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CN201394422Y - Fume purification device - Google Patents

Fume purification device Download PDF

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Publication number
CN201394422Y
CN201394422Y CN2008201554669U CN200820155466U CN201394422Y CN 201394422 Y CN201394422 Y CN 201394422Y CN 2008201554669 U CN2008201554669 U CN 2008201554669U CN 200820155466 U CN200820155466 U CN 200820155466U CN 201394422 Y CN201394422 Y CN 201394422Y
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CN
China
Prior art keywords
tower body
smoke
interface
fume
smoke eliminator
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Expired - Fee Related
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CN2008201554669U
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Chinese (zh)
Inventor
娄爱娟
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Individual
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Individual
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Priority to CN2008201554669U priority Critical patent/CN201394422Y/en
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Expired - Fee Related legal-status Critical Current

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Abstract

The utility model relates to novel fume purification device which comprises a purification tower and an in-line chimney arranged at the top of the purification tower, wherein the purification tower also comprises a cylindrical tower body, a bottom plate connected with the bottom end of the tower body, the tapered tower top connected with the top end of the tower body, a rectangular fume inlet connected with the tower body and a round fume outlet connected with the tower top. The rectangular fume inlet is arranged at the part with a height of one fourth to two thirds of the height of the towerbody. The long side of the rectangle is 0.55 time to 1.0 time of the inner diameter of the tower body in length. The area of the fume outlet is 0.10 time to 0.30 time of the area of the tower body. Inparticular, the in-line chimney is provided with a component used for eliminating fume rain, which can greatly reduce the fume condensate water on the inner wall of the chimney, thereby significantlyreducing the condensate water brought by the fume and eliminating the fume rain or mud rain phenomenon.

Description

A kind of smoke eliminator
Technical field
The utility model relates to a kind of smoke eliminator, and especially the emission abatement integration apparatus belongs to electric power, metallurgy, environmental protection and chemical technology field, especially is fit to the flue gas desulfurization technique field.
Background technology
The boiler of combustion of fossil fuels, the flue gas such as thermal power plant or steam power plant and metallurgical industry discharging contains acidic gaseous materials such as SOx, NOx, HCl and HF, SO especially wherein 3Gas makes flue gas show acid dew piont corrosion.The acid dew point of flue gas is between 100~150 ℃.In order to ensure not occurring acid dew piont corrosion in the fume emission process, the temperature during fume emission is higher 15~25 ℃ than dew point.
A large amount of fume emissions have caused the acid rain pollution.A kind of way that solves the acid rain pollution is exactly the purification of flue gas, and especially adopting alkaline matter is the flue gas desulfurization (FGD, Flue Gas Desulfurization) of raw material.Among the FGD, common alkaline matter is the natural crystal raw material, such as lime stone, i.e. and calcium carbonate, also has giobertite, the mixed ore of a kind of calcium carbonate and magnesium carbonate also has artificial synthetic alkaline matter, comprises weak base ammonia and caustic soda NaOH, for ease of discussing, respectively they are called calcium method, magnesium method, ammonia process and sodium method.The purification efficiency of FGD can reach more than the 95-99%, is extensive adopted method therefore.
Conventional FGD process mostly is the wet type operation, promptly the alkaline matter that is adopted must be mixed into a kind of alkaline aqueous solution with water, make it again to contact closely with flue gas, and guarantee purification efficiency in order to improve contacting efficiency, all adopt the aqueous solution of extremely low concentration, in the calcium method, the per kilogram flue gas needs the aqueous solution of 10-30 kilogram.So under the operating condition, flue gas is through contact arrangement, or after being called purifier and desulphurization plant, temperature obviously can be lower than acid dew point, more seriously, and the former SO that is present in the flue gas 3Can become sulfuric acid mist, make flue gas after being purified demonstrate strong acid corrosion.
Ways of addressing this issue has two kinds, the one, to the original former flue gas of direct discharging (without purification, and temperature is more than acid dew point, such as greater than 120 ℃) chimney (being called former chimney) carry out anti-corrosion treatment, make that again purifying flue gas gets back to former smoke stack emission, but it invests high, and for old equipment, such as old unit, boiler or sintering machine, can exist long-play to interrupt, influence is produced.In order to remedy the defective of this method, people have proposed another kind of method, are exactly that a chimney directly is set on purifier, be called in line chimney, or the top smoke evacuation chimney, make purifier have the incorporate function of emission abatement, this method investment is low, and can not influence production.
But, in the practice, it is found that this emission abatement integration apparatus that has in line chimney moves comparatively difficulty, be difficult to the effect that reaches default, comprise that purifying is that desulfuration efficiency is low, the consumption of raw materials height, but also can bring white plume contamination, even can produce misty rain, thereby seriously restricted the application of this equipment.
Summary of the invention
The utility model technical issues that need to address are to disclose a kind of novel smoke eliminator, disclose a kind of gas cleaning discharging integration apparatus that has in line chimney particularly.
Essence of the present utility model is, make purify flue gas can be without former smoke stack emission, and the upright chimney that directly connects from desulfurization or purifier outlet is called in line chimney or top smoke evacuation chimney directly to discharge, do not need former chimney is carried out anti-corrosion treatment, not breaks in production.
Major technique innovation of the present utility model is, optimized the locate mode of advancing the cigarette interface that flue gas enters described purifier, with the time of guaranteeing that enough flue gases contact with absorption liquid, also can not make equipment complicated, outside said in line chimney stack, be provided with simultaneously the structure of removing misty rain, this structure is a structure with insulation and adiabatic function particularly, can significantly reduce the flue gas condensing water of inner wall of stack, thereby significantly reduce flue gas carrying secretly to condensed water, so just tangible misty rain and mud rain phenomenon can as existing in line chimney, not occur, and then make that the emission abatement integration apparatus can be by normal use.
Particularly, the disclosed smoke eliminator of the utility model comprises a purifying column, is also referred to as desulfurizing tower, and the top of said purifying column is provided with in line chimney, and its novelty also comprises:
Cylindrical-shaped tower;
Be connected the base plate of tower body bottom;
Be connected the cat head on tower body top;
The rectangle that is connected on the tower body advances the cigarette interface, the position the position on distance floor be the tower body total height 1/4th to 2/3rds between, the length ratio on described rectangle minor face that advances the cigarette interface and the long limit of rectangle is between 0.25~0.5 times, and the long edge lengths of rectangle is between 0.55~1.0 times of described tower body internal diameter, have enough times of contact so that guarantee flue gas and absorption liquid, guarantee higher purification efficiency, simultaneously also can not make purifier complicated, promptly existing efficient preferably also has lower investment;
Be connected circle or rectangle smoke interface on the cat head, the position is in the cat head center, or near the center, described smoke interface area (promptly vertical with flue gas circulating direction area of section) is between 0.10~0.30 times of described tower body area (promptly vertical with flue gas circulating direction area of section), can guarantee that like this purifying column has lower resistance;
Being provided with air bubbling element in the described tower body inside of advancing below the cigarette interface, so that implement oxidation, is sulfate with the sulfite oxidation that forms in desulfurization or the purification process;
Be provided with atomization of liquid element in the described tower body inside of advancing above the cigarette interface, this atomization of liquid element has liquid and distributes female pipe and arm, and atomizer, the feasible absorption liquid that contacts with flue gas with sour gas effect in the purification flue gas, or claim that the washing absorption liquid is evenly distributed and fine and closely woven atomizing, improve mass-transfer efficiency;
And above described atomization of liquid element, also be provided with the gas-liquid separation element, be provided with two sections fillers in this gas-liquid separation element, make the fine drop that flue gas is carried secretly, even pulpous state or mud shape drop impinge upon, and coalescence is recovered for big drop on the filler, and on the tower body of the part of gas-liquid separation element, be provided with into water interface, its internal diameter is 0.5~2.5% of a described tower body internal diameter, with water jet wherein be set be connected, so that filler is washed immediately, prevent that mud from sticking to filling surface, stop up exhaust gases passes;
On the described tower body that advances below the cigarette interface, also be provided with air intlet and absorption liquid outlet, and described air intlet is apart from base plate 1.0~5.0m, described absorption liquid outlet is apart from base plate 0.5~2.5m, described absorption liquid outlet is below described air intlet, both in the vertical directions are at a distance of 1.0~4.0m, and the inner diameter of this absorption liquid outlet the tower body inner diameter a thirtieth to 1/10th between, can prevent that like this air that blasts from entering the absorption liquid conveyer that is provided with outside the tower body from the absorption liquid outlet, causes difficulty of transportation;
Be arranged on the smoke interface, and the in line chimney that directly is connected with the smoke interface, the cross section of in line chimney is circular, perhaps sub-circular, and its height is between 20~100m, to guarantee appropriate fume emission absolute altitude;
Be connected the absorption liquid import on the tower body, it is connected with atomization of liquid element in the tower body, especially distributes female pipe to be connected with liquid, and its diameter is that preferably, the diameter of two interfaces is identical between 0.75~1.25 times of absorption liquid outlet diameter;
Be arranged on outside the tower body, and connect the absorption liquid circulation pipe of absorption liquid export and import, and the absorption liquid conveyer that is connected with the absorption liquid circulation pipe;
And,
Outside the in line chimney stack; preferably be enclosed with smoke elimination rain member from top to bottom; and outside this member, also be enclosed with the protection shell; the thickness of described smoke elimination rain member is between 10~200mm; optimally at 80~150mm; be preferably between 50~120mm; described smoke elimination rain member adopts thermal conductivity factor to make less than the material of 0.5W/C.m; so that effectively reduce the flue gas condensing water yield of inner wall of stack; thereby reduce flue gas and carry and then eliminate misty rain secretly; described protection shell adopts aluminum material to make, and the thickness of this protective layer is guaranteed lighter quality and good barrier propterty at 0.3~1.5mm.
The disclosed smoke eliminator of the utility model is operated in the following manner:
Contain SO 2, SO 3, NO 2HCl/HF, the flue gas of pollutants such as flue dust, enter purifying column (being also referred to as desulfurizing tower) from advancing the cigarette interface, upwards flow, with washing absorption liquid (containing alkaline matter in the absorption liquid) counter current contacting of atomization of liquid element aerosol dispersion, the chemical reaction in mass transfer, heat transfer and the liquid phase of generation solution-air two-phase is deviate from pollutant.SO in the flue gas 2Become sulphite, SO 3Become sulfuric acid mist, also have part to become sulfate, HCl becomes chloride.The eliminating efficiency of these acid contaminants can reach 95%.The eliminating efficiency of the flyash in the flue gas (dirt) is greater than 60%-90%.
The washing absorption liquid is the pulpous state aqueous solution that contains alkaline desulfurizing agent, sulfate and crystalline solid thereof, and generally all is saturated near sulfate, preferably saturated the or oversaturated pulpous state aqueous mixtures by sulfate.
Big for unit or boiler capacity, perhaps SO in the flue gas 2The situation that concentration is high, if adopt extremely low calcium raw material (calcium method) or the magnesium raw material (magnesium method) of solubility, the cleaning solution flow will be very huge, flue gas must be through too much group of absorption liquid disperser, further upwards flow again and contact with the gas-liquid separation element, removing the flue gas droplets entrained, mostly is the muddy drop that contains solid.To removing the water flushing that the liquid member is also regular or the gap employing is cleaner, guarantee that the gas passage of gas-liquid separation element is unobstructed simultaneously.
After leaving the gas-liquid separation element, flue gas continues upwards to flow, and passes the smoke interface that is positioned at the purifying column top, enters the in line chimney that is positioned on the purifying column, directly enters atmosphere.Because outside the in line chimney stack, all being surrounded by smoke elimination rain member from top to bottom especially guaranteed the less condensed water that occurs of inner wall of stack, or condensed water seldom occurred, like this, flue gas is carried condensing drip secretly and misty rain occurred with regard to not returning by chimney.
On the other hand, the washing absorption liquid flows downward, contact with flue gas adverse current, be back in the tower body below the cigarette interface into, air oxidation by the dispersion of air bubbling element blasts makes sulphite become sulfate, becomes calcium sulfate and forms gypsum (calcium sulphate crystal that promptly has two crystallizations water) such as calcium sulfite, or ammonium sulfite is oxidized to ammonium sulfate, and then crystallization is corresponding crystal.Therefore, this section is also referred to as oxidation pond, or oxidizing and crystallizing pond, especially absorption liquid circulating slot.Fresh desulfurizing agent is such as the lime stone powder slurries of granularity more than the 250-325 order, and magnesia/magnesium carbonate slurries, or liquefied ammonia/vaporous ammonia/ammoniacal liquor directly are added in the cigarette interface circulating slot.Absorption liquid is by being arranged on outside the purification tower, the circulation fluid conveyer that is connected with tower body by circulating line is repeated to be transported to and is positioned at the into atomization of liquid element of the tower body of cigarette interface top, so as to make purifying column realize gas cleaning continuously and stable operation.
Simultaneously also must constantly get rid of absorption liquid, enter follow-up sulfate solid and separate and process equipment, to obtain desulfurization product, solid sulfate salt from circulating slot.
By above-mentioned disclosed technical scheme as seen, gas cleaning of the present utility model discharging integration apparatus has comprised four parts: be respectively air bubbling element, absorption liquid atomizing element, gas-liquid separation element from bottom to up and have the in line chimney of smoke elimination rain effect, make purifier efficient height, energy consumption is low, invest lowly, can also overcome simultaneously the shortcoming of existing equipment.
Description of drawings
Fig. 1 is the structural representation of smoke eliminator.
Fig. 2 is the structure elevation of in line chimney.
Fig. 3 is the structure vertical view of in line chimney.
The specific embodiment
Referring to accompanying drawing 1-3, smoke eliminator of the present utility model comprises:
Cylindrical-shaped tower 1;
Be connected the base plate 4 of tower body 1 bottom;
Be connected the cat head 10 on tower body 1 top;
The rectangle that is connected on the tower body 1 advances cigarette interface 2, and the position is 1/2nd of tower body 1 total height, and the long limit of this rectangle interface is 0.86 times of tower body 1 internal diameter;
Be connected the circular smoke interface 9 on the cat head 10, the position is in the cat head center, and the internal diameter of smoke interface is 0.5 times of described tower body internal diameter;
Be provided with air bubbling element 3 in tower body 1 inside of advancing below the cigarette interface 2;
Be provided with atomization of liquid element 12 in tower body 1 inside of advancing above the cigarette interface 2, atomization of liquid element 12 comprises that liquid distributes female pipe, arm and atomizer;
Also be provided with gas-liquid separation element 11 above atomization of liquid element 12, gas-liquid separation element 11 comprises two sections fillers, and has also arranged water inlet interface 15 on the tower body 1 of these gas-liquid separation element 11 correspondences, and its internal diameter is 0.125% of tower body 1 internal diameter;
Be arranged on the smoke interface 9, and the in line chimney 8 that directly is connected with smoke interface 9, the cross section of in line chimney 8 is circular, it highly is 60m;
On the tower body 1 that advances below the cigarette interface 2, be provided with air intlet 14 and absorption liquid outlet 5, and the described base plate 43.0m of air intlet 14 distances, absorption liquid outlet 5 is apart from base plate 41.0m, be that absorption liquid outlet 5 is below air intlet 14, both in the vertical directions are at a distance of 2.0m, in addition, the inner diameter of absorption liquid outlet 5 is 1/12nd of tower body 1 inner diameters;
Be arranged on outside the tower body 1, and connect the absorption liquid circulation pipe 7 of absorption liquid outlet 5 and absorption liquid import 13, and the absorption liquid conveyer 6 that is connected with absorption liquid circulation pipe 7;
Outside the cylindrical shell 801 of in line chimney 8; be enclosed with smoke elimination rain member 802 from top to bottom; and outside this member 802, also be enclosed with protection shell 803; the thickness of described smoke elimination rain member 802 is 120mm; the insulation material that described smoke elimination rain member 802 employing thermal conductivity factors are 0.12W/C.m is made; described protection shell 803 adopts aluminum material to make, and protective layer thickness is 0.6mm.

Claims (10)

1, a kind of smoke eliminator, comprise purifying column, and described purifying column comprises: cylindrical-shaped tower, be connected the base plate of described tower body bottom, be connected the cat head on described tower body top, the rectangle that is connected on the described tower body advances the cigarette interface, is connected circle or rectangle smoke interface on the described cat head, it is characterized in that the described long edge lengths of rectangle of advancing the cigarette interface is between 0.55~1.0 times of described tower body internal diameter.
2, smoke eliminator according to claim 1 is characterized in that, described advance the cigarette interface be positioned at described tower body total height 1/4th to 2/3rds between, and described smoke interface area is between 0.10~0.30 times of described tower body area.
3, smoke eliminator according to claim 1, it is characterized in that, be provided with air bubbling element in the described tower body inside of advancing below the cigarette interface, be provided with atomization of liquid element in the described tower body inside of advancing above the cigarette interface, and above described atomization of liquid element, also be provided with the gas-liquid separation element.
4, smoke eliminator according to claim 1, it is characterized in that, on the described tower body that advances below the cigarette interface, be provided with air intlet and absorption liquid outlet, and the described base plate 1.0~5.0m of described air intlet distance, the described base plate 0.5~2.5m of described absorption liquid outlet distance.
5, smoke eliminator according to claim 4 is characterized in that, described absorption liquid outlet is below described air intlet, and both in the vertical directions are at a distance of 1.0~4.0m.
6, smoke eliminator according to claim 3 is characterized in that, be provided with into water interface on the described tower body of the part of described gas-liquid separation element, and described water inlet interface internal diameter is 0.5~2.5% of a described tower body internal diameter.
According to each described smoke eliminator of claim 1 to 6, it is characterized in that 7, described purification cat head is provided with in line chimney, and described in line chimney is connected with the smoke interface.
8, smoke eliminator according to claim 7 is characterized in that, is wrapped with smoke elimination rain member at described in line chimney stack.
9, smoke eliminator according to claim 8 is characterized in that, described smoke elimination rain member is wrapped in outside the described in line chimney stack from top to bottom.
10, smoke eliminator according to claim 9 is characterized in that, the thickness of described smoke elimination rain member is between 10~200mm, and at described smoke elimination rain member outer wrapping one protective layer, and the thickness of described protective layer is between 0.3~1.5mm.
CN2008201554669U 2008-11-17 2008-11-17 Fume purification device Expired - Fee Related CN201394422Y (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2008201554669U CN201394422Y (en) 2008-11-17 2008-11-17 Fume purification device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2008201554669U CN201394422Y (en) 2008-11-17 2008-11-17 Fume purification device

Publications (1)

Publication Number Publication Date
CN201394422Y true CN201394422Y (en) 2010-02-03

Family

ID=41616911

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2008201554669U Expired - Fee Related CN201394422Y (en) 2008-11-17 2008-11-17 Fume purification device

Country Status (1)

Country Link
CN (1) CN201394422Y (en)

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C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20100203

Termination date: 20161117

CF01 Termination of patent right due to non-payment of annual fee