的1/2且互相不重叠。第一极耳12和第二极耳14都处于卷绕式电芯1的卷绕收尾处E。在卷绕式电芯1的卷绕收尾处E,第一极片11的第一集流体111未设置有第一膜片112,第二极片13的第二集流体131未设置有第二膜片132。Manufactured by a winding process, wherein the first tab 12 is copper, the second tab 14 is aluminum, the first tab 12 is welded to the first current collector 111, the second tab 14 is welded to the second current collector 131, The first pole piece 11, the second pole piece 13 and the separator 15 are wound into a bare cell, and the width of the first contact portion 121 of the first tab 12 and the second contact portion 141 of the second tab 14 is 25mm and 45mm in length, the width of the first lead-out part 122 and the second lead-out part 142 are 6mm, the length is 15mm, and the thickness is 0.08mm. The two parts form an inverted T shape. The wound battery core 1 has a width of about 53.5mm and a length of 46.5mm. The widths of the first contact portion 121 and the second contact portion 141 are respectively 1/2 of the width of the wound battery 1 and do not overlap each other. Both the first tab 12 and the second tab 14 are located at the winding end E of the wound cell 1 . At the winding end E of the wound battery 1, the first current collector 111 of the first pole piece 11 is not provided with the first diaphragm 112, and the second current collector 131 of the second pole piece 13 is not provided with the second Diaphragm 132 .
E锂离子电池的制备Preparation of Lithium-ion batteries
将卷绕式工艺制成的裸电芯装入铝塑膜制成的包装袋2中,向包装袋2内注入电解液,以六氟磷酸锂(LiPF6)为锂盐,乙烯碳酸酯(EC)和丙烯碳酸酯(PC)、二甲基碳酸酯(DMC),甲基乙酸酯(MA)的质量比为1:1:2:1,形成电解液,再经化成、陈化、排气、整形等工艺制备成宽度为55mm、长度为52mm、厚度为5.2mm的锂离子电池,容量为4.0Ah,电压范围为3.0~4.35V。Put the bare battery cell made by the winding process into the packaging bag 2 made of aluminum-plastic film, inject electrolyte into the packaging bag 2, use lithium hexafluorophosphate (LiPF 6 ) as lithium salt, ethylene carbonate (EC) and The mass ratio of propylene carbonate (PC), dimethyl carbonate (DMC), and methyl acetate (MA) is 1:1:2:1 to form an electrolyte solution, which is then formed, aged, exhausted, A lithium-ion battery with a width of 55mm, a length of 52mm, and a thickness of 5.2mm was prepared by shaping and other processes, with a capacity of 4.0Ah and a voltage range of 3.0-4.35V.
实施例2(参照图5)Example 2 (see Figure 5)
除以下不同外,其余同实施例1。Except following difference, all the other are with embodiment 1.
与实施例1不同之处在于,在步骤D(即卷绕式电芯1的制备)中,在实施例2中,第一极耳12为镍、第二极耳14为铝,第一极耳12与第一集流体111焊接,第二极耳14与第二集流体131焊接,将第一极片11、第二极极片13和隔离膜15卷绕成裸电芯,第一极耳12的第一接触部121和第二极耳14的第二接触部141的宽度分别为25mm和20mm、长度都为45mm,第一导出部122和第二导出部142的宽度为5mm、长度为18mm、厚度均为0.1mm,两部分构成倒T形。第一接触部121和第二接触部141的宽度分别为卷绕式电芯1的宽度的1/3且互相不重叠。第一极耳12和第二极耳14都处于卷绕式电芯1的卷绕起始处S。在卷绕式电芯1的卷绕起始处S,第一极片11的第一集流体111未设置有第一膜片112,第二极片13的第二集流体131未设置有第二膜片132。The difference from Example 1 is that in Step D (preparation of wound battery 1), in Example 2, the first tab 12 is made of nickel, the second tab 14 is made of aluminum, and the first tab 14 is made of aluminum. The ear 12 is welded to the first current collector 111, the second pole ear 14 is welded to the second current collector 131, and the first pole piece 11, the second pole pole piece 13 and the separator 15 are wound into a bare cell. The widths of the first contact portion 121 of the ear 12 and the second contact portion 141 of the second tab 14 are 25 mm and 20 mm respectively, and the length is 45 mm. The width of the first lead-out portion 122 and the second lead-out portion 142 are 5 mm and the length The thickness is 18mm and the thickness is 0.1mm, and the two parts form an inverted T shape. The widths of the first contact portion 121 and the second contact portion 141 are respectively 1/3 of the width of the wound battery 1 and do not overlap each other. Both the first tab 12 and the second tab 14 are located at the winding starting point S of the wound cell 1 . At the winding start point S of the wound battery 1, the first current collector 111 of the first pole piece 11 is not provided with the first diaphragm 112, and the second current collector 131 of the second pole piece 13 is not provided with the first diaphragm 112. Two diaphragms 132.
实施例3(参照图3)Example 3 (refer to Figure 3)
除以下不同外,其余同实施例1。Except following difference, all the other are with embodiment 1.
与实施例1不同之处在于,在步骤D(即卷绕式电芯1的制备)中,第一极耳12为镍、第二极耳14为铝,第一极耳12与第一集流体111焊接,第二极耳14与第二集流体131焊接,将第一极片11、第二极极片13和隔离膜15卷绕成裸电芯,第一极耳12的第一接触部121和第二极耳14的第二接触部141的宽度分别为46mm和46mm、长度都为70mm,第一导出部122和第二导出部142的宽度为7mm、长度为18mm、厚度均为0.1mm,两部分构成倒T形。卷绕式电芯1的宽度为93mm、长度为86mm。第一接触部121和第二接触部141的宽度分别为卷绕式电芯1的宽度的2/5且互相不重叠。第一极耳12和第二极耳14都处于卷绕式电芯1的卷绕收尾处E。在步骤E(即锂离子电池的制备)中,制备成宽度为96mm、长度为90mm、厚度为3.6mm的锂离子电池。The difference from Example 1 is that in step D (that is, the preparation of wound battery 1), the first tab 12 is made of nickel, the second tab 14 is made of aluminum, and the first tab 12 and the first set The fluid 111 is welded, the second tab 14 is welded to the second current collector 131, the first pole piece 11, the second pole piece 13 and the separator 15 are wound into a bare cell, and the first contact of the first tab 12 The width of the second contact part 141 of the part 121 and the second tab 14 is 46mm and 46mm respectively, and the length is 70mm. The width of the first lead-out part 122 and the second lead-out part 142 is 7mm, the length is 18mm, and the thickness is 0.1mm, the two parts form an inverted T shape. The wound battery core 1 has a width of 93mm and a length of 86mm. The widths of the first contact portion 121 and the second contact portion 141 are respectively 2/5 of the width of the wound battery 1 and do not overlap each other. Both the first tab 12 and the second tab 14 are located at the winding end E of the wound cell 1 . In step E (ie, the preparation of the lithium-ion battery), a lithium-ion battery with a width of 96 mm, a length of 90 mm, and a thickness of 3.6 mm was prepared.
实施例4(参照图5)Example 4 (refer to Figure 5)
除以下不同外,其余同实施例1。Except following difference, all the other are with embodiment 1.
与实施例1不同之处在于,在步骤D(即卷绕式电芯1的制备)中,在实施例2中,第一极耳12为镍、第二极耳14为铝,第一极耳12与第一集流体111焊接,第二极耳14与第二集流体131焊接,将第一极片11、第二极极片13和隔离膜15卷绕成裸电芯,第一极耳12的第一接触部121和第二极耳14的第二接触部141的宽度分别为46mm和35mm、长度都为85mm,第一导出部122和第二导出部142的宽度为7mm、长度为18mm、厚度均为0.1mm,两部分构成倒T形。卷绕式电芯1的宽度为93mm、长度为86mm。第一接触部121和第二接触部141的宽度分别为卷绕式电芯1的宽度的1/2且互相不重叠。第一极耳12和第二极耳14都处于卷绕式电芯1的卷绕起始处S。在卷绕式电芯1的卷绕起始处S,第一极片11的第一集流体111未设置有第一膜片112,第二极片13的第二集流体131未设置有第二膜片132。The difference from Example 1 is that in Step D (preparation of wound battery 1), in Example 2, the first tab 12 is made of nickel, the second tab 14 is made of aluminum, and the first tab 14 is made of aluminum. The ear 12 is welded to the first current collector 111, the second pole ear 14 is welded to the second current collector 131, and the first pole piece 11, the second pole pole piece 13 and the separator 15 are wound into a bare cell. The width of the first contact portion 121 of the ear 12 and the second contact portion 141 of the second tab 14 are 46mm and 35mm respectively, and the length is 85mm. The thickness is 18mm and the thickness is 0.1mm, and the two parts form an inverted T shape. The wound battery core 1 has a width of 93mm and a length of 86mm. The widths of the first contact portion 121 and the second contact portion 141 are respectively 1/2 of the width of the wound battery 1 and do not overlap each other. Both the first tab 12 and the second tab 14 are located at the winding starting point S of the wound cell 1 . At the winding start point S of the wound battery 1, the first current collector 111 of the first pole piece 11 is not provided with the first diaphragm 112, and the second current collector 131 of the second pole piece 13 is not provided with the first diaphragm 112. Two diaphragms 132.
在步骤E(即锂离子电池的制备)中,制备成宽度为96mm、长度为90mm、厚度为3.6mm的锂离子电池。In step E (ie, the preparation of the lithium-ion battery), a lithium-ion battery with a width of 96 mm, a length of 90 mm, and a thickness of 3.6 mm was prepared.
对比例1(参照图8)Comparative example 1 (refer to Figure 8)
除以下不同外,其余同实施例1。Except following difference, all the other are with embodiment 1.
与实施例1不同之处在于,在步骤D(即电芯1的制备)中,第一极耳12为镍、第二极耳14为铝,第一极耳12与第一集流体111焊接,第二极耳14与第二集流体131焊接,将第一极片11、第二极极片13和隔离膜15卷绕成裸电芯,第一极耳12和第二极耳14的宽度都为6mm、长度都为60mm、厚度都为0.1mm,两个极耳的导出部和接触部的宽度和厚度一样(即两个极耳为矩形)。第一极耳12和第二极耳14都处于卷绕式电芯1的卷绕起始处S。在卷绕式电芯1的卷绕起始处S,第一极片11的第一集流体111未设置有第一膜片112,第二极片13的第二集流体131未设置有第二膜片132。The difference from Example 1 is that in step D (that is, the preparation of the battery cell 1), the first tab 12 is made of nickel, the second tab 14 is made of aluminum, and the first tab 12 is welded to the first current collector 111 , the second tab 14 is welded to the second current collector 131, the first pole piece 11, the second pole piece 13 and the separator 15 are wound into a bare cell, the first pole piece 12 and the second pole piece 14 The width is 6mm, the length is 60mm, and the thickness is 0.1mm. The width and thickness of the lead-out part and the contact part of the two tabs are the same (that is, the two tabs are rectangular). Both the first tab 12 and the second tab 14 are located at the winding starting point S of the wound cell 1 . At the winding start point S of the wound battery 1, the first current collector 111 of the first pole piece 11 is not provided with the first diaphragm 112, and the second current collector 131 of the second pole piece 13 is not provided with the first diaphragm 112. Two diaphragms 132.
对比例2(参照图9)Comparative example 2 (refer to Figure 9)
除以下不同外,其余同实施例1。Except following difference, all the other are with embodiment 1.
与实施例1不同之处在于,在步骤D(即电芯1的制备)中,第一极耳12为镍合金、第二极耳14为铝,第一极耳12与第一集流体111焊接,第二极耳14与第二集流体131焊接,将第一极片11、第二极极片13和隔离膜15卷绕成裸电芯,第一极耳12和第二极耳14的宽度都为6mm、长度都为60mm、厚度都为0.05mm,且两个极耳的导出部和接触部的宽度和厚度一样(即两个极耳为矩形)。第一极耳12处于卷绕式电芯1的卷绕起始处S,第二极耳14处于卷绕式电芯1的卷绕收尾处E。在卷绕式电芯1的卷绕起始处S和卷绕收尾处E,第一极片11的第一集流体111未设置有第一膜片112,第二极片13的第二集流体131未设置有第二膜片132。The difference from Example 1 is that in step D (that is, the preparation of the battery cell 1), the first tab 12 is nickel alloy, the second tab 14 is aluminum, and the first tab 12 and the first current collector 111 Welding, the second tab 14 is welded with the second current collector 131, the first pole piece 11, the second pole piece 13 and the separator 15 are wound into a bare cell, the first tab 12 and the second tab 14 The width is 6mm, the length is 60mm, and the thickness is 0.05mm, and the width and thickness of the lead-out part and the contact part of the two tabs are the same (that is, the two tabs are rectangular). The first tab 12 is located at the winding start point S of the wound cell 1 , and the second tab 14 is located at the winding end point E of the wound cell 1 . At the winding start S and the winding end E of the wound battery 1, the first collector 111 of the first pole piece 11 is not provided with the first diaphragm 112, and the second collector of the second pole piece 13 The fluid 131 is not provided with a second membrane 132 .
对比例3(参照图7)Comparative example 3 (refer to Figure 7)
除以下不同外,其余同实施例1。Except following difference, all the other are with embodiment 1.
与实施例1不同之处在于,在步骤D(即电芯1的制备)中,第一极耳12为镍合金、第二极耳14为铝,第一极耳12与第一集流体111焊接,第二极耳14与第二集流体131焊接,将第一极片11、第二极极片13和隔离膜15卷绕成裸电芯,第一极耳12和第二极耳14的宽度都为3mm、长度都为60mm、厚度都为0.12mm,两个极耳的导出部和接触部的宽度和厚度一样(即两个极耳为矩形)。第一极耳12和第二极耳14都处于卷绕式电芯1的卷绕收尾处E。The difference from Example 1 is that in step D (that is, the preparation of the battery cell 1), the first tab 12 is nickel alloy, the second tab 14 is aluminum, and the first tab 12 and the first current collector 111 Welding, the second tab 14 is welded with the second current collector 131, the first pole piece 11, the second pole piece 13 and the separator 15 are wound into a bare cell, the first tab 12 and the second tab 14 The width is 3mm, the length is 60mm, and the thickness is 0.12mm. The width and thickness of the lead-out part and the contact part of the two tabs are the same (that is, the two tabs are rectangular). Both the first tab 12 and the second tab 14 are located at the winding end E of the wound cell 1 .
对比例4(参照图6)Comparative example 4 (refer to Figure 6)
与实施例1不同之处在于,在步骤D(即电芯1的制备)中,第一极耳12为镍合金、第二极耳14为铝,第一极耳12与第一集流体111焊接,第二极耳14与第二集流体131焊接,将第一极片11、第二极极片13和隔离膜15卷绕成裸电芯,第一极耳12的第一导出部122的宽度为6mm、长度为10mm;第一极耳12的第一接触部121的宽度为25mm、长度为45mm、厚度为0.05mm。第二极耳14宽度都为6mm、长度都为60mm;厚度都为0.05mm。第一极耳12处于卷绕式电芯1的卷绕起始处S,第二极耳14处于卷绕式电芯1的卷绕收尾处E。在卷绕式电芯1的卷绕起始处S和卷绕收尾处E,第一极片11的第一集流体111未设置有第一膜片112,第二极片13的第二集流体131未设置有第二膜片132。The difference from Example 1 is that in step D (that is, the preparation of the battery cell 1), the first tab 12 is nickel alloy, the second tab 14 is aluminum, and the first tab 12 and the first current collector 111 Welding, the second tab 14 is welded to the second current collector 131, the first pole piece 11, the second pole piece 13 and the separator 15 are wound into a bare cell, the first lead-out part 122 of the first tab 12 The width of the first tab 12 is 6 mm, and the length is 10 mm; the width of the first contact portion 121 of the first tab 12 is 25 mm, the length is 45 mm, and the thickness is 0.05 mm. The width of the second tabs 14 is 6mm, the length is 60mm, and the thickness is 0.05mm. The first tab 12 is located at the winding start point S of the wound cell 1 , and the second tab 14 is located at the winding end point E of the wound cell 1 . At the winding start S and the winding end E of the wound battery 1, the first collector 111 of the first pole piece 11 is not provided with the first diaphragm 112, and the second collector of the second pole piece 13 The fluid 131 is not provided with a second membrane 132 .
取上述各实施例、对比例中的锂离子电池以1C/1C进行充放电测试,每100次充放电后检查锂离子电池变形情况,其结果记录于下表1中;另取上述各实施例、对比例中的锂离子电池满充后进行60℃存储测试,15天后检查锂离子电池变形情况,其结果记录于下表1中。另以10C的倍率进行放电,以测试电池的放电容量保持率。Get the above-mentioned each embodiment, the lithium-ion battery in the comparative example carries out charging and discharging test with 1C/1C, check the lithium-ion battery deformation situation after every 100 times of charging and discharging, and its result is recorded in the following table 1; Take the above-mentioned each embodiment separately 1. After the lithium-ion battery in the comparative example was fully charged, it was stored at 60° C., and the deformation of the lithium-ion battery was checked after 15 days. The results were recorded in Table 1 below. In addition, it was discharged at a rate of 10C to test the discharge capacity retention rate of the battery.
表1实施例1-4与对比例1-4的测试结果The test result of table 1 embodiment 1-4 and comparative example 1-4
从表1可以看出,与现有技术相比,本实用新型的锂离子电池在正常的条件下使用时不会发生扭曲变形,很大程度上降低了锂离子电池使用过程中的变形风险,同时电池的内阻也有约20%的降低,10C放电容量保持率提高10%以上。在目前商业化的锂离子电池中,电池的宽度和长度增加后更容易发生变形。因此我们把此技术应用于宽度和长度比较大的电池上来进一步验证其应用的效果,如实施例3和实施例4,循环后变形的比例远小于改善前的小电池,如对比例1,证明此技术对不同尺寸的电池普遍有效。It can be seen from Table 1 that compared with the prior art, the lithium-ion battery of the present invention will not be distorted and deformed when used under normal conditions, which greatly reduces the risk of deformation during the use of the lithium-ion battery. At the same time, the internal resistance of the battery is also reduced by about 20%, and the 10C discharge capacity retention rate is increased by more than 10%. In currently commercialized lithium-ion batteries, deformation is more likely to occur when the width and length of the battery are increased. Therefore, we apply this technology to batteries with relatively large width and length to further verify the effect of its application, such as Example 3 and Example 4, the proportion of deformation after cycling is much smaller than that of the small battery before improvement, such as Comparative Example 1, proving This technique works universally with batteries of different sizes.
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